Thermoelectric power generation (TEG) devices typically use special semiconductor materials, which are optimized for the Seebeck effect. The simplest TEG device consists of a thermocouple, comprising a p-type and n-type material connected electrically in series and thermally in parallel. Heat is applied into one side of the couple and rejected from the opposite side. An electrical current is produced, proportional to the temperature gradient between the hot and cold junctions.

1. THERMOELECTRIC POWER
GENERATOR (TEG)
PRESENED BY
MISS. MADHURI MORE
PH D SCHOLAR
RENEWABLE ENERGY ENGINEERING
COLLEGE OG TECHOLOGY AND ENGINEERING, MPUAT,
UDAIPUR

2.  INTRODUCTION
 Thermoelectricity refers to a phenomena in which a
temperature difference creates an electric potential .
 The pioneer in thermoelectric was a German scientist
Thomas Johann Seebeck (1770-1831).
 Later, In 1834, French scientist, Peltier and in 1851,
Thomson described the thermal effects on conductor.

3.  What is TEG?
 It is a solid state device
that provides direct energy
conversion from thermal
energy into electrical
energy.
 Principle of operation is
“SEEBECK EFFECT”.

4.  Seebeck Effect
 This term was discovered by Thomas Seebeck in 1821.
 “When the junctions of two different metals are maintained at different temperature, the
emf is produced in the circuit. This is known as Seebeck effect.”
 The conductor 1 is maintained at ‘T+∆T’
temperature.
 The conductor 2 is maintained at
temperature ‘T’.
 Since, the junctions are maintained at
different temperature, the emf ‘U’ flows
across the circuit.

5.  Construction
 Thermoelectric power generation (TEG) devices typically use special
semiconductor materials, which are optimized for the Seebeck effect.
 The simplest TEG device consists of a thermocouple, comprising a p-
type and n-type material connected electrically in series and
thermally in parallel.
 Heat is applied into one side of the couple and rejected from the
opposite side.
 An electrical current is produced, proportional to the temperature
gradient between the hot and cold junctions.

6.  Therefore, for any TEG, there are four basic component
required such as
1. Heat source (fuel)
2. P and N type semiconductor stack (TE module)
3. Heat sink (cold side)
4. Electrical load (output voltage)
 The figure shows the construction of thermoelectric
power generator.
 There is a burner in which the propane fuel is used as heating source
in one side.
 The exhaust is used to transmit a burnt fuel.
 On the other side, a cold junction is kept.
 The thermoelectric module (TE) is kept in between the hot and cold
junction. The electrical out (load) is taken from the TE module.

7.  Working
 When the two sides of semiconductor are maintained with
different temperature, the emf is flows across the output
circuit
 As the heat moves from hot side to cold side, the charge
carrier moves in the semiconductor materials and hence the
potential difference is created.
 The electrons are the charge carriers in the case of N-type
semiconductor and Hole are in P-type semiconductors.
 In a stack, number of P-type and N-type semiconductors is
connected.
 A single PN connection can produce a Seebeck voltage of 40
mV.
 The heat source such as natural gas or propane are used for
remote power generation

8.  Thermoelectric Material
 The good thermoelectric materials should possess
1. Large Seebeck coefficients
2. High electrical conductivity
3. Low thermal conductivity
 The example for thermoelectric materials
I. BismuthTelluride (Bi2Te3)
II. Lead Telluride (PbTe)
III. Silicon Germanium (SiGe)
IV. Bismuth-Antimony (Bi-Sb)

9.  Material Used
 Ceramic plates usually made from alumina.
 Semiconductor thermo elements usually SiGe.
 The hot and cold plates are usually connected using highly
conductive material like copper.

10.  Conventional Material
 Alloys based on Bismuth (Bi) are referred to as low temperature materials and
can be used at temperatures up to around 450°K.
 The intermediate temperature range - up to around 850°K is the regime of
materials based on alloys of Lead (Pb)
 Thermo elements employed at the highest temperatures are fabricated from
SiGe alloys and operate up to 1300°K.
 Although these materials provide a limited efficiency.
 These are a cornerstone in practical and commercial application.

11.  Performance of Thermoelectric Power Generator
Performance of thermoelectric materials can be expressed as:
 Figure of Merit
 A high electrical conductivity is necessary to minimize Joule heating and low thermal
conductivity helps to retain heat at the junctions and maintain a large temperature
gradient. These three properties were later put together and it is called figure-of-merit
(ZT).
Where,
σ = electrical conductivity,
S = Seebeck coefficient,
T = mean operating temperature and
K= thermal conductivity.
𝐙𝐓 =
𝛔𝐒 𝟐
𝐓
𝐊

12.  Major Types Available
A. Fossil fuel generators
B. Solar Source generators
C. Nuclear Fuel generators

13.  Advantages
 Easy maintenance: They works electrically without any moving parts so
they are virtually maintenance free.
 Environment friendly: Thermoelectric generators produce no pollution.
Therefore they are eco friendly generators.
 Compact and less weight: The overall thermoelectric cooling system is
much smaller and lighter than a comparable mechanical system.
 High Reliability: Thermoelectric modules exhibit very high reliability due
to their solid-state construction
 No noise: They can be used in any orientation and in zero gravity
environments. Thus they are popular in many aerospace applications.
 Convenient Power Supply: They operate directly from a DC power source.

14.  Experiment - Thermoelectric Generator
 Apparatus:
I. Beakers
II. Hot plate0
III. Ice
IV. Fan
V. Digital Thermometer
 This experiment converts thermal energy to electrical energy by Seebeck
effect. Immerse the metal plates in two different temperature baths. This Unit
will generate 10mV/degree temperature difference. Show this with a multimeter
or use it to run a small fan.