This document describes the optimization of a packed bed reactor (PBR) and alternative fluidized bed reactor (FBR) designs for the production of styrene. Three methods for steam contacting are evaluated: a heat exchanger, direct injection, and heat exchanger for the FBR modeled as a continuous stirred tank reactor (CSTR). Optimization trials are performed by varying inlet temperature, pressure, and feed rate to maximize profit. Direct injection of steam into the PBR is found to be the most profitable design.
Post-combustion CO2 capture and its effects on power plantsHamid Abroshan
This slide is a presentation of a conference paper discussing the post-combustion Carbon Dioxide capture from steam power plants. The main question in this paper was to choose the best location in flue gas path, where flue gas will be extracted and sent to absorption tower.
Post-combustion CO2 capture and its effects on power plantsHamid Abroshan
This slide is a presentation of a conference paper discussing the post-combustion Carbon Dioxide capture from steam power plants. The main question in this paper was to choose the best location in flue gas path, where flue gas will be extracted and sent to absorption tower.
Module 1
Steam Engineering: Properties of steam - wet, dry and superheated steam -
dryness fraction - enthalpy and internal energy - entropy of steam - temperature
entropy diagram - process - Mollier chart - Rankine cycle for wet, dry and
superheated steam. Steam Generators - classification - modern steam generators -
boiler mountings and accessories.
Module 2
Steam nozzles - Mass flow rate - throat pressure for maximum discharge - throat
area - effect of friction - super saturated flow.
Steam turbines: velocity triangles, work done, governing, and efficiencies.
Module 3
Gas turbine Plants - Open and closed cycles - thermodynamics cycles -
regeneration, re heating - inter cooling - efficiency and performance of gas
turbines. Rotary Compressors - Analysis of rotary compressors - centrifugal and
axial compressors. Combustion - combustion chambers of gas turbines -
cylindrical, annular and industrial type combustion chamber - combustion
intensity - combustion chambers efficiency - pressure loss combustion process
and stability loop.
Module 4
Introduction to solar energy - solar collectors - Liquid flat plate collectors -
principle - thermal losses and efficiency - characteristics - overall loss coefficient
- thermal analysis - useful heat gained by fluid - mean plate temperature -
performance - focussing type solar collectors - solar concentrators and receivers
- sun tracking system - characteristics - optical losses - thermal performance -
solar pond - solar water heating - solar thermal power generation
Module 5
Thermal power plants: layout and operation of steam and diesel power plants - coal
burners - stockers - cooling ponds & towers - chimneys - draught - dust collectors -
precipitators - feed water heaters - evaporators - steam condensers - coal handling - ash
handling
HOT TOPIC
TON OF REFRIGERATION,
WORK, U FACTOR, LRA (Locked rotor amps)
RPM of motor, HEAT FORMULA, GAS PIPING (Sizing – CF/hr.), CALCULATING OIL NOZZLE SIZE (GPH):
PYTHAGOREAN THEOREM, Linear Measurement Equivalents (U.S. Conventional - SI Metric)
Theoretical cycle based on the actual properties of the cylinder contents is called the fuel air cycle.
The fuel air cycle takes into consideration the following.
The ACTUAL COMPOSITION of the cylinder contents.
The VARIATION OF SPECIFIC HEAT of the gases in the cylinder.
The DISSOCIATION EFFECT.
The VARIATION IN THE NUMBER OF MOLES present in the cylinder as the pressure and temperature change
Improving and Comparing the Coefficient of Performance of Domestic Refgirator...ijceronline
International Journal of Computational Engineering Research (IJCER) is dedicated to protecting personal information and will make every reasonable effort to handle collected information appropriately. All information collected, as well as related requests, will be handled as carefully and efficiently as possible in accordance with IJCER standards for integrity and objectivity.
Power Plant Performance/Efficiency Monitoring Tool -
Especially for them who really want to work with Efficiency monitoring, This Spread sheet include Boiler Efficiency (ASME PTC 4.0, 2008), Turbine Efficiency (ASME PTC 6.0, 1998), APH Performance (ASME PTC 4.3), Auxiliary Power Consumption (APC) moreover it generate plant MIS As well as complete report.
