2. Substrates and PaintsSubstrates and Paints
Substrates
Hot Dipped Galvanized
Galvalume®
Aluminum
Paint
The importance of pre-treatments
The importance of primers
Paint systems used in our industry:
Polyesters
Siliconized Polyester
Polyvinylidene Fluoride (PVDF)
4. Hot Dipped GalvanizedHot Dipped Galvanized
Zinc-coated carbon steel sheet that
meets ASTM A653-96
Coating weight of G-90
By volume consists of a minimum
thickness of .80 oz. of zinc per sq. ft.
for both sides of the steel sheet
Great sacrificial advantages
No applicable corrosion warranty
5. Galvanic ProtectionGalvanic Protection
Coating is 100% zinc by volume
Hot Dipped Galvanized offers a
desirable characteristic with respect
to corrosion by sacrificing itself to
protect slit edges and scratches
Generally has a smoother surface
for paint application purposes
Superior formability
6. GalvalumeGalvalume
By volume, Galvalume contains
80% aluminum in the coating;
the other 20% contains zinc and
silicon additive
Aluminum/Zinc coated carbon
steel sheet meets ASTM A792-96
By volume, consists of a
minimum thickness of .50 oz. per
sq. ft. of Zn/Al for both sides of
the steel sheet
7. GalvalumeGalvalume
Coating weight – AZ50 or AZ55
Great corrosion properties
Good sacrificial advantages
20 year, 6 month warranty against
corrosion
8. Galvalume vs. HD GalvanizedGalvalume vs. HD Galvanized
Hot Dipped Galvanized
After 18 years, G-90
Galvanized exhibits red
rust
Galvalume
Galvalume after 23 years
– no major sign of red
rust
Moderate Marine Rural
9. Corrosion Losses of Galvalume and Galvanized SheetsCorrosion Losses of Galvalume and Galvanized Sheets
After 13 Years of ExposureAfter 13 Years of Exposure
0 0.5 1
G
A
LVA
LU
M
E
H
.D
.G
A
LVA
N
IZED
RURAL
INDUSTRIAL
MARINE - 800 FT
SEVERE MARINE -
80 FT
Corrosion Loss (Mils)Corrosion Loss (Mils)
10. Salt Spray Corrosion ResistanceSalt Spray Corrosion Resistance
With cut edges protected, the coating on
Galvalume AZ50 lasts 5 to 10 times
longer than the coating on G90 HD
Galvanized
Salt spray tests conducted with bare cut
edges exposed, determined that the
corrosion resistance is typically three to
four times that of G90 HD Galvanized
11. Salt Spray Test Concerning the AmountSalt Spray Test Concerning the Amount
of Hours to First Significant Rustof Hours to First Significant Rust
0
500
1000
1500
2000
2500
3000
Unprotected
Edges
Protected Edges
Galvalume
H.D. Galvanized
Total # of Hours
14. What a Painted Product Consists of:What a Painted Product Consists of:
Cold Rolle d
Ste e l
Zinc (HDG) or
Zinc-Alum inum
(Galvalume®)
Subs trate
Pre -Tre atme nt
Laye r
Subs trate
Pre-Tre atme nt
Laye r
Primer
(0.20 - 0.25
mils)
TRINAR ®
Topcoat
(0.70 - 0 .90 m ils )
Primer
(0.20 - 0.25
mils)
Polyester Backer
(0.30 - 0 .50 m ils )
Prepaint Cross-Section
15. Pre-TreatmentsPre-Treatments
A liquid used to produce a
corrosion-resitant, organic bonding
coating on aluminum, Galvalume,
and Galvanized
An approved chromate rinse which
is the major agent that allows the
primer to bond to the substrate
Approved by Bethlehem Steel for
the use on Galvalume
16. Pre-TreatmentsPre-Treatments
Benefits of pre-treatments
Provide superior long-term
corrosion protection
Effective on aluminum,
Galvalume and Galvanized
Coating quality is consistently
maintained
17. PrimerPrimer
The base layer of the paint applied
by the coater
Formulated to provide corrosion
protection to the base metal and to
enhance adhesion between the top
coat (paint) and the base metal
18. Major Components That Make Up aMajor Components That Make Up a
Paint SystemPaint System
PigmentsPigments
ResinResin
SolventsSolvents
AdditivesAdditives
19. PigmentsPigments
Small solid particles
added to a paint to
enhance appearance
by providing color
and /or improve
physical (functional)
properties of a paint.
Pigments are
protected by the
resin system.
