This report discusses polymers and polymer synthesis. It defines polymers as large molecules composed of repeating structural units or monomers joined by covalent bonds. Polymers are classified as natural, synthetic, or semi-synthetic. The report examines important natural polymers like cellulose as well as common synthetic polymers like polyethylene. It explores the manufacturing of plastics from different polymer types and polymerization reactions like addition and condensation that link monomers. In conclusion, polymers are ubiquitous materials that have revolutionized daily life due to their versatile properties and wide applications in areas like packaging and clothing.
The document summarizes various mechanisms of polymerization, including chain-growth polymerization, step-growth polymerization, radical polymerization, cationic polymerization, anionic polymerization, coordination polymerization, Ziegler-Natta catalysis, ring-opening polymerization, and the polymerization of cyclic ethers, cyclic amides, and siloxanes. It discusses reaction initiation, mechanisms, applications, and stereochemistry for different polymerization methods.
The document discusses ring opening polymerization (ROP), which is a chain growth polymerization where cyclic monomers react to form polymer chains by opening their ring structures. There are three main types of ROP - radical, anionic, and cationic - depending on whether the reactive center is a radical, anion, or cation. Examples are given of monomers that can undergo each type of ROP, along with diagrams of the mechanisms. Common applications of ROP include nylon and biopolymers like polysaccharides.
Polymers are large molecules composed of many repeating structural units. The three main types of polymerization are addition, condensation, and insertion. Addition polymerization involves chain growth where a monomer adds to the end of the growing polymer chain. Condensation polymerization involves step growth where two monomers combine by removing a small molecule. Free radical polymerization is a common type of addition polymerization that uses an initiator to generate free radicals to start the chain reaction.
Introduction to pharmaceuitcal polymer chemistryGanesh Mote
The document discusses various types of polymers including their structure, properties, and uses. It defines a polymer as a large molecule formed by the repeated linking of small molecules called monomers. Polymers can be classified based on their source, structure, molecular forces, and mode of polymerization. Common polymers discussed include polyethylene, polypropylene, polystyrene, polyvinyl chloride, teflon, and poly(methyl methacrylate). Their properties and applications in various industries are also summarized.
This document provides an overview of polymers, including their structure, properties, synthesis and applications. It defines polymers as large molecules composed of repeating monomer units. The two main types of polymerization are addition and step-growth. Addition polymers grow by sequential monomer addition while step-growth requires monomers to react and form oligomers before resulting in high molecular weight polymers. Common polymers include polyolefins like polyethylene and polypropylene as well as nylons, polyesters and natural polymers. The polymer microstructure, such as being atactic, isotactic or syndiotactic, influences properties like crystallinity and melting points.
Addition polymerization, its examples and usesRamsha Afzal
Addition polymerization involves monomers joining together through a chain reaction without producing any byproducts. Common addition polymers include polyethylene, polyvinyl chloride, polyisoprene, polypropylene, and polystyrene. Addition polymerization can occur through bulk or solution polymerization. Bulk polymerization uses only the monomers while solution polymerization uses a solvent. Both methods have advantages like control over molecular weight but also disadvantages like poor heat transfer during bulk polymerization.
Polymers are macromolecules formed by linking together small repeating units called monomers. There are two main types of polymerization: addition and condensation. Addition polymers are formed without the elimination of small molecules when monomers containing carbon-carbon double bonds polymerize via a chain reaction mechanism involving three steps: initiation, propagation, and termination. Condensation polymers are formed with the elimination of small molecules like water or ammonia when bifunctional monomers react. Common examples of addition polymerization include polyethylene formed from ethylene monomers using a free radical initiator like benzoyl peroxide.
The document provides an introduction to polymers including definitions and classifications. It discusses that polymers are large molecules composed of repeating structural units called monomers. Polymerization is the process of forming polymers from monomers. Polymers can be classified based on their response to heat, type of polymerization reaction, chemical structure, and physical structure. The key properties of polymers like strength, plasticity, chemical resistance, physical state, glass transition temperature, and mechanical properties are also summarized. Finally, some major polymer-based industries like plastics, rubber, fibers, and coatings are listed.
The document summarizes various mechanisms of polymerization, including chain-growth polymerization, step-growth polymerization, radical polymerization, cationic polymerization, anionic polymerization, coordination polymerization, Ziegler-Natta catalysis, ring-opening polymerization, and the polymerization of cyclic ethers, cyclic amides, and siloxanes. It discusses reaction initiation, mechanisms, applications, and stereochemistry for different polymerization methods.
The document discusses ring opening polymerization (ROP), which is a chain growth polymerization where cyclic monomers react to form polymer chains by opening their ring structures. There are three main types of ROP - radical, anionic, and cationic - depending on whether the reactive center is a radical, anion, or cation. Examples are given of monomers that can undergo each type of ROP, along with diagrams of the mechanisms. Common applications of ROP include nylon and biopolymers like polysaccharides.
Polymers are large molecules composed of many repeating structural units. The three main types of polymerization are addition, condensation, and insertion. Addition polymerization involves chain growth where a monomer adds to the end of the growing polymer chain. Condensation polymerization involves step growth where two monomers combine by removing a small molecule. Free radical polymerization is a common type of addition polymerization that uses an initiator to generate free radicals to start the chain reaction.
Introduction to pharmaceuitcal polymer chemistryGanesh Mote
The document discusses various types of polymers including their structure, properties, and uses. It defines a polymer as a large molecule formed by the repeated linking of small molecules called monomers. Polymers can be classified based on their source, structure, molecular forces, and mode of polymerization. Common polymers discussed include polyethylene, polypropylene, polystyrene, polyvinyl chloride, teflon, and poly(methyl methacrylate). Their properties and applications in various industries are also summarized.
This document provides an overview of polymers, including their structure, properties, synthesis and applications. It defines polymers as large molecules composed of repeating monomer units. The two main types of polymerization are addition and step-growth. Addition polymers grow by sequential monomer addition while step-growth requires monomers to react and form oligomers before resulting in high molecular weight polymers. Common polymers include polyolefins like polyethylene and polypropylene as well as nylons, polyesters and natural polymers. The polymer microstructure, such as being atactic, isotactic or syndiotactic, influences properties like crystallinity and melting points.
Addition polymerization, its examples and usesRamsha Afzal
Addition polymerization involves monomers joining together through a chain reaction without producing any byproducts. Common addition polymers include polyethylene, polyvinyl chloride, polyisoprene, polypropylene, and polystyrene. Addition polymerization can occur through bulk or solution polymerization. Bulk polymerization uses only the monomers while solution polymerization uses a solvent. Both methods have advantages like control over molecular weight but also disadvantages like poor heat transfer during bulk polymerization.
Polymers are macromolecules formed by linking together small repeating units called monomers. There are two main types of polymerization: addition and condensation. Addition polymers are formed without the elimination of small molecules when monomers containing carbon-carbon double bonds polymerize via a chain reaction mechanism involving three steps: initiation, propagation, and termination. Condensation polymers are formed with the elimination of small molecules like water or ammonia when bifunctional monomers react. Common examples of addition polymerization include polyethylene formed from ethylene monomers using a free radical initiator like benzoyl peroxide.