If you want to download in Spreadsheet/excel format.
http://www.scribd.com/doc/157799307/Power-Plant-Performance-Efficiency-Monitoring-Tool
ज्ञान प्राप्त करने के तीन तरीके है. पहला चिंतन जो सबसे सही तरीका है. दूसरा अनुकरण जो सबसे आसान तरीका है और तीसरा अनुभव जो सबसे कष्टकारी है ~ कन्फ्यूसियस
HEAT TRANSFERCHARACTERISTICS OF A SELF ASPIRATING POROUS RADIANT BURNER FUELE...BIBHUTI BHUSAN SAMANTARAY
This work presents the heat transfer characteristics of a self-aspirating porous radiant burner (SAPRB) that operates on the basis of an effective energy conversion method between flowing gas enthalpy and thermal radiation. The temperature field at various flame zones was measured experimentally by the help of both FLUKE IR camera and K-type thermocouples. The experimental setup consisted of a two layered domestic cooking burner, a flexible test stand attached with six K-type thermocouples at different positions, IR camera, LPG setup and a hot wire anemometer. The two layered SAPRB consisted of a combustion zone and a preheating zone. Combustion zone was formed with high porosity, highly radiating porous matrix, and the preheating zone consisted of low porosity matrix. Time dependent temperature history from thermocouples at various flame zones were acquired by using a data acquisition system and the temperature profiles were analyzed in the ZAILA application software environments.In the other hand the IR graphs were captured by FLUKE IR camera and the thermographs were analyzed in the SMARTView software environments. The experimental results revealed that the homogeneous porous media, in addition to its convective heat exchange with the gas, might absorb, emit, and scatter thermal radiation. The maximum heat transfer coefficient h, of the PRB was 40 w/m2k. The rate of heat transfer was more at the center of the burner where a combined effect of both convection & radiation might be realized.
Immobilization of enzymes refers to the technique of confining/anchoring the enzymes in or on an inert support for their stability & functional reuse.
this slide is about the two most vastly used reactors i.e., batch and continuous.
Module 1
Steam Engineering: Properties of steam - wet, dry and superheated steam -
dryness fraction - enthalpy and internal energy - entropy of steam - temperature
entropy diagram - process - Mollier chart - Rankine cycle for wet, dry and
superheated steam. Steam Generators - classification - modern steam generators -
boiler mountings and accessories.
Module 2
Steam nozzles - Mass flow rate - throat pressure for maximum discharge - throat
area - effect of friction - super saturated flow.
Steam turbines: velocity triangles, work done, governing, and efficiencies.
Module 3
Gas turbine Plants - Open and closed cycles - thermodynamics cycles -
regeneration, re heating - inter cooling - efficiency and performance of gas
turbines. Rotary Compressors - Analysis of rotary compressors - centrifugal and
axial compressors. Combustion - combustion chambers of gas turbines -
cylindrical, annular and industrial type combustion chamber - combustion
intensity - combustion chambers efficiency - pressure loss combustion process
and stability loop.
Module 4
Introduction to solar energy - solar collectors - Liquid flat plate collectors -
principle - thermal losses and efficiency - characteristics - overall loss coefficient
- thermal analysis - useful heat gained by fluid - mean plate temperature -
performance - focussing type solar collectors - solar concentrators and receivers
- sun tracking system - characteristics - optical losses - thermal performance -
solar pond - solar water heating - solar thermal power generation
Module 5
Thermal power plants: layout and operation of steam and diesel power plants - coal
burners - stockers - cooling ponds & towers - chimneys - draught - dust collectors -
precipitators - feed water heaters - evaporators - steam condensers - coal handling - ash
handling
HOT TOPIC
TON OF REFRIGERATION,
WORK, U FACTOR, LRA (Locked rotor amps)
RPM of motor, HEAT FORMULA, GAS PIPING (Sizing – CF/hr.), CALCULATING OIL NOZZLE SIZE (GPH):
PYTHAGOREAN THEOREM, Linear Measurement Equivalents (U.S. Conventional - SI Metric)
Theoretical cycle based on the actual properties of the cylinder contents is called the fuel air cycle.
The fuel air cycle takes into consideration the following.
The ACTUAL COMPOSITION of the cylinder contents.
The VARIATION OF SPECIFIC HEAT of the gases in the cylinder.
The DISSOCIATION EFFECT.
The VARIATION IN THE NUMBER OF MOLES present in the cylinder as the pressure and temperature change
Improving and Comparing the Coefficient of Performance of Domestic Refgirator...ijceronline
International Journal of Computational Engineering Research (IJCER) is dedicated to protecting personal information and will make every reasonable effort to handle collected information appropriately. All information collected, as well as related requests, will be handled as carefully and efficiently as possible in accordance with IJCER standards for integrity and objectivity.
