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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 5089
BIODIESEL FROM PEANUT OIL AND ITS EMISSION AND
PERFORMANCE CHARECTERISTICS IN FOUR STROKE IC ENGINE
SANTHOSH SHIVAN D1, RANJITH S2, SHYAM PRAKASH K J3, Prof. A. GOWRISANKAR4
1,2,3B.E. Automobile Engineering Department, RVS TCC-COIMBATORE, Tamilnadu, India
4Associate Professor, Automobile Engineering Department, RVS TCC-COIMBATORE, Tamilnadu, India
---------------------------------------------------------------------***---------------------------------------------------------------------
Abstract - Biofuel is fuel from recently lifeless or living
biological material. And it is different to fossil fuels from long
dead biological material. Gasoline and diesel are actually
ancient biofuels. Peanut is a potential oil crop as it contains
the high amount of oil as compared to only about 15
percentage – 20 percentage for soybean oil. Aside fromengine
testing, emissions associated with the use of biodiesel also
need to be evaluated to assess its cleanliness as a fuel. Hence,
this study was conducted to investigate the application of
peanut oil biodiesel as an engine fuel. On observingtheresults
of Emission Tests we found out thattherewaslesseramountof
soot formation and absence of black smoke.
Key Words: Biodiesel, peanut oil, emission.
1. INTRODUCTION
Gasoline and diesel are actually ancient biofuels. But
they are known as fossil fuels because they are made from
decomposed plants and animals that havebeenburiedinthe
ground for millions of years. Biofuels are similar, exceptthat
they're made from plants grown today. Biofuel is fuel from
recently lifeless or living biological material. It is different to
fossil fuels from long dead biological material.Biofuel can be
in forms of solid, liquid or gas. Biofuels are usually used to
power cars, heat homes and for cooking. Growing concerns
over possible scarcity in petroleum fuel reserves as well as
increasing awareness on global environmental issues
prompted the developmentandutilizationofnon-petroleum
based fuels that are clean, sustainable and renewable. Oils
from biomass are a potential alternativetopetroleum-based
fuels; however, their high viscositylimitstheirapplicationas
engine fuel and therefore must be modified prior to
utilization. Hence, transesterification of the oils should be
done to improve their properties, producing a product
termed as biodiesel. Biodiesel is a mixture of mono-alkyl
esters of long chain fatty acids derived from a renewable
lipid feedstock, such as vegetable oil or animal fat. It can be
produced from the transesterification of any triglyceride
feedstock, which includes oil-bearing crops, animal fats and
algal lipids. The feedstock commonly utilized for biodiesel
production depends upon the country’s geographical,
climatic and economic conditions. Rapeseed and canola oil
are mainly used in Europe, palm oil in tropical countriesand
soybean oil and animal fats in the US. However, thesupplyof
these feed stocks may not be enough to displace all
petroleum-based diesel (petrodiesel) usage. In the US,
soybean oil alone cannot satisfy the demand of feedstock
quantity for biodiesel production since it accounts for only
13.5 percentage of the total production and only an
estimated 6percentage of petrodiesel demand can be
replaced if all US soybean production were utilized as
biodiesel feedstock. Consequently, alternative feed stocks
were identified such as sunflower, moringa, hazelnut and
jatropha seed oils among others. Peanut is a potential oil
crop as it contains the high amount ofoil (40percentage – 50
percentage of the mass of dried nuts) as compared to only
about 15 percentage – 20 percentage forsoybeanoil. The US
Department of agriculture reports an annual peanut yield of
4.70 metric tons per hr., which is almost twice as that for
soybean (2.66 metric tons per hr). Thus, oil yieldforpeanuts
can reach as much as 1059 L/hr while it is only 446 L/hr for
soybean oil. This product is a peanut oil-diesel blend which
was tested for peanut oil viscosity, flash point and fire point,
calorific value, ash content all ofwhichmettherequirements
for bio-diesel fuel. Moser, on the other hand, prepared
methyl esters using catalytic potassium hydroxide and
obtained 92 percentage yield of peanut methyl esters which
exhibited excellent oxidative stability but poor cold flow
properties. The obtained biodiesel has a viscosity close to
petrodiesel but has calorificvalue6percentagelessthanthat
for petrodiesel. Important fuel properties such as density,
flash point, cetane number fall within the set standards.
Another important aspect in biodiesel research thatmustbe
considered is the assessment ofitsperformanceasanengine
fuel. Studies involving the application of peanut oil biodiesel
in an engine are very limited in literature. A number of
studies discussed the performance of biodiesel from other
feed stocks such as soybean, sun- flower,canola,inanengine
which specifically has the effect of using biodiesel blends on
engine power and fuel economy. However, engine
performance may be affected by the variation in biodiesel
quality caused by differences in the esterification process
and the raw materials used, among others. Aside from
engine testing, emissions associatedwiththeuseofbiodiesel
also need to be evaluated to assess its cleanliness as a fuel.
