Life’s Chemical Basis
     Chapter 2
Elements
• Fundamental forms of
  matter
• Can’t be broken apart
  by normal means
• 92 occur naturally on
  Earth
Most Common Elements in Human
         Body (98%)

     Oxygen

     Hydrogen

     Carbon

     Nitrogen

     Calcium
What Are Atoms?
• Smallest particles that retain
  properties of an element
• Made up of subatomic particles:
   – Protons (+) located in the nucleus
   – Neutrons (no charge) located in
     the nucleus
   – Electrons (-) located in space
     around the nucleus
Atomic Number
         (whole # on the periodic table)
• = the # of protons
• All atoms of a specific element have
  the same atomic #
• Atomic # of hydrogen = 1
• Atomic # of carbon = 6
• Atomic # of helium = 2
• If you change the # of protons, you
  change the atom into a different
  element
Atomic Mass
   (decimal # on the periodic table)

Number of protons
        +
Number of neutrons


So why is it a decimal
 number? You’ll soon
     find out….
What is the role of neutrons?
• Since protons have a +
  charge, they repel
  each other

• Neutrons are neutral
  and help to stabilize
  the nucleus – think
  police
The Organization of the Periodic Table:
       Based on ELECTRONS!
Why Electrons Matter

• Atoms acquire, share, and
  donate electrons

• Whether an atom will
  interact with other atoms
  depends on how many
  electrons it has
Electrons

• Carry a negative charge
• Also repel one another
• Attracted to protons in the
  nucleus
• Move in volumes of space
  that surround the nucleus
Shell Model
• The shell model of electron orbitals
  diagrams electron vacancies, filled from
  inside out
• Each shell represents an energy level:
   – 1st shell: (2 electrons)
   – 2nd shell: (8 electrons)
   – 3rd shell: (8 electrons)
• Atoms with vacancies in their outer shell      CALCIUM
  tend to give up, acquire, or share electrons   20p+ , 20e-
Electron Vacancies

• Unfilled levels make
  atoms more likely to
  react with other atoms
                             CARBON       NITROGEN
• Hydrogen, carbon, and      6p+ , 6e-     7p+ , 7e-
  nitrogen are examples of
  elements with vacancies
  in their outer levels

                                   HYDROGEN
                                    1p+ , 1e-
Ion Formation
• Atoms that lose electron(s),
  become positively charged ions
   (cations)
• Atoms that gain electron(s),
  become negatively charged
  ions (anions)
• Electronegativity:
   – A measure of an atom’s
      ability to pull electrons from
      another atom
Atomic Structure: Helium


electron      proton
      -                 -
             neutron
 He
Atomic Structure: Nitrogen
N            -



    -
    -            -
         -           -



             -
Atomic Structure of Hydrogen




 HYDROGEN
  electron
  proton
  neutron
Isotopes: What are They?
• Atoms of an element with the SAME # of
  protons, but a DIFFERENT # of neutrons

• The atomic mass # on the periodic table is
  an avg. mass of all the different isotopes
  possible for the element
                                               “Carbon 12” has 6
                                               protons, 6 neutrons
• How do you figure out the number of
                                               “Carbon 14” has 6
  neutrons in an atom?                         protons, 8 neutrons
    Atomic mass – atomic number = #
     neutrons
Special Isotopes: Radioactive Isotopes

• Have an unstable nucleus
  that emits energy or some
  of the subatomic particles
  (protons or neutrons)
• Some are used in research
  and medical applications
  (pacemakers, radiation
  therapy, MRI)
Radioactive Isotopes Can be Used
                       as Tracers
• A tracer is a substance with a radioactive isotope attached
  to it
• Emissions from the tracer can be detected with special
  devices
• Following the movement of tracers is useful in many areas
  of biology and medicine
Next Lecture…




Chemical Bonds!
Lab 3: Making Conversions Between Various
                Measuring Systems

• Purpose of this lab:

  To become familiar
  with several systems of
  measurement and
  make conversions from
  one unit to another as
  well as learn to read
  syringes and graduated
  cylinders

Chapter 2 atomic structure

  • 1.
  • 2.
    Elements • Fundamental formsof matter • Can’t be broken apart by normal means • 92 occur naturally on Earth
  • 3.
    Most Common Elementsin Human Body (98%) Oxygen Hydrogen Carbon Nitrogen Calcium
  • 4.
    What Are Atoms? •Smallest particles that retain properties of an element • Made up of subatomic particles: – Protons (+) located in the nucleus – Neutrons (no charge) located in the nucleus – Electrons (-) located in space around the nucleus
  • 5.
    Atomic Number (whole # on the periodic table) • = the # of protons • All atoms of a specific element have the same atomic # • Atomic # of hydrogen = 1 • Atomic # of carbon = 6 • Atomic # of helium = 2 • If you change the # of protons, you change the atom into a different element
  • 6.
    Atomic Mass (decimal # on the periodic table) Number of protons + Number of neutrons So why is it a decimal number? You’ll soon find out….
  • 7.
    What is therole of neutrons? • Since protons have a + charge, they repel each other • Neutrons are neutral and help to stabilize the nucleus – think police
  • 8.
    The Organization ofthe Periodic Table: Based on ELECTRONS!
  • 9.
    Why Electrons Matter •Atoms acquire, share, and donate electrons • Whether an atom will interact with other atoms depends on how many electrons it has
  • 10.
    Electrons • Carry anegative charge • Also repel one another • Attracted to protons in the nucleus • Move in volumes of space that surround the nucleus
  • 11.
    Shell Model • Theshell model of electron orbitals diagrams electron vacancies, filled from inside out • Each shell represents an energy level: – 1st shell: (2 electrons) – 2nd shell: (8 electrons) – 3rd shell: (8 electrons) • Atoms with vacancies in their outer shell CALCIUM tend to give up, acquire, or share electrons 20p+ , 20e-
  • 12.
    Electron Vacancies • Unfilledlevels make atoms more likely to react with other atoms CARBON NITROGEN • Hydrogen, carbon, and 6p+ , 6e- 7p+ , 7e- nitrogen are examples of elements with vacancies in their outer levels HYDROGEN 1p+ , 1e-
  • 13.
    Ion Formation • Atomsthat lose electron(s), become positively charged ions (cations) • Atoms that gain electron(s), become negatively charged ions (anions) • Electronegativity: – A measure of an atom’s ability to pull electrons from another atom
  • 14.
    Atomic Structure: Helium electron proton - - neutron He
  • 15.
  • 16.
    Atomic Structure ofHydrogen HYDROGEN electron proton neutron
  • 17.
    Isotopes: What areThey? • Atoms of an element with the SAME # of protons, but a DIFFERENT # of neutrons • The atomic mass # on the periodic table is an avg. mass of all the different isotopes possible for the element “Carbon 12” has 6 protons, 6 neutrons • How do you figure out the number of “Carbon 14” has 6 neutrons in an atom? protons, 8 neutrons Atomic mass – atomic number = # neutrons
  • 18.
    Special Isotopes: RadioactiveIsotopes • Have an unstable nucleus that emits energy or some of the subatomic particles (protons or neutrons) • Some are used in research and medical applications (pacemakers, radiation therapy, MRI)
  • 19.
    Radioactive Isotopes Canbe Used as Tracers • A tracer is a substance with a radioactive isotope attached to it • Emissions from the tracer can be detected with special devices • Following the movement of tracers is useful in many areas of biology and medicine
  • 20.
  • 21.
    Lab 3: MakingConversions Between Various Measuring Systems • Purpose of this lab: To become familiar with several systems of measurement and make conversions from one unit to another as well as learn to read syringes and graduated cylinders