Power Plant Performance/Efficiency Monitoring Tool -
Especially for them who really want to work with Efficiency monitoring, This Spread sheet include Boiler Efficiency (ASME PTC 4.0, 2008), Turbine Efficiency (ASME PTC 6.0, 1998), APH Performance (ASME PTC 4.3), Auxiliary Power Consumption (APC) moreover it generate plant MIS As well as complete report.
If you want to download in Spreadsheet/excel format.
http://www.scribd.com/doc/157799307/Power-Plant-Performance-Efficiency-Monitoring-Tool
ज्ञान प्राप्त करने के तीन तरीके है. पहला चिंतन जो सबसे सही तरीका है. दूसरा अनुकरण जो सबसे आसान तरीका है और तीसरा अनुभव जो सबसे कष्टकारी है ~ कन्फ्यूसियस
HEAT TRANSFERCHARACTERISTICS OF A SELF ASPIRATING POROUS RADIANT BURNER FUELE...BIBHUTI BHUSAN SAMANTARAY
This work presents the heat transfer characteristics of a self-aspirating porous radiant burner (SAPRB) that operates on the basis of an effective energy conversion method between flowing gas enthalpy and thermal radiation. The temperature field at various flame zones was measured experimentally by the help of both FLUKE IR camera and K-type thermocouples. The experimental setup consisted of a two layered domestic cooking burner, a flexible test stand attached with six K-type thermocouples at different positions, IR camera, LPG setup and a hot wire anemometer. The two layered SAPRB consisted of a combustion zone and a preheating zone. Combustion zone was formed with high porosity, highly radiating porous matrix, and the preheating zone consisted of low porosity matrix. Time dependent temperature history from thermocouples at various flame zones were acquired by using a data acquisition system and the temperature profiles were analyzed in the ZAILA application software environments.In the other hand the IR graphs were captured by FLUKE IR camera and the thermographs were analyzed in the SMARTView software environments. The experimental results revealed that the homogeneous porous media, in addition to its convective heat exchange with the gas, might absorb, emit, and scatter thermal radiation. The maximum heat transfer coefficient h, of the PRB was 40 w/m2k. The rate of heat transfer was more at the center of the burner where a combined effect of both convection & radiation might be realized.
Immobilization of enzymes refers to the technique of confining/anchoring the enzymes in or on an inert support for their stability & functional reuse.
this slide is about the two most vastly used reactors i.e., batch and continuous.
5 Production Methods of Benzene cyclic hydrocarbon first isolated by Faraday a natural component of crude oil can be produced using different methods Pyrolysis gasoline, coal tar, Catalytic Reforming, Toluene hydrodealkylation, Toluene disproportionation
Benzene is an organic chemical compound with the molecular formula C6H6. Benzene is a colorless and highly flammable liquid with a sweet smell and a relatively high melting point
Equilibrium Effects
- Methane Steam
- Water Gas Shift
Relationship of Kp to Temperature
Relationship of WGS Kp to Temperature
Effect of Temperature on Methane Slip
Approach to Equilibrium
Reaction Path and Equilibrium
Effect of Pressure Increase
Operating Parameters
- Pressure
- Temperature
- Feed Rate
- Steam to Carbon
Effect of Exit Temperature Spread
Useful Tools
Calculating ATM
Thermal Power plant familarisation & its AuxillariesVaibhav Paydelwar
PPT in Relation to Power Plant familarisation, Coal to Electricity Basics,Power Plant cycles, Concepts of Supercritical Technology Boiler, Concepts Of BTG Package as well as Balance of Plant
New patented split flow technology increases the capacity of catalytic reformer heaters at a fraction of the cost of traditional revamps. Furnace Improvements has installed this technology in four reformer heaters at US refineries. This technology has also been used in several other heaters and one of the main benefits is lower pressure drop at increased capacity thus saving your pump or compressors.
2. Design Rational for PBR
Packed Bed Reactor:
• Versatile in predicting temperature progression that closely
follows real operations.
• Gases passing through packed beds approximate plug flow.
• Effective for contacting the catalyst.
• Effective when utilizing large quantities of catalyst.
• Large packed beds make effective temperature control
difficult.
• For endothermic reactions, rate always decreases with
conversion so plug flow reactors should always be used.
