Chapter 2 of "Network Security Essentials: Applications and Standards" discusses symmetric encryption and its role in message confidentiality. It outlines the essential components of a symmetric encryption scheme, including plaintext, encryption algorithm, secret key, ciphertext, and decryption algorithm, emphasizing that the security depends on the secrecy of the key rather than the algorithm. The chapter also categorizes cryptographic systems and attacks, highlighting the significance of developing strong encryption algorithms and maintaining key security.