Presented during workshop on oleochemicals by MPOC -Cairo By: Dr. Fathy Hassan, PhD COO, Oleo Misr

1. Application of Oleochemicals in Soap, Detergents and
Cosmetic Industries
Fathy Hassan, PhD
COO, Oleo Misr
drfh71@oleomisr.com
www.oleomisr.com

2. Focus Points
What is Oleochemicals
Vegetable Oil in Oleochemicals
Oleochemicals = Happy Life
Application of Oleochemicals in Soap Industry
Application of Oleochemicals in Cosmetic Industry
Conclusion

3. Non-Food Uses of Oleo Chemicals

4. OLEO CHEMICALS USED IN MANY INDUSTRIES

5. OLEO CHEMICALS USED IN MANY INDUSTRIES

6. OLEO CHEMICALS USED IN MANY INDUSTRIES
Oleochemicals are chemicals derived from Oils &
Fats (plant or animal). They are analogous to
petrochemicals derived from petroleum
Important processes in oleochemical
manufacturing include hydrolysis, splitting,
hydrogenation, methylation and transesterification,
among others.

7. OLEO CHEMICALS USED IN MANY INDUSTRIES
The formation of basic oleochemical substances like fatty
acids, glycerol, fatty acid methyl esters (FAME), fatty
alcohols, fatty amines and glycerols are by various chemical
and enzymatic reactions. Intermediate chemical substances
produced from these basic oleochemical substances include
alcohol ethoxylates, alcohol sulfates, alcohol ether glucose,
quaternary ammonium salts, monoacylglycerols (MAG),
diacylglycerols (DAG), structured triacylglycerols (TAG),
sugar esters, and other oleochemical products

8. OLEO CHEMICALS USED IN MANY INDUSTRIES
Adhesives & Sealants Metal Working
Agricultural Chemicals Oilfield Chemicals
Chemical Derivatives Paints, Coatings & Inks
Coatings and Inks Paper Chemicals
Construction Chemicals Personal Care
Electrodes Pharmaceutical
Emulsion Polymerization Polymers & Plastics
Flavors & Fragrance Rubber & Tires
Food Processing Textile Chemicals
Household Care Tobacco
Industrial & Institutional Cleaners Wax & Candles
Lubricants and Greases

9. OLEO CHEMICALS USED IN MANY INDUSTRIES
The expected total oleo chemical consumption
of Egypt, Africa and Middle east is about 1.5 :
1.7 million tons 2017.

10. Non-Food Uses of Oleo Chemicals
SUBJECT CONTENTS
OLEO CHEMICALS = HAPPY LIFE
VEGETABLE OIL IN OLEO CHEMICALS
OLEO CHEMICALS IN SOME INDUSTRIAL PROCESS
IN SOAP
IN COSMETICS
IN IN LEATHER
IN TEXTIAL
IN SURFACTANT, EMULSIFIERS & OTHERS
IN PHARMACEUTICALS, PAINTING & OTHERS

11. Non-Food Uses of Oleo Chemicals
OLEO CHEMICALS = HAPPY LIFE
WE CAN MAKE A DIFFERENCE TO THE FUTURE OF
OUR LIFE BY THE RIGHT CHOICE :
ALL OUR LIFE IS BOLUTED BY HYDROCARBON
IN FOOD / INKS / TEXTILE / COSMETICS
AGRICULTURE PESTICIDES / IN MANY
WHAT WE CAN DO?

12. Non-Food Uses of Oleo Chemicals
OLEO CHEMICALS = HAPPY LIFE
WRITE ANSWER BACK TO THE NATURE
(RIGHT CHOICE FOR GREEN LIFE)
OLEO CHEMICALS ARE USED IN ALL
SPECIALTIES IN OUR EVERY DAY LIFE
THANKS OLEO CHEMICALS WITH
RESPICT TO THE TRIGLYCERIDES

13. Non-Food Uses of Oleo Chemicals
Vegetable oil & FAT are being processed to produce a wide
variety of Fatty Acid based derivatives and end products
including oleo chemicals.

14. Non-Food Uses of Oleo Chemicals
What oleo chemicals are derived from Fat & Oil?
In addition to the Fat & Oil derivatives used for food
applications, there are also a number of Oil-based oleo
chemicals, including:
Fatty acids / Fatty alcohols / Fatty methyl ester
Fatty nitrogen compounds / Glycerine
These substances are used in cosmetics , painting ,
surfactants , emulsifiers , and among other products.

