HEAT AND
ENERGY
CONTENTS
• KINETIC MOLECULAR MODEL OF
MATTER
• HEAT &TEMPERATURE
• THERMOMETRY
• SPECIFIC HEAT CAPACITY
• SPECIFIC LATENT HEAT
• HEAT TRANSFER
KINETIC MODEL OF MATTER
• The Kinetic Molecular Theory of Matter
states that atoms and molecules possess
an energy of motion (kinetic energy) that
we perceive as temperature. Atoms and
molecules are constantly in motion , and
we measure the energy of these
movements as the temperature of that
substance.
Postulates
• The particles with which matter is made up
of are in constant motion.
• Molecular motion is random.
• Particles in motion possess kinetic energy.
• Their motion increase as they gain energy.
• There is an exchange (transfer) of energy
between particles (atoms and molecules)
during a collision between them.
Continues…
• Particles (molecules) in gases do not exert
large forces on each other, unless they
are in collision with each other.
• Collisions between these particles are
perfectly elastic.
• Molecular motion is greatest in gases, less
in liquids, and least in solids.
• Solids retain a fixed volume and shape –
particles are tightly packed, usually in a
regular pattern.
A few more…
• Liquids assume the shape of the container
which it occupies but maintain their
volume – particles close together with no
regular arrangement.
• Gases assumes the shape and volume of
its container and will expand to fill a
container of any size – particles are very
well far apart with no regular arrangement.
Solid liquid and Gas
https://www.chem.purdue.edu/gchelp/liquids/character.html
HEAT & TEMPERATURE
ARE THEY ONE AND THE SAME?
IF NOT, HOW WILL YOU EXPLAIN THE
DIFFERENCE?
Boiling water in a pot or a beaker has
more heat energy ?
HEAT
• Heat is a form of energy due to the moving
particles.
• It is a scalar quantity.
• It is measured in Joules.
• It can be exchanged between two object if
there is a difference in temperature.
• Heat flows from a hotter object to a cooler
object.
• Heat is the energy in transit.
Temperature
• Temperature is an indication of how hot or
cold a body is.
• Temperature doesn’t depends on the
mass of the object/ no of particles .
• It is the average kinetic energy of the
particles.
• It is measured in degree Celsius/
Fahrenheit /Kelvin
Thermomertry
• Galileo invented the first thermometer. In his
instrument, the changing temperature of an
inverted glass vessel produced the expansion or
contraction of the air within it, which in turn
changed the level of the liquid with which the
vessel’s long, open-mouthed neck was partially
filled. This general principle was perfected in
succeeding years by experimenting with liquids
such as mercury and by providing a scale to
measure the expansion and contraction brought
about in such liquids by rising and falling
temperature.
Thermometer
• An instrument, a thermometer, is required
to measure temperature objectively. The
thermometer makes use of a physical
property of a thermometric substance
which changes continuously with
temperature. The physical property is
referred to as thermometric property.
•
Different thermometric
properties and thermometers
THERMOMETRIC PROPERTY THERMOMETER
Volume expansion of a gas Gas thermometer
Volume expansion of a liquid Laboratory or clinical thermometer
Volume expansion of a solid Bi-metallic strip thermometer
Pressure change of a fixed mass of gas Constant – volume gas thermometer
Changes in e.m.f. Thermocouple
Changes in electrical resistance Resistance thermometer or thermistor
Thermometry
• A good thermometric property of matter
should vary: continuously with
temperature
uniquely over the range of temperature to
be measured its variation should be
measurable.
Developing a thermometer:
• Choose a thermometric substance with a
suitable thermometric properties.
• Select two fixed points which are easily
obtainable and reproducible.
• Divide the temperature range between the
two fixed points into equal divisions.
Calibration of thermometer:
• Fixed points are used in calibrating
thermometers. To calibrate a thermometer
is to mark a thermometer so that you can
use it to measure temperature accurately.
A fixed point is a standard degree of
hotness or coldness such as the melting
point of ice or boiling point of water
Fixed points in Celsius scale:
• Steam point (upper fixed point) – The
temperature at which pure water boils at
one atmospheric pressure and
is assigned the value of 100 °C.
