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Polymer Modifi ers & Additives News 
A Publication of Polymer Modifi ers and Additives Division of Society of Plastics Engineers 
TA B L E O F C O N T E N T S 
Division News ................................................................................................... 2 
Chairman’s Message ...................................................................................... 3 
Featured Paper: OPTUM® Technology an innovative barrier 
solution for polypropylene-based materials in food packaging 
applications ................................................................................................ 4-7 
PMAD Councilor’s Report ............................................................................ 8 
Technical Paper: How to improve (photo)oxidative stability of 
fl ame retarded polyolefi ns ....................................................................9-12 
PMAD Challenge 2014 ...............................................................................13 
PMAD Program at ANTEC 2014 .............................................. .........14-15
Division News 
PMAD Offi cers Election 
PMAD board of directors has held an election in April and 
the following volunteers have been elected for the positions 
announced. PMAD congratulates and thanks them for their 
continued support of our Division. 
Dr. Thoi Ho as PMAD Councilor 
Dr. Ray Pearson as PMAD Chair-elect 
Dr. Dick Grossman as PMAD Treasurer 
Dr. Ashok Adur as Communication Committee Chair and 
Newsletter Editor 
PMAD Wine and Cheese 
Reception at ANTEC, Tuesday 
April 29 
Time: 5:30 to 7:00 pm 
Location: Rio Hotel, Pavilion 5/6/7 
PMAD will hold a joint reception with Vinyl Division and 
Engineering Properties and Structure Division (EPSDIV) at 
ANTEC. Please join us to network with your peers, meet your 
board members and communicate your views and interests. 
During the reception, PMAD will introduce our new offi cers, 
PMAD challenge winners, and special recognition award 
winners. 
• New Chair and Offi cers Announcement (Saied) 
• PMAD Challenge Award Winners (Ray) 
• Special Recognition Award Winners (Kim/Thoi) 
• Polyolefi n PMAD Scholarship Winners (Thoi) 
PMAD Out-going Councilor 
Dr. Ernie Coleman, PMAD’s Elected councilor in 2013 is no 
longer able to continue in this role due to personal reasons. 
Ernie has recently gone through a surgery and we all wish him 
the best of health and quick recovery. PMAD has benefi ted 
from the long time support and great vision of Ernie over 
the years. Ernie has been one of the funding members of 
PMAD and you may fi nd a sample of his contribution in his 
last report on Page 8. 
PMAD also thanks Dr. David Riley, who temporarily acted as 
Proxy Councilor for PMAD until PMAD board elected Ernie’s 
replacement. David is another funding member and a great 
asset for PMAD. 
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For more information please contact 
Kim Crane 
kim.crane@boral.com 
C: (770) 331-3111 
SPE Polymer Modifi ers & Additives Division Page 2
Chairman’s Message 
This is my fi nal message as PMAD Chair to our colleagues, 
industry professional, friends, and members of Polymer 
Modifi ers and Additives Division and SPE. It is hard to 
believe that two years has passed since I took over this 
role. It has been a privilege to lead our division during 
this period and my primary goal was to ensure PMAD 
properly represents our industry and plays an active 
role is supporting student and academic activities 
related to polymer modifi ers and additives. I would 
like to thank all my good friends at PMAD Board of 
Directors who helped us moving in this direction, which 
resulted in achieving SPE’s Gold Pinnacle Award and 
SPE’s Communication Award both in 2013 and 2014. 
PMAD Technical Program Committee lead by Thoi Ho for SPE 
International Polyolefi ns Conference and by Baris Yalcin for SPE 
ANTEC has held strong programs in these two years, which was 
very well received by strong attendance for PMAD Sessions. 
PMAD Tutorial Sessions organized by Thoi for Polyolefi ns 
Conference receives more 100 attendees each year despite 
being held one day in advance of the main conference. Due to 
the strong success of our tutorial program, PMAD has started 
holding a tutorial session in this year’s ANTEC Conference. This 
would allow us to alternate tutorial sessions on the subject of 
polymer modifi ers and additives between Polyolefi ns Conference 
and ANTEC so that we do host a PMAD tutorial every year. 
