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Wastewater Treatment Using Novel
Impregnated Membranes in
Forward Osmosis
CE 498 Undergraduate Research
Ananthan Balachandran
May 8th, 2015
Presentation Outline
• Objective
• Introduction of forward osmosis in wastewater treatment
• Type of membranes
• TFC membrane, SW30 XLE membrane & impregnated
membrane
• Structure difference of membranes
• Research apparatus of forward osmosis
• Result
• Data for commercial membrane
• Data comparison
• Discussion
• Conclusion
1
Objective
• Currently, the commercial membrane structure is
thin film composite membrane which has larger
water transport resistance because of the thickness.
• To determine whether the impregnated membranes
are suitable for the wastewater treatment using
forward osmosis.
• To determine the water flux and salt rejection of
the impregnated membranes in forward osmosis.
2
Introduction
• Water becoming an scarce resource due to population growth &
economic development
• Lack access to clean water
• Methods of water filtration & purification
• Forward osmosis.
• Forward osmosis uses a semi-permeable membranes to get portable
water from the seawater.
• The driving force of forward osmosis is osmotic pressure difference
between draw & feed solutions.
3
Figure 2:
Forward
osmosis
process
Figure 1:
Water
Filtration
APEC Water System. (2013). A Complete Resource Guide on Osmosis. Retrieved from Free Drinking Water: http://www.freedrinkingwater.com/resource-a-complete-resource-guide-to-osmosis.htm
Types of membranes used in Forward
Osmosis
4
Figure 3: TFC membrane
(Commercial Membrane)
Figure 5: Impregnated
Membrane
Figure 4: SW30 XLE membrane
Reverse Osmosis Membrane
Thickness of the impregnated membrane & commercial
membrane
a) Impregnated membrane
b) Commercial membrane
5
Research apparatus for forward osmosis
B
DE
A
C
Figure 6: Schematic of forward osmosis membrane test apparatus
6
Coat the polymer on both side of the support, using ethyl alcohol as the solvent
Method to prepare impregnated membrane
7
Result
Total Time (min) Salt Rejection (%) Water Flux (LMH) Salt Flux (gMH)
50 98.6 10.71 7.93
60 98.7 11.57 7.84
95 99.0 11.14 5.85
130 98.9 11.27 5.86
Theoretical Flux : 75.5 LMH
Experimental Flux : 11.1 LMH
Performance Ratio : 0.15
TFC Membrane from HTI ( Commercial Membrane)
Table 1: Data of TFC Membrane in Forward Osmosis
8
Result
Type of membranes
Water Flux
(LMH/bar)
Expected Water
Flux (LMH/bar)
Salty Water Flux
(LMH/bar)
Performance Ratio Salt Rejection (%)
TFC 0.23 1.54 N/A 0.15 98.9
SW30 XLE 0.05 1.47 N/A 0.04 99.0
80 PEGDA 20
Ethanol
0.05 0.28 0.23 0.23 95.3
60 PEGDA 40
Ethanol
0.08 0.41 0.31 0.25 96.8
Comparison Between The Membranes
Table 2: Data comparison between commercial membrane, RO membrane and
impregnated membrane
9
Discussion
• Water flux & salt flux in impregnated membrane is
lower because of concentration polarization.
-decrease the driving force
• The absolute water flux of impregnated membrane
is lower than the commercial membrane.
10
Conclusion
• Impregnated membrane has higher performance
ratio and acceptable salt rejection although water
flux is lower
• The novel impregnated membrane has higher
efficient in forward osmosis in wastewater
treatment
11
Questions?

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Novel Impregnated Membranes for Wastewater Treatment in Forward Osmosis

  • 1. Wastewater Treatment Using Novel Impregnated Membranes in Forward Osmosis CE 498 Undergraduate Research Ananthan Balachandran May 8th, 2015
  • 2. Presentation Outline • Objective • Introduction of forward osmosis in wastewater treatment • Type of membranes • TFC membrane, SW30 XLE membrane & impregnated membrane • Structure difference of membranes • Research apparatus of forward osmosis • Result • Data for commercial membrane • Data comparison • Discussion • Conclusion 1
  • 3. Objective • Currently, the commercial membrane structure is thin film composite membrane which has larger water transport resistance because of the thickness. • To determine whether the impregnated membranes are suitable for the wastewater treatment using forward osmosis. • To determine the water flux and salt rejection of the impregnated membranes in forward osmosis. 2
  • 4. Introduction • Water becoming an scarce resource due to population growth & economic development • Lack access to clean water • Methods of water filtration & purification • Forward osmosis. • Forward osmosis uses a semi-permeable membranes to get portable water from the seawater. • The driving force of forward osmosis is osmotic pressure difference between draw & feed solutions. 3 Figure 2: Forward osmosis process Figure 1: Water Filtration APEC Water System. (2013). A Complete Resource Guide on Osmosis. Retrieved from Free Drinking Water: http://www.freedrinkingwater.com/resource-a-complete-resource-guide-to-osmosis.htm
  • 5. Types of membranes used in Forward Osmosis 4 Figure 3: TFC membrane (Commercial Membrane) Figure 5: Impregnated Membrane Figure 4: SW30 XLE membrane Reverse Osmosis Membrane
  • 6. Thickness of the impregnated membrane & commercial membrane a) Impregnated membrane b) Commercial membrane 5
  • 7. Research apparatus for forward osmosis B DE A C Figure 6: Schematic of forward osmosis membrane test apparatus 6
  • 8. Coat the polymer on both side of the support, using ethyl alcohol as the solvent Method to prepare impregnated membrane 7
  • 9. Result Total Time (min) Salt Rejection (%) Water Flux (LMH) Salt Flux (gMH) 50 98.6 10.71 7.93 60 98.7 11.57 7.84 95 99.0 11.14 5.85 130 98.9 11.27 5.86 Theoretical Flux : 75.5 LMH Experimental Flux : 11.1 LMH Performance Ratio : 0.15 TFC Membrane from HTI ( Commercial Membrane) Table 1: Data of TFC Membrane in Forward Osmosis 8
  • 10. Result Type of membranes Water Flux (LMH/bar) Expected Water Flux (LMH/bar) Salty Water Flux (LMH/bar) Performance Ratio Salt Rejection (%) TFC 0.23 1.54 N/A 0.15 98.9 SW30 XLE 0.05 1.47 N/A 0.04 99.0 80 PEGDA 20 Ethanol 0.05 0.28 0.23 0.23 95.3 60 PEGDA 40 Ethanol 0.08 0.41 0.31 0.25 96.8 Comparison Between The Membranes Table 2: Data comparison between commercial membrane, RO membrane and impregnated membrane 9
  • 11. Discussion • Water flux & salt flux in impregnated membrane is lower because of concentration polarization. -decrease the driving force • The absolute water flux of impregnated membrane is lower than the commercial membrane. 10
  • 12. Conclusion • Impregnated membrane has higher performance ratio and acceptable salt rejection although water flux is lower • The novel impregnated membrane has higher efficient in forward osmosis in wastewater treatment 11