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MEMBRANE
DISTILLATION
Submitted to- Submitted by-
Dr. Brishti Mitra Km. Deeksha Jaiswal
H.O.D. Chemical Engineering CSJMA14001390202
CONTENT
• Introduction
• History
• Principle
• Types of membrane distillation
• Membrane module, material & characteristics
• Heat and mass transfer
• Advantages and disadvantages
• Application
• References
1
INTRODUCTION
2
HISTORY
• There was first proposal is given in Athens
(Greece) for pure water from sea in
May 1967
• In 1974 scientist Rodgers presented a method of desalination
• In India it is still on research in B.A.R.C
3
PRINCIPLE
4
TYPES OF MEMBRANE DISTILLATION
5
MEMBRANE MODULE
Flat sheet membrane Hollow fiber Membrane
6
MEMBRANE MATERIAL
S.No Name Of
Material
1 POLY TETRA -
FLUROETHYLEN
E
2 POLYPROYLENE
3 POLYVINYLIDEN
-EFLURIDE
SURFACE
TENSION
(Dynes/cm)
CONTACT
ANGLE
(Degree)
19 123
29 100
25 111
7
HEAT & MASS TRANSFER IN M.D
• Heat transfer through feed side boundary layer
Qf = hf(Tf – T1)
• Heat transfer through the membrane
Qm = hm(T1 – T2)+Jw*∆Hv
• Heat transfer through the permeate side
Qp = hp(T2 – Tp)
MEMBRANEHot fluid
Cold permeate
8
Tf
T1
T2
Tp
MASS TRANSFER
Hot fluid Cold permeate
9
By Stephan’s law
Jv = K∆Pv
Jv = vapor flux across the membrane
K = permeability of membrane
∆Pv = (PT1 - PT2) vapor pressure difference
MEMBRANE
PT1
PT2
• The membrane permeability K can be calculated by
K =
k = partition coefficient of membrane
D = diffusion coefficient
∆x = thickness of membrane
• PT1 and PT2 can be calculated by Antoine equation –
log10 P = A – B/C + T
where p is the vapor pressure,
T is temperature
A,B and C are constants
11
∆xkD/
• Advantages
 Membrane distillation has high rejection factor of waste
 It has low energy cost
• Disadvantages
 Membrane distillation gives low permeate flux
11
APPLICATION
• Water purification
• Food industry
12
CONCLUSION
• Membrane distillation is known since 1970 and is still being
developed at laboratory stage for different purposes and not
fully execution in industry
• It has advantages like lower operating pressure and
temperature but its time taking process can not be neglected
13
REFERENCES
• Sina Zereshki (2012), Membrane
Distillation:principle, application and future aspects,
Distillation- Advances from modelling to application,
232-257
• http://en.m.wikipedia.org/wiki/membrane-
distillation
• Separatioprocesses.com/membrane-distillation
• blog.innovation4e.de.en/2016/10/14iinovative-
methods-for-water-treatment
• http:/advanceseseng.com/chemical-
engineering/desalination-across-membrane-
distillation 14
THANK YOU
15

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Deeksha membrane distillation

  • 1. MEMBRANE DISTILLATION Submitted to- Submitted by- Dr. Brishti Mitra Km. Deeksha Jaiswal H.O.D. Chemical Engineering CSJMA14001390202
  • 2. CONTENT • Introduction • History • Principle • Types of membrane distillation • Membrane module, material & characteristics • Heat and mass transfer • Advantages and disadvantages • Application • References 1
  • 4. HISTORY • There was first proposal is given in Athens (Greece) for pure water from sea in May 1967 • In 1974 scientist Rodgers presented a method of desalination • In India it is still on research in B.A.R.C 3
  • 6. TYPES OF MEMBRANE DISTILLATION 5
  • 7. MEMBRANE MODULE Flat sheet membrane Hollow fiber Membrane 6
  • 8. MEMBRANE MATERIAL S.No Name Of Material 1 POLY TETRA - FLUROETHYLEN E 2 POLYPROYLENE 3 POLYVINYLIDEN -EFLURIDE SURFACE TENSION (Dynes/cm) CONTACT ANGLE (Degree) 19 123 29 100 25 111 7
  • 9. HEAT & MASS TRANSFER IN M.D • Heat transfer through feed side boundary layer Qf = hf(Tf – T1) • Heat transfer through the membrane Qm = hm(T1 – T2)+Jw*∆Hv • Heat transfer through the permeate side Qp = hp(T2 – Tp) MEMBRANEHot fluid Cold permeate 8 Tf T1 T2 Tp
  • 10. MASS TRANSFER Hot fluid Cold permeate 9 By Stephan’s law Jv = K∆Pv Jv = vapor flux across the membrane K = permeability of membrane ∆Pv = (PT1 - PT2) vapor pressure difference MEMBRANE PT1 PT2
  • 11. • The membrane permeability K can be calculated by K = k = partition coefficient of membrane D = diffusion coefficient ∆x = thickness of membrane • PT1 and PT2 can be calculated by Antoine equation – log10 P = A – B/C + T where p is the vapor pressure, T is temperature A,B and C are constants 11 ∆xkD/
  • 12. • Advantages  Membrane distillation has high rejection factor of waste  It has low energy cost • Disadvantages  Membrane distillation gives low permeate flux 11
  • 14. CONCLUSION • Membrane distillation is known since 1970 and is still being developed at laboratory stage for different purposes and not fully execution in industry • It has advantages like lower operating pressure and temperature but its time taking process can not be neglected 13
  • 15. REFERENCES • Sina Zereshki (2012), Membrane Distillation:principle, application and future aspects, Distillation- Advances from modelling to application, 232-257 • http://en.m.wikipedia.org/wiki/membrane- distillation • Separatioprocesses.com/membrane-distillation • blog.innovation4e.de.en/2016/10/14iinovative- methods-for-water-treatment • http:/advanceseseng.com/chemical- engineering/desalination-across-membrane- distillation 14