PMAD Education Committee lead by Ray Pearson has 
held strong PMAD Challenge programs, which saw 
growth in student participation. PMAD Challenge 
program encourages research activities in the fi eld 
of polymer modifi ers and additives and awards 
students based on their review of technical papers 
and proposal for continued research. PMAD also 
continued its support of other SPE student activities. 
h 
a 
p 
o 
s 
a 
c 
P 
PMAD has also been looking for other ways to contribute 
to our industry through improving the technical 
content of our Newsletter and looking for other conferences 
and technical programs that PMAD can lead or participate in. 
We have made some progress, and we will continue working 
in these directions to enhance PMAD representation of our 
industry under the leadership of Kim Crane, Ray Pearson, 
and Thoi Ho as PMAD upcoming Chair , Chair-elect, and 
Councilor, respectively. I would like to thank you all for your 
support in the past two years and will continue supporting 
PMAD as the Past-Chair and Membership Committee Chair. 
Saied Kochesfahani 
PMAD Chair 
PMAD OFFICERS and BOARD OF DIRECTORS Director – Askok Adur, aadur@vertellus.com 
Chair – Saied Kochesfahani, saied.kochesfahani@imerys.com 
Chair-elect – Kim Crane, kim.crane@boral.com 
Past Chair / Membership Chair – Thoi Ho, thoi.ho@sbcglobal.net 
Councilor – Ernie Coleman, eccpt@aol.com 
Secretary – David Schultz, schultzd@harwickstandard.com 
Treasurer – Angelika Clark, den1cl@insightbb.com 
Technical Program Chair – Baris Yalcin, byalcin2@mmm.com 
Communication Committee Chair – OPEN 
Education Committee Chair – Ray Pearson, rpo2@lehigh.edu 
Director – Ron Becker, ron.becker@verizon.net 
Director – Frank Cangelosi, fcangelosi@unimin.com 
Director – David Riley, drdavidwriley@msn.com 
Director – Joseph Fay, joseph.fay@basf.com 
Director – Dick Grossman, groley@verizon.net 
Director – Stu Kapp, stukapp@alec-usa.com 
Director – Tie Lan, tie.lan@nanocor.com 
Director – Kasinath (Kas) Nayak, Kas.nayak@albemarle.com 
Director – Tariq Oweimreen, TOweimreen@hppelzer.com 
Director – Hayder Zahalka, hayder.zahalka@chemtura.com 
SPE Polymer Modifi ers & Additives Division Page 3
Featured Paper 
SPE Polymer Modifi ers & Additives Division Page 4
SPE Polymer Modifi ers & Additives Division Page 5
SPE Polymer Modifi ers & Additives Division Page 6
The Advantage 
is Clear 
www.PlasticFilmAdditives.com 
Discover the 
Harwick Standard 
Difference 
www.HarwickStandard.com 
Phone: 330.798.9300 
Fax: 330.798.4089 
®MINBLOC is a registered trademark. All rights reserved. 
Harwick Standard is a premier supplier to the rubber, 
plastics, and adhesives industries 
Advertise in PMAD News 
Contact 
kim.crane@boral.com or 
saied.kochesfahani@imerys.com 
SPE Polymer Modifi ers & Additives Division Page 7
PMAD Councilor Report 
SPE Council Meeting of November 14 and 15, 2013 
Ernie Coleman 
The SPE Council met on November 14 and 15, 2013 in San 
Diego, CA. There were two major topics: elections and mem-bership. 
Dick Cameron a long time personal friend was chosen 
chair elect. I know him to be an open minded innovator who 
will lead SPE in growth. Along with Dick we have Scott Owens 
as Senior VP and Jamie Gomez as VP. These are more strong 
leaders and SPE is fortunate to have them. These elected offi - 
cers along with council and current SPE members are working 
with Executive Director De Vos on growth of SPE membership. 
The following is my personal understanding of current mem-bership 
problems. Many companies are fi nding that current 
employment conditions are such that funding or encouraging 
individual memberships in professional organizations such as 
SPE are not essential. This is short sighted in terms of em-ployee 
growth and plastics industry expansion. We are all 
sales people who know the benefi ts of plastics and will teach 
others. Our source of information that we can openly discuss 
is the SPE and its technical data resources. 