The document provides an introduction to polymers including definitions and classifications. It discusses that polymers are large molecules composed of repeating structural units called monomers. Polymerization is the process of forming polymers from monomers. Polymers can be classified based on their response to heat, type of polymerization reaction, chemical structure, and physical structure. The key properties of polymers like strength, plasticity, chemical resistance, physical state, glass transition temperature, and mechanical properties are also summarized. Finally, some major polymer-based industries like plastics, rubber, fibers, and coatings are listed.
Polymer Rheology(Properties study of polymer)Haseeb Ahmad
This document discusses fundamentals of polymer rheology. It defines rheology as the study of flow of matter, primarily liquids but also soft solids. Rheology is important for characterizing polymers and understanding how polymer structure affects processing behavior. The document describes different types of fluids and their viscosity properties. It also discusses various rheological measurement techniques like rotational rheometers, capillary rheometers and melt flow indexers.
Polyamides, also known as nylons, are polymers containing amide bonds along the polymer chain. Naturally occurring polyamides include proteins like wool and silk, while synthetic polyamides like nylon 6 and nylon 6,6 are produced through polymerization reactions and are widely used in textiles, automotive parts, and other applications due to their strength and durability. Polyamides are synthesized from monomers like caprolactam and can be processed via common plastic molding techniques. They possess good mechanical properties but also have limitations such as moisture absorption.
Determining molecular weights of polymers is important because it controls properties like solubility, elasticity, and mechanics. Polymers do not have uniform molecular weights but a distribution of different sizes. Molecular weight can be determined through various physical and chemical methods like end group analysis, light scattering, viscosity measurements, and gel permeation chromatography. These methods provide information about the number average molecular weight and distribution across molecules in a sample.
This document summarizes key aspects of polymer science including polymerization, monomers, and polymerization mechanisms. It discusses that polymerization is the process that links monomer molecules into polymer chains. There are different polymerization mechanisms including chain-growth and free radical polymerization. Chain-growth polymerization proceeds through initiation, propagation, and termination steps. Free radical polymerization uses initiators to generate free radicals to start the polymerization reaction. The document provides examples of monomers and initiators and discusses how functionality of monomers affects the structure of the resulting polymer chains.
Polymers are large molecules composed of repeated chemical units. The smallest repeating unit is called monomer (mono [Single] + mer [part]). The word polymer is derived from the Greek word „poly‟ = many; mers = parts. It is generally described in terms of single repeated units
Acrylics are a family of transparent plastics that include polymethyl methacrylate (PMMA). PMMA was first synthesized in 1877 and commercialized in the 1930s for uses like aircraft canopies. It is produced through radical polymerization of methyl methacrylate. PMMA has good clarity, weatherability, and scratch resistance but limited chemical resistance. It finds wide use in glazing, lighting, medical devices, and coatings. Other acrylics include polyacrylamide, used as a flocculant and soil conditioner, and sodium polyacrylate, a super absorbent polymer used in diapers and water-retention products.
The document discusses various topics related to polymers including their classification, types, mechanisms of polymerization, and methods of polymerization. Polymers can be classified based on their chain structure, chemical composition, source, and backbone. The main types are thermoplastics, thermosets, and elastomers. Polymerization can occur via addition or condensation reactions and methods include bulk, solution, suspension, and emulsion polymerization.
The document discusses crystallization and crystallinity of polymers. It defines crystallinity as the degree of structural order in a solid, where the atoms or molecules are arranged in a regular, periodic manner. Crystalline polymers have long-range order arrangement of some segments of polymer chains, while amorphous polymers do not have any degree of crystallinity. Crystallinity depends on factors like length and branching of polymer chains. Methods to evaluate crystallinity include differential scanning calorimetry, X-ray diffraction, infrared spectroscopy, and nuclear magnetic resonance. Crystallinity affects important physical properties of polymers.
Polymers are long chains of repeating molecular units called monomers. There are several types of polymers including polyethene, polypropene, nylons, polyurethanes, and polyesters. Polymers are classified based on their structure and production method. Properties depend on factors like chain length and structure. Common applications include plastic containers, clothing, pipes, sports equipment, and medical devices.
It consists classification of polymerization techniques. What is bulk polymerization, how will the reaction proceed, and what are the advantages, disadvantages, and applications. Similarly, what is solution polymerization and how it will be carried out, what are the advantages, disadvantages, and applications behind it everything is explained in detail. Some of the related questions are also included for practice. All the contents taken from different websites and books are also mentioned.
Polymer - a long chain molecule made up of many small identical units of Monomer is known as Polymer.
Monomer - the smallest repeating unit is known as Monomer.
Polymer is a molecule is obtained by natural and synthetic origin having group of Smallest repeating unit is known as polymer.
Polymer is important for increasing the stability of drug molecule, it is important to influencing the solubility of drug molecule, it is important to maintain the Physicochemical properties, it is important to maintain the prolong stability of drug molecule in extended period of time, it is important for influencing the Bioavailability of drug.
Polymer is important for Pharmaceutical industries and research purpose.
This document provides an introduction to polymers including their classification, structure, common types, and mechanisms of polymerization. Polymers are macromolecules composed of repeating structural units connected through polymerization reactions. They can be classified based on their structure as linear, branched, or cross-linked. Common addition polymers include polyethylene, polypropylene, polyvinyl chloride, and nylon. Condensation polymers include polyethylene terephthalate and polyamides. Polymerization occurs primarily through either addition or condensation reactions. Free radical addition polymerization follows initiation, propagation, and termination steps.
Polymer science deals with large macromolecules made of repeating monomer units. Polymers can be classified in several ways, including by their origin (synthetic, biopolymer, etc.), monomer composition (homopolymer, copolymer like statistical, alternating, block, and graft), chain structure (linear, branched, cross-linked, network), and thermal behavior (thermoplastics and thermosets). Polymerization can occur through step-growth or chain-growth mechanisms. Polymers degrade through various means including chemical, biological, mechanical, chlorine-induced, thermal, and photo degradation which can impact properties like strength, color, and shape over time.
The document discusses the mechanisms of polymerization, including chain growth and step growth polymerization. Chain growth polymerization involves the repeated addition of monomers with double or triple bonds to form polymers. Step growth polymerization occurs through condensation reactions between bifunctional or multifunctional monomers to form dimers, trimers, and eventually long chain polymers. The key mechanisms of chain growth polymerization, including free radical, cationic, and anionic polymerization are described. The mechanisms of step growth polymerization through condensation reactions are also outlined.
Condensation polymerization involves monomers with functional groups like alcohols and carboxylic acids. During condensation polymerization, these functional groups react to form polymer chains, releasing small molecules like water or methanol as byproducts. This results in strong covalent bonds between the monomers, such as amide or ester linkages. Common examples of condensation polymerization are the reaction of a carboxylic acid and amine to form an amide linkage, or a carboxylic acid and alcohol to form an ester linkage. Condensation polymerization is an important process that allows for the production of many plastics and other materials.
The document discusses various topics related to polymerization including:
1. Definitions of polymerization, degree of polymerization, and different polymerization mechanisms including addition, condensation, and co-polymerization.
