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Today’s Objectives Dielectrics and Ferroelectrics ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Capacitance ,[object Object],[object Object],[object Object],[object Object],[object Object]
Why does charge built up? ,[object Object],[object Object],[object Object],[object Object]
Polarization in Insulators Positively charged species in insulators shift/rotate/align toward the negative electrode and negatively charged species shift/rotate/align towards the positive electrode; creating dipoles. The  dipole moment density  is termed the  Polarization   (P)  and has the units of C/m 2 . + - Electron Cloud Electron Cloud + E Electronic polarization, occurs in all insulators - + + + - + + E Ionic polarization occurs in all ionic solids: NaCl, MgO… - - - - + - - + + - + + E Molecular polarization, occurs in all insulating molecules; oils, polymers, H 2 O…  Electric Dipole Moment Polarization
Frequency Response (Switching Time) Electronic Polarization Ionic Polarization Molecular  Polarization
Microwave Ovens ,[object Object],[object Object],[object Object],http://home.howstuffworks.com/framed.htm?parent=micriwave.htm&url=http://www.amasci.com/weird/microexp.html
Relative Dielectric Constants ,[object Object]
A Materials/Design Problem How can we increase the charge stored in a parallel-plate capacitor? This is an  extremely important  problem in  solid state computer memories   (RAMs, DRAMs, SDRAMs)  that are based on capacitors. ,[object Object],[object Object],[object Object],[object Object]
Breakdown Strength ,[object Object],[object Object],[object Object],[object Object],> 10 000 SiO 2  in  ICs > 1 000 000 Thin films in ICs 50...900 Polymers 1800 Oiled paper 200...700 Mica 200...400 Glass, ceramics 200 Oil Critical Field Strength  (kV/cm) Material
Dielectric Breakdown Mechanisms ,[object Object],[object Object],[object Object],[object Object]
Slight Ionic Asymmetry - Ferroelectrics ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Perovskite Structure
Ferroelectrics
Spontaneous Polarization
Electrostriction and Piezoelectricity FEs possess a spontaneous strain. This is called  electrostriction .  The FE crystal can be deformed by the application of an electric field or it generates a  potential  when there is an applied stress. This is called  piezoelectricity.
Pyroelectricity The spontaneous polarization is strongly dependent on the temperature. It dissapears completely at the phase transformation temperature T C . The variation in the polarization with respect to the temperature is called the  pyroelectric effect .
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Applications of Ferroelectrics
Non-Volatile RAMs (memory)
Non-Volatile RAMs (memory) Smart cards use ferroelectric memories. They can hold relatively large amounts of information and do not wear out from use, as magnetic strips do, because they use contactless radio frequency input/output. These cards are the size and shape of credit cards but contain ferroelectric memory that can carry substantial information, such as its bearer's medical history for use by doctors, pharmacists and even paramedics in an emergency. Current smart cards carry about 250 kilobytes of memory.
Dynamic RAMs (capacitors) High dielectric constant near phase transformation from the cubic to the tetragonal phase  (500~15,000) Tetragonal Cubic ,[object Object]
Tunable Microwave Devices / Optical Waveguides Filters Phase shifters Delay lines Oscillators   ( E =0)
Pyroelectric Detectors/Sensors
Pyroelectric Detectors/Sensors
Piezoelectric Sensors/Actuators, MEMS
Piezoelectric Sensors/Actuators, MEMS
Summary ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Reading for next class Magnetic properties I Chapter sections: 20.1-6

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Lecture 17

  • 1.
  • 2.
  • 3.
  • 4. Polarization in Insulators Positively charged species in insulators shift/rotate/align toward the negative electrode and negatively charged species shift/rotate/align towards the positive electrode; creating dipoles. The dipole moment density is termed the Polarization (P) and has the units of C/m 2 . + - Electron Cloud Electron Cloud + E Electronic polarization, occurs in all insulators - + + + - + + E Ionic polarization occurs in all ionic solids: NaCl, MgO… - - - - + - - + + - + + E Molecular polarization, occurs in all insulating molecules; oils, polymers, H 2 O… Electric Dipole Moment Polarization
  • 5. Frequency Response (Switching Time) Electronic Polarization Ionic Polarization Molecular Polarization
  • 6.
  • 7.
  • 8.
  • 9.
  • 10.
  • 11.
  • 14. Electrostriction and Piezoelectricity FEs possess a spontaneous strain. This is called electrostriction . The FE crystal can be deformed by the application of an electric field or it generates a potential when there is an applied stress. This is called piezoelectricity.
  • 15. Pyroelectricity The spontaneous polarization is strongly dependent on the temperature. It dissapears completely at the phase transformation temperature T C . The variation in the polarization with respect to the temperature is called the pyroelectric effect .
  • 16.
  • 18. Non-Volatile RAMs (memory) Smart cards use ferroelectric memories. They can hold relatively large amounts of information and do not wear out from use, as magnetic strips do, because they use contactless radio frequency input/output. These cards are the size and shape of credit cards but contain ferroelectric memory that can carry substantial information, such as its bearer's medical history for use by doctors, pharmacists and even paramedics in an emergency. Current smart cards carry about 250 kilobytes of memory.
  • 19.
  • 20. Tunable Microwave Devices / Optical Waveguides Filters Phase shifters Delay lines Oscillators   ( E =0)
  • 25.