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Building Battery Arrays
with Lithium-Ion Cells
About the Sponsor
 Micro Power Electronics
 Design and manufacture of lithium battery packs,
chargers and power supplies for mission-critical
applications
 OEM Customers include leading medical, data
collection, and military manufacturers of portable
devices
 20+ years experience with over 1000 battery system
designs
 FDA Registered and ISO 9001:2000 and 13485
certified
Agenda
 Market drivers/applications for
high-cell count battery packs
 Challenges to the designers of
large arrays
 Technology solutions available
 Cell imbalance and TI’s solution
 Question and Answer
Introduction
 Li-ion desirable because of energy density and higher voltage
 Traditional applications require fewer than 12 cells
 Applications require high wattage and/or long runtime
 High voltage (cells in series)
 High capacity (cells in parallel)
 Issues arise in high cell count packs
Tesla Electric Vehicle Battery
Comparison of “Large Size” and Mid Size”
Large: Electric
Vehicle
Mid: Remote
Monitor
Operating Voltage 375V 21.6V
Stored energy 53kWh
142Ah
0.33kWh
15.4Ah
Pack mass 450kg ~2kg
# 18650 cells used 6800 42
Topology 9s69p
X11 modules
6s7p
Electric Vehicles
Bikes
UAV
Powertools
Lawn and garden equipment
UPS
Telecom backup
Oil and gas exploration
Automated CPR
Ventilators
Wheelchairs
Oxygen concentrators
Ventricular assist devices
Intra Aortic Balloon Pump
Market Demand for Large and Mid Size Batteries
with Li-ion
Anatomy of a Portable Battery System
 Cells
 Circuit board
 protection circuitry
 fuel gauge
 communications bus
 Insulation
 External contacts
 Vent holes
 Plastic enclosure
Safety Circuits for Lithium-Ion Batteries
Large Scale Battery Management:
Challenges for high capacity
 Vendor Support
 Balancing
 High current circuit design
 Diodes- odd number of cells
 Fuel gauge limitations
 Shipping regulations
 Solutions:
 Bigger cells
 Modules
 Heat sinks
 Active cooling
 Large ICs
Large Scale Battery Management:
Challenges for high voltage
 Shipping
 Thermal management
 Cell matching
 Pack reliability
 Fuel gauging
 Cycle life
 Cell balancing
 Solutions for cell balancing and fuel gauging are
new on market
 High voltage chemistries far off
For a given wattage
high series is more
effective than high
parallel cell count
Large Module Solutions
Cathode Materials on the horizon
Material Nominal Voltage
vs. Li
Specific Capacity
mAh/g
LiCoO2 3.7-3.8 ~190 (Practical)
Li(NiCoMn)O2 3.7-3.8 >160
LiMn2O4 ~3.8 ~120
LiFePO4 3.45 130-150
LiFe1-xMxPO4 3.45 130-160
Li3V2(PO4)3 3.6-4.7 197
LiVPO4F 4.2 155
LiVPO4.OH 4.1 158
LiVP2O7 4.1 116
Li2MPO4F 4.7 143
Na2MPO4F 4.7 122
Li4V2(SiO4)(PO4)2 3.6-4.7 260
Li3V1.5Al0.5(PO4)3 3.6-4.7 203
β-LiVOPO4 4.0 159
NaVPO4F 3.7 143
Na3V2(PO4)2F3 3.7 192
Electrolyte
window is
fundamental
limitation
This IBM ThinkPad™ 600 shows peak base
temperatures of 116.6°F (pink/grey), &
significant areas above 100°F (orange).
Causes of Cell Imbalance
Thermal Gradients
Pack Imbalance
 Poor Cell Capacity Matching
 Impedance Variations
 Heat – Self discharge doubles
for each 10º C rise
 Non-Uniform Thermal Stress
 Non-Uniform Electrical
Loading of Pack
 Chemical Efficiency Variations
 High discharge rates
High-Cell Count Imbalance
 Temperature Becomes a
Greater Factor:
 Gradients Are Larger
 Physical Cell Arrangement Can
Influence Temperature
 High Rate Charge/Discharge
Prismatic HEV Cell Array
Top: Cooling Fan Failure
Bottom: Left to Right Low Flow
Cooling
(Images copyright/courtesy NREL)
© Micro Power Electronics, Inc. and POWERPRECISE
Real Thermal image 4s6p 2.4Ah
Texas Instruments
Cell Balancing Strategies
Cell Balancing Techniques
 Purpose
 Deliver as much energy during discharge as
possible.