20. Types of pigments:
Ceramic
Earth tones
Organic
Two classes of
pigments:
Appearance
Functional
PigmentsPigments
21. Resin SystemsResin Systems
The most important part of any paint
system
The liquid “glue” of the paint system that
surrounds the pigment particles,
protecting them from environmental
pollutants such as airborne chemicals and
salt
Types of resin systems:
Polyester
Siliconized Polyester
Polyvinylidene Fluoride (PVDF)
22. SolventsSolvents
The vehicle by which the pigment is
“transported” to the metal surface
Solvents evaporate during the
curing process to permit the
formation of a paint film
23. AdditivesAdditives
Any number of chemicals added to
the paint, usually in small amounts,
to bring special effects to the paint
24. Component FunctionsComponent Functions
Pigment Resin Solvent Additive
Aesthetics Properties Application Enhancement
Color Durability Stability Mar Resistance
Gloss Adhesion Viscosity Curing Agent
Adhesion Flexibility Compatibility Settling
Film Strength Color Retention Film Control Dispersion
Water Resistance Abrasion Adhesion Anti-Freeze
Corrosion Resistance Impact Resistance Leveling De-Foaming
25. Types of Paint SystemsTypes of Paint Systems
Polyester
Siliconized Polyester
Polyvinylidene Fluoride (PVDF)
26. Polyester Paint SystemsPolyester Paint Systems
A generic polymer coating with
limited weathering performance
End uses: interior applications
Home appliances
Lighting fixtures
Wall panels
27. Siliconized Polyester PaintSiliconized Polyester Paint
SystemsSystems
A generic coating type that represents a
wide range of topcoats used on pre-
painted metal in construction
The silicon extends the service life of the
base polymer and improves weathering
End uses:
Metal building components
Agricultural and corrugated panels
28. Polyvinylidene Fluoride (PVDF)Polyvinylidene Fluoride (PVDF)
A fluoropolymer resin used as the
major vehicle (base resin) in the paint
system
Paint chemistry is 70% by weight PVDF
resin
Exhibits superior:
Color retention
Chalk resistance
Corrosion resistance
Flexibility
Stain resistance
Overall exterior durability
29. PVDF CoatingsPVDF Coatings
Architectural coatings thatArchitectural coatings that
extend building life and keep itextend building life and keep it
looking the way it was designed!looking the way it was designed!
30. How it worksHow it works
Advance molecular structural of
PVDF utilizes carbon-fluorine bond –
the strongest bond known in the
chemical world – combined with a
carbon-hydrogen bond, which
creates a structure that is extremely
durable
31. is the measured effect of
sunlight, UV radiation,
heat, and moisture on
pre-painted steel
32. Paint weathering is measuredPaint weathering is measured
in resistance to:in resistance to:
33. DefinitionsDefinitions
Chalk:
Residue resulting from weathering
decomposition of paint films
Visual ratings are assigned according
to ASTM D659; ratings range from 10-
0 (10 is best)
Fade: change in a paint film color
and appearance due to
degradation from weathering and
UV radiation in sunlight
34. DefinitionsDefinitions
Color fade:
Expressed in calculated “delta E”
values or NBS units which are
measured and calculated according to
ASTM D2244
Values range from 0 to infinity,
where0 is best; i.e., no color change
35. PVDF CoatingsPVDF Coatings
Made with 70% PVDF resin –
KYNAR® 500 or HYLAR®
5000
Exhibit excellent fabrication
flexibility and weatherability
Use ceramic-inorganic
pigments, which provide
excellent resistance to color
chalking and fading
36. Cold Rolled Steel
Zinc or Zinc-Aluminum Layer
Ceramic/Inorganic Topcoat Pigment
PVDF Resins Surrounding Topcoat
Pigment
Metal
Treatment
0.2-mil
Primer
0.8-mil
Topcoat
Topcoat Layer: Protects AgainstTopcoat Layer: Protects Against
UV Radiation, Heat and MoistureUV Radiation, Heat and Moisture
44. Superior Chalking andSuperior Chalking and
Weathering ResistanceWeathering Resistance
These panels
exposed at an
independent test
facility in Southern
Florida clearly
demonstrate the
superior weather-
ability of PVDF (left
sample)
45. Elements of a PVDF WarrantyElements of a PVDF Warranty
PVDF paint
warranties cover
the following for
20 years:
Film integrity
Color fade
Chalk resistance
Delamination
PVDF paint
warranties do not
cover:
Corrosion /
degradation of the
substrate