15. Non-Food Uses of Oleo Chemicals

16. Non-Food Uses of Oleo Chemicals

17. Non-Food Uses of Oleo Chemicals
The most important of non-food
application of fatty acids in OLEO MISR
COMPANY. / Egypt now is for the
production of BASIC OLEO
CHEMICALS i.e. All fatty acids and
special oleo chemicals i.e. palmetic,
stearic, oleic fatty acids and their
derivatives with respect to the tri
glycerides .

18. Non-Food Uses of Oleo Chemicals
OLEO CHEMICALS IN SOME INDUSTRIAL PROCESS
IN SOAP

19. Non-Food Uses of Oleo Chemicals
.
ITS SOO EASY TO MAKE A SOAP BUT ITS
VERY DIFFICULT TO MAKE A GOOD SOAP
OLEO CHEMICALS IN SOAP PROCESS

20. Non-Food Uses of Oleo Chemicals
OLEO CHEMICALS IN SOAP PROCESS

21. Non-Food Uses of Oleo Chemicals
SOAP ( salt of fatty acid ) is not use only as soap
bar for cleaning but its use in many field
We have the calcium, potassium, lithium salt of
fatty acid , soap amine , natural hand soap, and
Soap of carboxylic acids and amines which is
useful in removal and prevention of scale.
OLEO CHEMICALS IN SOAP PROCESS

22. Non-Food Uses of Oleo Chemicals
Fatty amine : in chemistry, is any amine attached to a C
12 or more . These are classified as oleochemicals. More
commonly are derived from C12-C18 , coco amine,
oleylamine, tallow amine, and soya amine. Some
applications of these compounds are in Soap Bar fabric
softeners, and corrosion inhibitors. They are the basis for
a variety of soap & cosmetic formulations.
OLEO CHEMICALS IN SOAP PROCESS

23. Non-Food Uses of Oleo Chemicals
OLEO MISR COMPANY. / Egypt has a facility to produce
snow white soap noodles via a continuous neutralization process.
Snow White soap cannot be prepared directly from continuous
Saponification process because of their high Saponification color
values. When palm fatty acids are distilled, however, some of the
impurities are removed and good quality soaps can therefore be made
from them. In addition to ease of production, the fatty acid route
allows soap formulators to determine the ratio of fatty acids to be
used, by blending, thus offering greater flexibility.

24. Non-Food Uses of Oleo Chemicals
OLEO MISR WILL PRODUCE DIFFERENT FORMULATION FOR
TOILET SOAP, NOODLES , COMBAR, TRANSLUCENT AND
TRANSPARANT SOAP NOODLES
ALSO WE HAVE A FACILITIES TO PRODUCE SWING SOAP
NOODLES DIRECT FROM OIL WITHOUT SEPARATING THE
GLYCEROL

25. Non-Food Uses of Oleo Chemicals
QUALITY DIFFERENCE BETWEEN SOAP
NOODLES FROM OILS AND FATTY ACIDS
SOAP NOODLES FROM FATTY ACID SOAP NOODLES FROM OILS
Color Top white fancy color Yellowish
Dust Little High
Salt 0.1 : as req. 0.4 min.
Alk. 0.0 : as req. Difficult to adjust.
Glycerol 0.1 : as req. 1.0 min.
Un-sap 0.15 max. 0.25 min.
Irritation - +

26. Non-Food Uses of Oleo Chemicals
QUALITY DIFFERENCE BETWEEN SOAP
NOODLES FROM OILS AND FATTY ACIDS
•Less qty. Of TiO2 and bighting agent
•Less qty. Of Caustic soda
•Less qty. Of sodium salt
•Less qty. Of fragrance
•Less qty. Of preservative
•High quality with different formulations

27. Non-Food Uses of Oleo Chemicals
OUR TARGET IN SOAP MANUFACTURE WILL BE NEW
FORMULATION WITH HIGH QUALITY TO EXCEED THE
CUSTOMER EXPECTATIONS :
OLEO MISR WILL PRODUCE DIFFERENT BLEND
OF SOAP NOODLES TO ACHIEVE THE STANDARD
No. OF INS, HR, & S.R.
USE NEW TECHNOLOGY TO
PRODUSE SNOW WHITE SOAP
NOODLES FROM METHYL ESTER

28. Non-Food Uses of Oleo Chemicals
OIL DREVATIVES AS OLEO SOAP
ON THE OTHER HAND GLYCEROL COMES
FROM SPLITING OF VEGETABLE OIL IS MORE
HIGH QUALITY THAN THIS ONE COMES
FROM SAPONIFICATION i.e. Odder, Colour and
free of chloride ion and triglycerides

29. Non-Food Uses of Oleo Chemicals
OLEO CHEMICALS IN SOME INDUSTRIAL PROCESS
IN COSMETICS & BODY CARE / HOME CARE & DRILLING
DETERGENTS
IN COSMETICS

