Crystal field theory
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Hi guys !!!!! This is a presentation on the crystal field theory.Here you can find the complete information regarding the CFT . If you have any doubts regarding the crystal field theory feel free to ask in the comments section. THANK YOU!!!!
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1. pdf file on Termmate: https://www.termmate.com/rabia.aziz
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3. Facebook: https://web.facebook.com/Chemist.Rabia.Aziz/
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particular optical spectra (colours). CFT successfully accounts for some magnetic properties,
colours, hydration enthalpies, and spinel structures of transition metal complexes, but it does not
attempt to describe bonding. CFT was developed by physicists Hans Bethe and John Hasbrouck
van Vleck[1] in the 1930s. CFT was subsequently combined with molecular orbital theory to
form the more realistic and complex ligand field theory (LFT), which delivers insight into the
process of chemical bonding in transition metal complexes. In chemistry, valence bond (VB)
theory is one of two basic theories, along with molecular orbital (MO) theory, that were
developed to use the methods of quantum mechanics to explain chemical bonding. It focuses on
how the atomic orbitals of the dissociated atoms combine to give individual chemical bonds
when a molecule is formed. In contrast, molecular orbital theory has orbitals that cover the whole
molecule.
Solution
The term Lewis acid refers to a definition of acid published by Gilbert N. Lewis in
1923, specifically: An acid substance is one which can employ an electron lone pair from another
molecule in completing the stable group of one of its own atoms.[1] Thus, H+ is a Lewis acid,
since it can accept a lone pair, completing its stable form, which requires two electrons. The
modern-day definition of Lewis acid, as given by IUPAC is a molecular entity (and the
corresponding chemical species) that is an electron-pair acceptor and therefore able to react with
a Lewis base to form a Lewis adduct, by sharing the electron pair furnished by the Lewis
base.[2] This definition is both more general and more specific—the electron pair need not be a
lone pair (it could be the pair of electrons in a p bond, for example.
Metals, semiconductors and semiconductors
The document discusses the properties of metals and their crystalline structure. It begins by explaining that metals have a closely packed crystalline structure, usually face centered cubic, body centered cubic, or hexagonal close packed. This gives metals their high conductivity of heat and electricity as well as their malleability, ductility, and high melting and boiling points. Metals also have metallic luster and can emit electrons through thermionic or photoemissive processes due to their mobile electrons.
Chemical bonding
The document summarizes different types of chemical bonds including ionic bonds, covalent bonds, metallic bonds, hydrogen bonds, and Van der Waals interactions. It describes how each type of bond forms and provides examples. Ionic bonds form through electrostatic attraction between oppositely charged ions. Covalent bonds form when atoms share one or more pairs of electrons. Metallic bonds result from delocalized electrons within metal structures. Hydrogen bonds are electrostatic attractions between hydrogen and electronegative atoms. Van der Waals interactions arise from correlations in polarizations between particles.
BONDING.pptx
The atomic mass of an element can vary because the number of neutrons in the nucleus may be variable, even though the number of protons remains the same for a given element. There are four main types of atomic bonding - ionic, covalent, metallic, and van der Waals - which determine key material properties like hardness, melting point, and whether a material is a metal, polymer, or ceramic based on electron configuration and bonding forces between atoms. These bonding types arise from atoms seeking stable electron configurations through gaining, losing, or sharing valence electrons.
Similar to Crystal field theory (20)
محاضراتكيمياء-تناسقية-المرحلة-الثالثة-فصل-اول.pptx
محاضراتكيمياء-تناسقية-المرحلة-الثالثة-فصل-اول.pptx
Coordination Chemistry, Fundamental Concepts and Theories
Coordination Chemistry, Fundamental Concepts and Theories
Inorganic Chemistry : Periodic Table (Periodicity)
Inorganic Chemistry : Periodic Table (Periodicity)
The term Lewis acid refers to a definition of aci.pdf
The term Lewis acid refers to a definition of aci.pdf
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Electronic stability control
Electronic stability control (ESC) uses sensors to detect loss of control and applies brakes to individual wheels to help drivers maintain control and bring the vehicle back on the intended path. ESC was first introduced by BMW in 1980 and later adopted by other manufacturers. It uses wheel speed, vehicle speed, steering wheel angle, and yaw rate sensors along with brake force controllers and a master cylinder to stabilize the vehicle. Studies show ESC can prevent about one-third of fatal accidents.
Cs lab ppt academic freedom
The document discusses the concept of academic freedom. It defines academic freedom as the freedom of teachers, students, and institutions to pursue knowledge without unreasonable interference. It notes that academic freedom is not unlimited and is still subject to general laws. Teachers have more freedom within their disciplines, and students and teachers gain more freedom as they progress in their education. The document also discusses the 1940 Statement on Principles of Academic Freedom and Tenure by the American Association of University Professors, which aims to protect academic freedom. It notes that while academic freedom is important to allow the open pursuit of knowledge, institutions still have authority over determining educational policies and standards.
