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Carbon, Macromolecules and
      Carbohydrates



                             1
Elements Found in Living Organisms
• Living organisms contain
  many chemical elements,
  some in large quantities
  and some in very small
  amounts
• The 3 most common
  chemical elements of life
  are carbon, hydrogen, and
  oxygen (CHO)
• They are part of all the
  main organic compounds
  in living organisms
• Organic compounds:
  – contain carbon
  – found in living organisms
     • carbohydrates, lipids,
       amino acids are all organic
       molecules                          2
3
Examples of Chemical Elements
          and Their Roles
Element          Role in Plants or Animals

Nitrogen         Part of the amine groups of amino
                 acids and therefore proteins

Calcium          Needed to make the mineral that
                 strengthens bones and teeth

Phosphorus       Part of the phosphate groups in ATP
                 and DNA molecules

Iron             Needed to make hemoglobin and
                 thus to carry oxygen in blood

Sodium           Used in neurons (nerve cells) for
                 the transmission of nerve impulses 4
Organic Chemistry
• Study of carbon
  compounds
• Occur in more
  than just living
  things
• Are typically made
  by living things
  – Organic
    compounds come
    from organisms
  – The chemistry that
    you study in HS is
    inorganic
     • Compounds that
       are found in the
       non-living world   http://www.chemistryland.com/ElementarySchool/BuildingBlocks/BuildingOrganic.htm   5
Organic Compounds
• The molecules of many organic compounds are large and
  may seem complex, but they are built up using small and
  relatively simple subunits




                                          YOU MUST BE ABLE
                                          TO IDENTIFY THESE
                                          STRUCTURES, you do
                                          not have to be able to
                                          draw them.
                           Fatty Acid
                                                               6
Carbon Skeletons
• Vary in             • Isomers have the same
       – Length         molecular formula
       – Branching    • Isomers varying in their
       – Double bonds   structures
       – Rings                                            – Have different properties




http://fig.cox.miami.edu/~cmallery/255/255chem/p2x1.jpg
                                                                                        7
COPY THIS ENTIRE CHART!

 small organic molecules 
  larger organic molecules




                             8
SUBUNITS      MACROMOLECULES:    MACROMOLECULE
                                    ASSEMBLIES:
 ex: sugars,      ex: globular
amino acids,   proteins and RNA   ex: ribosome
nucleotides
                                                  9
• In a condensation
  reaction, 2 molecules     Condensation           Reactions
  are joined together to
  form a larger molecule
• Water is also formed in
  the reaction
• For example, 2 amino
  acids can be joined
  together to form a
  dipeptide by a
  condensation reaction
• The new bond formed is
  a peptide linkage
• Further condensation
  reactions can link amino
  acids to either end of the
  dipeptide, eventually
  forming a chain of many
  amino acids
• This is called a
  polypeptide                                                     10
                  www.pearsonsuccessnet.com activity 5.1 page 2
Condensation Reactions
• In a similar way, condensation reactions can be used to
  build up carbohydrates and lipids
• The basic subunits of carbohydrates are monosaccharides
• 2 monosaccharides can be linked to form a disaccharide
  and more monosaccharides can be linked to a
  disaccharide to form a large molecule a polysaccharide




                                                        11
glycerol
                                                      + 3H20




              three fatty-acid         triglyceride
              tails
• Fatty acids can be linked to glycerol by condensation
  reactions to produce lipids called glycerides
• A max of 3 fatty acids can be linked to each glycerol,
                                                               12
  producing a triglyceride
Hydrolysis Reactions
• Large molecules such as polypeptides, polysaccharides
  and triglycerides can be broken down into smaller
  molecules by hydrolysis
• Polypeptides + water  dipeptides or amino acids
• Polysaccharides + water  disaccharides or
  monosaccharides
• Glycerides + water  Fatty acids + glycerol




                                                          13
Monosaccharides




                  •   glucose
                  •   ribose
                  •   deoxyribose
                  •   fructose
                  •   galactose
                                    14
15
Disaccharides


                                        COMPONENT
  DISACCHARIDE     DESCRIPTION       MONOSACCHARIDES

SUCROSE       COMMON TABLE SUGAR          GLU + FRU


LACTOSE         MAIN SUGAR IN MILK     GALACTOSE + GLU


MALTOSE    PRODUCT OF STARCH HYDROLYSIS      GLU + GLU
          CAN BE USED IN BEER FERMENTATION
                                                         16
Starch




         • repeating, branching
           macromolecule
         • carb storage for plants
           – For energy
           – Cellulose               17
18
Glycogen
• storage of glucose in the liver and
  muscle
  – For energy
• animals only




                                        19
• forms exoskeleton of
Chitin     arthropods: insects,
           lobsters, shrimp,
           spiders




                                  20
POLYSACCHARIDES

Polysaccharide         Description          Monomer Unit
• STARCH         energy storage in plants          α-glucose

