B.ED., PRACTICAL EXAMINATION
(2019 – 2021)
LEVEL - I
K. DEEPIKA
1122119BD027
Contents:
✓ Electrochemistry
✓ Electrochemical cell
✓ Components of electrochemical cell
✓ Types of electrochemical cell
- Galvanic cell
- Electrolytic cell
✓ Significance of electrochemistry
How does
battery
produce
electricity?
Because,battery
contains some
chemicals in it.
✓ The chemical reactions (chemical energy) that take place in the battery
produce electricity (electrical energy).
✓ Scientists realized that chemical energy can be converted into
electrical energy and vice versa.
✓ Another branch of applied chemistry is evolved - Electrochemistry.
✓ Electrochemistry is the branch of chemistry which deals with the
relation between electrical energy and chemical change.
✓ It mainly concerned with the process taking place between the
electrode and solution having ions called electrolyte.
Electrochemical Cell
✓ The device that make use of a chemical change to produce electricity or
electricity to produce chemical change is called Electrochemical cell.
Use chemical change Produce Electricity
Use Electricity Produce Chemical change
Components of Electrochemical Cell
✓ Electrode
✓ Electrolyte
Electrode
❑Solid electrical conductor made of
metal (sometimes non-metal like
graphite).
❑A cell consists of two electrodes –
Anode, Cathode.
Electrolyte
❑Solution made up of ions or molten
salts which can conduct electricity.
Cell reactions
An electrochemical cell involves two reactions simultaneously.
Oxidation – Loss of electron, it takes place at anode.
Metal Metal ion + electron (e-1)
Reduction – Gain of electron, it takes place at cathode.
Metal ion + electron (e-1) Metal
Since both the reactions take place simultaneously, the interconversion of
electrical and chemical energy in electrochemical cells involves a
redox reaction.
Types of Electrochemical cell
Classified based on nature of conversion as,
- Galvanic Cell
- Electrolytic cell
Galvanic cell
✓ It is an electrochemical cell which converts chemical energy into
electrical energy.
✓ It produces electricity from chemical reactions.
✓ It consists of two half cells namely anodic half – cell and
cathodic half - cell
✓ In anodic half-cell, the anode is in contact with its electrolyte whereas
in cathodic half-cell the cathode is in contact with its electrolyte.
✓ The anode and cathode are connected by a conductor wire.
✓ The electrolytes of half-cells are connected through a tube containing
a saturated salt solution. It is called Salt-bridge.
✓ In galvanic cell, both the half cells are kept separately but stay
connected electrically.
Working of Galvanic cell
✓ At anode, oxidation takes place which releases electrons .
✓ Electrons attracted by cathode and hence electrons flowing from
anode to cathode are gained in reduction reaction.
✓ As long as the redox reaction proceeds, there is a flow of electrons
and hence electricity
Electrolytic cell
✓ It is an electrochemical cell which converts
electrical energy into chemical energy into
chemical energy.
✓ In electrolytic cells, electricity is used to bring
about the chemical reactions.
✓ Here, both anode and cathode are in contact with
the same electrolyte and thus the half-cells are not
separated.
✓ In Galvanic cell electricity is produced, but in
electrolytic cell, electricity is used to produce
chemical reaction.
✓ In electrolytic cells, when electricity is passed to the
electrolyte, it dissociates into its constituent ions.
✓ These ions undergo redox reaction forming the
respective elements. This phenomenon is called
Electrolysis.
✓ Electrolysis is a process by which an electrolyte is
decomposed into its constituent elements by
passing electricity through its aqueous solution or
fused state ( molten state).
Significance of electrochemistry
✓ It is used in the electrorefining of many non- ferrous metals.
✓ The production of high-purity lead, zinc, aluminium, and copper
involves the use of electrolytic cells.
✓ Metallic sodium can be extracted from molten sodium chloride by
placing it in an electrolytic cell and passing an electric current through
it.
✓ Many commercially important batteries are made up of galvanic cells.
✓ Fuel cells are an important class of electrochemical cells that serve as a
source of clean energy in several remote locations.