The Environmental Protection Agency reported that non-
road diesel engines have a substantial role in contributing to
the nation’s air pollution and therefore stricter emission
standards were imposed with regards to the amounts of
particulate matter, nitrogen oxides and sulphur oxides.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 5090
Hence, this study was conducted to investigate the
application of peanut oil biodiesel as an engine fuel. This
study aims to:
 Assess fuel properties of the peanut oil biodiesel in
accordance with ASTM standards.
 Determine the effect of blending percentage of
biodiesel on the characteristic engine performance
(i.e. net brake power, torque and specific
consumption).
1.1 BIODIESEL 1
Biodiesel is fuel from recently lifeless or living
biological material. It is different to fossil fuels from long
dead biological material. Biodiesel can be in forms of solid,
liquid or gas. Biodiesel are usually used to power cars, heat
homes and for cooking.
1.2 PEANUT 2
A peanut is a plant in the legume family,Fabaceae.It
is native to South America, Central America and Mexico.
Binomial Name : Arachis hypogaea.
Genus : Arachis
Species : hypogaea
Family : Fabaceae
1.3 TYPES OF PEANUT 3
Although peanuts come in many varieties, there are
four basic market types: Runner, Virginia, Spanish and
Valencia. Each of the peanut types is distinctiveinsize,flavor,
and nutritional composition. Within each four basic types of
peanuts, there are several “varieties”forseedandproduction
purposes.Eachvarietycontainsdistinctcharacteristicswhich
allows a producer to select the peanut that is best suited for
its region and market.
2. LITERATURE REVIEW
Gandhi, A.P., K. Jha, et al. 1992, [7]., Peanut seeds
contain 27–29 percentage (w/w) protein and 40–50
percentage (w/w) oil
Bari, S., Yu, C. W., et al. 2002, [2]., Increasingly strict
emissions regulations have forced researchers to look for
ways to achieve emission reductions through fuel
modifications. Biofuels are potential renewable alternative
fuels for internal combustion engines.
Bian, Y.-Z, et al. 2003, [3]., Biodiesel is a fuel
consisting of the alky-mono-ester of fatty acids from
vegetable oils or animal fats
Bari, S., Yu, C. W., et al. 2004, [1]., The world
petroleum reserve to production ratio (R/P) stood at about
40 years from the year 2004, but China’sR/P isonlyabout20
years.
Carraretto, et al. 2004, [4]., Biodiesel is similar to
diesel fuel in some of its chemical and physical attributes,
including its combustion characteristics.
DemirbasA, et al. 2005,[5].,Therefore,biodieselfuel
can be used in diesel engines with little or no modification.
Demirbas A, et al. 2006, [6]., Biodiesel has a higher
cetane number than diesel fuel,noaromatics,andnosulphur,
and it contains 10–11percentage oxygen. These
characteristics of biodiesel reduce some exhaust emissions.
Biodiesel has virtually the same miles per gallon rating as
petrodiesel. Biodiesel has a very high flash point, making it
one of the safest of all alternative fuels. It is the only
alternative fuel that can actually extendenginelifebecauseof
its superior lubricating properties. Peanutsare an important
source of lipid and protein in developingaswellasdeveloped
countries, and peanut oil is one of the major oils in biodiesel
production.
3. METHODOLOGY
There are two main process are performed in the
production of the peanut oil biodiesel. These were
transesterification and washing process.Transesterification
is the process of exchanging the alkoxy group of an ester
compound by another alcohol. These reactions are often
catalyzed by the addition of an acid or base. Washing
Biodiesel with water is the oldest and mostcommonmethod
of cleaning biodiesel. About 3 Percentage of raw, unwashed
biodiesel is methanol. Methanol is a solvent, it capturessoap
and other impurities and holds them dissolved in the
biodiesel. Water soaks up that methanol, releasing
impurities to be washed away with water. And pure
biodiesel of peanut oil is collected.
4. METHODS AND PROCEDURES
4.1 WORKING PROCESS
Two operations are performed in the production of
the peanut oil ethyl ester. Theseweretransesterificationand
washing process.