*Information gathered from (3)
3. Base Case
• Independent Variables:
- Inlet Pressure = 5 atm
- Inlet Temperature = 950 K
- Feed Mass Flow Rate = 10,000 lb/hr
- Inlet Steam Mass Flow Rate = 0 lb/hr
8. Base Case: Converting outlet extents of reaction from the reactor
back into molar flow rates.
9. Base Case: Pressure and temperature as they appear in the solve
block along with outlet pressure and temperature from the
reactor at given catalyst weight.
11. Base Case: Outlet temperature and pressure from the reactor
versus weight of catalyst.
12. Performance Sensitivities- Temp
• Increasing the temperature into the reactor
increases the temperature in the reactor and the
rate constants.
• Rates of reaction and extent of reaction increase
within a certain temperature range. This is what
effects the flow rates.
• Looking to optimize the profit by altering the
temperature to maximize styrene with respect to
limiting benzene and toluene.
– Unwanted reactions indicate wasted feed.
13. Influence of Temperature: T0 = 800K
Analyze Flows of Styrene (2), Hydrogen (3), Benzene (4), Ethylene (5), Toluene (6)
and methane (7) in terms of the how they balance in the profit function.
14. Influence of Temperature: T0 = 890K
(Optimum for base conditions)
Analyze Flows of Styrene (2), Hydrogen (3), Benzene (4), Ethylene (5), Toluene (6) and
methane (7) in terms of the how they balance in the profit function.
15. Influence of Temperature: T0 = 1000K
Analyze Flows of Styrene (2), Hydrogen (3), Benzene (4), Ethylene (5), Toluene (6) and
methane (7) in terms of the how they balance in the profit function.
16. Performance Sensitivities- Pressure and Feed Rate
• Lowering the pressure significantly decreases the
rates of reaction of reactions 2 and 3, decreasing
the yield of benzene (4) and toluene (6).
• With the base case conditions, 1.7 atm is the
optimum inlet pressure to minimize the deficit
(maximize styrene (2) in comparison to benzene
(4) and toluene (6)).
• Because the process is losing money in this base
case design, minimizing the feed rate will
decrease this deficit at the base inlet pressure
and temperature.
17. Influence of Pressure- P0 = 1 atm
Notice the large increase in the difference between the production of the styrene (2) and
the production of the benzene (4) and toluene (6). See how this corresponds to the
increasing profit.
18. Influence of Pressure- P0 = 1 atm (Optimum for
base conditions)
There is an even greater increase in the difference between the production of
the styrene (2) and the production of the benzene (4) and toluene (6). See how
this corresponds to the increasing profit.
19. Influence of Pressure- P0 = 3 atm
Notice the difference between the production of styrene (2) and the production
of the benzene (4) and toluene (6) has decreased from the optimized case;
however the profit is not as negative as when the pressure was set to 5 atm.
20. Base Case Stream Table
Stream ID Units Initial Conditions Feed into Reactor Outlet Conditions
Temperature Kelvin 713.15 950 874.05
Pressure atm 5 5 5
Hydrocarbon Mass Flow Total lb/hr 10000 10000
Hydrocarbon Molar Flow Total lbmol/hr 94.53 121.828
Steam Mass Flow lb/hr 0 0
Molar Flow of Components
Ethylbenzene lbmol/hr 90.47 45.159
Styrene lbmol/hr 1.631 25.681
Hydrogen lbmol/hr 0 6.039
Benzene lbmol/hr 0.256 3.507
Ethylene lbmol/hr 0 3.251
Toluene lbmol/hr 2.169 20.18
Methane lbmol/hr 0 18.011
Catalyst Weight lb 500
Profit $/hr -207.707
21. Steam Contacting Method 1:
Heat Exchanger
*The steam mass flow rate is held constant at its maximum value (18,000 lb/hr) for each trial
**Optimum pressure was found to be less than one atmosphere for each trial but the lowest
achievable pressure for this process is 1 atm. It was found that 1 atm is the optimum pressure
at each trial for this method.
22. Block Flow Diagram- PBR with Heat
Exchanger
Actual mass of the catalyst was calculated using data specific to our catalyst given in
the problem statement rather than the 500 lb given in the base case.
23. Optimization of PBR with Heat Exchanger
• Notice minimizing the pressure to 1 atm and
maximizing the temperature of the steam to 1050
K are two of the optimized conditions.
– Optimized pressure is below 1 atm.
– Lowering steam pressure increases the amount of
steam needed to be used (decreases profit).