2. Addition polymerization involves monomers adding to the growing chain without byproducts, while condensation polymerization eliminates molecules like water as monomers join.
3. Common polymerization techniques are discussed briefly, including bulk, solution, suspension, and emulsion polymerization.
Copolymerization involves polymerizing two or more different monomers simultaneously so that the resulting polymer contains more than one type of repeating unit in the polymer chain. There are several types of copolymers including random, alternating, block, and graft copolymers. The composition of a copolymer depends on factors like the monomer concentrations and their reactivity ratios. Kinetic models can be used to predict the monomer composition of the copolymer based on the monomer feed using methods like the Mayo-Lewis equation or the Fineman-Ross equation. The reactivity ratios influence whether an ideal random copolymer, alternating copolymer, or block copolymer will form. Ionic copolymerization
- Polymers are giant molecules formed by linking together small repeating units called monomers via covalent bonds. There are three main types of polymerization: addition, condensation, and copolymerization.
- Properties of polymers depend on factors like the monomer type, the degree of polymerization, tacticity, and whether the polymer is crystalline or amorphous. Common polymers include polyethylene, polypropylene, nylon, polyethylene terephthalate.
- Natural rubbers are polymers of the monomer isoprene that provide flexibility and elasticity. However, natural rubber has limitations that are overcome through vulcanization, which introduces cross-links between polymer chains through the addition of sulfur.
This document discusses synthetic polymers. Synthetic polymers are man-made polymers created through chemical processes in laboratories by linking monomers together. Examples of synthetic polymers include plastics, fibers, and elastomers. While synthetic polymers have many applications, they also cause pollution problems as most are non-biodegradable. Methods to address this include reducing use, reusing and recycling polymers, as well as developing biodegradable polymers.
This document discusses synthetic polymers. Synthetic polymers are man-made polymers created through chemical processes in laboratories by linking monomers together. Examples of synthetic polymers include plastics, fibers, and elastomers. While synthetic polymers have many applications, they also cause pollution problems as most are non-biodegradable. Methods to address this include reducing use, reusing and recycling polymers, as well as developing biodegradable polymers.
Polymer Rheology(Properties study of polymer)Haseeb Ahmad
This document discusses fundamentals of polymer rheology. It defines rheology as the study of flow of matter, primarily liquids but also soft solids. Rheology is important for characterizing polymers and understanding how polymer structure affects processing behavior. The document describes different types of fluids and their viscosity properties. It also discusses various rheological measurement techniques like rotational rheometers, capillary rheometers and melt flow indexers.
Polyamides, also known as nylons, are polymers containing amide bonds along the polymer chain. Naturally occurring polyamides include proteins like wool and silk, while synthetic polyamides like nylon 6 and nylon 6,6 are produced through polymerization reactions and are widely used in textiles, automotive parts, and other applications due to their strength and durability. Polyamides are synthesized from monomers like caprolactam and can be processed via common plastic molding techniques. They possess good mechanical properties but also have limitations such as moisture absorption.
Determining molecular weights of polymers is important because it controls properties like solubility, elasticity, and mechanics. Polymers do not have uniform molecular weights but a distribution of different sizes. Molecular weight can be determined through various physical and chemical methods like end group analysis, light scattering, viscosity measurements, and gel permeation chromatography. These methods provide information about the number average molecular weight and distribution across molecules in a sample.
This document summarizes key aspects of polymer science including polymerization, monomers, and polymerization mechanisms. It discusses that polymerization is the process that links monomer molecules into polymer chains. There are different polymerization mechanisms including chain-growth and free radical polymerization. Chain-growth polymerization proceeds through initiation, propagation, and termination steps. Free radical polymerization uses initiators to generate free radicals to start the polymerization reaction. The document provides examples of monomers and initiators and discusses how functionality of monomers affects the structure of the resulting polymer chains.
Polymers are large molecules composed of repeated chemical units. The smallest repeating unit is called monomer (mono [Single] + mer [part]). The word polymer is derived from the Greek word „poly‟ = many; mers = parts. It is generally described in terms of single repeated units
Acrylics are a family of transparent plastics that include polymethyl methacrylate (PMMA). PMMA was first synthesized in 1877 and commercialized in the 1930s for uses like aircraft canopies. It is produced through radical polymerization of methyl methacrylate. PMMA has good clarity, weatherability, and scratch resistance but limited chemical resistance. It finds wide use in glazing, lighting, medical devices, and coatings. Other acrylics include polyacrylamide, used as a flocculant and soil conditioner, and sodium polyacrylate, a super absorbent polymer used in diapers and water-retention products.
The document discusses various topics related to polymers including their classification, types, mechanisms of polymerization, and methods of polymerization. Polymers can be classified based on their chain structure, chemical composition, source, and backbone. The main types are thermoplastics, thermosets, and elastomers. Polymerization can occur via addition or condensation reactions and methods include bulk, solution, suspension, and emulsion polymerization.
The document discusses crystallization and crystallinity of polymers. It defines crystallinity as the degree of structural order in a solid, where the atoms or molecules are arranged in a regular, periodic manner. Crystalline polymers have long-range order arrangement of some segments of polymer chains, while amorphous polymers do not have any degree of crystallinity. Crystallinity depends on factors like length and branching of polymer chains. Methods to evaluate crystallinity include differential scanning calorimetry, X-ray diffraction, infrared spectroscopy, and nuclear magnetic resonance. Crystallinity affects important physical properties of polymers.
Polymers are long chains of repeating molecular units called monomers. There are several types of polymers including polyethene, polypropene, nylons, polyurethanes, and polyesters. Polymers are classified based on their structure and production method. Properties depend on factors like chain length and structure. Common applications include plastic containers, clothing, pipes, sports equipment, and medical devices.
It consists classification of polymerization techniques. What is bulk polymerization, how will the reaction proceed, and what are the advantages, disadvantages, and applications. Similarly, what is solution polymerization and how it will be carried out, what are the advantages, disadvantages, and applications behind it everything is explained in detail. Some of the related questions are also included for practice. All the contents taken from different websites and books are also mentioned.
Polymer - a long chain molecule made up of many small identical units of Monomer is known as Polymer.
Monomer - the smallest repeating unit is known as Monomer.
Polymer is a molecule is obtained by natural and synthetic origin having group of Smallest repeating unit is known as polymer.
Polymer is important for increasing the stability of drug molecule, it is important to influencing the solubility of drug molecule, it is important to maintain the Physicochemical properties, it is important to maintain the prolong stability of drug molecule in extended period of time, it is important for influencing the Bioavailability of drug.
Polymer is important for Pharmaceutical industries and research purpose.
This document provides an introduction to polymers including their classification, structure, common types, and mechanisms of polymerization. Polymers are macromolecules composed of repeating structural units connected through polymerization reactions. They can be classified based on their structure as linear, branched, or cross-linked. Common addition polymers include polyethylene, polypropylene, polyvinyl chloride, and nylon. Condensation polymers include polyethylene terephthalate and polyamides. Polymerization occurs primarily through either addition or condensation reactions. Free radical addition polymerization follows initiation, propagation, and termination steps.