30. Non-Food Uses of Oleo Chemicals
EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS
MOST OF THE R.M IN COSMETICS ARE OLEO
CHEMICALS, WHICH USED IN BODY CARE,
PERSONAL CARE , HOME CARE , HAIR CARE ,
BABY CARE, & ALL KINDS OF DETERGENTS
WHICH USED IN HOUSE, HOTELS, PAPER,
TANNING, TEXTILE , AGRICULTURE, PESTICIDES,
DRILLING, OTHERS

31. Non-Food Uses of Oleo Chemicals
EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS
MOST OF OLEO CHEMICALS IN THE ABOVE
WORKS AS ACTIVE MATTER, SURFACTANTS,
EMULSIFIER, WETING AGENTS, PLASTICIZER,
LUBRICANTS, EMOLLIENTS, THICKENER,
MOISTURIZERS ---------------------

32. Non-Food Uses of Oleo Chemicals
.Hypoallergenic
Biodegradable
Septic System Safe
EcoLogo compliant
Vegan
Leaping Bunny approved
WELCOME OLEO CHEMICALS IN COSMETICS

33. Non-Food Uses of Oleo Chemicals
WELCOME OLEO CHEMICALS IN COSMETICS
Good bye to these ingredients in Cosmetics and detergents products:
Sodium Lauryl Sulphate free
Chlorine Free
Phosphates Free
Synthetic fragrances Free
Ethylenediaminetetraacetic acid (EDTA) Free
Alkylphenol ethoxylates (APEs) Free
Petrochemical R.M Free

34. Non-Food Uses of Oleo Chemicals
WELCOME OLEO CHEMICALS IN COSMETICS
Do you know the main ingredient in shampoo & hand Soap?
Sodium Lauryl Sulphate / ether sulphate 10 : 20 %
We need all cosmetics products sulphate free
Its better to use Lauryl glucoside / succinate or
Use fatty Acid & fatty acid derivatives in hand soap & shampoo

35. Non-Food Uses of Oleo Chemicals
STABLE SOAP BASED CLEANSING SYSTEM
( More particularly )
The liquid skin cleansing relates to phase stable liquid
skin cleansing compositions comprising a fatty acid soap,
and acrylate based copolymer and an acidifying agent.
OLEO CHEMICALS IN HAND SOAP .

36. Non-Food Uses of Oleo Chemicals
OLEO CHEMICALS IN HAND SOAP .
A liquid soap composition is prepared by the back-acid formulation
technique utilizing the following recipe.

37. Non-Food Uses of Oleo Chemicals
OLEO CHEMICALS IN HAND SOAP .
The pH is sequentially lowered by back-acid treating with citric acid. The
viscosity and yield values following the sequential reduction of the pH values
of the liquid soap composition are reported in the table below.

38. Non-Food Uses of Oleo Chemicals
OLEO CHEMICALS IN HAND SOAP
.The back-acid technique with citric acid (25% solution) to a pH of 8.6
Different formula with low % of fatty acid blend

39. OLEOCHEMICAL IN COSMETICS
Oleo chemical in disinfectant :
We know that the custor Soap used in disinfectant with
PCMX / IRGAZAN / OTHERS AS anti-bacterial agent
and ( Isopropyl + D.I water ), caramel as color .
OUR COMPANY PRODUSED NEW FORMULA FROM
OLEO CHEMICAL 100 %
Non-Food Uses of Oleo Chemicals

40. Non-Food Uses of Oleo Chemicals
EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS
Caprylyl / Myristyl Glucoside Caprylyl /Myristyl
Glucoside are cleaning agent, an Amine Oxide surfactant
that can also be found in a variety of products including
shampoos and dishwashing detergents. It removes dirt
and deposits by surrounding dirt particles to loosen them
from the surface they're attached to, so they can be rinsed
away. Function: Plant based cleaning agent (Surfactant),
Liquid Laundry .

41. Non-Food Uses of Oleo Chemicals
EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS
Cocamidopropyl Hydroxysultaine used in (Hand soap,
soaps, shampoos, lotions etc.) It has uses as a foam booster,
viscosity builder, and an antistatic agent. : Made by blending raw
coconut oil with a naturally-derived chemical. This ingredient usually
provides the mild and gentle "sudsing" base for body washes, facial
cleansers, shampoos, bubble bath, and other liquid cleansing
formulations. It is also has properties that can be used to adjust the
thickness (viscosity) of formulations. Function: Viscosity adjuster

42. Non-Food Uses of Oleo Chemicals
EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS
Lauramine Oxide : Function: Plant based cleaning agent
(Surfactant) . Produced by the reaction of glucose from
corn starch with the fatty alcohol from P. kernel oil or
coconut. It is a cleaning agent that can also be found in a
variety of products including shampoos and dishwashing
detergents

