IONIC VS MOLECULAR
COMPOUNDS
INTRO TO IONIC COMPOUNDS
- Elements become stable by achieving 8 valence electrons (except for
hydrogen and helium, which achieve 2 electrons)
- Noble gases are non-reactive because they have 8 electrons
- This is called the Octet Rule
The number of valence
electrons can determine
reactivity:
INTRO TO IONIC COMPOUNDS
How many valence electrons
does each atom need to gain or
lose to achieve a full octet?
Alkali metals
lose 1
electron
Alkali earth
metals lose 2
electrons
Group 13
elements lose 3
electrons
Group 14 elements
lose or gain 4
electrons
INTRO TO IONIC COMPOUNDS
How many valence electrons
does each atom need to gain or
lose to achieve a full octet?
Group 14
elements lose or
gain 4 electrons
Group 15
elements gain
3 electrons
Group 16
elements gain
2 electrons
Halogens
gain 1
electron
Noble gases
already have
a full octet
INTRO TO IONIC COMPOUNDS
- Alkali metals have 1 electron in their valence
shell
- They can achieve a full octet by losing this
electron
- Thus they lose their valence electron easily to
another element, making them very reactive
Alkali metals
K
19P+
20N
Na
11P+
12N
INTRO TO IONIC COMPOUNDS
- Halogens have 7 valence electrons
- They can achieve a full octet by gaining one
electron
- Thus they readily take an electron from other
atoms, making them very reactive
Halogens
Cl
17P+
18N
F
9P+
10N
IONIC COMPOUNDS
Na
11P+
12N
Cl
17P+
18N
Forming an ionic bond:
1) An electron from Na is transferred to Cl
2) Na becomes a positive ion, Cl becomes a negative ion
3) Positive and negative ions attract, forming an ionic compound
+ -
Ionic bond = bond formed by the transfer of electron(s) from
metal to non-metal, making ions that attract each other
IONIC COMPOUNDS
Na
11P+
12N
Cl
17P+
18N
Drawing an ionic compound using a Bohr-Rutherford Diagram:
Example: NaCl
IONIC COMPOUNDS
Drawing an ionic compound using a Lewis Dot Diagram:
Example: NaCl
Na[ ]
+
Cl
..
:: ..[ ]
-
Rule: Square brackets must appear around ions
IONIC COMPOUNDS
Cl
17P+
18N
Drawing an ionic compound using a Bohr-Rutherford Diagram:
Example: AlCl3
Al
13P+
14N
Cl
17P+
18N
Cl
17P+
18N
IONIC COMPOUNDS
Drawing an ionic compound using a Lewis Dot Diagram:
Example: AlCl3
Al
.
.
.[ ]
3+
Cl
..
:: ..[ ]
-
Cl
..
:: ..[ ]
-
Cl
..
:: ..[ ]
-
Rule: Square brackets must appear around ions
PROPERTIES OF IONIC COMPOUNDS
Properties:
-Hard (ionic bond is strong)
-High boiling point (i.e. NaCl boils at 1413˚C)
-Brittle (shatters when hammered)
-Several ionic compounds dissolve in water
-Conducts electricity when dissolved
PROPERTIES OF IONIC COMPOUNDS
Several ionic compounds dissolve in water
Cl-
Na+
Cl-
Na+
Cl-
Na+
PROPERTIES OF IONIC COMPOUNDS
Several ionic compounds dissolve in water
NEGATIVELY-CHARGEDELECTRODE
POSITIVELY-CHARGEDELECTRODE
Na+
Cl-
Na+Cl-
Na+
Cl-
Na+
Cl-
- +
PROPERTIES OF IONIC COMPOUNDS
Several ionic compounds are also
electrolytes, which means they
dissolve to form a solution that
conducts electricity
MOLECULAR COMPOUNDS
MOLECULAR COMPOUNDS
Some elements share electrons to achieve a stable octet.
This allows a covalent bond to form between two elements.
O
8P+
8N
H
1P+
0N
H
1P+
0N
Covalent bond = bond formed by sharing of outer electrons
between non-metal atoms
Molecule = a particle in which atoms are joined by covalent bonds
MOLECULAR COMPOUNDS
F
9P+
10N
Drawing a molecular compound using a Bohr-Rutherford Diagram:
Example: HF
H
1P+
0N
MOLECULAR COMPOUNDS
Drawing a molecular compound using a Lewis Dot Diagram:
Example: HF
H:F
..
:..
Hydrogen fluoride is a diatomic molecule.
Diatomic molecule = Molecule consisting of only two atoms of
either the same or different elements
MOLECULAR COMPOUNDS
Some diatomic molecules consist of the same two elements:
i.e. O2
O :O
..
:
..
..
..
The following elements are diatomic when found in nature:
H2 O2 F2 Br2 I2 N2 Cl2
PROPERTIES OF MOLECULAR COMPOUNDS
Properties:
There are so many different molecular compounds that there are no
specific properties for them
H2 O2 F2 Br2 I2 N2 Cl2
gas gas gas liquid solid gas gas
HOMEWORK
Classify the following compounds as ionic or molecular. Then draw
the Bohr-Rutherford and Lewis Dot Diagram of each one:
a)Cl2
b)NH3
c)KCl
d)H2S
e)K2O

02 b ionic vs. molecular compounds, bohr rutherford and lewis

  • 1.