4.1.1 THE TRANSESTERIFICATION PROCESS
The reaction temperature of 60ºC was selected as
suggested by Alamu et al. (2007). Potassium hydroxide was
added to methanol to form potassium methoxide. The
methanol-KOH mixture (potassium methoxide) was poured
into the groundnut oil in a transesterification reactor, and
the following transesterification reaction occurred. The
mixture of potassium hydroxide and methanol in the flask
was stirred vigorously. The methanol catalyst mixture was
poured into the oil in the main reactor and stirred rapidly,
settle for 48 hrs. After settling and completion of separation,
glycerol which is the heavier liquid collected at the bottom,
while the ester product was at the top. The glycerol layer
was drained off and the ester layer remained.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 5091
4.1.2 WASHING PROCESS
The method used for washing consists of two steps
developed by Peterson et al. (1996), is described as follows:
The glycerol layer was re-mixed with the ester layer after
initial settling has occurred, then 15percentage water was
added and the entire mixtures were re-stirred for 10 min
and allowed to settle for 48 hrs.
FIG 1 – WASHING PROCESS OF BIOFUEL
The ester product was washed after drainingoff the
glycerol layer. The ester was washed with water at about
30percentage of the estervolume.Thewater wasstirredinto
the ester with mechanical stirring using a blender. After 10
mins, the stirring was stopped, and the water wasallowed to
settle out for two days. At this point, the process was
complete and the crystal clearproductwasthegroundnut oil
ethyl ester. Water soaks up that methanol, releasing
impurities to be washed away with water. Most dry wash
methods require we evapourateordistill themethanol intoa
flammable and toxic gas as part of the purification process.
Water washing is the most flexible way to purify biodiesel.
4.2 TESTING PROCESS
4.2.1 FLASH AND FIRE POINT TEST
The flash point of a material is the lowest
temperature at which the vapour of substance momentarily
takes fire in the form of a flash under specified condition of
test. The fire point is the lowest temperature at which the
material gets ignited and burns under specified condition of
test The material is filled in the cup up to a filling mark. The
lid is placed to close the cup in a closed system. All
accessories includingthermometerofthespecifiedrange are
suitably fixed. The bitumen sample is then heated. The test
flame is lit and adjusted in such a way that the size of a bleed
is of 4mm diameter. The heating is done at the rate of 5°C to
6°C per minute. The stirring is done at a rate of
approximately 60 revolutions per minute. The test flame is
applied at intervals depending upon the expected flash and
fire points. First application is made at least 17°C below the
actual flash point and then at every 1°C to 3℃. The stirring is
discontinued during the application of the test flame.
4.2.2 VISCOSITY TEST
Preparation of the Sample - Heat the sample to a
temperature not more than 60°C for the tarsandpitchesand
not more than 90°C for bitumens above their respective
approximate softening point temperature respectively until
it has become sufficiently fluid to pour. Transferabout20 ml
into a suitable container and maintain it to a temperature of
135 ± 5.5°C stirring occasionallytopreventlocal overheating
and allow the entrapped airtoescape. Chargetheviscometer
by pouring the prepared sample to within ± 2 mm of fill line
E. Place the charged viscometer in an oven or bath
maintained at 135 ± 5.5°C for a period of 10 ± 2 min to allow
large air bubbles to escape. Testing - Maintainthe bathatthe
test temperature within ± O.1°C. Place the charged
viscometer vertically in the water bath with the help of a
holder so that the uppermost timing mark is at least 2 below
the surface of the bath liquid. After the viscometer has
remained in the bath for 30 ± 5 min open the valveandallow
the asphalt to flow into the viscometer. Measure to within ±
0.5 sec the time required for the leading edge. Upon
completion of the test, remove the viscometer from the bath
and place it in an inverted position in an oven maintained at
135 ± 5°C until asphalt is drained off thoroughly from the
viscometer.
4.2.3 CALORIFIC VALUE TEST
Prepare the sample in the bomb. The sample is put
in the crucible together with a piece of cotton wool.Aknown
length of fuse wire is passed through the sample with both
ends of the wire being attached to the 2 electrodes of the
bomb. Closing the bomb. Care must be taken not to disturb
the sample when moving the bomb head to the bomb
cylinder. Check the sealing ring to be sure that it is in good
condition and moisten it with a bit of water so that it will
slide freely into the cylinder; then slide the head into the
cylinder and push it down as far as it will go. For easy
insertion, push the head straight down without twistingand
leave the gas release valve open during this operation. Set
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 5092
the screw cap on the cylinder and turn it down firmly by
hand to a solid stop. When properlyclosed,nothreadson the
cylinder should be exposed. Filling the bomb. Connect the
oxygen supply to the bomb and close the gas release valve.
Open the filling connection control valve slowly and watch
the gauge as the bomb pressure rises to the desired filling
pressure (usually 30 atm., but never more than 40atm)then
close the control valve. Fill the calorimeter bucket. Put the
bomb inside the calorimeter bucket by attaching the lifting
handle to the screw cap and lowering the bomb with its feet
spanning the circular boss in the bottom of the bucket.
Handle the bomb carefully during this operation so that the
sample will not be disturbed. Remove the lifting handle and
add 1.2 liters of water inside the bucket. Final settings.