This failure of many companies in our industry to encourage 
membership in professional organizations such as SPE makes 
it diffi cult for SPE to recruit young members. Young members 
of our wonderful industry have to be shown how to grow in 
the industry. Personal mentors along with management 
encouragement are a necessary part of the process. Right 
now, many companies are failing in this important employee 
training activity. 
SPE is reaching out to young members as never before with 
the Next Generation Committee. ANTEC 2014 in Las Vegas 
will be different. In order to make the professional meeting 
entertaining as well as educational there will be a race or 
form of a treasure hunt based on plastics and related sciences 
that ties into physical locations in the city of LV. This brave 
experiment will include special “T” shirts so we will know that 
this activity is occurring. Funding for this new activity will be 
generated by donations. The modest goal is $20,000. 
SPE has talked about doing something about young members 
for a long time. Now we are doing something. Like many cur-rent 
SPE members I am over 65 and I do not know many of the 
likes and dislikes of the under 30 age group. I do know that 
SPE like many other professional organizations is not currently 
meeting the needs of this group and therefore we need to 
change our approach. Well, that is happening. 
The Student Activities Committee awards travel money at AN-TEC 
and this insures that the student is present. This year at 
ANTEC there will be the usual poster sessions, student lunch 
and something else (a plant tour) besides the fun race men-tioned 
above. About $39,000 was raised from Sections and 
Divisions to pay for these youth related activities. Another good 
suggestion for keeping young members comes from the Sec-tions 
and Divisions Committees. The idea is to make room on the 
boards for appointed members to serve for one or two years 
and then stand for election or move on to another position. 
The hard facts of membership are that SPE retains about 73% 
of members and this is not enough to maintain current member-ship 
of about 14,000. New members and continuing members 
minus loss of members lead to an annual loss of membership of 
about 31%. This is not new and it must be reversed. Younger 
members may not like the current SPE web page. Last year 
money was approved for an upgrade to the web page. This is 
ongoing and accounts for fi nancial losses in 2013. 
The SPE income base is mostly membership but other sources 
are important. TOPCOM income is being reviewed and there 
will be changes. Section and Division rebates are also under 
review and in all likelihood will be reduced. Growth in inter-national 
membership and different international currencies are 
included in the fi nancial reviews. All international SPE members 
will be charged a fair price for membership. 
As your councilor I will keep an eye on all these issues and make 
sure that Divisions and Sections are treated reasonably. Chang-es 
are coming and PMAD must be prepared to grow as SPE 
changes. 
SPE Polymer Modifi ers & Additives Division Page 8
Technical Paper 
SPE Polymer Modifi ers & Additives Division Page 9
SPE Polymer Modifi ers & Additives Division Page 10
SPE Polymer Modifi ers & Additives Division Page 11
Do 
More 
Expand your design possibilities – with 3M™ Glass Bubbles 
For injection molding, extrusion & more! 
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compounded – helping to reduce part weight and much, much more: 
Reduce part weight by 15% or more 
Make more parts per hour by improving cycle time 15–25% 
Reduce waste by improving dimensional stability 
Contribute to environmental sustainability and better fuel economy 
For more information, or IRUKHOSGHWHUPLQLQJ which 3M glass bubble is 
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Learn how you can Do More with 3M. 
Visit our technical resource center for technical articles, 
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©3M 2012. All rights reserved. 3M 
is a trademark of 3M. 