• Ice point (lower fixed point) – The
temperature at which pure ice melts at one
atmospheric pressure and is assigned the
value of 0 °C.
•
Sensitivity of a thermometer:
• Small expansion of the liquid in the liquid
bulb will cause a big change in the length
of the liquid thread in the capillary tube as
it is made narrow. The narrower the bore,
the higher the sensitivity.
What happens when we heat a
substance?
• When we heat a
substance it becomes
hotter or changes state.
How much heat is needed to raise
the temperature of an object?
• As heat energy increases, temperature
increases. Q∞ Temperature.
• As mass increases, more heat energy is
required to reach the same temperature
• Q ∞ Mass of the object.
• It depends on the material!
• Each material has its own specific heat
capacity (c).
Specific Heat (c)
•The specific heat capacity of a
material is the amount of heat energy
required to change the temperature of
1kg of the substance by 1°C/ 1K.
TcmEh ∆=
Specific Heat Capacity
TcmEh
∆=
Heat energy (J)
mass (kg)
Change in
temperature (°C)
Specific heat capacity
RADIATOR
Why is water used as the coolant?
Because water has a high specific
heat capacity, it can take away a lot
of energy without boiling away.
What happens when we heat a
substance?
When we heat the air in a room, the
kinetic energy of the molecules increases.
The air molecules move faster.
When we heat water, the molecules
vibrate faster.
When we heat snow,
the vibration of the
molecules increases
and it eventually
melts.
The temperature does not
always rise!
Heating curve/ warming curve
Where is the absorbed heat
energy hiding?
• During the melting and boiling the heat
energy is absorbed but the temperature is
not increasing.
• Where does the heat energy go?
• We must supply energy to change a solid
to a liquid or a liquid to a gas.
Specific latent heat of fusion:
• When we heat a solid, it will melt and become a liquid.
• At this point, energy is required but the temperature
• does not rise.
• The specific latent heat of fusion of a
• substance is the heat energy required to
• change 1kg of solid at its melting point to
• 1 kg of liquid – without a change in
• temperature.
Specific Latent Heat of Fusion
• The specific latent heat of fusion of a
• substance is the heat energy required to
• change 1kg of solid at its melting point to
• 1kg of liquid – without a change in
• temperature.
mlEh
=
Heat energy (J)
mass (kg)
Specific latent
heat
Units of Specific Latent Heat
m
E
l h
=
(J)
(kg)
Specific latent
heat J/kg
Specific latent heat of
vaporisation
• When we heat a liquid, it will evaporate and become a
gas. At this point, energy is required but the
temperature does not rise.
• The specific latent heat of vaporisation
of a substance is the heat energy
required to change 1kg of liquid at its
boiling point to 1kg of vapour (gas) –
without a change in temperature.
• A solid is continuously
heated until it eventually
reaches the gas state.
temperature / °C
time / s
What’s happening
Here? The
temperature of
the solid is rising
What’s happening
here? There’s no
change in
temperature
because there is a
change of state –
the solid is melting
What’s happening
here? There is a
change of state
from liquid to gas
so no change in
temperature
What’s h
here? Al
has turne
the gas t
begins to
What’s
happening
here? The
temperature of
the liquid is
rising
Question time
• Calculate the time taken for a 500 W
• heater to melt 2 kg of ice at 0 °C.
• Given that, Latent heat of fusion of ice l =
3.34x105
J/kg
• Specific latent heat of vaporisation=2.26
x105
J/kg
Transfer of heat
• Conduction
• Convection
• Radiation
Conduction
• Transfer of energy from molecule to
molecule
• Most common in solids
• KE is transferred when particles collide
• MUST have direct contact
Convection
• Convection is heat transfer by mass
motion of a fluid such as air or water when
the heated fluid is caused to move away
from the source of heat, carrying energy
with it. Convection above a hot surface
occurs because hot air expands, becomes
less dense, and rises . Hot water is
likewise less dense than cold water and
rises, causing convection currents which
transport energy.
•
Radiation
• Thermal radiation is energy transfer by the
emission of electromagnetic waves which
carry energy away from the emitting
object. For ordinarytemperatures (less
than red hot"), the radiation is in
the infrared region of the electromagnetic
spectrum.
