2. What is Battery
History
Introduction of electricity
Sustainable energy
Types of fuel
Recent advances in batteries
Conclusion
References
3. “Battery is a storage device used for the storage of
chemical energy and for transformation of chemical
energy into electrical energy”
4. In 1800, Volta invented the first true battery,
which came to be known as the voltaic pile.
The voltaic pile consisted of pairs of copper
and zinc discs piled on top of each other,
separated by a layer of cloth or cardboard
soaked in brine
The term ‘Volt’ was named in the honor of
Volta
6. The current era is justified and frequently
referred to the Age of Information
Recent years have seen the added twist that
users in this era expect to information to be
readily available at all times and at all places
Energy production and storage have become
key issues concerning our welfare in daily life
Present challenges for batteries are twofold
7. In the first place, the increasing demand for
powering systems of portable electronic
devices and zero emission vehicles stimulates
research towards high energy and voltage
system
In the second system, low cost batteries are
required in order to advance towards smart
electric grids that integrate discontinuous
energy flow from renewable sources
optimizing the performance of clean energy
sources
8. Sustainable Next-Generation Energy Technologies
Sustainability Profile
lasts a long time
does no harm
leaves no change
Solar electricity: a fully sustainable energy chain
breakthroughs needed
lower cost, higher efficiency photovoltaics
third generation materials and nanostructures
electricity storage
9. Electrify Transportation
Sustainability Profile
lasts a long time
does no harm
leaves no change
+
+
+
+
+
+
+
+
e
-
H2
H2O
O2 tesla motors
renewable
electricity
production
renewable
hydrogen
production
breakthroughs needed
x2-5 higher energy density in batteries
catalysts, membranes and electrodes in fuel
electric motor
replaces
gasoline engine
battery
fuel cell
hydrogen
storage
10. Two ways to supply electricity- from a battery
and ultimately the grid, and from a fuel cell
with local supply of hydrogen
The electric motor is typically > 90% efficient,
compared to 25%-30% for gasoline engines
Sustainabilty profile depends entirely on
production method – the electric car itself is
fully sustainable
11. gas CH4
oil CH2
coal CH0.8
heat useful
work
combustioncommodity materials
disposable fuels
sustainable energy requires controlling complex,
functional, high tech materials and chemistry
traditional energy
sunlight
wind
Water and
geothermal
biomass
electricity
biofuels
useful
work
direct
conversion
sustainable energy
Sustainable Energy is High Tech Materials and Chemistry
high tech materials and chemistry
e.g., photovoltaics, electrodes,
superconductors, catalysts
12. Replace Conventional Oil
cellulosic biofuel: recycles carbon dioxide
solar fuel without biology: thermo- or photo-chemistry
oil sands and shale, coal to liquid: 50% more carbon dioxide
more pollutants
recycles CO2
cellulosic biofuel
solar chemical fuel
lasts a long time
does no harm
leaves no change
oil sands and shale
coal to liquid
lasts a long time
does no harm
leaves no change
switchgrass ethanol plant
breakthroughs needed
cellulosic breakdown to sugar fuel
chemistry of carbon dioxide to fuel
13. The battery hasn't advanced in decades. But
we're on the verge of a power revolution
Big technology companies and now car
companies that are making electric vehicles
Tech companies and car manufacturers are
pumping money into battery development
And with races like Formula E adding pressure
to improve, that technology is only going to get
greater
14.
15. Because of the huge availability of sodium, its
low price and similarity of both Li and Na
insertion chemistries
In spite of lower energy density and voltage of
Na –ion based technologies they can be focused
on the applications, where the weight and
footprint requirement is less drastic such as
grid storage
Much work has to be done in the field of Na-
ion in order to catch up with Li –ion technology
16. Cathodic and anodic materials must be
optimized and new electrolytes will be key
point for Na-ion success
This battery uses a standard that means it can
be placed in laptops and even work in electric
cars like the Tesla Model S
The 6.5cm battery can manage 90 watt-hours
per kilogram, making it comparable to lithium-
ion but with a 2000 cycle lifespan, which
should be improved
17. Lithium-ion batteries rely on an electrolyte
liquid to transport charged particles between
the two electrodes. It's this liquid that can be
flammable and which degrades the battery
limiting life
Battery can operate at super capacitor levels to
completely charge or discharge in just seven
minutes - making it ideal for cars. Since it's
solid state that also means it's far more stable
and safer than current batteries
18. The solid-state unit should also be able to work
in as low as minus 30 degrees Celsius and up to
one hundred
The electrolyte materials still pose challenges
so don't expect to see these in cars soon, but it's
a step in the right direction towards safer,
faster charging batteries
19. This alternative type of battery to that Lithium
ion battery that uses sand to achieve three
times better performance than current efforts
The battery is still lithium-ion like that found in
your smartphone, but it uses sand instead of
graphite in the anodes. This means it's not only
three times better performing but it's also low
cost, non toxic and environmentally friendly
20. Gives 1,100 mile drive on a charge
This uses oxygen naturally occurring in the air
to fill its cathode
This drain turning the metal into aluminium
