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Electrochemical Cells
NIELBERT RANER & JUBY ANN BOCBOC
Objectives
• To know and understand the concept of
electrochemical cells.
• To understand the basics of voltaic and
electrolytic cells.
• To connect voltage from voltaic cells to
underlying REDOX chemistry.
• To determine the purpose of electric current in
electrolytic cells.
Electrochemical Cell
is a device capable of either
generating electrical energy from
chemical reactions or using
electrical energy to cause
chemical reactions.
Voltaic(Galvanic) Cell
• Uses the energy released during
spontaneous redox reaction to
generate electricity.
Luigi Galvani (1737-1798)
Alessandro Volta (1745-1827)
Application
• Portable voltaic cells generate
electricity to power devices for
our convenience such as battery
• All batteries are based on redox
reactions
Electrolytic Cell
• Is a device use to convert electrical
energy into chemical potential
energy.
• Here, redox reaction is non-
spontaneous. This means that the
oxidation will not occur
spontaneously or can't occur by
itself, without any external driving
force.
Electrolysis
A process in which electricity is used to
make a chemical change happen that
wouldn’t happen otherwise.
Electrolysis of
Water (H₂O)
H₂O ------> 2H₂ + O₂
We need to use an electrical energy
from a battery that can force this
process to happen.
2H₂O (l) -------> 2H₂ (g) + O₂ (g)
Application
• Electroplating
• Recharging Batteries
• Separating pure metals
from metallic compound.
• Manufacturing Sodium

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Electrochemical cells 1

Editor's Notes

  1. Chemical potential energy is the energy stored in the chemical bonds of a substance. The various chemicals that make up gasoline contain a large amount of chemical potential energy that is released when the gasoline is burned in a controlled way in the engine of the car. Non-spontaneous means- It can't happen unless we make it happen.