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C6g                            Natural Fats and Oils

   •      Natural fats and oils are important raw materials for the chemical industry

               e.g. they are used in

   •      At room temperature __________ are solid and _________ are liquids



                Animal fats and oils                        Vegetable fats and oils
                   lard (pork fat)                                  olive oil
                blubber (whale fat)                                walnut oil
                  ghee (butter oil)                                 soya oil
                     cod liver oil                                coconut oil




What type of chemicals are fats and oils?

   •      Animal and vegetable fats and oils are esters.



                                                •   Fats and oils are made when an alcohol
C1c Revision                                        called glycerol reacts with fatty acids:

Esters are made in the following
reaction:

alcohol    +    acid        ester   +   water




   •      In a saturated fat all of the carbon-carbon bonds are _________ bonds

   •      An unsaturated fat or oil has at least one carbon-carbon ________ bond, C=C.




   Test for unsaturation (C=C):                     •   The more bromine water the fat/oil

   Test = bromine water                                 can decolourise the more

   Result = bromine water turns                         _______________ it is (more C=C).

                from orange to colourless
How is Margarine Made?
                                                             Why are unsaturated fats
                                                             healthier?
•   ______________ fats are better for our health

•   Vegetable oils are often more unsaturated                Saturated fats increase the
                                                             amount of cholesterol in the
    (lots of C=C) than animal fats and oils
                                                             blood which can block up the
•   Unsaturation makes oils runny - too runny to spread      arteries and increase the
                                                             risk of heart disease
•   So, to make margarine from vegetable oils something

    must be done to make them less runny.



Hydrogenation:




    •   You can see above that the runny oil has hydrogen added to it to make it more
        saturated. This is called “hydrogenation”. A _____________ catalyst is used
        and it is carried out at about _____oC.

    •   Not all of the C=C are hydrogenated because the oil would become too
        ___________ to spread.



           Advantage of hydrogenated            Disadvantage of hydrogenated
                 vegetable oils                         vegetable oils

                                              Although naturally unsaturated oils
                                              decrease cholesterol, when you
                                              hydrogenate them ____________
                                              __________________________
                                              __________________________
                                              __________________________




What else are vegetable oils used for?
Vegetable oils can be used to make___________________, an alternative
to diesel from crude oil.
What is an emulsion?                                                   Revision of C1a

Examples include:




•    Oils do not mix with water – they are _______________________.

•    But you can make an emulsion by ______________ the oil and water vigorously



    If there is _______ oil than water             If there is _________ water than oil

    then the oil breaks up into tiny               then the water breaks up into tiny

    droplets that disperse throughout              droplets that disperse throughout the

    the water         e.g. milk                    oil         e.g. butter




           oil-in-water emulsion                               water–in-oil emulsion




Making Soap from Vegatable Oil                                         Revision C4

     •   Vegetable oils react with _____________________to produce a soap.

     •   Natural fats and oils can be split up by hot sodium hydroxide solution to

         produce ___________ and _______________.

     •   This process of splitting up natural fats and oils using sodium hydroxide

         solution is called ________________________.


Higher
                                         Hydrolysis Reaction

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C6g Natural Fats And Oils

  • 1. C6g Natural Fats and Oils • Natural fats and oils are important raw materials for the chemical industry e.g. they are used in • At room temperature __________ are solid and _________ are liquids Animal fats and oils Vegetable fats and oils lard (pork fat) olive oil blubber (whale fat) walnut oil ghee (butter oil) soya oil cod liver oil coconut oil What type of chemicals are fats and oils? • Animal and vegetable fats and oils are esters. • Fats and oils are made when an alcohol C1c Revision called glycerol reacts with fatty acids: Esters are made in the following reaction: alcohol + acid ester + water • In a saturated fat all of the carbon-carbon bonds are _________ bonds • An unsaturated fat or oil has at least one carbon-carbon ________ bond, C=C. Test for unsaturation (C=C): • The more bromine water the fat/oil Test = bromine water can decolourise the more Result = bromine water turns _______________ it is (more C=C). from orange to colourless
  • 2. How is Margarine Made? Why are unsaturated fats healthier? • ______________ fats are better for our health • Vegetable oils are often more unsaturated Saturated fats increase the amount of cholesterol in the (lots of C=C) than animal fats and oils blood which can block up the • Unsaturation makes oils runny - too runny to spread arteries and increase the risk of heart disease • So, to make margarine from vegetable oils something must be done to make them less runny. Hydrogenation: • You can see above that the runny oil has hydrogen added to it to make it more saturated. This is called “hydrogenation”. A _____________ catalyst is used and it is carried out at about _____oC. • Not all of the C=C are hydrogenated because the oil would become too ___________ to spread. Advantage of hydrogenated Disadvantage of hydrogenated vegetable oils vegetable oils Although naturally unsaturated oils decrease cholesterol, when you hydrogenate them ____________ __________________________ __________________________ __________________________ What else are vegetable oils used for? Vegetable oils can be used to make___________________, an alternative to diesel from crude oil.
  • 3. What is an emulsion? Revision of C1a Examples include: • Oils do not mix with water – they are _______________________. • But you can make an emulsion by ______________ the oil and water vigorously If there is _______ oil than water If there is _________ water than oil then the oil breaks up into tiny then the water breaks up into tiny droplets that disperse throughout droplets that disperse throughout the the water e.g. milk oil e.g. butter oil-in-water emulsion water–in-oil emulsion Making Soap from Vegatable Oil Revision C4 • Vegetable oils react with _____________________to produce a soap. • Natural fats and oils can be split up by hot sodium hydroxide solution to produce ___________ and _______________. • This process of splitting up natural fats and oils using sodium hydroxide solution is called ________________________. Higher Hydrolysis Reaction