Connect the power source to the bomb and put the
thermometer inside the bucket. Set the cover on the jacket
and start the stirrer. Read and record temperatures. Let the
stirrer run for 5 minutes to reachequilibriumbeforestarting
a measured run. At the end of this period start a timer and
read the temperature. Read and recordtemperaturesatone-
minute intervals for 5 minutes. Then, at the start of the 5th
minute. Recording change in temperature. The bucket
temperature will start to rise within 30 seconds after firing.
This rise will be rapid during the first few minutes,
measuring the energy content of sample using the Bomb
Calorimeter then it will become slower as the temperature
approaches a stable maximum as shown by the typical
temperature rise curve. Record temperatures at one minute
intervals until the difference between successive readings
have been constant for 3 minutes. Usually the temperature
will reach a maximum; then drop very slowly. But this is not
always true since a low starting temperature may result in a
slow continuous rise without reaching a maximum. As
stated above, the difference between successive readings
must be noted and the readings continued at one-minute
intervals until the rate of the temperature change becomes
constant over a period of 3 minutes.Openingthebomb.After
the last temperature reading, stop the motor and lift the
cover from the calorimeter. Lift the bomb out of the bucket
and open the gas release valve on the bomb head to release
the gas pressure before attempting to remove the cap. After
all pressure has been released, unscrew the cap and lift the
head out of the cylinder. Examine the interior of the bomb
for soot or other evidence of incomplete combustion. If such
evidence is found, the test will have to be discarded. Fuse
wire burnt. Remove all unburned pieces of fuse wire from
the bomb electrodes; straighten them and measure their
combined length in centimeters. Subtract this length from
the initial length of fuse wire used and enter this quantity on
the data sheet as the net amount of wire burned.
4.2.4 ASH CONTENT TEST
When determining the ash content of asphalt
cement, the reference to the dry residue from the
determination of residue by evaporation in section 10 are
referring to asphalt cement. Incinerate the content of the
crucible for 2 hours and remove the crucible from the
furnace to cool to room temperature. Once the crucible is at
room temperature, the sample weight shall be determined
and recorded to the nearest 1 ml. Return the crucible to the
muffle furnace and heat the sample for an additional 30
minutes. After heating, cool the crucible again to room
temperature. Once at room temperature, determine and
record the sample weight to the nearest 1 ml. If a constant
weight has not been achieved, repeat step 3 until a constant
weight is reached. Calculate the ash content of a sample as a
percent of the asphalt cement or residue by evaporation as
applicable. Report the ash content to the nearest 0.1
percentage.
4.2.5 PERFORMANCE TEST
The useful power available at the crank shaft of the
engine is called brake power (BP). Torque is a measure of
the force that can cause an object to rotate aboutanaxis.Just
as force is what causes an object to accelerate in linear
kinematics, torque is what causes an object to acquire
angular acceleration. Total fuel consumption is the mass of
fuel consumed at particularloadconsumedatparticularload
per hour .It is expressed in kg / hr. Specific fuel consumption
is defined as the mass of the fuel consumed per hour per
brake power of the engine. The indicated power actually
developed inside the cylinder due to the combustion of fuel
are called indicated power (IP) Brake thermal efficiency is
defined as the ratio of brake power to heat supplied by the
combustion of fuel Indicated thermal efficiency is defined as
the ratio of indicated power to heat supplied by the
combustion of fuel Mechanical efficiency is defined as the
ratio of Brake power to indicated power Calculate the
maximum load that can be applied on the given engine.
Check the engine for fuel availability, lubricant and cooling
water connection. Release the load on the engine and start
the engine with no load condition. Allow the engine to run
for few minute to attain rated speed. Note the speed of the
engine and time taken for consumption of 10 cc of fuel.
Increase the load on the engine and note the speed of the
engine and time taken for 10cc of fuel consumption Repeat
the procedure up to 75 percentage of the maximumloadand
tabulate the readings.
4.2.6. EMISSION TEST
The first emissions testing was done in California in
1966. Emissions testingdeterminesthelevel ofairpollutants
emitted from the exhaust of a motor vehicle. Since then,
many states began requiring testing for all registered
vehicles. If a vehicle fails the emissions test, repairs must be
done and the vehicle retested. An emission test cycle is a
protocol contained in an emission standard to allow
repeatable and comparable measurement of exhaust
emissions for different engines or vehicles. Test cycles
specify the specific conditions under which the engine or
vehicle is operated during the emissiontest. Therearemany
different test cycles issued by various national and
international governments and working groups. Specified
parameters in a test cycle include a range of operating
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 5093
temperature, speed, and load. Ideally these are specified so
as to accurately and realistically represent the range of
conditions under which the vehicle or engine will be
operated in actual use. Because it is impractical to test an
engine or vehicle under everypossiblecombinationofspeed,
load, and temperature, this may not actually be the case.