• Lowering steam flow, at a given steam
temperature, decreases product flow rates and the
profit (for conditions below maximum steam
pressure and temperature).
• To optimize, find an inlet temperature and feed
flow rate that maximize the amount of styrene (2)
produced in comparison to benzene (4) and
toluene (6).
24. Energy Balance
• Because the steam is not being injected, it does not alter the
reaction as shown in the base case.
• Must include the energy balance as mass flow rate and
temperature of the steam affect the profit.
Note the steam leaving the heat exchanger will not reach the inlet temperature to
the reactor (T0). A factor of 10 K is added to T0 on the steam side of the energy
balance to account for this.
25. Trial 1a
*Approximate maximum profit at these conditions before exceeding maximum steam flow rate (18000 lb/hr)
0
5
10
15
20
25
30
35
870 875 880 885 890 895 900 905 910
Profit($/hr)
Inlet Temperature (K))
Profit vs Temperature @1 atm
11000 lb/hr
12000 lb/hr
13000 lb/hr
26. Trial 1b
*Approximate maximum profit at these conditions before exceeding maximum steam flow rate (18000 lb/hr)
0
5
10
15
20
25
30
35
0 2000 4000 6000 8000 10000 12000 14000 16000
Profit($/hr)
Mass Feed Rate (lb/hr)
Profit vs Feed Rate @1 atm
890 K
900 K
910 K
27. Heat Exchanger Packed Bed Stream Table
Stream ID Units Initial Conditions Feed into Reactor Outlet Conditions
Temperature Kelvin 713.15 900 810.812
Pressure atm 1 1 0.969
Hydrocarbon Mass Flow Total lb/hr 12100 12100
Hydrocarbon Molar Flow Total lbmol/hr 120.397 149.203
Steam Mass Flow lb/hr 18000 18000
Steam Temperature Kelvin 1050 1050
Molar Flow of Components
Ethylbenzene lbmol/hr 115.231 77.789
Styrene lbmol/hr 2.078 30.25
Hydrogen lbmol/hr 0 19.536
Benzene lbmol/hr 0.326 0.96
Ethylene lbmol/hr 0 0.634
Toluene lbmol/hr 2.763 11.399
Methane lbmol/hr 0 8.636
Catalyst Weight lb 13580
Profit $/hr 34.167
28. Steam Contacting Method 2:
Direct Injection
*The steam mass flow rate is held constant at its maximum value (18,000
lb/hr) for each trial
30. Optimization of PBR with Direct Injection
• Maximizing the steam flow rate and the steam
temperature again maximizes the difference in
wanted vs unwanted products.
– Optimized pressure is not below 1 atm.
• Inlet pressure and temperature into the reactor,
as well as the feed flow rate are to be optimized
to obtain the maximum pressure.
• Optimized profit of $370.94 $/hr is greater than
the profit of $34.17 $/hr using a heat exchanger.
31. Adjustments from Base Case
Alters the total output flow within the rate
of reaction equations
Alters the total value of the flow* heat
capacities, used in the temperature
equation of the ODE solve block- same
equation as the base.
32. Energy Balance
Note the temperature of the steam reaches that of the feed upon heating because
of the direct injection. Steam flow rate and steam temperature are within the
profit function:
33. Trial 1a
*950 K Data omitted for exceeding maximum steam temperature (1050 K)
310
315
320
325
330
335
340
345
350
355
3 4 5 6
Profit($/hr)
Inlet Pressure (atm)
Profit vs Pressure @7000 lb/hr
930 K
940 K
34. Trial 2a
*950 K Data omitted for exceeding maximum steam temperature (1050 K)
**All data for Trial 3a was omitted for exceeding maximum steam temperature (1050 K)
340
341
342
343
344
345
346
347
348
3 4 5 6
Profit($/hr)
Inlet Pressure (atm)
Profit vs Pressure @8000 lb/hr
930 K
35. Trial 1b
*Approximate maximum profit at these conditions before exceeding maximum steam temperature (1050 K)
315
320
325
330
335
340
345
350
355
360
365
370
928 930 932 934 936 938 940 942 944 946
Profit($/hr)
Inlet Temperature (K))
Profit vs Temperature @7000 lb/hr
4.2 atm
4.4 atm
4.6 atm
36. Trial 2b