hydroxide which can be recycled
Water dew powered batteries
The device uses interleaved flat metal plates to
produce power from the water dew in the air
15 picowatts
21. Nanowires, a thousand times thinner than a
human hair
Can withstand plenty of recharging, the result
could be future batteries that don't die
Ideal for future electric cars, spacecraft and
phones that will never need new batteries
Magnesium batteries
Smaller, more densely packed units that won't
need shielding
22. One company has developed a new battery
called Grabat that could offer electric cars a
driving range of up to 500 miles on a charge
The capacity of the 2.3V Grabat is huge with
around 1000 Wh/kg which compares to
lithium ion's current 180 Wh/kg
Upp hydrogen fuel cell charger
It uses hydrogen to power your phone
keeping you off the gird and remaining
environmentally friendly
23. One hydrogen cell will provide five full
charges of a mobile phone (25Wh capacity per
cell
A USB type A socket means it will charge most
USB devices with a 5V, 5W, 1000mA output
Transparent solar charger
Alcatel has demoed a mobile phone with a
transparent solar panel over the screen that
would let users charge their phone by simply
placing it in the sun
24. Conclusion
nanoscience
computer
modeling
complex
materials
controlling
materials and chemistries
in ultra-small and ultra-fast regimes
We are at the dawn of a new era
• build materials with atom-by-atom chemical precision
• predict behavior of materials that have not been made
• design new materials and chemistries for specific tasks
to meet all the challenges
breakthroughs to next-generation
sustainable energy technologies are within reach
25. References
Secure Energy Future, 2002
Hydrogen Economy, 2003
Solar Energy Utilization, 2005
Superconductivity, 2006
Solid-state Lighting, 2006
Advanced Nuclear Energy Systems, 2006
Clean and Efficient Combustion of Fuels, 2006
Electrical Energy Storage, 2007
Geosciences: Facilitating 21st Century
Energy Systems, 2007
Catalysis for Energy, 2007
Materials Under Extreme Environments, 2007
Directing Matter and Energy: Five Grand
Challenges for Science and the Imagination, 2007
New Science for a Secure and Sustainable Energy Future, 2008
Editor's Notes
What do we mean by sustainable energy technology?
Experts argue over what sustainabiilty means, but here are three key features.
Not all need to be realized to quallify as sustainable, but the most benefit comes from the most sustainable
It may seem difficult to satisfy all three criteria, but we have existing technologies that do
Solar photons produce electrons and holes in semiconductors
the electrons travel through transmission lines to do work for us, then return through transmission lines to recombine with the hole in the semiconductor, leaving no trace
the only change is that there is one less photon in the sun, and the sun has plenty of photons for a few billion more years
Although it is fully sustainable, solar electricity faces several fundamental science roadblocks to widespread deployment
the electric motor is typically > 90% efficient, compared to 25%-30% for gasoline engines
It is much simpler, with one shaft moving inside wire coils. The gasoline engine has valves, fuel injectors, high temperature explosions several times per revolution, exhaust gases
Two ways to supply electricity- from a battery and ultimately the grid, and from a fuel cell with local supply of hydrogen.
More energy in hydrogen + fuel cell, batteries are a major weak link in the electric vehicle energy chain
sustainabilty profile depends entirely on production method – the electric car itself is fully sustainable.
We can replace oil with fuel made from plants – biomass
corn ethanol is our major biofuel source now, made from corn kernals
It is limited by its energy quotient – approximately break even on energy in vs energy out
and by the amount of fuel that can be produced. Corn ethanol also competes with food for humans and animals
cellulosic ethanol is a better bet, where the leaves and stalks of the plant are used, not just the seeds
This produces significantly more energy out than put in, and it can be grown on land that is not now farmed
There are scientific roadblocks- we do not know how to break down cellulose (and lignin) to sugars that can be fermented to fuel, or how to turn cellulose directly into fuel
There are other ways to recycle carbon dioxide to fuel without biology
We can use the heat from the sun to split carbon dioxide to carbon monoxide and water to hydrogen, and these can then be reacted with each other to produce hydrocarbons like gasoline
We can use photons from the sun to excite electrons in semiconductors or in chemical dyes and then use the excited electrons to drive the chemical reactions of fuel production at near room temperature, as plants do.
This thermo- or photo-chemical fuel production can recycle carbon dioxide emissions back into fuel
Oils sands and shale are another substitute for conventional oil. They contain a lot more carbon and a host of harmful chemicals like sulfur.
Because they have so much carbon, they are solid and are mined more like coal than pumped like oil.
They produce 50% more carbon dioxide per gallon of gasoline than light sweet crude, and many more pollutants
The BES workshops have identified the roadblocks to next generation sustainable energy technologies.
We know what they are, the challenge now is to overcome them.
Each one of these reports is a treasure trove of information.
They are long, 150 or more pages.
But if you want a quck overview, read the executive summary, the introduction, the conclusions. These are short, you can read them in an hour for each report.