 Extend cycle life of battery pack
 Two Techniques
 Bleed or Bypass : providing alternative current path
to a cell that is out of balance to other cells in
series
 Active or Charge Redistribution : moving charge
from higher charged cells to lower charged cells in
series
Internal Cell Balancing – Charge Cycle
+
Rext
Cext
IC VCn pin
IC VCn+1 pin
Rext
Ibalance
 Limit to internal FET capacity
 10 - 200 mA per datasheet
 Real value based on thermals
+
Rext
Cext
Rextbal
IC VCn pin
IC VCn+1 pin
Rext
Battery
Cell
Ibalance
Ibias
- Vgate +
 External MOSFET can be controlled by the state of the
integrated FET
 Higher bypassing current is achieved due to low Rdson of
the external FETs
 Gate voltage is limited by resistance across the “lower”
Rext (Rvcx)
10 Series System 50mA
VC11
VC2
VC3
VC9
VC10
VC1
Cell Measurement /
Interface Circuits
CB2
CB1
CB9
CB10
10 Series System 200mA
VC11
VC2
VC3
VC9
VC10
VC1
CB2
CB1
CB9
CB10
Cell Measurement /
Interface Circuits
Bypass Balance Review
 Ends of OCV curve makes largest difference
 Recommended to balance during charge cycle
 Duty cycle limitations
 Amount of energy moved is limited to by time,
temperature and current
 Cost of high current resistors & low ohm FETs
 Energy conservation vs energy stored/delivered
 Thermally challenging at high temp portions of pack life
Charge Redistribution Cell Balancing
Basics
 Energy transfer between adjacent cells
 Move energy where and when its needed to minimize
global imbalance
 Current path is outside of charge / discharge path
 Can be implemented during charge, idle and discharge
periods
Topology Choices
 Capacitive – switch capacitor across higher cell to lower
cell
 Inductive – store energy from higher cell before delivering
it to lower cell
Capacitive Redistribution
 Simple higher voltage to lower voltage measurements and shuttle
 Maximum 50% efficiency
 High voltage differences only happens at ends of cycle
 Bidirectional energy movement
Inductive Redistribution
 FET Capacitor and inductor used to create a mini
dc/dc boost converter
 Bi-directional transfers energy efficiently between
adjacent cells
 “Bucket brigade” allows redistribution anywhere in
pack
 Move energy where and when it is needed to
minimize global imbalance
 Not as efficiency challenged at mid charge /
capacity levels
Inductive Redistribution
Imbalance example:
 Cell 2 is a lower voltage or
capacitance
 Move energy from Cell 1 and
Cell 2
PowerPumpTM Operation
 Example: Pumping from Cell 3 Cell 2
 P3S frequency is 200 kHz, 33% positive Duty Cycle
 P3S Turns PFET ON
 DI/DT = V/L : Energy in Inductor builds
Control Signals
from IC
PowerPumpTM Operation
 Example: Pumping from Cell 3 Cell 2
 P3S Turns FET Off
 Current continues through NFET (body diode)
 Energy transfers to Cell 2
 Time average Balancing current is 40 to 50 mA
 HF AC Currents confined to PCB
Control Signals
from IC
Multiple Balancing Control Options
Balance on Cell Terminal Voltage
 Easiest to understand – provides the basis for more
complex control
Balance on Cell OCV Estimates
 Based on Pack current and Cell Impedance
measurements
 Compensates for impedance differences
Balance for SOC at 100% (or 0%)
 Based on how far each cell is from Full Charge Capacity
 Compensates for capacity divergence and OCV
differences
Balancing Strategy
Voltage Balancing Does NOT Always Insure Balance is
Maintained Through the Cycle...
Voltage Balanced...
... Here. ... But Capacity Not
Balanced Here.