*Approximate maximum profit at these conditions before exceeding maximum steam temperature (1050 K)
340
345
350
355
360
365
370
375
929 930 931 932 933 934 935 936 937 938
Profit($/hr)
Inlet Temperature (K)
Profit vs Temperature @8000 lb/hr
4.2 atm
4.4 atm
4.6 atm
37. Trial 3b
*Approximate maximum profit at these conditions before exceeding maximum steam temperature (1050 K)
325
330
335
340
345
350
355
360
919 920 921 922 923 924 925 926 927 928
Profit($/hr)
Inlet Temperature (K)
Profit vs Temperature @9000 lb/hr
4.2 atm
4.4 atm
4.6 atm
38. Trial 1c
*Approximate maximum profit at these conditions before exceeding maximum steam temperature (1050 K)
342
344
346
348
350
352
354
356
358
360
362
7900 8000 8100 8200 8300 8400 8500 8600 8700 8800
Profit($/hr)
Mass Feed Rate (lb/hr)
Profit vs Feed Rate @930 K
4.2 atm
4.4 atm
4.6 atm
39. Trial 2c
*Approximate maximum profit at these conditions before exceeding maximum steam temperature (1050 K)
345
350
355
360
365
370
375
6900 7000 7100 7200 7300 7400 7500 7600 7700 7800
Profit($/hr)
Mass Feed Rate (lb/hr)
Profit vs Feed Rate @940 K
4.2 atm
4.4 atm
4.6 atm
40. Trial 3c
*Approximate maximum profit at these conditions before exceeding maximum steam temperature (1050 K)
340
345
350
355
360
365
370
375
5900 6000 6100 6200 6300 6400 6500 6600 6700 6800
Profit($/hr)
Mass Feed Rate (lb/hr
Profit vs Feed Rate @950 K
4.2 atm
4.4 atm
4.6 atm
41. Direct Injection Packed Bed Stream Table
Stream ID Units Initial Conditions Feed into Reactor Outlet Conditions
Temperature Kelvin 713.15 940 879
Pressure atm 4.5 4.5 4.455
Hydrocarbon Mass Flow Total lb/hr 7770 7770
Hydrocarbon Molar Flow Total lbmol/hr 77.313 111.722
Steam Mass Flow lb/hr 18000 18000
Steam Temperature Kelvin 1050 1050
Molar Flow of Components
Ethylbenzene lbmol/hr 73.995 34.794
Styrene lbmol/hr 1.334 33.97
Hydrogen lbmol/hr 0 27.844
Benzene lbmol/hr 0.209 1.983
Ethylene lbmol/hr 0 1.773
Toluene lbmol/hr 1.774 6.567
Methane lbmol/hr 0 4.792
Catalyst Weight lb 13580
Profit $/hr 370.937
42. Alternative Design Rational- Adiabatic
FBR Modeled as a CSTR
Fluidized Bed Reactor:
• Does not resemble a plug flow reactor and is
modeled as CSTR.
• Requires more catalyst than a packed bed for
the same conversion.
• Effective in controlling temperature when
operating in a narrow temperature range.
• Effective when utilizing small quantities of
catalyst.
43. Adjustments of FBR from PBR
Adjustments are due to the differences
between energy balances of a PFR and a
mixed flow. In this case we are modeling
an adiabatic FRB as a CSTR.
Mixed Flow Energy Balance:
44. FBR Modeled as CSTR ODE Solver
Note the lack of pressure drop as it is adiabatic
45. Steam Contacting Method 3: Heat
Exchanger Adiabatic Fluidized Bed
Modeled as a CSTR
*The steam mass flow rate is held constant at its maximum value
(18,000 lb/hr) for each trial
**Optimum pressure was found to be less than one atmosphere for each
trial but the lowest achievable pressure for this process is 1 atm. It was
found that 1 atm is the optimum pressure at each trial for this method.
46. Optimization of FBR- Heat Exchanger
• Notice minimizing the pressure to 1 atm and maximizing
the temperature of the steam to 1050 K are two of the
optimized conditions.
– Optimized pressure is below 1 atm.
– Lowering steam pressure increases the amount of steam
needed to be used (decreases profit).
• Although there is a negative profit, data indicates that
there are conditions of inlet pressure and temperature
and a mass flow rate that minimize the deficit, aside
extremely low values of mass flow rate.
• As the mass flow rate approaches zero, the reaction does
not take place, and the deficit decreases.
– Not a profitable model.