Time travel
Hi guys!!!
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A proprietary approach developed by bringing together the best of learning theories from Psychology, design principles from the world of visualization, and pedagogical methods from over a decade of training experience, that enables you to: Learn better, faster!
Authoring a personal GPT for your research and practice: How we created the Q...
Thematic analysis in qualitative research is a time-consuming and systematic task, typically done using teams. Team members must ground their activities on common understandings of the major concepts underlying the thematic analysis, and define criteria for its development. However, conceptual misunderstandings, equivocations, and lack of adherence to criteria are challenges to the quality and speed of this process. Given the distributed and uncertain nature of this process, we wondered if the tasks in thematic analysis could be supported by readily available artificial intelligence chatbots. Our early efforts point to potential benefits: not just saving time in the coding process but better adherence to criteria and grounding, by increasing triangulation between humans and artificial intelligence. This tutorial will provide a description and demonstration of the process we followed, as two academic researchers, to develop a custom ChatGPT to assist with qualitative coding in the thematic data analysis process of immersive learning accounts in a survey of the academic literature: QUAL-E Immersive Learning Thematic Analysis Helper. In the hands-on time, participants will try out QUAL-E and develop their ideas for their own qualitative coding ChatGPT. Participants that have the paid ChatGPT Plus subscription can create a draft of their assistants. The organizers will provide course materials and slide deck that participants will be able to utilize to continue development of their custom GPT. The paid subscription to ChatGPT Plus is not required to participate in this workshop, just for trying out personal GPTs during it.
EWOCS-I: The catalog of X-ray sources in Westerlund 1 from the Extended Weste...
Context. With a mass exceeding several 104 M⊙ and a rich and dense population of massive stars, supermassive young star clusters
represent the most massive star-forming environment that is dominated by the feedback from massive stars and gravitational interactions
among stars.
Aims. In this paper we present the Extended Westerlund 1 and 2 Open Clusters Survey (EWOCS) project, which aims to investigate
the influence of the starburst environment on the formation of stars and planets, and on the evolution of both low and high mass stars.
The primary targets of this project are Westerlund 1 and 2, the closest supermassive star clusters to the Sun.
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s
−1
. The X-ray sources exhibit a highly concentrated spatial distribution,
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The debris of the ‘last major merger’ is dynamically young
The Milky Way’s (MW) inner stellar halo contains an [Fe/H]-rich component with highly eccentric orbits, often referred to as the
‘last major merger.’ Hypotheses for the origin of this component include Gaia-Sausage/Enceladus (GSE), where the progenitor
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measurement of phase mixing (2D causticality). The observed local phase-space distribution best matches the simulated data
1–2 Gyr after collision, and certainly not later than 3 Gyr. This is further evidence that the progenitor of the ‘last major merger’
did not collide with the MW proto-disc at early times, as is thought for the GSE, but instead collided with the MW disc within
the last few Gyr, consistent with the body of work surrounding the VRM.
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Micronuclei test.M.sc.zoology.fisheries.
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快速办理(UAM毕业证书)马德里自治大学毕业证学位证一模一样
学校原件一模一样【微信：741003700 】《(UAM毕业证书)马德里自治大学毕业证学位证》【微信：741003700 】学位证，留信认证（真实可查，永久存档）原件一模一样纸张工艺/offer、雅思、外壳等材料/诚信可靠,可直接看成品样本，帮您解决无法毕业带来的各种难题！外壳，原版制作，诚信可靠，可直接看成品样本。行业标杆！精益求精，诚心合作，真诚制作！多年品质 ,按需精细制作，24小时接单,全套进口原装设备。十五年致力于帮助留学生解决难题，包您满意。
本公司拥有海外各大学样板无数，能完美还原。
1:1完美还原海外各大学毕业材料上的工艺：水印，阴影底纹，钢印LOGO烫金烫银，LOGO烫金烫银复合重叠。文字图案浮雕、激光镭射、紫外荧光、温感、复印防伪等防伪工艺。材料咨询办理、认证咨询办理请加学历顾问Q/微741003700
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一.毕业证【q微741003700】成绩单、使馆认证、教育部认证、雅思托福成绩单、学生卡等！
二.真实使馆公证(即留学回国人员证明,不成功不收费)
三.真实教育部学历学位认证（教育部存档！教育部留服网站永久可查）
四.办理各国各大学文凭(一对一专业服务,可全程监控跟踪进度)
如果您处于以下几种情况：
◇在校期间，因各种原因未能顺利毕业……拿不到官方毕业证【q/微741003700】
◇面对父母的压力，希望尽快拿到；
◇不清楚认证流程以及材料该如何准备；
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◇企事业单位必须要求办理的
