SlideShare a Scribd company logo
• Introduction
• History
• Materials & Methods of Production
• Transesterification
• What is cottonseed ?
• Separation Of Biodiesel
• purification Of Biodiesel
• Advantages & Disadvantage
• Conclusion
• Reference
• Need of Alternative Fuel
• Why Biodiesel? & What is it?
History
 Rudolf Diesel firstly tested the PEANUT OIL in
compression ignition in 1912
 Materials:-
• Cottonseed oil
• Ethanol
• Methanol
• Potassium hydroxide
• Shrub: 3 - 5 foot in height
• Draught resistant, perennial
• Starts producing after 5-6 months of plantation
• Seeds contain 50% oil (approx. 30% is extractable)
• Oil: non-edible
• Seed production: 0.8 to 5.2 tons per acre per annum (depending on soil &
Irrigation)
WHAT IS COTTON SEED ?
 Methods of Production :-
1.Thermal cracking or pyrolysis
2.Microemulsions
3.Transesterification
• Base Esterification
Triglycerides + Free Fatty Acids (<4%) + Alcohol ————>
Alkyl esters + glycerine Base
•Acid Esterification
Triglycerides + Free Fatty Acids (>4%) + Alcohol ————>
Alkyl esters + glycerine Acid
 Transesterification
 Separation of Byproduct
 Glycerine Refining
 Methanol Recovery
 Purification of Bio-Diesel
TRANESTERFICATION
 SEPARATION OF BY PRODUCT
Biodiesel and Glycerol are two major products that exists once transesterification
reaction is completed.
The Glycerol phase is much denser than biodiesel phase.
The Glycerol layer is drained out from separating funnel.
 Purification of Bio-Diesel
 Washing
 Dry Washing
 Less polluting than petroleum diesel
 Can use in existing diesel engine without any
modification
 Lack of Sulphur extends the life of catalytic
convertors
 1&1/2 times more expensive than petroleum based
fuel
 Can harm rubber hoses in some engines
 Due to no. Of processes cost of production is high
 Improved lubricity, , reduce global warming
 Contribute to rural development, allowing
additional income and job creation for developing
countries.
Diversifying the world’s fuel needs.
Prof. (Dr.) R. K. Khotoliya, Dr. Harminder Kaur &
Rupinder Sing, Biodiesel Production from
Cottonseed(Source-Kurukshetra, volume-55, No-4,
February-2007).
Van Gerpen, J.2005. Biodiesel processing & production
Fuel processing technology. 86:1097-1107.
T. Mirunalini, R.Anand & N.V.Mahalakshmi. Cottonseed
oil as a renewable fuel in diesel engine.
THANK YOU

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Bio diesel

  • 1.
  • 2. • Introduction • History • Materials & Methods of Production • Transesterification • What is cottonseed ? • Separation Of Biodiesel • purification Of Biodiesel • Advantages & Disadvantage • Conclusion • Reference
  • 3. • Need of Alternative Fuel • Why Biodiesel? & What is it?
  • 4. History  Rudolf Diesel firstly tested the PEANUT OIL in compression ignition in 1912
  • 5.  Materials:- • Cottonseed oil • Ethanol • Methanol • Potassium hydroxide
  • 6. • Shrub: 3 - 5 foot in height • Draught resistant, perennial • Starts producing after 5-6 months of plantation • Seeds contain 50% oil (approx. 30% is extractable) • Oil: non-edible • Seed production: 0.8 to 5.2 tons per acre per annum (depending on soil & Irrigation) WHAT IS COTTON SEED ?
  • 7.  Methods of Production :- 1.Thermal cracking or pyrolysis 2.Microemulsions 3.Transesterification
  • 8. • Base Esterification Triglycerides + Free Fatty Acids (<4%) + Alcohol ————> Alkyl esters + glycerine Base •Acid Esterification Triglycerides + Free Fatty Acids (>4%) + Alcohol ————> Alkyl esters + glycerine Acid
  • 9.  Transesterification  Separation of Byproduct  Glycerine Refining  Methanol Recovery  Purification of Bio-Diesel
  • 11.  SEPARATION OF BY PRODUCT Biodiesel and Glycerol are two major products that exists once transesterification reaction is completed. The Glycerol phase is much denser than biodiesel phase. The Glycerol layer is drained out from separating funnel.
  • 12.  Purification of Bio-Diesel  Washing  Dry Washing
  • 13.
  • 14.  Less polluting than petroleum diesel  Can use in existing diesel engine without any modification  Lack of Sulphur extends the life of catalytic convertors
  • 15.  1&1/2 times more expensive than petroleum based fuel  Can harm rubber hoses in some engines  Due to no. Of processes cost of production is high
  • 16.  Improved lubricity, , reduce global warming  Contribute to rural development, allowing additional income and job creation for developing countries. Diversifying the world’s fuel needs.
  • 17. Prof. (Dr.) R. K. Khotoliya, Dr. Harminder Kaur & Rupinder Sing, Biodiesel Production from Cottonseed(Source-Kurukshetra, volume-55, No-4, February-2007). Van Gerpen, J.2005. Biodiesel processing & production Fuel processing technology. 86:1097-1107. T. Mirunalini, R.Anand & N.V.Mahalakshmi. Cottonseed oil as a renewable fuel in diesel engine.