47. Trial 1a
*Values at 6000 lb/hr & 960 K and 7000 lb/hr 950 & 960 K the maximum steam temperature (1050 K) was exceeded so
the data were omitted
**Further optimization of this reactor was deemed unnecessary as all independent variable combinations were
resulting in negative profits
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
935 940 945 950 955 960 965
Profit($/hr)
Inlet Temperature (K))
Profit vs Temperature @1 atm
5000 lb/hr
6000 lb/hr
7000 lb/hr
48. Alt Design Heat Exchanger Fluidized Bed Stream Table
Stream ID Units Initial Conditions Feed into Reactor Outlet Conditions
Temperature Kelvin 713.15 940 861.523
Pressure atm 1 1 1
Hydrocarbon Mass Flow Total lb/hr 7000 7000
Hydrocarbon Molar Flow Total lbmol/hr 69.651 91.865
Steam Mass Flow lb/hr 18000 18000
Steam Temperature Kelvin 1050 1050
Molar Flow of Components
Ethylbenzene lbmol/hr 66.662 34.305
Styrene lbmol/hr 1.202 22.651
Hydrogen lbmol/hr 0 11.305
Benzene lbmol/hr 0.189 0.954
Ethylene lbmol/hr 0 0.765
Toluene lbmol/hr 1.598 11.742
Methane lbmol/hr 0 10.143
Catalyst Weight lb 13580
Profit $/hr -21.411
49. Steam Contacting Method 4: Direct
Injection Adiabatic Fluidized Bed
Modeled as a CSTR
*The steam mass flow rate is held constant at its maximum value (18,000
lb/hr) for each trial
50. Optimization of FBR- Direct Injection
• Just as is the case for the direct injection of
steam with the PBR, maximizing steam flow
rate and temperature maximizes the difference
in wanted vs unwanted products.
– Optimized pressure is not below 1 atm.
• Inlet pressure and temperature into the
reactor, as well as the feed flow rate are to be
optimized to obtain the maximum pressure.
• Optimized profit of $156.04 is less than the
optimized profit of $370.94 for the direct
injection into the PBR.
51. Trial 1a
*980 K Data omitted for exceeding maximum steam temperature (1050 K)
132
134
136
138
140
142
144
146
148
150
3 4 5 6
Profit($/hr)
Inlet Pressure (atm)
Profit vs Pressure @4500 lb/hr
960 K
970 K
52. Trial 2a
*970 & 980 K Data omitted for exceeding maximum steam temperature (1050 K)
142.8
143
143.2
143.4
143.6
143.8
144
144.2
144.4
144.6
3.9 4 4.1 4.2 4.3 4.4 4.5 4.6 4.7 4.8 4.9
Profit($/hr)
Inlet Pressure (atm)
Profit vs Pressure @5000 lb/hr
960 K
53. Trial 3a
*970 & 980 K Data omitted for exceeding maximum steam temperature (1050 K)
149.2
149.4
149.6
149.8
150
150.2
150.4
150.6
150.8
151
3.9 4 4.1 4.2 4.3 4.4 4.5 4.6 4.7 4.8 4.9
Profit($/hr)
Inlet Pressure (atm)
Profit vs Pressure @5500 lb/hr
960 K
54. Trial 1b
*Approximate maximum profit at these conditions before exceeding maximum steam temperature (1050 K)
140
142
144
146
148
150
152
154
156
964 966 968 970 972 974 976
Profit($/hr)
Inlet Temperature (K))
Profit vs Temperature @4500 lb/hr
4 atm
4.2 atm
4.4 atm
55. Trial 2b
*Approximate maximum profit at these conditions before exceeding maximum steam temperature (1050 K)
134
136
138
140
142
144
146
148
150
152
954 956 958 960 962 964 966
Profit($/hr)
Inlet Temperature (K)
Profit vs Temperature @5000 lb/hr
4 atm
4.2 atm
4.4 atm
56. Trial 3b
*Approximate maximum profit at these conditions before exceeding maximum steam temperature (1050 K)
125
130
135
140
145
150
155
944 946 948 950 952 954 956 958 960 962
Profit($/hr)
Inlet Temperature (K)
Profit vs Temperature @5500 lb/hr
4 atm
4.2 atm
4.4 atm
57. Trial 1c
*Approximate maximum profit at these conditions before exceeding maximum steam temperature (1050 K)
132
134
136
138
140
142
144
146
148
150
152
4000 4200 4400 4600 4800 5000 5200 5400 5600
Profit($/hr)
Mass Feed Rate (lb/hr)
