Chapter 4 of 'Understanding Cryptography' provides an overview of the Advanced Encryption Standard (AES), detailing its selection process, algorithm structure, and layers of operation. AES is a widely used symmetric cipher chosen by NIST, featuring varying rounds based on key lengths of 128, 192, and 256 bits. The chapter also covers AES's implementation, key schedules, and security aspects, affirming its robustness against brute-force and analytical attacks.