Heat and energy

Heat and energy

  • 1.
  • 2.
    CONTENTS • KINETIC MOLECULARMODEL OF MATTER • HEAT &TEMPERATURE • THERMOMETRY • SPECIFIC HEAT CAPACITY • SPECIFIC LATENT HEAT • HEAT TRANSFER
  • 3.
    KINETIC MODEL OFMATTER • The Kinetic Molecular Theory of Matter states that atoms and molecules possess an energy of motion (kinetic energy) that we perceive as temperature. Atoms and molecules are constantly in motion , and we measure the energy of these movements as the temperature of that substance.
  • 4.
    Postulates • The particleswith which matter is made up of are in constant motion. • Molecular motion is random. • Particles in motion possess kinetic energy. • Their motion increase as they gain energy. • There is an exchange (transfer) of energy between particles (atoms and molecules) during a collision between them.
  • 5.
    Continues… • Particles (molecules)in gases do not exert large forces on each other, unless they are in collision with each other. • Collisions between these particles are perfectly elastic. • Molecular motion is greatest in gases, less in liquids, and least in solids. • Solids retain a fixed volume and shape – particles are tightly packed, usually in a regular pattern.
  • 6.
    A few more… •Liquids assume the shape of the container which it occupies but maintain their volume – particles close together with no regular arrangement. • Gases assumes the shape and volume of its container and will expand to fill a container of any size – particles are very well far apart with no regular arrangement.
  • 7.
    Solid liquid andGas https://www.chem.purdue.edu/gchelp/liquids/character.html
  • 8.
    HEAT & TEMPERATURE ARETHEY ONE AND THE SAME? IF NOT, HOW WILL YOU EXPLAIN THE DIFFERENCE? Boiling water in a pot or a beaker has more heat energy ?
  • 9.
    HEAT • Heat isa form of energy due to the moving particles. • It is a scalar quantity. • It is measured in Joules. • It can be exchanged between two object if there is a difference in temperature. • Heat flows from a hotter object to a cooler object. • Heat is the energy in transit.
  • 10.
    Temperature • Temperature isan indication of how hot or cold a body is. • Temperature doesn’t depends on the mass of the object/ no of particles . • It is the average kinetic energy of the particles. • It is measured in degree Celsius/ Fahrenheit /Kelvin
  • 11.
    Thermomertry • Galileo inventedthe first thermometer. In his instrument, the changing temperature of an inverted glass vessel produced the expansion or contraction of the air within it, which in turn changed the level of the liquid with which the vessel’s long, open-mouthed neck was partially filled. This general principle was perfected in succeeding years by experimenting with liquids such as mercury and by providing a scale to measure the expansion and contraction brought about in such liquids by rising and falling temperature.
  • 12.
    Thermometer • An instrument,a thermometer, is required to measure temperature objectively. The thermometer makes use of a physical property of a thermometric substance which changes continuously with temperature. The physical property is referred to as thermometric property. •
  • 13.
    Different thermometric properties andthermometers THERMOMETRIC PROPERTY THERMOMETER Volume expansion of a gas Gas thermometer Volume expansion of a liquid Laboratory or clinical thermometer Volume expansion of a solid Bi-metallic strip thermometer Pressure change of a fixed mass of gas Constant – volume gas thermometer Changes in e.m.f. Thermocouple Changes in electrical resistance Resistance thermometer or thermistor
  • 14.
    Thermometry • A goodthermometric property of matter should vary: continuously with temperature uniquely over the range of temperature to be measured its variation should be measurable.
  • 15.
    Developing a thermometer: •Choose a thermometric substance with a suitable thermometric properties. • Select two fixed points which are easily obtainable and reproducible. • Divide the temperature range between the two fixed points into equal divisions.
  • 16.
    Calibration of thermometer: •Fixed points are used in calibrating thermometers. To calibrate a thermometer is to mark a thermometer so that you can use it to measure temperature accurately. A fixed point is a standard degree of hotness or coldness such as the melting point of ice or boiling point of water
  • 17.