Profit vs Feed Rate @960 K
4 atm
4.2 atm
4.4 atm
58. Trial 2c
*Approximate maximum profit at these conditions before exceeding maximum steam temperature (1050 K)
100
110
120
130
140
150
160
3000 3200 3400 3600 3800 4000 4200 4400 4600
Profit($/hr)
Mass Feed Rate (lb/hr)
Profit vs Feed Rate @970 K
4 atm
4.2 atm
4.4 atm
59. Trial 3c
*Approximate maximum profit at these conditions before exceeding maximum steam temperature (1050 K)
100
105
110
115
120
125
130
135
140
145
150
2500 2700 2900 3100 3300 3500 3700 3900 4100
Profit($/hr)
Mass Feed Rate (lb/hr
Profit vs Feed Rate @980 K
4 atm
4.2 atm
4.4 atm
60. Alt Design Direct Injection Fluidized Bed Stream Table
Stream ID Units Initial Conditions Feed into Reactor Outlet Conditions
Temperature Kelvin 713.15 967 879
Pressure atm 4.3 4.3 4.455
Hydrocarbon Mass Flow Total lb/hr 5200 7770
Hydrocarbon Molar Flow Total lbmol/hr 51.741 134.595
Steam Mass Flow lb/hr 18000 18000
Steam Temperature Kelvin 1050 1050
Molar Flow of Components
Ethylbenzene lbmol/hr 49.521 26.797
Styrene lbmol/hr 0.893 19.81
Hydrogen lbmol/hr 0 16.122
Benzene lbmol/hr 0.14 1.152
Ethylene lbmol/hr 0 1.012
Toluene lbmol/hr 1.187 3.982
Methane lbmol/hr 0 2.795
Catalyst Weight lb 13580
Profit $/hr 156.036
61. Analysis of Rates of Reactions and Production of All Reactors
PBR FBR PBR FBR
Rate of RXN 1 (lbmol/ lb*hr) 7.882*10^-4 0.001 3.459*10^-4 0.002
Rate of RXN 2 (lbmol/ lb*hr) 3.692*10^-5 7.45*10^-5 1.131*10^-5 5.635*10^-5
Rate of RXN 3 (lbmol/ lb*hr) 3.022*10^-4 2.058*10^-4 4.498*10^-4 7.469*10^-4
Flow of Styrene Out (lbmol/ hr) 33.97 19.81 30.25 22.651
Flow of Benzene Out (lbmol/hr) 1.983 1.152 0.96 0.954
Flow of Toluene Out (lbmol/hr) 6.567 3.982 11.399 11.742
Feed Rate (lb/hr) 7770 5200 12100 7000
Percent Diff Styrene vs sum of
unwanted compounds 74.83% 74.08% 59.14% 43.95%
Direct Injection of Steam Heat Exchanger
The PBR with direct injection of steam is the most profitable reactor. It has very low reaction rates
for 2 and 3, and the largest percent difference between producing desired styrene and unwanted
toluene and benzene. The FBR with the direct injection of steam produces the least amount of
benzene and toluene collectively; however, the PBR has a higher profit due to the larger amount of
styrene being made (mass feed rate is 33% greater). The PBR using a heat exchanger is able to
operate at a high flow rate, but it produces a large amount of toluene, decreasing the profit. As
seen on the chart, the FBR utilizing a heat exchanger has a very poor percent difference between
styrene and the two main unwanted products without an exceptionally large feed rate.
62. Evaluation of Adiabatic FBR to PBR
As can be seen from the conversions of Ethylbenzene for the four cases, a high conversion of
this reactant does not necessarily coordinate to a higher profit. The importance lies in how
much of the desired products are formed from the ethylbenzene.
• Conversion of Ethylbenzene
63. Appendix
• Thermodynamic Equilibrium
This graph compares the equilibrium constant given in the
problem statement to the general equilibrium constant equation
versus temperature. It is clear that both of these methods yield
similar results because their data overlaps one another.
64. References
(1) Levine, Ira N. "Atomic Weights." Physical
Chemistry. 6th ed. New York: McGraw-Hill,
1978. 990-91. Print.
(2) Yaws, Carl L. Chemical Properties Handbook.
N.p.: n.p., n.d. - Access Engineering from
McGraw-Hill. Web.
(3) Levenspiel, Octave. Chemical Reaction
Engineering. 3rd ed. New York: Wiley, 1972.
Print.