Photos courtesy of REHAU, 
9LVWHRQDQG+DQLOH+ZD 
Polymer Modifi ers  
Additives News 
Can be found on PMAD page on SPE 
website at: http://www.4spe.org/ 
technical-groups/newsletters 
PMAD wins 2014 SPE 
Pinnacle Gold Award 
PMAD wins 2014 SPE 
Communication Award 
SPE Polymer Modifi ers  Additives Division Page 12
SPE Polymer Modifi ers  Additives Division Page 13
PMAD Program at ANTEC 2014 
SPE Polymer Modifi ers  Additives Division Page 14
PMAD Program at ANTEC 2014, Continued 
Join Us at PMAD 
Reception at 
ANTEC, Tuesday 
April 29 
Time: 5:30 to 7:00 pm 
Location: Rio Hotel, 
Pavilion 5/6/7 
SPE Polymer Modifi ers  Additives Division Page 15
SPE Polymer Modifi ers  Additives Division Page 16

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Polymer Modifiers & Additives News Spring 2014

  • 1. Vo l u m e 2 , N u m b e r 1 , S p r i n g 2 0 1 4 Polymer Modifi ers & Additives News A Publication of Polymer Modifi ers and Additives Division of Society of Plastics Engineers TA B L E O F C O N T E N T S Division News ................................................................................................... 2 Chairman’s Message ...................................................................................... 3 Featured Paper: OPTUM® Technology an innovative barrier solution for polypropylene-based materials in food packaging applications ................................................................................................ 4-7 PMAD Councilor’s Report ............................................................................ 8 Technical Paper: How to improve (photo)oxidative stability of fl ame retarded polyolefi ns ....................................................................9-12 PMAD Challenge 2014 ...............................................................................13 PMAD Program at ANTEC 2014 .............................................. .........14-15
  • 2. Division News PMAD Offi cers Election PMAD board of directors has held an election in April and the following volunteers have been elected for the positions announced. PMAD congratulates and thanks them for their continued support of our Division. Dr. Thoi Ho as PMAD Councilor Dr. Ray Pearson as PMAD Chair-elect Dr. Dick Grossman as PMAD Treasurer Dr. Ashok Adur as Communication Committee Chair and Newsletter Editor PMAD Wine and Cheese Reception at ANTEC, Tuesday April 29 Time: 5:30 to 7:00 pm Location: Rio Hotel, Pavilion 5/6/7 PMAD will hold a joint reception with Vinyl Division and Engineering Properties and Structure Division (EPSDIV) at ANTEC. Please join us to network with your peers, meet your board members and communicate your views and interests. During the reception, PMAD will introduce our new offi cers, PMAD challenge winners, and special recognition award winners. • New Chair and Offi cers Announcement (Saied) • PMAD Challenge Award Winners (Ray) • Special Recognition Award Winners (Kim/Thoi) • Polyolefi n PMAD Scholarship Winners (Thoi) PMAD Out-going Councilor Dr. Ernie Coleman, PMAD’s Elected councilor in 2013 is no longer able to continue in this role due to personal reasons. Ernie has recently gone through a surgery and we all wish him the best of health and quick recovery. PMAD has benefi ted from the long time support and great vision of Ernie over the years. Ernie has been one of the funding members of PMAD and you may fi nd a sample of his contribution in his last report on Page 8. PMAD also thanks Dr. David Riley, who temporarily acted as Proxy Councilor for PMAD until PMAD board elected Ernie’s replacement. David is another funding member and a great asset for PMAD. . Imerys talcs for improved plastics performance HAR® . Maximum reinforcement, dimensional stability and barrier performance Jetfi ne® / JetFil® . Best stiffness, impact balance Cimpact® . High brightness, high performance Mistron® . Effi cient and low-haze anti-blocking Engineered talcs . Superior foam nucleation . Full range of muscovite/phlogopite micas and kaolin products NEW www.imerystalc.com - www.imerys-perfmins.com Celceram®: An excellent source of economical, recycled filler content for polymer applications! For more information please contact Kim Crane kim.crane@boral.com C: (770) 331-3111 SPE Polymer Modifi ers & Additives Division Page 2