Polymer science deals with large macromolecules made of repeating monomer units. Polymers can be classified in several ways, including by their origin (synthetic, biopolymer, etc.), monomer composition (homopolymer, copolymer like statistical, alternating, block, and graft), chain structure (linear, branched, cross-linked, network), and thermal behavior (thermoplastics and thermosets). Polymerization can occur through step-growth or chain-growth mechanisms. Polymers degrade through various means including chemical, biological, mechanical, chlorine-induced, thermal, and photo degradation which can impact properties like strength, color, and shape over time.
The document discusses the mechanisms of polymerization, including chain growth and step growth polymerization. Chain growth polymerization involves the repeated addition of monomers with double or triple bonds to form polymers. Step growth polymerization occurs through condensation reactions between bifunctional or multifunctional monomers to form dimers, trimers, and eventually long chain polymers. The key mechanisms of chain growth polymerization, including free radical, cationic, and anionic polymerization are described. The mechanisms of step growth polymerization through condensation reactions are also outlined.
Condensation polymerization involves monomers with functional groups like alcohols and carboxylic acids. During condensation polymerization, these functional groups react to form polymer chains, releasing small molecules like water or methanol as byproducts. This results in strong covalent bonds between the monomers, such as amide or ester linkages. Common examples of condensation polymerization are the reaction of a carboxylic acid and amine to form an amide linkage, or a carboxylic acid and alcohol to form an ester linkage. Condensation polymerization is an important process that allows for the production of many plastics and other materials.
The document discusses various topics related to polymerization including:
1. Definitions of polymerization, degree of polymerization, and different polymerization mechanisms including addition, condensation, and co-polymerization.
2. Addition polymerization involves monomers adding to the growing chain without byproducts, while condensation polymerization eliminates molecules like water as monomers join.
3. Common polymerization techniques are discussed briefly, including bulk, solution, suspension, and emulsion polymerization.
Copolymerization involves polymerizing two or more different monomers simultaneously so that the resulting polymer contains more than one type of repeating unit in the polymer chain. There are several types of copolymers including random, alternating, block, and graft copolymers. The composition of a copolymer depends on factors like the monomer concentrations and their reactivity ratios. Kinetic models can be used to predict the monomer composition of the copolymer based on the monomer feed using methods like the Mayo-Lewis equation or the Fineman-Ross equation. The reactivity ratios influence whether an ideal random copolymer, alternating copolymer, or block copolymer will form. Ionic copolymerization
- Polymers are giant molecules formed by linking together small repeating units called monomers via covalent bonds. There are three main types of polymerization: addition, condensation, and copolymerization.
- Properties of polymers depend on factors like the monomer type, the degree of polymerization, tacticity, and whether the polymer is crystalline or amorphous. Common polymers include polyethylene, polypropylene, nylon, polyethylene terephthalate.
- Natural rubbers are polymers of the monomer isoprene that provide flexibility and elasticity. However, natural rubber has limitations that are overcome through vulcanization, which introduces cross-links between polymer chains through the addition of sulfur.
This document discusses synthetic polymers. Synthetic polymers are man-made polymers created through chemical processes in laboratories by linking monomers together. Examples of synthetic polymers include plastics, fibers, and elastomers. While synthetic polymers have many applications, they also cause pollution problems as most are non-biodegradable. Methods to address this include reducing use, reusing and recycling polymers, as well as developing biodegradable polymers.
This document discusses synthetic polymers. Synthetic polymers are man-made polymers created through chemical processes in laboratories by linking monomers together. Examples of synthetic polymers include plastics, fibers, and elastomers. While synthetic polymers have many applications, they also cause pollution problems as most are non-biodegradable. Methods to address this include reducing use, reusing and recycling polymers, as well as developing biodegradable polymers.
Polymers Meyer (2014) suggests that a contemporary culture could n.docxChantellPantoja184
Polymers Meyer (2014) suggests that a contemporary culture could not long endure without the goods or products that the polymer industry provides (p. 607). These polymeric products include clothing, household/office, indoor and outdoor gadgets, and furnishings that are manufactured from natural and synthetic polymers. Polymers are not ordinarily considered hazardous materials since they are stable at ambient conditions; however, most of the products burn and produce toxic gases (Meyer, 2014). Because of their widespread use, it is of benefit to understand why and how they can pose hazards, especially during fires. For this unit, we will study the features and structural characteristics of commonly encountered polymers as well as the hazards that they pose when they burn. What are polymers? The International Union of Pure and Applied Chemistry (IUPAC) education website defines polymers as substances or macromolecules that “are composed of very large molecules with molecular weights ranging from a few thousand to as high as millions of grams/mole” (n.d., para. 1). For additional information on polymers, visit http://www.iupac.org/polyedu/page33/page33.html. The structure of a macromolecule is essentially comprised of multiple repetitions of units derived, actually or conceptually, from molecules of low molecular mass. Polymers can be natural or synthetic, but most of us probably associate polymers with the synthetic ones such as plastic. Examples of natural polymers include protein, starch, cellulose, and DNA that make up most of the structures of living tissue. Synthetic polymers include polyvinyl chloride (PVC), polycarbonate, and polyethylene. UNIT VII STUDY GUIDE Chemistry of Toxic Substances BOS 3640, Interactions of Hazardous Materials 2 UNIT x STUDY GUIDE Title Types of synthetic polymers: Synthetic polymers are often referred to as plastics, and most of them can be classified into the categories of elastomers, thermoplastics, and thermosets: Thermoplastics are polymers that soften when heated but return to their original condition on cooling to ambient temperature (e.g., polyvinyl chloride (PVC), polyethylene). Thermosets are polymers that cannot be remolded once they have solidified, such as polyurethane. Elastomers have elasticity like rubber (Polymer Science Learning Center, 2005). Polymerization is the chemical reaction during which monomers are linked and cross-linked to form polymers. The polymerization reaction is characterized by the macromolecule/polymer that is produced (see Figures 14.1 and 14.2 of the textbook). According to Meyer (2014), chemists have found when they examined the three-dimensional structure of polymers that the chains of repeating units are invariably cross-linked as shown in Figure 14.3 of the textbook. Note the following information about polymers: Intentional cross-linking technique for polymers is used during the production of thermoset plastics to make the polymer denser, stronger, and even elastic.
Plastic is any of a wide range of synthetic or semi-synthetic materials that are moldable. Most plastics are derived from petrochemicals but some are partially natural. Plastics have a variety of properties including strength, flexibility, durability and the ability to be easily molded. There are two main types of plastics - thermoplastics, which soften when heated and can be reshaped, and thermosets, which cannot be reshaped after manufacture. Common plastics include polyvinyl chloride (PVC), polyethylene, and polypropylene, each with different chemical compositions and physical properties used in a wide range of applications.
This document provides an overview of pharmaceutical polymers. It begins by listing 8 objectives for understanding polymers and their applications. The introduction defines polymers as large molecules composed of repeating monomer units and notes their growing use in pharmaceuticals and biomedical applications. The history section outlines some important early polymers like celluloid and nylon and their uses. The document then covers general polymer concepts including monomer definition and molecular weight before discussing polymer synthesis methods of addition and condensation polymerization.