• CELLULOSE      structure of plant cell walls     β-glucose

• GLYCOGEN       energy storage in animals         α-glucose

• CHITIN         structure of fungi cell walls &   β-glucose
                 exoskeleton of insects
                                                               21

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06 macromolecule construction and carbs

  • 1. Carbon, Macromolecules and Carbohydrates 1
  • 2. Elements Found in Living Organisms • Living organisms contain many chemical elements, some in large quantities and some in very small amounts • The 3 most common chemical elements of life are carbon, hydrogen, and oxygen (CHO) • They are part of all the main organic compounds in living organisms • Organic compounds: – contain carbon – found in living organisms • carbohydrates, lipids, amino acids are all organic molecules 2
  • 3. 3
  • 4. Examples of Chemical Elements and Their Roles Element Role in Plants or Animals Nitrogen Part of the amine groups of amino acids and therefore proteins Calcium Needed to make the mineral that strengthens bones and teeth Phosphorus Part of the phosphate groups in ATP and DNA molecules Iron Needed to make hemoglobin and thus to carry oxygen in blood Sodium Used in neurons (nerve cells) for the transmission of nerve impulses 4
  • 5. Organic Chemistry • Study of carbon compounds • Occur in more than just living things • Are typically made by living things – Organic compounds come from organisms – The chemistry that you study in HS is inorganic • Compounds that are found in the non-living world http://www.chemistryland.com/ElementarySchool/BuildingBlocks/BuildingOrganic.htm 5
  • 6. Organic Compounds • The molecules of many organic compounds are large and may seem complex, but they are built up using small and relatively simple subunits YOU MUST BE ABLE TO IDENTIFY THESE STRUCTURES, you do not have to be able to draw them. Fatty Acid 6
  • 7. Carbon Skeletons • Vary in • Isomers have the same – Length molecular formula – Branching • Isomers varying in their – Double bonds structures – Rings – Have different properties http://fig.cox.miami.edu/~cmallery/255/255chem/p2x1.jpg 7
  • 8. COPY THIS ENTIRE CHART! small organic molecules  larger organic molecules 8
  • 9. SUBUNITS MACROMOLECULES: MACROMOLECULE ASSEMBLIES: ex: sugars, ex: globular amino acids, proteins and RNA ex: ribosome nucleotides 9
  • 10. • In a condensation reaction, 2 molecules Condensation Reactions are joined together to form a larger molecule • Water is also formed in the reaction • For example, 2 amino acids can be joined together to form a dipeptide by a condensation reaction • The new bond formed is a peptide linkage • Further condensation reactions can link amino acids to either end of the dipeptide, eventually forming a chain of many amino acids • This is called a polypeptide 10 www.pearsonsuccessnet.com activity 5.1 page 2
  • 11. Condensation Reactions • In a similar way, condensation reactions can be used to build up carbohydrates and lipids • The basic subunits of carbohydrates are monosaccharides • 2 monosaccharides can be linked to form a disaccharide and more monosaccharides can be linked to a disaccharide to form a large molecule a polysaccharide 11
  • 12. glycerol + 3H20 three fatty-acid triglyceride tails • Fatty acids can be linked to glycerol by condensation reactions to produce lipids called glycerides • A max of 3 fatty acids can be linked to each glycerol, 12 producing a triglyceride
  • 13. Hydrolysis Reactions • Large molecules such as polypeptides, polysaccharides and triglycerides can be broken down into smaller molecules by hydrolysis • Polypeptides + water  dipeptides or amino acids • Polysaccharides + water  disaccharides or monosaccharides • Glycerides + water  Fatty acids + glycerol 13
  • 14. Monosaccharides • glucose • ribose • deoxyribose • fructose • galactose 14
  • 15. 15
  • 16. Disaccharides COMPONENT DISACCHARIDE DESCRIPTION MONOSACCHARIDES SUCROSE COMMON TABLE SUGAR GLU + FRU LACTOSE MAIN SUGAR IN MILK GALACTOSE + GLU MALTOSE PRODUCT OF STARCH HYDROLYSIS GLU + GLU CAN BE USED IN BEER FERMENTATION 16
  • 17. Starch • repeating, branching macromolecule • carb storage for plants – For energy – Cellulose 17
  • 18. 18
  • 19. Glycogen • storage of glucose in the liver and muscle – For energy • animals only 19
  • 20. • forms exoskeleton of Chitin arthropods: insects, lobsters, shrimp, spiders 20
  • 21. POLYSACCHARIDES Polysaccharide Description Monomer Unit • STARCH energy storage in plants α-glucose • CELLULOSE structure of plant cell walls β-glucose • GLYCOGEN energy storage in animals α-glucose • CHITIN structure of fungi cell walls & β-glucose exoskeleton of insects 21