  • 3. Chairman’s Message This is my fi nal message as PMAD Chair to our colleagues, industry professional, friends, and members of Polymer Modifi ers and Additives Division and SPE. It is hard to believe that two years has passed since I took over this role. It has been a privilege to lead our division during this period and my primary goal was to ensure PMAD properly represents our industry and plays an active role is supporting student and academic activities related to polymer modifi ers and additives. I would like to thank all my good friends at PMAD Board of Directors who helped us moving in this direction, which resulted in achieving SPE’s Gold Pinnacle Award and SPE’s Communication Award both in 2013 and 2014. PMAD Technical Program Committee lead by Thoi Ho for SPE International Polyolefi ns Conference and by Baris Yalcin for SPE ANTEC has held strong programs in these two years, which was very well received by strong attendance for PMAD Sessions. PMAD Tutorial Sessions organized by Thoi for Polyolefi ns Conference receives more 100 attendees each year despite being held one day in advance of the main conference. Due to the strong success of our tutorial program, PMAD has started holding a tutorial session in this year’s ANTEC Conference. This would allow us to alternate tutorial sessions on the subject of polymer modifi ers and additives between Polyolefi ns Conference and ANTEC so that we do host a PMAD tutorial every year. PMAD Education Committee lead by Ray Pearson has held strong PMAD Challenge programs, which saw growth in student participation. PMAD Challenge program encourages research activities in the fi eld of polymer modifi ers and additives and awards students based on their review of technical papers and proposal for continued research. PMAD also continued its support of other SPE student activities. h a p o s a c P PMAD has also been looking for other ways to contribute to our industry through improving the technical content of our Newsletter and looking for other conferences and technical programs that PMAD can lead or participate in. We have made some progress, and we will continue working in these directions to enhance PMAD representation of our industry under the leadership of Kim Crane, Ray Pearson, and Thoi Ho as PMAD upcoming Chair , Chair-elect, and Councilor, respectively. I would like to thank you all for your support in the past two years and will continue supporting PMAD as the Past-Chair and Membership Committee Chair. Saied Kochesfahani PMAD Chair PMAD OFFICERS and BOARD OF DIRECTORS Director – Askok Adur, aadur@vertellus.com Chair – Saied Kochesfahani, saied.kochesfahani@imerys.com Chair-elect – Kim Crane, kim.crane@boral.com Past Chair / Membership Chair – Thoi Ho, thoi.ho@sbcglobal.net Councilor – Ernie Coleman, eccpt@aol.com Secretary – David Schultz, schultzd@harwickstandard.com Treasurer – Angelika Clark, den1cl@insightbb.com Technical Program Chair – Baris Yalcin, byalcin2@mmm.com Communication Committee Chair – OPEN Education Committee Chair – Ray Pearson, rpo2@lehigh.edu Director – Ron Becker, ron.becker@verizon.net Director – Frank Cangelosi, fcangelosi@unimin.com Director – David Riley, drdavidwriley@msn.com Director – Joseph Fay, joseph.fay@basf.com Director – Dick Grossman, groley@verizon.net Director – Stu Kapp, stukapp@alec-usa.com Director – Tie Lan, tie.lan@nanocor.com Director – Kasinath (Kas) Nayak, Kas.nayak@albemarle.com Director – Tariq Oweimreen, TOweimreen@hppelzer.com Director – Hayder Zahalka, hayder.zahalka@chemtura.com SPE Polymer Modifi ers & Additives Division Page 3
  • 4. Featured Paper SPE Polymer Modifi ers & Additives Division Page 4
  • 5. SPE Polymer Modifi ers & Additives Division Page 5
  • 6. SPE Polymer Modifi ers & Additives Division Page 6
  • 7. The Advantage is Clear www.PlasticFilmAdditives.com Discover the Harwick Standard Difference www.HarwickStandard.com Phone: 330.798.9300 Fax: 330.798.4089 ®MINBLOC is a registered trademark. All rights reserved. Harwick Standard is a premier supplier to the rubber, plastics, and adhesives industries Advertise in PMAD News Contact kim.crane@boral.com or saied.kochesfahani@imerys.com SPE Polymer Modifi ers & Additives Division Page 7
  • 8. PMAD Councilor Report SPE Council Meeting of November 14 and 15, 2013 Ernie Coleman The SPE Council met on November 14 and 15, 2013 in San Diego, CA. There were two major topics: elections and mem-bership. Dick Cameron a long time personal friend was chosen chair elect. I know him to be an open minded innovator who will lead SPE in growth. Along with Dick we have Scott Owens as Senior VP and Jamie Gomez as VP. These are more strong leaders and SPE is fortunate to have them. These elected offi - cers along with council and current SPE members are working with Executive Director De Vos on growth of SPE membership. The following is my personal understanding of current mem-bership problems. Many companies are fi nding that current employment conditions are such that funding or encouraging individual memberships in professional organizations such as SPE are not essential. This is short sighted in terms of em-ployee growth and plastics industry expansion. We are all sales people who know the benefi ts of plastics and will teach others. Our source of information that we can openly discuss is the SPE and its technical data resources. This failure of many companies in our industry to encourage membership in professional organizations such as