4.2.6.1. SMOKE TEST
The smoke emitted from all diesel engine heavy
goods vehicles and buses is assessed for its density. It is
carried out by the use of an approved and calibrated smoke
meter. The engine will be accelerated up to governed speed
and the density of the smoke measured. After the third
acceleration the average readingisrecorded.Ifthereadingis
below 2.5m1 for non-turbocharged engines or 3.0m1 for
turbocharged engines the vehicle will pass. Diesel vehicles
first used from 1 July 2008 to 1 January 2014 must have a
reading of 1.50, and those vehicles first used on or after 1
January 2014 must have a reading of below 0.7ml. However
if the average is higher, a further acceleration is carried out
and the average of the last three readings are used, this will
continue until a maximum of six accelerations have been
carried out. If the average of the fourth, fifth and sixth
acceleration is higher than the right level the vehicle will not
pass the test. Also, any of the following will result in the
vehicle being refused a certificate:
 exhaust emits too much smoke or vapour of any
color, to an extent likely to obscure vision
 emissions cannot be measured because a tail pipeis
damaged or an accessory is fitted which prevents
the insertion of the smoke meter probe
 insufficient oil in the engine or low oil pressure
which could cause engine damage if engine is
accelerated
 obvious signs of an engine defectsuchasanunusual
noise or emission of smoke
 The emissions of CO increase with increasing load.
Higher the load, richer fuel–air mixture is burned,
and thus more CO is produced due tolack ofoxygen.
At lower loads, CO emissions for biodiesel blends
are close to mineral diesel.
 At higher load the biodiesel blends show significant
reduction in CO emission. All the biodiesel blends
exhibit lower HC emissions compared to mineral
diesel. This may be due to better combustion of
biodiesel blends due to presence of oxygen.
 Increase in the emission of NO was observed in
comparison with diesel for the biodiesel fueled
engines. The smoke opacity for biodiesel blend
fueled engines was lower than diesel at all loads.
5. RESULTS AND DISCUSSIONS
Bio-fuel and Diesel blending ratio - 3:7 [B30]
5.1 FLAS AND FIRE POINT
FLASH POINT OBTAINED - 75℃
FIRE POINT OBTAINED - 84℃
5.2 VISCOSITY TEST
TABLE 1 – VISCOSITY OF THE BIODIESEL
S.NO TEMPERATURE
(℃)
TIME
(Sec.)
QUANTITY
(ml)
1 40 32 50
2 45 30 50
3 50 28 50
4 55 25 50
5 60 21 50
5.3. CALORIFIC VALUE
Calorific value of Diesel - 45.5 MJ/kg
Calorific value of Bio-Diesel - 39.6 MJ/kg
5.4 ASH CONTENT
Ash content of Diesel - 0.1% to 0.2%
Ash content of Bio-Diesel - 0.2% to 0.5%
5.5 PERFORMANCE TEST
TABLE 2 – PERFORMANCE OF BIODIESEL VS
DIESEL
S.NO PERFORNAMNCE
CHARECTERISTICS
DIESEL B30
1 BP (KW) 1.9025 1.9027
3 TFC (Kg/hr) 0.3678 0.3641
4 SFC (Kg/hr) 0.134 0.132
5 Heat supplied (KW) 4.4955 4.2785
6 Induction power (KW) 3.0025 2.5052
7 BTE (percentage) 37.19 45.28
8 IPE (percentage) 62.89 32.71
9 ME (percentage) 50.37 59.47
FIG 2 – PERFORMANCE GRAPH OF BIODIESEL VS
DIESEL
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 5094
5.6 EMISSION TEST
TABLE 2 – EMISSION OF BIODIESEL VS DIESEL
S.NO EMISSION B100 B30
1 HC -67
percentage
-20 percentage
2 CO -48
percentage
-12 percentage
3 NOX +10
percentage
+2 percentage
to -2 percentage
4 PM -47
percentage
-12 percentage
-80
-60
-40
-20
0
20
HC CO NOX PM
E M I S S I ON
B100 B30
FIG 3 –EMISSION OF BIODIESEL VS DIESEL
5.7 DISCUSSIONS
From the figure 2, comparing normal diesel with
biodiesel is obtained very nearest value of various
performance test.
From the figure 3 the emission of biodiesel blend
is less compared to normal diesel and also due to less soot
formation, absence of black smoke occurs during emission
test.
6. CONCLUSIONS
It is a simple, eco-friendly, fast and green methodto
synthesize Biodiesel from peanut oil. In the present study it
was found that peanut oil could be a good source for the
synthesis of Biodiesel with several advantages. The
synthesized Biodiesel was confirmed by FlashandFirepoint
test. The Emission test of the synthesized Biodiesel showed
nearby values of standard emission tests.