This document discusses polymers used in everyday life. It begins with an abstract that outlines how polymers have become revolutionary materials in modern life due to their vast array of properties. It then provides classifications of polymers based on source, molecular structure, bonding type, and polymerization process. Common polymers discussed include polyethylene, polypropylene, nylon, polyester, and polymers used in packaging, clothing, construction materials, and more. Polymers are shown to pervade many industries and aspects of modern life due to their versatility and material properties.
The document discusses various topics related to polymers including their classification, modes of polymerization, applications, and synthesis methods. It describes how polymers can be classified based on their source (natural, semi-synthetic, synthetic) or mode of polymerization (addition, condensation, photopolymers, copolymers). Major applications of polymers discussed include elastomers like rubber, plastics, and synthetic fibers. The synthesis of polymers is described as occurring via chain growth polymerization methods like radical chain-growth and cationic chain-growth, or step growth polymerization. Thermoplastic and thermosetting resins are also differentiated.
This document discusses various topics related to polymers including their classification, modes of polymerization, applications, and synthesis methods. It describes how polymers can be classified based on their source (natural, semi-synthetic, synthetic) or mode of polymerization (addition, condensation, photopolymers). Important applications of polymers discussed include elastomers, plastics, fibers, conducting polymers, and biodegradable polymers. The document also explains chain and step growth polymerization, thermoplastic vs thermosetting resins, and provides examples of important polymers like styrene-butadiene rubber, polyethylene, nylon, and lignin.
The document discusses performance materials and textiles, including how properties of polymers influence textile applications and how unique textiles can be developed using nanotechnology. It provides examples of potential applications such as bulletproof clothing using carbon nanotubes and self-repairing uniforms that could help spinal patients. The document also explores how properties of synthetic textiles can be controlled chemically and how nanotechnology is being used to create textiles with novel functions such as odor elimination, environmental sensing, and intelligent design.
PLASTICS.pdf ALL ABOUT THE JOURNEY OF PLASTICSShriguniAdmane
Plastics are a wide range of synthetic or semi-synthetic materials that use polymers as a main ingredient. Their plasticity makes it possible for plastics to be moulded, extruded or pressed into solid objects of various shapes. This adaptability, plus a wide range of other properties, such as being lightweight, durable, flexible, and inexpensive to produce, has led to its widespread use. Plastics typically are made through human industrial systems. Most modern plastics are derived from fossil fuel-based chemicals like natural gas or petroleum; however, recent industrial methods use variants made from renewable materials, such as corn or cotton derivatives.[1]
9.2 billion tonnes of plastic are estimated to have been made between 1950 and 2017. More than half this plastic has been produced since 2004. In 2020, 400 million tonnes of plastic were produced.[2] If global trends on plastic demand continue, it is estimated that by 2050 annual global plastic production will reach over 1.1 billion tonnes.
The success and dominance of plastics starting in the early 20th century has caused widespread environmental problems,[3] due to their slow decomposition rate in natural ecosystems. Most plastic produced has not been reused, or is incapable of reuse, either being captured in landfills or persisting in the environment as plastic pollution and microplastics. Plastic pollution can be found in all the world's major water bodies, for example, creating garbage patches in all of the world's oceans and contaminating terrestrial ecosystems. Of all the plastic discarded so far, some 14% has been incinerated and less than 10% has been recycled.[2]
In developed economies, about a third of plastic is used in packaging and roughly the same in buildings in applications such as piping, plumbing or vinyl siding.[4] Other uses include automobiles (up to 20% plastic[4]), furniture, and toys.[4] In the developing world, the applications of plastic may differ; 42% of India's consumption is used in packaging.[4] In the medical field, polymer implants and other medical devices are derived at least partially from plastic. Worldwide, about 50 kg of plastic is produced annually per person, with production doubling every ten years.
The world's first fully synthetic plastic was Bakelite, invented in New York in 1907, by Leo Baekeland,[5] who coined the term "plastics".[6] Dozens of different types of plastics are produced today, such as polyethylene, which is widely used in product packaging, and polyvinyl chloride (PVC), used in construction and pipes because of its strength and durability. Many chemists have contributed to the materials science of plastics, including Nobel laureate Hermann Staudinger, who has been called "the father of polymer chemistry," and Herman Mark, known as "the father of polymer physics"The word plastic derives from the Greek πλαστικός (plastikos) meaning "capable of being shaped or molded," and in turn from πλαστός (plastos) meaning "molded."
Many materials in day to day use are made from natural and synthetic polymers as constituents. Polymer based industries are products of research and development.
Polymers are giant molecules composed of repeating structural units joined together. They can be classified based on their origin (natural, semi-synthetic, synthetic), thermal response (thermoplastic, thermosetting), structure (linear, branched, cross-linked), and application (rubber, plastic, fibers). Polymerization is the process of linking monomers together to form polymers. It occurs via two main mechanisms: step-growth polymerization (condensation polymerization) and chain-growth polymerization (addition polymerization). Step-growth involves the elimination of a small molecule as monomers react together in a step-wise manner, while chain-growth is a chain reaction with no byproducts as monomers continuously add to the
This document provides an overview of topics that will be covered in a Polymer Chemistry course. The topics include: introduction to polymer chemistry including history, definitions, classifications and structures; mechanisms and nomenclature of polymers; chemistry of polymerization including chain, step and ring opening polymerization; polymerization techniques; polymer additives; molecular weights of polymers; silicone and cellulose polymers; and polymer reactions. The course will reference several textbooks on polymer science and chemistry.
Polymers are long-chain molecules composed of repeating structural units called monomers. They can be classified in several ways: by source (natural, synthetic, semi-synthetic), structure (linear, branched, cross-linked), polymerization type (addition, condensation), molecular forces (elastomers, thermoplastics, thermosets, fibers), and as biopolymers from living organisms. Polymers have a variety of uses depending on their properties and classifications.
Plastics are a wide range of synthetic or semi-synthetic organic compounds that are malleable and so can be molded into solid objects. Plasticity is the general property of all materials which can deform irreversibly without breaking but, in the class of moldable polymers, this occurs to such a degree that their actual name derives from this specific ability.
The document provides an overview of the key concepts and lessons to be covered in a 12-lesson module on materials. The lessons will cover choosing materials based on their properties, polymers, testing materials, and zooming in on fibers at the molecular level. Specific topics include natural vs synthetic materials, polymers and monomers, tensile strength testing, and how the structure of fibers like cotton and wool impact the properties of woven cloth.
This document provides an overview of polymers including their classification, characteristics, and applications. It discusses how polymers are large molecules formed from monomers linking together in chains. Polymers can be classified based on their source, structure, polymerization method, or molecular forces. They have properties like low density, moldability, and corrosion resistance. Important applications of polymers discussed are for oral, transdermal, and ocular drug delivery systems where they can control and sustain drug release through diffusion, degradation, or swelling mechanisms.
This document summarizes the history and development of plastics. It discusses how plastics originated from natural resins and cellulose derivatives in the 1860s. Major milestones included the development of Bakelite in the early 1900s and nylon in the 1930s. World War II provided a boost to plastics development as alternatives were needed for scarce natural materials. Common plastics developed after the war include polyethylene and polypropylene. Plastics are classified based on their chemical structure and have a wide range of uses but also disadvantages like non-biodegradability and contribution to pollution.