Challenges with New Chemistries
Voltage Balance but Capacity Imbalance ... At End-of-Discharge
2
2.2
2.4
2.6
2.8
3
3.2
3.4
3.6
3.8
0.00 10.00 20.00 30.00 40.00
Time Minutes
CellVoltage
Equal Cell Voltages here
Leaves cells with SOC imbalance
Allowing cells to drop below cutoff
2
2.2
2.4
2.6
2.8
3
3.2
3.4
3.6
3.8
10.00 15.00 20.00 25.00 30.00 35.00 40.00
Time Minutes
CellVoltage
Each Cell is driven
to a Voltage Offset
learned to maintain equal SOC.
Results in cells reaching cutoff together
Challenges with New Chemistries
Predictive Balancing Maintains EOD Balance
Choice of Balancing Strategy
Predictive Balancing for Capacity Match at End Points
Added Benefit: Minimizes Overall Balancing Activity
Less Balancing ...
... And Capacity
Balanced at EOC
Example Schematic
PowerPumpTM Balancing
 Cell-to-Cell Energy Transfer
 Efficient - No Heat
 Can be enabled anytime
(Charge, Idle, Discharge)
 Balance Current
Sized Externally
Inductor and
Dual FETs
Example 2-cell circuit
shown. ICs available for
up to 6 series cells.
VSS
V1
V2
PUMP2S
PUMP2N
PUMP1N
1.0
+
+
76PL102
SDI
SDO
.001
3300pF
3300pF
20K
20K
15µH
2K
3300pF
3300pF
20K
20K
15µH
2K
1.0
1.0
1.0
1.0
TAB
VLDO
VPP
PUMP1S
XTMPx
PUMP1S (Next 76PL102 above)
PowerLAN™
1.0
Typical
Temperature
Sensor
MMBD4148SE
.001
To Node n+1To Node n+1
V2+
n
V2-
n
V1+
n
V1-
n
V1-
n+1V1+
n+1
V2+
n-1To Node n-1
To Node n-1
PUMP1S (Next 76PL102 below)
Cell Balancing Comparison
Bypass
 Simplest and least expensive for low currents
 High currents bring higher costs and thermal
constraints
 Limited to ends of charge and discharge cycle
Redistribution
 Complex control algorithms
 Inductive has higher part counts and cost
 Able to be implemented at any time in pack life
Question and Answer

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Building Battery Arrays with Lithium-Ion Cells High cell count

  • 1. Building Battery Arrays with Lithium-Ion Cells
  • 2. About the Sponsor  Micro Power Electronics  Design and manufacture of lithium battery packs, chargers and power supplies for mission-critical applications  OEM Customers include leading medical, data collection, and military manufacturers of portable devices  20+ years experience with over 1000 battery system designs  FDA Registered and ISO 9001:2000 and 13485 certified
  • 3. Agenda  Market drivers/applications for high-cell count battery packs  Challenges to the designers of large arrays  Technology solutions available  Cell imbalance and TI’s solution  Question and Answer
  • 4. Introduction  Li-ion desirable because of energy density and higher voltage  Traditional applications require fewer than 12 cells  Applications require high wattage and/or long runtime  High voltage (cells in series)  High capacity (cells in parallel)  Issues arise in high cell count packs
  • 5.
  • 6.
  • 8. Comparison of “Large Size” and Mid Size” Large: Electric Vehicle Mid: Remote Monitor Operating Voltage 375V 21.6V Stored energy 53kWh 142Ah 0.33kWh 15.4Ah Pack mass 450kg ~2kg # 18650 cells used 6800 42 Topology 9s69p X11 modules 6s7p
  • 9. Electric Vehicles Bikes UAV Powertools Lawn and garden equipment UPS Telecom backup Oil and gas exploration Automated CPR Ventilators Wheelchairs Oxygen concentrators Ventricular assist devices Intra Aortic Balloon Pump Market Demand for Large and Mid Size Batteries with Li-ion
  • 10. Anatomy of a Portable Battery System  Cells  Circuit board  protection circuitry  fuel gauge  communications bus  Insulation  External contacts  Vent holes  Plastic enclosure
  • 11. Safety Circuits for Lithium-Ion Batteries
  • 12. Large Scale Battery Management: Challenges for high capacity  Vendor Support  Balancing  High current circuit design  Diodes- odd number of cells  Fuel gauge limitations  Shipping regulations  Solutions:  Bigger cells  Modules  Heat sinks  Active cooling  Large ICs
  • 13. Large Scale Battery Management: Challenges for high voltage  Shipping  Thermal management  Cell matching  Pack reliability  Fuel gauging  Cycle life  Cell balancing  Solutions for cell balancing and fuel gauging are new on market  High voltage chemistries far off For a given wattage high series is more effective than high parallel cell count
  • 15.
