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Electrochemistry
( Electrolytic cell )
Std 12 sci ( E )
Chapter-3 – Electrochemistry
Lecture – 1
By :- Ms. MAYRI R SOMPURA
HJD INSTITUTE KERA-KUTCH
Electrochemistry
CATHODE – WHERE REDUCTION OCCURS
ANODE – WHERE OXIDATION OCCURS
Electro - chemistry
ELECTRICAL ENERGY CHEMICAL ENERGY
ELECTRICAL ENERGY CHEMICAL ENERGY ELECTROLYTIC CELL
ELECTRICAL ENERGY CHEMICAL ENERGY GALVANIC CELL
ELECTROCHEMISTRY
ELECTROLYTIC
CELL
GALVANIC CELL
CONDUCTION OF
SOLUTION
ELECTROLYTIC CELL
ELECTRICAL ENERGY CHEMICAL ENERGY ELECTROLYTIC CELL
INPUT OUTPUT
• NON SPONTANEOUS Redox reaction occurs.
• Change in ΔG = - ve
• ΔG = ΔH - TΔS
Non spontaneous
rxn = ΔG = +ve
Spontaneous = ΔG
= - ve
NOTE
ELECTROLYTIC CELL
 Electrolytic solution :- It is a solution where molecules are
bound by an electrovalent bond.
 Electrovalent bond :- It is also known as IONIC BOND,
i.e. a complete transfer of electrons.
 Eg, NaCl
 At anode :- ( +ve terminal )
 A- → 1e- + A ( Half oxidation )
 At cathode :- ( -ve terminal )
 C+ + 1e- → C ( half reduction )
Overall reaction :-
A- → 1e- + A
C+ + 1e- → C
A- + C+ → C + A
ELECTROLYTIC CELL
CATION CATHODE REDUCTION
ANION ANODE OXIDATION
ELECTRON
GAIN
ELECTRON
LOSS
 ELECTRO CHEMISTRY l  electrolytic cell std 12 lec 1

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ELECTRO CHEMISTRY l electrolytic cell std 12 lec 1

  • 1. Electrochemistry ( Electrolytic cell ) Std 12 sci ( E ) Chapter-3 – Electrochemistry Lecture – 1 By :- Ms. MAYRI R SOMPURA HJD INSTITUTE KERA-KUTCH
  • 2. Electrochemistry CATHODE – WHERE REDUCTION OCCURS ANODE – WHERE OXIDATION OCCURS
  • 3. Electro - chemistry ELECTRICAL ENERGY CHEMICAL ENERGY ELECTRICAL ENERGY CHEMICAL ENERGY ELECTROLYTIC CELL ELECTRICAL ENERGY CHEMICAL ENERGY GALVANIC CELL ELECTROCHEMISTRY ELECTROLYTIC CELL GALVANIC CELL CONDUCTION OF SOLUTION
  • 4. ELECTROLYTIC CELL ELECTRICAL ENERGY CHEMICAL ENERGY ELECTROLYTIC CELL INPUT OUTPUT • NON SPONTANEOUS Redox reaction occurs. • Change in ΔG = - ve • ΔG = ΔH - TΔS Non spontaneous rxn = ΔG = +ve Spontaneous = ΔG = - ve NOTE
  • 5. ELECTROLYTIC CELL  Electrolytic solution :- It is a solution where molecules are bound by an electrovalent bond.  Electrovalent bond :- It is also known as IONIC BOND, i.e. a complete transfer of electrons.  Eg, NaCl  At anode :- ( +ve terminal )  A- → 1e- + A ( Half oxidation )  At cathode :- ( -ve terminal )  C+ + 1e- → C ( half reduction ) Overall reaction :- A- → 1e- + A C+ + 1e- → C A- + C+ → C + A
  • 6. ELECTROLYTIC CELL CATION CATHODE REDUCTION ANION ANODE OXIDATION ELECTRON GAIN ELECTRON LOSS