REFERENCES
[1] Bari, S., Yu, et al. [2004] Effect of fuel injection
timing with waste cooking oil as a fuel in a direct
injection diesel engine. Proc.InstnMech.Engrs,Part
D: J. Automobile Engineering, 218, 93–104.
[2] Bari, S., et al. [2002] Filter clogging and power loss
issues while running a diesel engine with waste
cooking oil. Proc. Instn Mech. Engrs, Part D: J.
Automobile Engineering, 216, 993–1001.
[3] Bian, Y.-Z, et al. [2003] New automobile energy
technology, (China CommunicationsPress,Beijing).
[4] Carraretto, C., et al. [2004] Biodiesel as alternative
fuel: experimental analysis and energetic
evaluations. Energy, 29, 2195–2211.
[5] Demirbas A, et al. [2005] Biodiesel productionfrom
vegetable oils via catalytic and noncatalytic
supercritical methanol transesterificationmethods.
Prog Energy Combus Sci;31:466–87.
[6] Demirbas A, et al. [2006] Biodiesel production via
non-catalytic SCF method and biodiesel fuel
characteristics. Energy Convers Manage;47:2271–
82.
[7] Gandhi, A.P., et al. [1992] Status of Soymeal
Production and Its Utilization for Human Food in
India, Souvenir SOPA convention, Indore,India,,pp.
24–34.
BIOGRAPHIES
SANTHOSH SHIVAN D
B.E. Automobile Engineering
RVS Technical Campus-Coimbatore
RANJITH S
B.E. Automobile Engineering
RVS Technical Campus-Coimbatore
SHYAM PRAKASH K J
B.E. Automobile Engineering
RVS Technical Campus-Coimbatore
Prof. A. GOWRISANKAR
Associate Professor
Department of Automobile
Engineering
RVS Technical Campus-Coimbatore

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IRJET- Biodiesel from Peanut Oil and its Emission and Performance Charecteristics in Four Stroke IC Engine

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 5089 BIODIESEL FROM PEANUT OIL AND ITS EMISSION AND PERFORMANCE CHARECTERISTICS IN FOUR STROKE IC ENGINE SANTHOSH SHIVAN D1, RANJITH S2, SHYAM PRAKASH K J3, Prof. A. GOWRISANKAR4 1,2,3B.E. Automobile Engineering Department, RVS TCC-COIMBATORE, Tamilnadu, India 4Associate Professor, Automobile Engineering Department, RVS TCC-COIMBATORE, Tamilnadu, India ---------------------------------------------------------------------***--------------------------------------------------------------------- Abstract - Biofuel is fuel from recently lifeless or living biological material. And it is different to fossil fuels from long dead biological material. Gasoline and diesel are actually ancient biofuels. Peanut is a potential oil crop as it contains the high amount of oil as compared to only about 15 percentage – 20 percentage for soybean oil. Aside fromengine testing, emissions associated with the use of biodiesel also need to be evaluated to assess its cleanliness as a fuel. Hence, this study was conducted to investigate the application of peanut oil biodiesel as an engine fuel. On observingtheresults of Emission Tests we found out thattherewaslesseramountof soot formation and absence of black smoke. Key Words: Biodiesel, peanut oil, emission. 1. INTRODUCTION Gasoline and diesel are actually ancient biofuels. But they are known as fossil fuels because they are made from decomposed plants and animals that havebeenburiedinthe ground for millions of years. Biofuels are similar, exceptthat they're made from plants grown today. Biofuel is fuel from recently lifeless or living biological material. It is different to fossil fuels from long dead biological material.Biofuel can be in forms of solid, liquid or gas. Biofuels are usually used to power cars, heat homes and for cooking. Growing concerns over possible scarcity in petroleum fuel reserves as well as increasing awareness on global environmental issues prompted the developmentandutilizationofnon-petroleum based fuels that are clean, sustainable and renewable. Oils from biomass are a potential alternativetopetroleum-based fuels; however, their high viscositylimitstheirapplicationas engine fuel and therefore must be modified prior to utilization. Hence, transesterification of the oils should be done to improve their properties, producing a product termed as biodiesel. Biodiesel is a mixture of mono-alkyl esters of long chain fatty acids derived from a renewable lipid feedstock, such as vegetable oil or animal fat. It can be produced from the transesterification of any triglyceride feedstock, which includes oil-bearing crops, animal fats and algal lipids. The feedstock commonly utilized for biodiesel production depends upon the country’s geographical, climatic and economic conditions. Rapeseed and canola oil are mainly used in Europe, palm oil in tropical countriesand soybean oil and animal fats in the US. However, thesupplyof these feed stocks may not be enough to displace all petroleum-based diesel (petrodiesel) usage. In the US, soybean oil alone cannot satisfy the demand of feedstock quantity for biodiesel production since it accounts for only 13.5 percentage of the total production and only an estimated 6percentage of petrodiesel demand can be replaced if all US soybean production were utilized as biodiesel feedstock. Consequently, alternative feed stocks were identified such as