  • 16. Cathode Materials on the horizon Material Nominal Voltage vs. Li Specific Capacity mAh/g LiCoO2 3.7-3.8 ~190 (Practical) Li(NiCoMn)O2 3.7-3.8 >160 LiMn2O4 ~3.8 ~120 LiFePO4 3.45 130-150 LiFe1-xMxPO4 3.45 130-160 Li3V2(PO4)3 3.6-4.7 197 LiVPO4F 4.2 155 LiVPO4.OH 4.1 158 LiVP2O7 4.1 116 Li2MPO4F 4.7 143 Na2MPO4F 4.7 122 Li4V2(SiO4)(PO4)2 3.6-4.7 260 Li3V1.5Al0.5(PO4)3 3.6-4.7 203 β-LiVOPO4 4.0 159 NaVPO4F 3.7 143 Na3V2(PO4)2F3 3.7 192 Electrolyte window is fundamental limitation
  • 17. This IBM ThinkPad™ 600 shows peak base temperatures of 116.6°F (pink/grey), & significant areas above 100°F (orange). Causes of Cell Imbalance Thermal Gradients Pack Imbalance  Poor Cell Capacity Matching  Impedance Variations  Heat – Self discharge doubles for each 10º C rise  Non-Uniform Thermal Stress  Non-Uniform Electrical Loading of Pack  Chemical Efficiency Variations  High discharge rates
  • 18. High-Cell Count Imbalance  Temperature Becomes a Greater Factor:  Gradients Are Larger  Physical Cell Arrangement Can Influence Temperature  High Rate Charge/Discharge Prismatic HEV Cell Array Top: Cooling Fan Failure Bottom: Left to Right Low Flow Cooling (Images copyright/courtesy NREL) © Micro Power Electronics, Inc. and POWERPRECISE
  • 19. Real Thermal image 4s6p 2.4Ah
  • 21. Cell Balancing Techniques  Purpose  Deliver as much energy during discharge as possible.  Extend cycle life of battery pack  Two Techniques  Bleed or Bypass : providing alternative current path to a cell that is out of balance to other cells in series  Active or Charge Redistribution : moving charge from higher charged cells to lower charged cells in series
  • 22. Internal Cell Balancing – Charge Cycle + Rext Cext IC VCn pin IC VCn+1 pin Rext Ibalance  Limit to internal FET capacity  10 - 200 mA per datasheet  Real value based on thermals + Rext Cext Rextbal IC VCn pin IC VCn+1 pin Rext Battery Cell Ibalance Ibias - Vgate +  External MOSFET can be controlled by the state of the integrated FET  Higher bypassing current is achieved due to low Rdson of the external FETs  Gate voltage is limited by resistance across the “lower” Rext (Rvcx)
  • 23. 10 Series System 50mA VC11 VC2 VC3 VC9 VC10 VC1 Cell Measurement / Interface Circuits CB2 CB1 CB9 CB10
  • 24. 10 Series System 200mA VC11 VC2 VC3 VC9 VC10 VC1 CB2 CB1 CB9 CB10 Cell Measurement / Interface Circuits
  • 25. Bypass Balance Review  Ends of OCV curve makes largest difference  Recommended to balance during charge cycle  Duty cycle limitations  Amount of energy moved is limited to by time, temperature and current  Cost of high current resistors & low ohm FETs  Energy conservation vs energy stored/delivered  Thermally challenging at high temp portions of pack life
  • 26. Charge Redistribution Cell Balancing Basics  Energy transfer between adjacent cells  Move energy where and when its needed to minimize global imbalance  Current path is outside of charge / discharge path  Can be implemented during charge, idle and discharge periods Topology Choices  Capacitive – switch capacitor across higher cell to lower cell  Inductive – store energy from higher cell before delivering it to lower cell
  • 27. Capacitive Redistribution  Simple higher voltage to lower voltage measurements and shuttle  Maximum 50% efficiency  High voltage differences only happens at ends of cycle  Bidirectional energy movement