◇需要报考公务员、购买免税车、落转户口
◇申请留学生创业基金
留信网认证的作用:
1:该专业认证可证明留学生真实身份
2:同时对留学生所学专业登记给予评定
3:国家专业人才认证中心颁发入库证书
4:这个认证书并且可以归档倒地方
5:凡事获得留信网入网的信息将会逐步更新到个人身份内，将在公安局网内查询个人身份证信息后，同步读取人才网入库信息
6:个人职称评审加20分
7:个人信誉贷款加10分
8:在国家人才网主办的国家网络招聘大会中纳入资料，供国家高端企业选择人才
Immersive Learning That Works: Research Grounding and Paths Forward
We will metaverse into the essence of immersive learning, into its three dimensions and conceptual models. This approach encompasses elements from teaching methodologies to social involvement, through organizational concerns and technologies. Challenging the perception of learning as knowledge transfer, we introduce a 'Uses, Practices & Strategies' model operationalized by the 'Immersive Learning Brain' and ‘Immersion Cube’ frameworks. This approach offers a comprehensive guide through the intricacies of immersive educational experiences and spotlighting research frontiers, along the immersion dimensions of system, narrative, and agency. Our discourse extends to stakeholders beyond the academic sphere, addressing the interests of technologists, instructional designers, and policymakers. We span various contexts, from formal education to organizational transformation to the new horizon of an AI-pervasive society. This keynote aims to unite the iLRN community in a collaborative journey towards a future where immersive learning research and practice coalesce, paving the way for innovative educational research and practice landscapes.
Gadgets for management of stored product pests_Dr.UPR.pdf
Insectsplayamajorroleinthedeteriorationoffoodgrainscausingbothquantitativeandqualitativelosses
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Applied Science: Thermodynamics, Laws & Methodology.pdf
When I was asked to give a companion lecture in support of ‘The Philosophy of Science’ (https://shorturl.at/4pUXz) I decided not to walk through the detail of the many methodologies in order of use. Instead, I chose to employ a long standing, and ongoing, scientific development as an exemplar. And so, I chose the ever evolving story of Thermodynamics as a scientific investigation at its best.
Conducted over a period of >200 years, Thermodynamics R&D, and application, benefitted from the highest levels of professionalism, collaboration, and technical thoroughness. New layers of application, methodology, and practice were made possible by the progressive advance of technology. In turn, this has seen measurement and modelling accuracy continually improved at a micro and macro level.
Perhaps most importantly, Thermodynamics rapidly became a primary tool in the advance of applied science/engineering/technology, spanning micro-tech, to aerospace and cosmology. I can think of no better a story to illustrate the breadth of scientific methodologies and applications at their best.
Describing and Interpreting an Immersive Learning Case with the Immersion Cub...
Current descriptions of immersive learning cases are often difficult or impossible to compare. This is due to a myriad of different options on what details to include, which aspects are relevant, and on the descriptive approaches employed. Also, these aspects often combine very specific details with more general guidelines or indicate intents and rationales without clarifying their implementation. In this paper we provide a method to describe immersive learning cases that is structured to enable comparisons, yet flexible enough to allow researchers and practitioners to decide which aspects to include. This method leverages a taxonomy that classifies educational aspects at three levels (uses, practices, and strategies) and then utilizes two frameworks, the Immersive Learning Brain and the Immersion Cube, to enable a structured description and interpretation of immersive learning cases. The method is then demonstrated on a published immersive learning case on training for wind turbine maintenance using virtual reality. Applying the method results in a structured artifact, the Immersive Learning Case Sheet, that tags the case with its proximal uses, practices, and strategies, and refines the free text case description to ensure that matching details are included. This contribution is thus a case description method in support of future comparative research of immersive learning cases. We then discuss how the resulting description and interpretation can be leveraged to change immersion learning cases, by enriching them (considering low-effort changes or additions) or innovating (exploring more challenging avenues of transformation). The method holds significant promise to support better-grounded research in immersive learning.