Electrochemistry

Electrochemistry

  • 1.
    B.ED., PRACTICAL EXAMINATION (2019– 2021) LEVEL - I K. DEEPIKA 1122119BD027
  • 3.
    Contents: ✓ Electrochemistry ✓ Electrochemicalcell ✓ Components of electrochemical cell ✓ Types of electrochemical cell - Galvanic cell - Electrolytic cell ✓ Significance of electrochemistry
  • 4.
  • 5.
    ✓ The chemicalreactions (chemical energy) that take place in the battery produce electricity (electrical energy). ✓ Scientists realized that chemical energy can be converted into electrical energy and vice versa. ✓ Another branch of applied chemistry is evolved - Electrochemistry. ✓ Electrochemistry is the branch of chemistry which deals with the relation between electrical energy and chemical change. ✓ It mainly concerned with the process taking place between the electrode and solution having ions called electrolyte.
  • 6.
    Electrochemical Cell ✓ Thedevice that make use of a chemical change to produce electricity or electricity to produce chemical change is called Electrochemical cell. Use chemical change Produce Electricity Use Electricity Produce Chemical change Components of Electrochemical Cell ✓ Electrode ✓ Electrolyte
  • 7.
    Electrode ❑Solid electrical conductormade of metal (sometimes non-metal like graphite). ❑A cell consists of two electrodes – Anode, Cathode. Electrolyte ❑Solution made up of ions or molten salts which can conduct electricity.
  • 8.
    Cell reactions An electrochemicalcell involves two reactions simultaneously. Oxidation – Loss of electron, it takes place at anode. Metal Metal ion + electron (e-1) Reduction – Gain of electron, it takes place at cathode. Metal ion + electron (e-1) Metal Since both the reactions take place simultaneously, the interconversion of electrical and chemical energy in electrochemical cells involves a redox reaction.
  • 9.
    Types of Electrochemicalcell Classified based on nature of conversion as, - Galvanic Cell - Electrolytic cell Galvanic cell ✓ It is an electrochemical cell which converts chemical energy into electrical energy. ✓ It produces electricity from chemical reactions. ✓ It consists of two half cells namely anodic half – cell and cathodic half - cell
  • 10.
    ✓ In anodichalf-cell, the anode is in contact with its electrolyte whereas in cathodic half-cell the cathode is in contact with its electrolyte. ✓ The anode and cathode are connected by a conductor wire. ✓ The electrolytes of half-cells are connected through a tube containing a saturated salt solution. It is called Salt-bridge. ✓ In galvanic cell, both the half cells are kept separately but stay connected electrically. Working of Galvanic cell ✓ At anode, oxidation takes place which releases electrons . ✓ Electrons attracted by cathode and hence electrons flowing from anode to cathode are gained in reduction reaction. ✓ As long as the redox reaction proceeds, there is a flow of electrons and hence electricity
  • 11.
    Electrolytic cell ✓ Itis an electrochemical cell which converts electrical energy into chemical energy into chemical energy. ✓ In electrolytic cells, electricity is used to bring about the chemical reactions. ✓ Here, both anode and cathode are in contact with the same electrolyte and thus the half-cells are not separated. ✓ In Galvanic cell electricity is produced, but in electrolytic cell, electricity is used to produce chemical reaction.
  • 12.
    ✓ In electrolyticcells, when electricity is passed to the electrolyte, it dissociates into its constituent ions. ✓ These ions undergo redox reaction forming the respective elements. This phenomenon is called Electrolysis. ✓ Electrolysis is a process by which an electrolyte is decomposed into its constituent elements by passing electricity through its aqueous solution or fused state ( molten state).
  • 13.
    Significance of electrochemistry ✓It is used in the electrorefining of many non- ferrous metals. ✓ The production of high-purity lead, zinc, aluminium, and copper involves the use of electrolytic cells. ✓ Metallic sodium can be extracted from molten sodium chloride by placing it in an electrolytic cell and passing an electric current through it. ✓ Many commercially important batteries are made up of galvanic cells. ✓ Fuel cells are an important class of electrochemical cells that serve as a source of clean energy in several remote locations.