  • 28. Inductive Redistribution  FET Capacitor and inductor used to create a mini dc/dc boost converter  Bi-directional transfers energy efficiently between adjacent cells  “Bucket brigade” allows redistribution anywhere in pack  Move energy where and when it is needed to minimize global imbalance  Not as efficiency challenged at mid charge / capacity levels
  • 29. Inductive Redistribution Imbalance example:  Cell 2 is a lower voltage or capacitance  Move energy from Cell 1 and Cell 2
  • 30. PowerPumpTM Operation  Example: Pumping from Cell 3 Cell 2  P3S frequency is 200 kHz, 33% positive Duty Cycle  P3S Turns PFET ON  DI/DT = V/L : Energy in Inductor builds Control Signals from IC
  • 31. PowerPumpTM Operation  Example: Pumping from Cell 3 Cell 2  P3S Turns FET Off  Current continues through NFET (body diode)  Energy transfers to Cell 2  Time average Balancing current is 40 to 50 mA  HF AC Currents confined to PCB Control Signals from IC
  • 32. Multiple Balancing Control Options Balance on Cell Terminal Voltage  Easiest to understand – provides the basis for more complex control Balance on Cell OCV Estimates  Based on Pack current and Cell Impedance measurements  Compensates for impedance differences Balance for SOC at 100% (or 0%)  Based on how far each cell is from Full Charge Capacity  Compensates for capacity divergence and OCV differences
  • 33. Balancing Strategy Voltage Balancing Does NOT Always Insure Balance is Maintained Through the Cycle... Voltage Balanced... ... Here. ... But Capacity Not Balanced Here.
  • 34. Challenges with New Chemistries Voltage Balance but Capacity Imbalance ... At End-of-Discharge 2 2.2 2.4 2.6 2.8 3 3.2 3.4 3.6 3.8 0.00 10.00 20.00 30.00 40.00 Time Minutes CellVoltage Equal Cell Voltages here Leaves cells with SOC imbalance Allowing cells to drop below cutoff
  • 35. 2 2.2 2.4 2.6 2.8 3 3.2 3.4 3.6 3.8 10.00 15.00 20.00 25.00 30.00 35.00 40.00 Time Minutes CellVoltage Each Cell is driven to a Voltage Offset learned to maintain equal SOC. Results in cells reaching cutoff together Challenges with New Chemistries Predictive Balancing Maintains EOD Balance
  • 36. Choice of Balancing Strategy Predictive Balancing for Capacity Match at End Points Added Benefit: Minimizes Overall Balancing Activity Less Balancing ... ... And Capacity Balanced at EOC
  • 37. Example Schematic PowerPumpTM Balancing  Cell-to-Cell Energy Transfer  Efficient - No Heat  Can be enabled anytime (Charge, Idle, Discharge)  Balance Current Sized Externally Inductor and Dual FETs Example 2-cell circuit shown. ICs available for up to 6 series cells. VSS V1 V2 PUMP2S PUMP2N PUMP1N 1.0 + + 76PL102 SDI SDO .001 3300pF 3300pF 20K 20K 15µH 2K 3300pF 3300pF 20K 20K 15µH 2K 1.0 1.0 1.0 1.0 TAB VLDO VPP PUMP1S XTMPx PUMP1S (Next 76PL102 above) PowerLAN™ 1.0 Typical Temperature Sensor MMBD4148SE .001 To Node n+1To Node n+1 V2+ n V2- n V1+ n V1- n V1- n+1V1+ n+1 V2+ n-1To Node n-1 To Node n-1 PUMP1S (Next 76PL102 below)
  • 38. Cell Balancing Comparison Bypass  Simplest and least expensive for low currents  High currents bring higher costs and thermal constraints  Limited to ends of charge and discharge cycle Redistribution  Complex control algorithms  Inductive has higher part counts and cost  Able to be implemented at any time in pack life