在线办理(salfor毕业证书)索尔福德大学毕业证毕业完成信一模一样
学校原件一模一样【微信：741003700 】《(salfor毕业证书)索尔福德大学毕业证》【微信：741003700 】学位证，留信认证（真实可查，永久存档）原件一模一样纸张工艺/offer、雅思、外壳等材料/诚信可靠,可直接看成品样本，帮您解决无法毕业带来的各种难题！外壳，原版制作，诚信可靠，可直接看成品样本。行业标杆！精益求精，诚心合作，真诚制作！多年品质 ,按需精细制作，24小时接单,全套进口原装设备。十五年致力于帮助留学生解决难题，包您满意。
本公司拥有海外各大学样板无数，能完美还原。
1:1完美还原海外各大学毕业材料上的工艺：水印，阴影底纹，钢印LOGO烫金烫银，LOGO烫金烫银复合重叠。文字图案浮雕、激光镭射、紫外荧光、温感、复印防伪等防伪工艺。材料咨询办理、认证咨询办理请加学历顾问Q/微741003700
【主营项目】
一.毕业证【q微741003700】成绩单、使馆认证、教育部认证、雅思托福成绩单、学生卡等！
二.真实使馆公证(即留学回国人员证明,不成功不收费)
三.真实教育部学历学位认证（教育部存档！教育部留服网站永久可查）
四.办理各国各大学文凭(一对一专业服务,可全程监控跟踪进度)
如果您处于以下几种情况：
◇在校期间，因各种原因未能顺利毕业……拿不到官方毕业证【q/微741003700】
◇面对父母的压力，希望尽快拿到；
◇不清楚认证流程以及材料该如何准备；
◇回国时间很长，忘记办理；
◇回国马上就要找工作，办给用人单位看；
◇企事业单位必须要求办理的
◇需要报考公务员、购买免税车、落转户口
◇申请留学生创业基金
留信网认证的作用:
1:该专业认证可证明留学生真实身份
2:同时对留学生所学专业登记给予评定
3:国家专业人才认证中心颁发入库证书
4:这个认证书并且可以归档倒地方
5:凡事获得留信网入网的信息将会逐步更新到个人身份内，将在公安局网内查询个人身份证信息后，同步读取人才网入库信息
6:个人职称评审加20分
7:个人信誉贷款加10分
8:在国家人才网主办的国家网络招聘大会中纳入资料，供国家高端企业选择人才
(June 12, 2024) Webinar: Development of PET theranostics targeting the molecu...
(June 12, 2024) Webinar: Development of PET theranostics targeting the molecu...Scintica Instrumentation
Targeting Hsp90 and its pathogen Orthologs with Tethered Inhibitors as a Diagnostic and Therapeutic Strategy for cancer and infectious diseases with Dr. Timothy Haystead.The cost of acquiring information by natural selection
This is a short talk that I gave at the Banff International Research Station workshop on Modeling and Theory in Population Biology. The idea is to try to understand how the burden of natural selection relates to the amount of information that selection puts into the genome.
It's based on the first part of this research paper:
The cost of information acquisition by natural selection
Ryan Seamus McGee, Olivia Kosterlitz, Artem Kaznatcheev, Benjamin Kerr, Carl T. Bergstrom
bioRxiv 2022.07.02.498577; doi: https://doi.org/10.1101/2022.07.02.498577
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Slides from talk:
Aleš Zamuda: Randomised Optimisation Algorithms in DAPHNE .
Austrian-Slovenian HPC Meeting 2024 – ASHPC24, Seeblickhotel Grundlsee in Austria, 10–13 June 2024
https://ashpc.eu/
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Isolation of pure culture, its various method.
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Crystal field theory
- 2. HISTORY OF CRYSTAL FIELD THEORY CFT was developed by physicists Hans Bethe and John Hasbrouk van VECK in 1930’s. CFT was subsequently combined with Molecular Orbital Theory. CFT is a bonding model that explains many important properties of transition metal complexes , including their colours, magnetism ,structures , stability etc.
- 3. FEATURES OF CRYSTAL FIELD THEORY CFT assume that bonds between central metal atom or ion and ligands are purely ionic. Examples of central metal atoms are Cu ,Mg ,Ca etc. Ligands are of three types positive, neutral, and negative. Examples of :- -ve ligands : F-,Cl-,OH-, CN- +ve ligands :NO+ Neutral : NH3,H20
- 4. The arrangement of ligands around the central metal atom or ion is such that the repulsion between these negative points or dipoles are minimum.
- 5. The forces between metals and ligands are of two types :- 1. Attraction Force :- positive charge of the central metal atom and negative charge of ligands. 2. Repulsion Force :- D-electrons of central metal atom and lone pair electrons of ligands. D-orbitals of central metal atom are divided into two sets depending on their orientation. Non-axial orbitals/ t2g orbitals/ three fold degenerate orbitals :- dxy, dyz, dxz Axial orbitals/ eg orbitals/ two fold degenerate orbitals :- dx2-y2, dz2
- 7. Splitting of d- orbitals in octahedral complex :-
- 8. Example :-
- 10. Splitting of d-orbitals in tetrahedral complex :-
- 12. Example :-
- 13. Relation between crystal field splitting of tetrahedral and octahedral complex is :-
- 14. Uses of Crystal Field Theory :- 1. It can explain high spin and low spin state of coordinate compounds. 2. It can explain magnetic properties of complex compounds. 3. It also explains colour of complex compounds.
- 17. Sauare planar :-