Thermal cracking is a process that breaks down heavy hydrocarbon molecules into lighter products like gasoline. It involves heating residues from crude oil distillation under pressure without a catalyst. There are different types of thermal cracking processes, including visbreaking which mildly cracks residues into fuel oil, and coking which fully converts residues into lighter products and coke. Thermal cracking is an older process that produces more olefinic and aromatic products compared to catalytic cracking.
This document provides an overview of numerical analysis methods and their applications in chemical engineering. It begins with introductions to numerical analysis and its history. Literature review sections define numerical analysis and discuss why it is used in engineering and examples of its applications in chemical processes. The methodology section describes how numerical methods are applied and examples of specific methods. Results and discussion evaluate accuracy of numerical methods. The conclusion states that numerical methods are necessary for complex problems that cannot be solved analytically. References are provided.
This document provides an overview of Hazard and Operability Studies (HAZOP). It discusses the importance and methodology of HAZOP analysis, including forming a team, identifying system elements and parameters, considering deviations, and identifying hazards. Keywords such as "no", "less", and "more" are used to systematically analyze each part of a process. The document also briefly discusses applications of HAZOP for design, operational, and procedural assessments and compares it to other risk analysis tools. An example HAZOP study for an acetylene production industry is referenced.
This document discusses process simulation software used in chemical engineering. It begins with definitions of simulation and discusses the history and advantages of simulation. It then reviews common simulation software programs including Aspen Plus, Aspen HYSYS, ProMax, ChemCAD, and PRO/II. These programs are widely used in chemical engineering applications such as petroleum processing, refining, petrochemicals, and more. The document concludes that simulation is a powerful tool that allows testing of scenarios without costly real-world experimentation. Aspen Plus and HYSYS are among the most commonly used simulation programs.
This document provides an overview of a crude oil desalting unit. The desalting unit removes salt, water, and other contaminants from crude oil through a washing process before refining. It discusses the types of desalters as well as single-stage and two-stage desalting systems. The key steps of the desalting process are described as mixing fresh water with crude oil to dilute salt levels, heating the mixture, and applying an electric field to coalesce water droplets and promote separation from the crude oil. The goal is to reduce salt levels and water content to levels suitable for further refining.
This document provides an overview of process control applications in chemical industries. It discusses what process control is, why it is needed, common control techniques like feedback control, and examples of control systems for units like chemical reactors and boilers. Process control is used to maximize safety, quality and efficiency in chemical processes. It allows preserving product quality while optimizing production. The document also reviews various software and instruments used for process control and highlights its importance across many industrial sectors.
The document describes the process of refining crude oil at an oil refinery. It discusses that crude oil is a complex mixture of hydrocarbons extracted from underground that is refined through processes like distillation, cracking, and reforming. The refining process involves separating crude oil through a crude distillation unit and vacuum distillation unit. Further stages include conversion processes that break down larger molecules into lighter products, as well as hydrotreating to remove impurities. The overall refining process transforms crude oil into useful products like gasoline, diesel, and feedstocks for petrochemicals.
This document provides an overview of balance sheets and income statements for engineering economics. It defines key terms like assets, liabilities, equity, revenues and expenses. A balance sheet captures a company's financial position at a point in time by listing assets, liabilities, and equity. An income statement measures performance over time by reporting revenues and expenses to determine profit or loss. The document discusses uses of each statement and provides examples to analyze financial performance and health.
This lab report describes an experiment on linear heat conduction. The experiment was conducted by a group of students to calculate the thermal conductivity of stainless steel and brass. Temperature readings were recorded at different points along the length of each material as heat was applied to one end. The thermal conductivity was then calculated using Fourier's law of heat conduction. The results found that stainless steel has a thermal conductivity of 33.49 W/mK and brass has a thermal conductivity of 47.02 W/mK. A graph was included showing the relationship between temperature and distance for each material.
This lab report summarizes an experiment conducted to calculate the overall heat transfer coefficient (U) of a shell and tube heat exchanger with uniflow configuration. Temperature and flow rate data was collected for the hot and cold water streams at various flow rates. The heat transfer rate (Q) was calculated using this data and equations for mass flow rate and log mean temperature difference. The overall heat transfer coefficient (U) was then calculated for each set of data using the equation U=Q/(A*ΔTlm). U values ranged from 1.696 to 92.05 W/m2K over the range of flow rates tested in the uniflow shell and tube heat exchanger.
This lab report summarizes an experiment conducted to calculate the overall heat transfer coefficient in a shell and tube heat exchanger with uniflow configuration. Temperature and flow rate data was collected for the hot and cold fluids. The average temperature difference and heat transfer rate were calculated. The overall heat transfer coefficient was determined to be 1285.8 W/m2.K.
This lab report summarizes an experiment conducted on a double pipe heat exchanger to determine the amount of heat loss by hot water flowing through in a uniflow configuration. The experiment involved measuring the temperatures at the inlet and outlet of the hot and cold water pipes. The measurements were used to calculate the average temperature, mass flow rate, heat capacity, and temperature difference to determine the quantity of heat lost by the hot water. The purpose was to study heat transfer through a double pipe heat exchanger and understand how it can be used for applications like cooling fluids.
1. The purpose of the experiment is to determine the thermal conductivity (k) of materials using linear and radial heat conduction.
2. The document outlines the theory of linear and radial heat conduction according to Fourier's law. It provides the equations to calculate thermal conductivity based on heat transfer rate, temperature gradient, thickness/radius, and area.
3. The experiment procedures involve measuring temperature gradients across materials and calculating k for different materials using the provided equations. Graphs of temperature vs. position will also be analyzed to determine k. Results will be reported and compared to literature values.
The document describes an experiment conducted to determine the residence time and conversion in three continuous stirred tank reactors (CSTRs) of different heights (7 cm, 5 cm, and 4 cm) at room temperature. Sodium hydroxide and ethyl acetate solutions were continuously fed into each reactor, and the conductivity was measured to calculate the concentration and conversion. The residence time was calculated by dividing the reactor volume by the volumetric flow rate. It was found that as the reactor height decreased, both the residence time and conversion also decreased, indicating the two values are directly proportional.
This lab report summarizes an experiment examining the impact of ethyl acetate flow rate on conversion in a plug flow reactor at 21°C. Students measured conductivity at four increasing flow rates and calculated conversion using conductivity readings. Results showed conversion decreased as flow rate increased, because higher flow rates gave reactants less time to fully react before exiting the reactor. The experiment helped students learn how conversion in a plug flow reactor is affected by changing an inlet flow rate.
The document summarizes a lab experiment on the impact of limiting reactant flow rate on conversion in a plug flow reactor at 21°C. Sodium hydroxide and ethyl acetate solutions were pumped through the reactor at increasing flow rates of the limiting reactant, sodium hydroxide. Conductivity readings were taken and used to calculate concentration and conversion. It was found that increasing the limiting reactant flow rate increased conductivity but decreased conversion, as the reaction had less time to fully complete. Group members' discussions analyzed the procedure and results, noting the inverse relationship between conductivity and conversion with changing flow rate.