  • 2.
    INTRO TO IONICCOMPOUNDS - Elements become stable by achieving 8 valence electrons (except for hydrogen and helium, which achieve 2 electrons) - Noble gases are non-reactive because they have 8 electrons - This is called the Octet Rule The number of valence electrons can determine reactivity:
  • 3.
    INTRO TO IONICCOMPOUNDS How many valence electrons does each atom need to gain or lose to achieve a full octet? Alkali metals lose 1 electron Alkali earth metals lose 2 electrons Group 13 elements lose 3 electrons Group 14 elements lose or gain 4 electrons
  • 4.
    INTRO TO IONICCOMPOUNDS How many valence electrons does each atom need to gain or lose to achieve a full octet? Group 14 elements lose or gain 4 electrons Group 15 elements gain 3 electrons Group 16 elements gain 2 electrons Halogens gain 1 electron Noble gases already have a full octet
  • 5.
    INTRO TO IONICCOMPOUNDS - Alkali metals have 1 electron in their valence shell - They can achieve a full octet by losing this electron - Thus they lose their valence electron easily to another element, making them very reactive Alkali metals K 19P+ 20N Na 11P+ 12N
  • 6.
    INTRO TO IONICCOMPOUNDS - Halogens have 7 valence electrons - They can achieve a full octet by gaining one electron - Thus they readily take an electron from other atoms, making them very reactive Halogens Cl 17P+ 18N F 9P+ 10N
  • 7.
    IONIC COMPOUNDS Na 11P+ 12N Cl 17P+ 18N Forming anionic bond: 1) An electron from Na is transferred to Cl 2) Na becomes a positive ion, Cl becomes a negative ion 3) Positive and negative ions attract, forming an ionic compound + - Ionic bond = bond formed by the transfer of electron(s) from metal to non-metal, making ions that attract each other
  • 8.
    IONIC COMPOUNDS Na 11P+ 12N Cl 17P+ 18N Drawing anionic compound using a Bohr-Rutherford Diagram: Example: NaCl
  • 9.
    IONIC COMPOUNDS Drawing anionic compound using a Lewis Dot Diagram: Example: NaCl Na[ ] + Cl .. :: ..[ ] - Rule: Square brackets must appear around ions
  • 10.
    IONIC COMPOUNDS Cl 17P+ 18N Drawing anionic compound using a Bohr-Rutherford Diagram: Example: AlCl3 Al 13P+ 14N Cl 17P+ 18N Cl 17P+ 18N
  • 11.
    IONIC COMPOUNDS Drawing anionic compound using a Lewis Dot Diagram: Example: AlCl3 Al . . .[ ] 3+ Cl .. :: ..[ ] - Cl .. :: ..[ ] - Cl .. :: ..[ ] - Rule: Square brackets must appear around ions
  • 12.
    PROPERTIES OF IONICCOMPOUNDS Properties: -Hard (ionic bond is strong) -High boiling point (i.e. NaCl boils at 1413˚C) -Brittle (shatters when hammered) -Several ionic compounds dissolve in water -Conducts electricity when dissolved
  • 13.
    PROPERTIES OF IONICCOMPOUNDS Several ionic compounds dissolve in water
  • 14.
    Cl- Na+ Cl- Na+ Cl- Na+ PROPERTIES OF IONICCOMPOUNDS Several ionic compounds dissolve in water
  • 15.
    NEGATIVELY-CHARGEDELECTRODE POSITIVELY-CHARGEDELECTRODE Na+ Cl- Na+Cl- Na+ Cl- Na+ Cl- - + PROPERTIES OFIONIC COMPOUNDS Several ionic compounds are also electrolytes, which means they dissolve to form a solution that conducts electricity
  • 16.
  • 17.
    MOLECULAR COMPOUNDS Some elementsshare electrons to achieve a stable octet. This allows a covalent bond to form between two elements. O 8P+ 8N H 1P+ 0N H 1P+ 0N Covalent bond = bond formed by sharing of outer electrons between non-metal atoms Molecule = a particle in which atoms are joined by covalent bonds
  • 18.
    MOLECULAR COMPOUNDS F 9P+ 10N Drawing amolecular compound using a Bohr-Rutherford Diagram: Example: HF H 1P+ 0N
  • 19.
    MOLECULAR COMPOUNDS Drawing amolecular compound using a Lewis Dot Diagram: Example: HF H:F .. :.. Hydrogen fluoride is a diatomic molecule. Diatomic molecule = Molecule consisting of only two atoms of either the same or different elements
  • 20.
    MOLECULAR COMPOUNDS Some diatomicmolecules consist of the same two elements: i.e. O2 O :O .. : .. .. .. The following elements are diatomic when found in nature: H2 O2 F2 Br2 I2 N2 Cl2
  • 21.
    PROPERTIES OF MOLECULARCOMPOUNDS Properties: There are so many different molecular compounds that there are no specific properties for them H2 O2 F2 Br2 I2 N2 Cl2 gas gas gas liquid solid gas gas
  • 22.
    HOMEWORK Classify the followingcompounds as ionic or molecular. Then draw the Bohr-Rutherford and Lewis Dot Diagram of each one: a)Cl2 b)NH3 c)KCl d)H2S e)K2O