sunflower, moringa, hazelnut and jatropha seed oils among others. Peanut is a potential oil crop as it contains the high amount ofoil (40percentage – 50 percentage of the mass of dried nuts) as compared to only about 15 percentage – 20 percentage forsoybeanoil. The US Department of agriculture reports an annual peanut yield of 4.70 metric tons per hr., which is almost twice as that for soybean (2.66 metric tons per hr). Thus, oil yieldforpeanuts can reach as much as 1059 L/hr while it is only 446 L/hr for soybean oil. This product is a peanut oil-diesel blend which was tested for peanut oil viscosity, flash point and fire point, calorific value, ash content all ofwhichmettherequirements for bio-diesel fuel. Moser, on the other hand, prepared methyl esters using catalytic potassium hydroxide and obtained 92 percentage yield of peanut methyl esters which exhibited excellent oxidative stability but poor cold flow properties. The obtained biodiesel has a viscosity close to petrodiesel but has calorificvalue6percentagelessthanthat for petrodiesel. Important fuel properties such as density, flash point, cetane number fall within the set standards. Another important aspect in biodiesel research thatmustbe considered is the assessment ofitsperformanceasanengine fuel. Studies involving the application of peanut oil biodiesel in an engine are very limited in literature. A number of studies discussed the performance of biodiesel from other feed stocks such as soybean, sun- flower,canola,inanengine which specifically has the effect of using biodiesel blends on engine power and fuel economy. However, engine performance may be affected by the variation in biodiesel quality caused by differences in the esterification process and the raw materials used, among others. Aside from engine testing, emissions associatedwiththeuseofbiodiesel also need to be evaluated to assess its cleanliness as a fuel. The Environmental Protection Agency reported that non- road diesel engines have a substantial role in contributing to the nation’s air pollution and therefore stricter emission standards were imposed with regards to the amounts of particulate matter, nitrogen oxides and sulphur oxides.
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 5090 Hence, this study was conducted to investigate the application of peanut oil biodiesel as an engine fuel. This study aims to:  Assess fuel properties of the peanut oil biodiesel in accordance with ASTM standards.  Determine the effect of blending percentage of biodiesel on the characteristic engine performance (i.e. net brake power, torque and specific consumption). 1.1 BIODIESEL 1 Biodiesel is fuel from recently lifeless or living biological material. It is different to fossil fuels from long dead biological material. Biodiesel can be in forms of solid, liquid or gas. Biodiesel are usually used to power cars, heat homes and for cooking. 1.2 PEANUT 2 A peanut is a plant in the legume family,Fabaceae.It is native to South America, Central America and Mexico. Binomial Name : Arachis hypogaea. Genus : Arachis Species : hypogaea Family : Fabaceae 1.3 TYPES OF PEANUT 3 Although peanuts come in many varieties, there are four basic market types: Runner, Virginia, Spanish and Valencia. Each of the peanut types is distinctiveinsize,flavor, and nutritional composition. Within each four basic types of peanuts, there are several “varieties”forseedandproduction purposes.Eachvarietycontainsdistinctcharacteristicswhich allows a producer to select the peanut that is best suited for its region and market. 2. LITERATURE REVIEW Gandhi, A.P., K. Jha, et al. 1992, [7]., Peanut seeds contain 27–29 percentage (w/w) protein and 40–50 percentage (w/w) oil Bari, S., Yu, C. W., et al. 2002, [2]., Increasingly strict emissions regulations have forced researchers to look for ways to achieve emission reductions through fuel modifications. Biofuels are potential renewable alternative fuels for internal combustion engines. Bian, Y.-Z, et al. 2003, [3]., Biodiesel is a fuel consisting of the alky-mono-ester of fatty acids from vegetable oils or animal fats Bari, S., Yu, C. W., et al. 2004, [1]., The world petroleum reserve to production ratio (R/P) stood at about 40 years from the year 2004, but China’sR/P isonlyabout20 years. Carraretto, et al. 2004, [4]., Biodiesel is similar to diesel fuel in some of its chemical and physical attributes, including its combustion characteristics. DemirbasA, et al. 2005,[5].,Therefore,biodieselfuel can be used in diesel engines with little or no modification. Demirbas A, et al. 2006, [6]., Biodiesel has a higher cetane number than diesel fuel,noaromatics,andnosulphur, and it contains 10–11percentage oxygen. These characteristics of biodiesel reduce some exhaust emissions. Biodiesel has virtually the same miles per gallon rating as petrodiesel. Biodiesel has a very high flash point, making it one of the safest of all alternative fuels. It is the only alternative fuel that can actually extendenginelifebecauseof its superior lubricating properties. Peanutsare an important source of lipid and protein in developingaswellasdeveloped countries, and peanut oil is one of the major oils in biodiesel production. 