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Nature of mixtures
 Consists of two or more kinds of matter
 Each substance in a mixture retains its own
properties
• sugar and water - sweet and wet
• brine (salt water) - salty liquid
The composition is variable (not constant)
Can be separated by physical means
DEFINITION OF SOLUTION
Definition: Solution = homogeneous mixture
Solutions vs. Mechanical Mixtures
• Solutions are composed of two or more substances BUT the
particles are distributed evenly throughout each other SO the
composition is uniform.
SOLUTION MECHANICAL MIXTURE
Homogeneous Heterogeneous
• The solution appears to be one substance even though
it is two or more.
A solution consists of a solute dissolved in a solvent.
• Solute - substance that IS dissolved by another
• Solvent
-substance that dissolves another
- continuous phase
Example: Salt dissolved in water appears to be
a liquid.
The water is the continuous phase.
The water is the solvent.
The ability to dissolve in water
SOLUBILITY.
Degree of solubility (how much dissolves)
Temperature
Pressure
FACTORS AFFECTING SOLUBILITY
Like dissolves like.
Degree of Solubility
 Nature of solute and solvent
•In order for a solvent to dissolve a solute, it must exert forces of attraction on the
solute.
•Polar solvents such as water dissolve polar and ionic solutes because they exert
mutual attractions that cause their particles to intermingle.
• Nonpolar solvents such as benzene do NOT dissolve polar and ionic substances
because they exert no forces of attraction that would cause the particles to separate
so they can intermingle.
 Oil and water do NOT mix.
• Nonpolar substances such as fat dissolve in nonpolar solvents such as benzene
because the forces of attraction are too weak to prevent the particles from freely
intermingling.
SOLUBILITY GUIDELINES
The Reference Tables provide solubility guidelines.
T E M P E R AT U R E
CONSIDERATIONS EFFECT OF TEMPERATURE
What happens to the particles of a solid
when they dissolve in water?
•THEY SEPERATE.
What happens to the particles of a gas
when they dissolve in water?
•THEY COME TOGETHER.
•Solubility of solid solutes
generally increases as
temperature increases.
•Solubility of gaseous solutes
generally decreases as
temperature increases.
When solids dissolve in water the particles Solubility of solid solutes is not affected
separate. What effect does pressure have on the by pressure.
distance between the particles of a solid?
-NONE
When gases dissolve in water the particles Solubility of gaseous solutes increases
come together. What effect does pressure have as pressure increases.
on the distance between the particles of a gas? Henry’s Law-the mass of a dissolved
- PRESSURE PRESSURES DOWN TOGETHER gas in a liquid is directly
CONSIDERATIONS EFFECT OF PRESSURE
proportional to the pressure of
the gas.
P R E S S U R E
the nature of solution
the nature of solution

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the nature of solution

  • 1.
  • 2. Nature of mixtures  Consists of two or more kinds of matter  Each substance in a mixture retains its own properties • sugar and water - sweet and wet • brine (salt water) - salty liquid The composition is variable (not constant) Can be separated by physical means DEFINITION OF SOLUTION Definition: Solution = homogeneous mixture
  • 3. Solutions vs. Mechanical Mixtures • Solutions are composed of two or more substances BUT the particles are distributed evenly throughout each other SO the composition is uniform. SOLUTION MECHANICAL MIXTURE Homogeneous Heterogeneous • The solution appears to be one substance even though it is two or more.
  • 4. A solution consists of a solute dissolved in a solvent. • Solute - substance that IS dissolved by another • Solvent -substance that dissolves another - continuous phase Example: Salt dissolved in water appears to be a liquid. The water is the continuous phase. The water is the solvent.
  • 5. The ability to dissolve in water SOLUBILITY.
  • 6. Degree of solubility (how much dissolves) Temperature Pressure FACTORS AFFECTING SOLUBILITY
  • 7. Like dissolves like. Degree of Solubility  Nature of solute and solvent •In order for a solvent to dissolve a solute, it must exert forces of attraction on the solute. •Polar solvents such as water dissolve polar and ionic solutes because they exert mutual attractions that cause their particles to intermingle. • Nonpolar solvents such as benzene do NOT dissolve polar and ionic substances because they exert no forces of attraction that would cause the particles to separate so they can intermingle.  Oil and water do NOT mix. • Nonpolar substances such as fat dissolve in nonpolar solvents such as benzene because the forces of attraction are too weak to prevent the particles from freely intermingling.
  • 8. SOLUBILITY GUIDELINES The Reference Tables provide solubility guidelines.
  • 9. T E M P E R AT U R E CONSIDERATIONS EFFECT OF TEMPERATURE What happens to the particles of a solid when they dissolve in water? •THEY SEPERATE. What happens to the particles of a gas when they dissolve in water? •THEY COME TOGETHER. •Solubility of solid solutes generally increases as temperature increases. •Solubility of gaseous solutes generally decreases as temperature increases.
  • 10. When solids dissolve in water the particles Solubility of solid solutes is not affected separate. What effect does pressure have on the by pressure. distance between the particles of a solid? -NONE When gases dissolve in water the particles Solubility of gaseous solutes increases come together. What effect does pressure have as pressure increases. on the distance between the particles of a gas? Henry’s Law-the mass of a dissolved - PRESSURE PRESSURES DOWN TOGETHER gas in a liquid is directly CONSIDERATIONS EFFECT OF PRESSURE proportional to the pressure of the gas. P R E S S U R E