The document describes a lab experiment conducted to determine the conversion of a plug flow reactor (PFR) at 20°C. Two reactants, 0.05M NaOH and 0.05M CH3COOHC2H5, were pumped through the PFR and the conductivity was measured to calculate conversion. The conversion was found to be 0.965. Previous experiments showed laminar flow reactors have the highest conversion rates, followed by batch reactors and then PFRs. Group members discussed the procedure, calculations, and comparison to other reactor types.
The students conducted an experiment using a laminar flow reactor to determine conductivity and conversion of reactants at 20°C. They introduced 0.05M solutions of NaOH and CH3COOHC2H5 into the reactor and measured a conductivity of 2.8μS. Using the conductivity readings and known values, they calculated the concentration of reactants and determined the conversion to be 0.99. The students discussed the procedure and goals of the experiment and potential sources of error in their measurements and calculations.
The lab report describes an experiment conducted to determine the conversion in a tubular flow reactor at 21°C. Two reactants, 1L of 0.05M NaOH and 1L of 0.05M CH3COOHC2H5, were pumped through the reactor and the conductivity of the product was measured over time. The conductivity readings were used to calculate the concentration and conversion using provided equations. The group determined the conversion in the tubular flow reactor at 21°C was 0.917 based on their calculations and results.
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Polymer and polymer synthesis
1. Koya University
Faculty of Engineering
Chemical Engineering Department
Engineering Materials
Engineering Materials Report
Polymer and Polymer Synthesis (Polymerization)
Instructor
Mr. Majeed Kakarash
Prepared by
Safeen Yaseen Jafar
Submitted Date
22 Apr 2021
2. TABLE OF CONTENTS
ABSTRACT/SUMMARY................................................................................................ 1
1. INTRODUCTION........................................................................................................ 2
2. BODY ........................................................................................................................5-11
2.1 WHAT ARE POLYMERS AND POLYMERIZATION .......................................................... 5
2.2 Classifications of Polymers................................................................................... 5
2.2.1 Natural Polymers ............................................................................................... 6
2.2.2 Synthetic Polymers .............................................................................................. 8
2.3 WHY POLYMERS ARE IMPORTANT?............................................................................ 9
2.4 PRIMARY PLASTIC PRODUCTION FROM POLYMER TYPES......................................... 10
2.5 POLYMERIZATION - HOW POLYMERS ARE SYNTHESIZES?......................................... 11
3. DISCUSSION ............................................................................................................. 12
4. CONCLUSION........................................................................................................... 14
5. LIST OF REFERENCES ......................................................................................... 15
4. 1
Abstract
We know that the materials are all around of us and they have most effects on many
things, benefits, contribution with very large amount of each matter in this world and also have
different properties. If we look anywhere, we can feel the materials in there. So, in this report we
talk about one of the materials which contribute with most of the materials of our equipments in
daily life which we will mention in the next sections in this report. This report helps us to
understand the polymers and how they made or joined together. However, this report includes
the classifications of polymers, types, importance, applications in our life, So on. You can get
other information about the polymers and synthesis of polymers.
5. 2
1. Introduction
Polymers are all around us. The foods we eat and clothes we wear are made of polymers.
Some of the most common natural polymers include starch, cellulose, and proteins. Some
synthetic polymers may be familiar to you as plastics and synthetic fibers. Polymers become the
raw materials for products we now use every day, including: synthetic clothing, fiberglass,
plastic bags, nylon bearing, polyethylene cups, epoxy glue, silicone heart valves, Teflon-coated
cookware and our personal favorite, polymer-based paints. Today, polymeric materials are used
in nearly all areas of daily life and their production and fabrication are major worldwide
industries. [1]
However, polymers exist in difference types by another word the can classified into some
types. For instance, in this page, you can see this picture on the right hand two main class of
polymers.
Polymers generally have high molecular weights ranging from 10,000 to 1,000,000 g/mol.
Synthetic polymers are really mixtures of individual polymer chains of varying lengths, so the
reported molecular weight is an average value based on the average size of the polymer chain.
We can write the structure of a polymer by shorthand and in simple by placing brackets round
the retelling unit that forms the chain. [2]
Figure (1) – In these two figures you can see too class of polymers which are Natural Polymers
and Synthetic Polymers
Figure (2) – this figure shown as the drawing of polymer structures.
6. 3
Polymers have many usages and applications in our daily life. By another word we can
say polymers play a huge role in our day to day lives. Also, their usages are wide and include
many our needs or helpful works. It is important to understand that most of the alkene monomers
are obtained in some part from crude oil and therefore it is critical that we recycle plastics to
conserve our natural resources for the future manufacture of these polymers. There are also big
problems with the disposal of polymers. However, the burning of polymers produces many toxic
gases which themselves can damage the environment and cause pollution. [3]
Figure (3) – If you see this figure, you can feel many applications of polymers around yourself.
7. 4
1.2 History of Polymer and It’s synthesis (Polymerization)
The word (Polymer) is derived from the Greek word (poly) and (mer), poly means many
and mer means parts, respectively. Some scientists prefer to use the word macromolecule, or
large molecule, instead of polymer. Polymers have existed in natural form since life began, and
those such as DNA, RNA, proteins and polysaccharides play crucial roles in plant and animal
life. During the last century and a half, new families of engineering materials known as polymers
have been discovered and produced, that have not only challenged the classical materials but
have also made possible the realization of new products which have contributed to extend the
range of activities of mankind. [4]
Figure (4) - This figure shows the
graph that related to plastic
production growing (one of
polymers)
In 1820, Thomas Hancock discovered that when masticated, natural rubber becomes
more fluid making it easier to blend with additives and to mound. Some years later, in 1839,
Charles Goodyear found that the elastic properties of natural rubber could be improved, and its
tackiness eliminated, by heating with sulfur. Patents for this discovery were issued in 1844 to
Goodyear, and slightly earlier to Hancock, who christened the process vulcanization. In 1851,
Nelson Goodyear, Charles’ brother, patented the vulcanization of natural rubber with large
amounts of sulfur to produce a hard material more commonly known as hard rubber, ebonite or
vulcanite. [5]
Polymers History of Polymers
1. From earliest time to 1900: the realization of a new material group.
2. 1900-1930 The birth of a plastic technology.
3. 1930-1950 Plastics as substitute materials.
4. 1950-1970 The “Plastics” age.
5. 1970-now Engineering Plastics.
8. 5
Figure (5) –
In this diagram you
can see the history
or timeline of
polymers in
medicine.
2.1 What are Polymers and Polymerization or Polymer synthesis?
Polymers: are large molecules made of many small units joined to each other through
organic reactions. The small units are monomers. A polymer can be made from identical or
different monomers. Polymer synthesis, also called Polymerization Process, is the process by
which monomers are covalently bonded to form a (usually long) polymer chain or network. [6]
Figure (6) – Same or different Monomers bonded together to make polymers
2.2 Classifications of Polymers
Polymers can be classifying as some categories by their source, structure and properties.