SPE makes it diffi cult for SPE to recruit young members. Young members of our wonderful industry have to be shown how to grow in the industry. Personal mentors along with management encouragement are a necessary part of the process. Right now, many companies are failing in this important employee training activity. SPE is reaching out to young members as never before with the Next Generation Committee. ANTEC 2014 in Las Vegas will be different. In order to make the professional meeting entertaining as well as educational there will be a race or form of a treasure hunt based on plastics and related sciences that ties into physical locations in the city of LV. This brave experiment will include special “T” shirts so we will know that this activity is occurring. Funding for this new activity will be generated by donations. The modest goal is $20,000. SPE has talked about doing something about young members for a long time. Now we are doing something. Like many cur-rent SPE members I am over 65 and I do not know many of the likes and dislikes of the under 30 age group. I do know that SPE like many other professional organizations is not currently meeting the needs of this group and therefore we need to change our approach. Well, that is happening. The Student Activities Committee awards travel money at AN-TEC and this insures that the student is present. This year at ANTEC there will be the usual poster sessions, student lunch and something else (a plant tour) besides the fun race men-tioned above. About $39,000 was raised from Sections and Divisions to pay for these youth related activities. Another good suggestion for keeping young members comes from the Sec-tions and Divisions Committees. The idea is to make room on the boards for appointed members to serve for one or two years and then stand for election or move on to another position. The hard facts of membership are that SPE retains about 73% of members and this is not enough to maintain current member-ship of about 14,000. New members and continuing members minus loss of members lead to an annual loss of membership of about 31%. This is not new and it must be reversed. Younger members may not like the current SPE web page. Last year money was approved for an upgrade to the web page. This is ongoing and accounts for fi nancial losses in 2013. The SPE income base is mostly membership but other sources are important. TOPCOM income is being reviewed and there will be changes. Section and Division rebates are also under review and in all likelihood will be reduced. Growth in inter-national membership and different international currencies are included in the fi nancial reviews. All international SPE members will be charged a fair price for membership. As your councilor I will keep an eye on all these issues and make sure that Divisions and Sections are treated reasonably. Chang-es are coming and PMAD must be prepared to grow as SPE changes. SPE Polymer Modifi ers & Additives Division Page 8
  • 9. Technical Paper SPE Polymer Modifi ers & Additives Division Page 9
  • 10. SPE Polymer Modifi ers & Additives Division Page 10
  • 11. SPE Polymer Modifi ers & Additives Division Page 11
  • 12. Do More Expand your design possibilities – with 3M™ Glass Bubbles For injection molding, extrusion & more! )URPXWLOLWJUDGH¿OOHUVWRKLJKVWUHQJWKDGGLWLYHVIRULQMHFWLRQPROGLQJ 3M™*ODVV%XEEOHVDUHUHVKDSLQJWKHZDWRGD¶VSODVWLFVDUH compounded – helping to reduce part weight and much, much more: Reduce part weight by 15% or more Make more parts per hour by improving cycle time 15–25% Reduce waste by improving dimensional stability Contribute to environmental sustainability and better fuel economy For more information, or IRUKHOSGHWHUPLQLQJ which 3M glass bubble is best for your application, contact us. Learn how you can Do More with 3M. Visit our technical resource center for technical articles, application information, videos and more! 3M.com/engineeredadditives New 3M™ Glass Bubbles iM16K Featuring an ideal combination of high strength, small particle VL]HDQGXOWUDORZ density: 0.46 g/cc. Order samples of 3M glass bubbles online at Shop3M.com ©3M 2012. All rights reserved. 3M is a trademark of 3M. Photos courtesy of REHAU, 9LVWHRQDQG+DQLOH+ZD Polymer Modifi ers Additives News Can be found on PMAD page on SPE website at: http://www.4spe.org/ technical-groups/newsletters PMAD wins 2014 SPE Pinnacle Gold Award PMAD wins 2014 SPE Communication Award SPE Polymer Modifi ers Additives Division Page 12
  • 13. SPE Polymer Modifi ers Additives Division Page 13
  • 14. PMAD Program at ANTEC 2014 SPE Polymer Modifi ers Additives Division Page 14
  • 15. PMAD Program at ANTEC 2014, Continued Join Us at PMAD Reception at ANTEC, Tuesday April 29 Time: 5:30 to 7:00 pm Location: Rio Hotel, Pavilion 5/6/7 SPE Polymer Modifi ers Additives Division Page 15
  • 16. SPE Polymer Modifi ers Additives Division Page 16