Gases
Gas equations
BOYLE’S LAW
P

1

V
have

Temperature
Volume
Pressure
Amount
Volume

Pressure

(dm3)
1

5

2

2,5

3

1,67

4

1,25

5

1

6

0,833

k

(units)

x
x
x
x
x
x

1
2
3
4
5

6

(proportionality
constant: PV)
5
=

=
=
=
=
=

5
5
5
5

5
Volume

k

Pressure

1 V1 = 5

P1 = 1

(proportionality
constant: PV)
5

2 2,5

2

5

3 1,67

3

5

4 1,25

4

5

5 1

5

5

6 0,833

6

5

(dm3)

(units)
V1 x P 1 = k
Volume

k

Pressure

1 V1 = 5

P1 = 1

(proportionality
constant: PV)
5

2 V2 = 2,5

P2 = 2

5

3 1,67

3

5

4 1,25

4

5

5 1

5

5

6 0,833

6

5

(dm3)

(units)
V1 x P 1 = k
V2 x P2 = k
V1 x P 1 = k
V2 x P2 = k
V1 x P1 = V2 x P2
V1 x P 1 = k
V2 x P2 = k
V1 x P1 = V2 x P2
P1V1 = P2V2
V1 x P 1 = k
V2 x P2 = k
V1 x P1 = V2 x P2
P1V1 = P2V2
P1V1 = P2V2
PRESSURE AND TEMPERATURE
P

T
have

Temperature
Volume
Pressure
Amount
Temperature

Pressure
(kPa)

( C)

(K)

1 20

293

1,00

0,0034

2 40

313

1,07

0,0034

3 60

333

1,14

0,0034

4 80

353

1,21

0,0034

5 100

373

1,28

0,0034

6 313

586

2,01

0,0034
Temperature

Pressure
(kPa)

( C)

(K)

1 20

T1=293

P1=1,00

0,0034

2 40

313

1,07

0,0034

3 60

333

1,14

0,0034

4 80

353

1,21

0,0034

5 100

373

1,28

0,0034

6 313

586

2,01

0,0034
Temperature

Pressure
(kPa)

( C)

(K)

1 20

T1=293

P1=1,00

0,0034

2 40

T2=313

P2=1,07

0,0034

3 60

333

1,14

0,0034

4 80

353

1,21

0,0034

5 100

373

1,28

0,0034

6 313

586

2,01

0,0034
CHARLES’ LAW
V

T
have

Temperature
Volume
Pressure

Amount
Temperature

Volume
(cm3)

( C)

(K)

1 1

274

34

0,12

2 14

287

36

0,13

3 53

326

37

0,11

4 76

349

41

0,12
GENERAL GAS EQUATION
have

Temperature
Volume
Pressure

Amount
have

Temperature
Volume
Pressure

Amount
QUESTION 1
Question
A gas bubble at the bottom of a lake has a
volume of 200cm3 at a temperature of 8 C.
This bubble rises and when it reaches the
surface where the temperature is 15 C and
the pressure is 100kPa, its volume
increases to 550cm3. Calculate the
pressure on the bubble when it was at the
bottom of the lake.
8 C = 281 K
15 C = 288 K
have

Temperature
Volume
Pressure

Amount
have

Temperature
Volume
Pressure

Amount
Amount
(n)
Amount
(n)
measured in

moles
(mol)
movie
n

n

n

n
n

P

n

P

n

P

nP
P

n
QUESTION
Question
1 mole of gas at 101,3 kPa and 273
K has a volume of 22,4 dm3. What
is the volume of 5 moles of gas at
120 kPa and 280 K?
Standard Temperature: 273 K
Standard Pressure: 101,3 kPa
STP
Standard Temperature: 273 K
Standard Pressure: 101,3 kPa
STP
Standard Temperature: 273 K
Standard Pressure: 101,3 kPa
Volume of 1 mole of any gas at STP: 22,4 dm3
PV = nRT

GENERAL GAS EQUATION
Universal Gas Constant

R = 8,3 J • mol-1 • K-1
Universal Gas Equation

PV = nRT
1 000 Pa = 1 kPa
1 m3 = 1 000 dm3
1 000 Pa = 1 kPa
1 m3 = 1 000 dm3
Universal Gas Constant
Universal Gas Constant
QUESTION
Question
What is the volume of 5 moles of
gas at 120 kPa and 280 K?
SI units
P : Pa
T:K
V : m3
n : mol
Question
What is the volume of 5 moles of
gas at 120 kPa and 280 K?
120 kPa = 120 000 Pa
QUESTION
Question
A sample of nitrogen gas has a mass of
7 g and a volume of 5,6 dm3 at a
temperature of 27 °C. Calculate the
pressure of the gas.
PV = nRT
N2 (g)
N2
M = 2(14)g•mol-1
-1
M = 28 g•mol
T = 27 + 273 = 300 K
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Editor's Notes

  • #101 http://upload.wikimedia.org/wikipedia/commons/6/6c/Nitrogen-3D-vdW.png