No. According to Source According to Structure According to Properties
1. Natural Polymers Linear Polymers Rubbers
2. Semi-synthetic Polymers Branched Chain Polymers Plastics
3. Synthetic Polymers Cross Linked Polymers Fibers
Now we focus on the natural polymers and synthetic polymers also, their applications,
advantages and disadvantages. [7]
9. 6
2.2.1 Natural Polymers
As you see in the names of this type of polymer which derived from the word nature. So,
the natural polymers are existing naturally and can be find from the environment nature. Some
examples of the nature polymers are:
• Hair
• Skin
• Tissue
• DNA
• RNA
• Cellulose
• Proteins.
Figure (7) – Structure of most shared natural polymers: a) cellulose, b) lignin and c) chitin.
Figure (8) – Derivatives of Cellulose
10. 7
Application of Natural Polymers
The products from natural sources have become an integral part of human health care system
because of some side effects and toxicity of synthetic drugs. Applications of natural polymers in
pharmacy are comparable to the synthetic polymers and they possess wide scope in food and
cosmetic industries. The present paper gives a state-of-the-art of available information on naturally
available polymers and their versatile uses. [8]
1. It can be used in pharmaceutical industry to make the variety of pharmaceutical products.
2. To manufacturing many drugs.
3. They can formulate the foods and used in cosmetic industries.
Impacts of Natural Polymers
• Environmental Impact: As
you on the right side in this
paper. This figure explains the
contributions of many of
natural polymers in the
environment.
• Economic Impacts: Natural
Polymers are affecting the
economics of countries by
enormous effects on
companies. [9]
Figure (9) – This figure shows us the biomass
production by contribution of natural polymers
11. 8
2.2.2 Synthetic Polymers
Synthetic polymers are the polymers which made by human. these polymers consist of
repeated organizational units named as monomers. However, one of the simplest polymers is the
Polyethylene, it has ethene or ethylene as the monomer unit while the linear polymer is called as
the high-density polyethylene-HDPE. [10]
Application of Synthetic Polymers
Some uses are given below-
1. Polyethylene is used to make plastic sandwich bags.
2. We can make milk jugs from the synthetic polymers
such as (HDPE).
3. Another use of synthetic polymers can be used to
make specialty athletic clothing such as: Nylon,
Spandex or Lycra.
4. Compact discs are made from them such as
polycarbonate.
5. Also, the soda bottles are examples which made
from polyethylene terephthalate.
6. See the figure below to see two more of synthetic polymers applications. [11]
Figure (11) – In this figure you can see some examples or usages of Synthetic Materials.
Figure (10) – We can see many
samples of synthetic polymers
around of us.
12. 9
Synthetic Polymer Effects
Nowadays problems which caused by synthetic polymers are too much. There are some
problems of them: [12]
1. Environmental Problems
Synthetic polymers can combust in the incinerators that cause to air pollution and release the
poisonous gases. They toxic for water sources like seas and oceans also tend to foods. Also, they
can have effects on the workers especially workers in polymer and plastic industries.
2. Their Effects on Humans
Many polymers such as plastics and others can cause to bad impact on the human body. For
instance, phthalate ester plasticizers are taken out by the blood from the plastic bags which are
used for the storage of blood. It enters in the blood stream of patient when he receives that blood.
2.3 Why Polymers are Important?
Advantages (Benefits) of Polymers
✓ Polymers are used in all materials, which are can find nearly in each material which used
in our everyday life.
✓ Natural polymers are abundant, renewable, diverse, versatile, biodegradable,
biocompatible, safe, non-toxic and inexpensive sources of biomaterials.
✓ Other benefits of polymers especially natural polymers are that they include the proteins,
which are the polymers of amino acids, and the nucleic acids.
✓ Synthetic and natural polymers could be used in the form of inorganic and organic
polymers; coatings, elastomers, adhesives, blends, plastics, fibers, caulks, ceramics, and
composites. [13]
13. 10
2.4 Primary Plastic Production from Polymer Types (2015)
Figure (12) – This chart show us the Plastic production by various types of polymers. [14]
14. 11
2.5 Polymerization (How polymers are synthesizes?)
Polymerization is the process of combination of monomers to build polymers. and these
polymers are then used to make many types of products such as plastics, rubbers and others.
During polymerization, these monomers are chemically combined to make larger particles. [15]
Classification of Polymerization Reaction
We can classify the polymerization processes by mechanism of the reaction of the monomers.
Thus, here we have two types of polymerization reaction below:
Addition Polymerization
As we see in the word ‘’addition’’ in this type, polymers are created while the monomers are
added or increased to each other. There are uses of monomers as unsaturated compound. it
means the carbon compounds which are connected by double or triple covalent bonds. For
instance, alkenes and alkynes.
Condensation Polymerization
We have more categories of polymerization reaction like Condensation which is a method of
stage-progress polymerization in which monomers or oligomers react to form larger structural
units while releasing smaller molecules as a byproduct, such as water or methanol. A well-
known condensation reaction is the esterification of carboxylic acids with alcohols. [16]
Figure (13) – Now you look above reaction that shows the condensation polymerization.
15. 12
3. Resulting (Discussion)
Polymers and their synthesis need more information or facts. However, in this report we
talked about some details about polymers and some terms which related to it. Thus, now we can
discuss why polymers are important than other types of materials which used in daily lives. So,
you can check following points to understand these reasons:
Polymers are organic materials which most of them are naturally exist in the world.
We can use polymers as thing that we need or that we like.
They have best properties for using, it means their uses are so simple and so easy.
Many things around us are made from polymers, such as plastics, elastics, our home
equipment, etc.
16. 13
4. Conclusion
In previous sections in this report, we talked about polymers and polymerization as brief
and very important subject in material engineering and science. However, we discussed this
report before this section. Polymers are most important which are one of group of materials
while we mention it in anywhere, we remember that it is more important than we think. Finally,
we can brief our report below. A revolution has occupied residence over the last 50 years in the
ground of synthetic polymers, which usages have quickly infused many of aspects of our day-to-
day life. This quick step of the advance in polymers with just a few decades which separate their
first commercial development from their present universal use, has been amazing. Synthetic
polymers are so well integrated into the fabric of society that we take little notice of our
dependence on them.
17. 14
5. References
1. Turner, R. (2018). Part One: Polymers in Our Daily Life | Gellner Industrial. [online]
Gellner Industrial LLC. Available at: https://www.gellnerindustrial.com/part-one-
polymers-daily-life/#:~:text=Polymers%20become%20the%20raw%20materials
[Accessed 14 Mar. 2021].
2. slideplayer.com. (2016). Polymers Introduction - ppt download. [online] Available at:
https://slideplayer.com/slide/6019694/ [Accessed 14 Mar. 2021].
3. www.e-education.psu.edu. (2019). Basic Polymer Structure | MATSE 81: Materials In
Today’s World. [online] Available at: https://www.e-
education.psu.edu/matse81/node/2210. [Accessed 14 Mar. 2021].
4. Feldman, D. (2008). Polymer History. Designed Monomers and Polymers. [pdf] 11(1),
pp.1–15. Available at:
https://www.tandfonline.com/doi/pdf/10.1163/156855508X292383 . [Accessed 14 Mar.
2021].
5. Young, R.J. and Lovell, P.A. (2011). Introduction to Polymers, Third Edition.
[ebook] Google Books. CRC Press. Available at:
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