43. Non-Food Uses of Oleo Chemicals
EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS
Glyceryl Oleate is the ester of glycerin and oleic
acid. It is produced from oils that contain high
concentrations of oleic acid, such as olive oil,
peanut oil, teaseed oil or pecan oil. It is used as
an emulsifier in Hand soap & others (mixes oil
and water). Function: Lipid enhancer

44. Non-Food Uses of Oleo Chemicals
EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS
Glycerine is derived from Vegetable Oil, and is a by-
product of soap making process. Glycerine is a
moisturizer that can also be found in personal care
products such as skin lotion. It helps prevent a product
from drying out and breaking apart. It works by drawing
water in and forming a barrier on a surface to help retain
moisture. Function: Solvent / Foam stabilizer

45. Non-Food Uses of Oleo Chemicals
EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS
Methyl Bis (soya amidoethyl) -2-Hydroxyethyl
Quaternary Ammonium Methyl Sulphate: A soy based
ingredient and an alkaline based compound that is used to
soften garments and also acts an anti-static agent to
reduce static cling. Used in Fabric Softener .Function:
Plant based softening agent

46. Non-Food Uses of Oleo Chemicals
EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS
Sodium Methyl 2-Sulfolaurate/Disodium 2-
Sulfolaurate Is derived from Vegetable oil as a
renewable natural resources. It is Produced by
the reaction of between an acidic and alkaline
compounds. A cleaning agent that can also be
found in a variety of laundry products. Function:
Plant based cleaning agent (Surfactant)

47. Non-Food Uses of Oleo Chemicals
EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS
Alkyl polyglycosides (APGs)
Illustrative of green cleaning agents are APGs, a class of non-
ionic surfactants widely used in a variety of household and industrial
applications. APG are derived from sugars, usually glucose
derivatives, and fatty alcohols. They are used to enhance the
formation of foams in detergents for dishwashing and for delicate
fabrics. In addition to their favourable foaming properties, they are
attractive because they readily biodegrade. The raw materials for
industrial manufacture are typically starch and fat.

48. Non-Food Uses of Oleo Chemicals
EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS
Stearyl alcohol with the formula
CH3 (CH2)16CH2OH. It is classified as a fatty alcohol. which are insoluble
in water. It has a wide range of uses as an ingredient
in lubricants, resins, perfumes and cosmetics. It is used as
an emollient, emulsifier, and thickener in ointments of various sorts, and is
widely used as a hair coating in shampoos and hair conditioners. It has also
found application as an evaporation suppressing monolayer when applied
to the surface of water. Stearyl alcohol is prepared from stearic acid by the
process of catalytic hydrogenation. It has low toxicity.

49. Non-Food Uses of Oleo Chemicals
EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS
Cetyl alcohol
also known as hexadecan-1-ol and palmityl alcohol, is a fatty alcohol with
the formula CH3(CH2)15OH. At room temperature, cetyl alcohol takes the form of
a waxy white solid or flakes.
Preparation
Cetyl alcohol Modern production is based on the reduction of palmitic acid, which
is obtained from vegetable oil.
Uses
Cetyl alcohol is used in the cosmetic industry as an opacifier in shampoos, or as
an emollient, emulsifier or thickening agent in the manufacture of skin creams and
lotions It is also employed as a lubricant for nuts and bolts, and is the active
ingredient in some "liquid pool covers" (forming a surface layer to reduce
evaporation and retain heat).

50. Non-Food Uses of Oleo Chemicals
EXAMPLE : OIL DREVATIVES AS OLEO CHEMICALS IN COSMETICS
Sorbitanne Stearate or Oleates used as Emulsifying agent in many
Cosmetics i.e. Cream , Lotions, Shaving Foams
Glycerol monostearate used as an Emulsifier & Pacifier in
Cosmetics , also as Lubricant, Anti-static agent . Fabric Softener in
Textile , Drilling & Cutting Oil
Lauryl Glucoside is a surfactant used in cosmetics. It is produced
from glucose and lauryl alcohol. Also as a Foaming agent

51. Non-Food Uses of Oleo Chemicals
Some Oleo chemical products in Personal care Formula
Peel off Face Mask & Scrub
Ceraphyl 791 Isocetyl Stearoyl Stearate
Cetyl Alcohol
Ceraphyl 368 Octyl Palmitate

52. Application of Oleochemicals in Soap, Detergents and
Cosmetic Industries
Fathy Hassan, PhD
COO, Oleo Misr
drfh71@oleomisr.com
www.oleomisr.com