    Fixed points inCelsius scale: • Steam point (upper fixed point) – The temperature at which pure water boils at one atmospheric pressure and is assigned the value of 100 °C. • Ice point (lower fixed point) – The temperature at which pure ice melts at one atmospheric pressure and is assigned the value of 0 °C. •
  • 18.
    Sensitivity of athermometer: • Small expansion of the liquid in the liquid bulb will cause a big change in the length of the liquid thread in the capillary tube as it is made narrow. The narrower the bore, the higher the sensitivity.
  • 19.
    What happens whenwe heat a substance? • When we heat a substance it becomes hotter or changes state.
  • 20.
    How much heatis needed to raise the temperature of an object? • As heat energy increases, temperature increases. Q∞ Temperature. • As mass increases, more heat energy is required to reach the same temperature • Q ∞ Mass of the object. • It depends on the material! • Each material has its own specific heat capacity (c).
  • 21.
    Specific Heat (c) •Thespecific heat capacity of a material is the amount of heat energy required to change the temperature of 1kg of the substance by 1°C/ 1K. TcmEh ∆=
  • 22.
    Specific Heat Capacity TcmEh ∆= Heatenergy (J) mass (kg) Change in temperature (°C) Specific heat capacity
  • 23.
    RADIATOR Why is waterused as the coolant? Because water has a high specific heat capacity, it can take away a lot of energy without boiling away.
  • 24.
    What happens whenwe heat a substance? When we heat the air in a room, the kinetic energy of the molecules increases. The air molecules move faster. When we heat water, the molecules vibrate faster. When we heat snow, the vibration of the molecules increases and it eventually melts. The temperature does not always rise!
  • 25.
  • 26.
    Where is theabsorbed heat energy hiding? • During the melting and boiling the heat energy is absorbed but the temperature is not increasing. • Where does the heat energy go? • We must supply energy to change a solid to a liquid or a liquid to a gas.
  • 27.
    Specific latent heatof fusion: • When we heat a solid, it will melt and become a liquid. • At this point, energy is required but the temperature • does not rise. • The specific latent heat of fusion of a • substance is the heat energy required to • change 1kg of solid at its melting point to • 1 kg of liquid – without a change in • temperature.
  • 28.
    Specific Latent Heatof Fusion • The specific latent heat of fusion of a • substance is the heat energy required to • change 1kg of solid at its melting point to • 1kg of liquid – without a change in • temperature. mlEh = Heat energy (J) mass (kg) Specific latent heat
  • 29.
    Units of SpecificLatent Heat m E l h = (J) (kg) Specific latent heat J/kg
  • 30.
    Specific latent heatof vaporisation • When we heat a liquid, it will evaporate and become a gas. At this point, energy is required but the temperature does not rise. • The specific latent heat of vaporisation of a substance is the heat energy required to change 1kg of liquid at its boiling point to 1kg of vapour (gas) – without a change in temperature.
  • 31.
    • A solidis continuously heated until it eventually reaches the gas state. temperature / °C time / s What’s happening Here? The temperature of the solid is rising What’s happening here? There’s no change in temperature because there is a change of state – the solid is melting What’s happening here? There is a change of state from liquid to gas so no change in temperature What’s h here? Al has turne the gas t begins to What’s happening here? The temperature of the liquid is rising
  • 32.
    Question time • Calculatethe time taken for a 500 W • heater to melt 2 kg of ice at 0 °C. • Given that, Latent heat of fusion of ice l = 3.34x105 J/kg • Specific latent heat of vaporisation=2.26 x105 J/kg
  • 33.
    Transfer of heat •Conduction • Convection • Radiation
  • 34.
    Conduction • Transfer ofenergy from molecule to molecule • Most common in solids • KE is transferred when particles collide • MUST have direct contact
  • 35.
    Convection • Convection isheat transfer by mass motion of a fluid such as air or water when the heated fluid is caused to move away from the source of heat, carrying energy with it. Convection above a hot surface occurs because hot air expands, becomes less dense, and rises . Hot water is likewise less dense than cold water and rises, causing convection currents which transport energy. •
  • 36.
    Radiation • Thermal radiationis energy transfer by the emission of electromagnetic waves which carry energy away from the emitting object. For ordinarytemperatures (less than red hot"), the radiation is in the infrared region of the electromagnetic spectrum.