3. METHODOLOGY There are two main process are performed in the production of the peanut oil biodiesel. These were transesterification and washing process.Transesterification is the process of exchanging the alkoxy group of an ester compound by another alcohol. These reactions are often catalyzed by the addition of an acid or base. Washing Biodiesel with water is the oldest and mostcommonmethod of cleaning biodiesel. About 3 Percentage of raw, unwashed biodiesel is methanol. Methanol is a solvent, it capturessoap and other impurities and holds them dissolved in the biodiesel. Water soaks up that methanol, releasing impurities to be washed away with water. And pure biodiesel of peanut oil is collected. 4. METHODS AND PROCEDURES 4.1 WORKING PROCESS Two operations are performed in the production of the peanut oil ethyl ester. Theseweretransesterificationand washing process. 4.1.1 THE TRANSESTERIFICATION PROCESS The reaction temperature of 60ºC was selected as suggested by Alamu et al. (2007). Potassium hydroxide was added to methanol to form potassium methoxide. The methanol-KOH mixture (potassium methoxide) was poured into the groundnut oil in a transesterification reactor, and the following transesterification reaction occurred. The mixture of potassium hydroxide and methanol in the flask was stirred vigorously. The methanol catalyst mixture was poured into the oil in the main reactor and stirred rapidly, settle for 48 hrs. After settling and completion of separation, glycerol which is the heavier liquid collected at the bottom, while the ester product was at the top. The glycerol layer was drained off and the ester layer remained.
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 5091 4.1.2 WASHING PROCESS The method used for washing consists of two steps developed by Peterson et al. (1996), is described as follows: The glycerol layer was re-mixed with the ester layer after initial settling has occurred, then 15percentage water was added and the entire mixtures were re-stirred for 10 min and allowed to settle for 48 hrs. FIG 1 – WASHING PROCESS OF BIOFUEL The ester product was washed after drainingoff the glycerol layer. The ester was washed with water at about 30percentage of the estervolume.Thewater wasstirredinto the ester with mechanical stirring using a blender. After 10 mins, the stirring was stopped, and the water wasallowed to settle out for two days. At this point, the process was complete and the crystal clearproductwasthegroundnut oil ethyl ester. Water soaks up that methanol, releasing impurities to be washed away with water. Most dry wash methods require we evapourateordistill themethanol intoa flammable and toxic gas as part of the purification process. Water washing is the most flexible way to purify biodiesel. 4.2 TESTING PROCESS 4.2.1 FLASH AND FIRE POINT TEST The flash point of a material is the lowest temperature at which the vapour of substance momentarily takes fire in the form of a flash under specified condition of test. The fire point is the lowest temperature at which the material gets ignited and burns under specified condition of test The material is filled in the cup up to a filling mark. The lid is placed to close the cup in a closed system. All accessories includingthermometerofthespecifiedrange are suitably fixed. The bitumen sample is then heated. The test flame is lit and adjusted in such a way that the size of a bleed is of 4mm diameter. The heating is done at the rate of 5°C to 6°C per minute. The stirring is done at a rate of approximately 60 revolutions per minute. The test flame is applied at intervals depending upon the expected flash and fire points. First application is made at least 17°C below the actual flash point and then at every 1°C to 3℃. The stirring is discontinued during the application of the test flame. 4.2.2 VISCOSITY TEST Preparation of the Sample - Heat the sample to a temperature not more than 60°C for the tarsandpitchesand not more than 90°C for bitumens above their respective approximate softening point temperature respectively until it has become sufficiently fluid to pour. Transferabout20 ml into a suitable container and maintain it to a temperature of 135 ± 5.5°C stirring occasionallytopreventlocal overheating and allow the entrapped airtoescape. Chargetheviscometer by pouring the prepared sample to within ± 2 mm of fill line E. Place the charged viscometer in an oven or bath maintained at 135 ± 5.5°C for a period of 10 ± 2 min to allow large air bubbles to escape. Testing - Maintainthe bathatthe test temperature within ± O.1°C. Place the charged viscometer vertically in the water bath with the help of a holder so that the uppermost timing mark is at least 2 below the surface of the bath liquid. After the viscometer has remained in the bath for 30 ± 5 min open the valveandallow the asphalt to flow into the viscometer. Measure to within ± 0.5 sec the time required for the leading edge. Upon completion of the test, remove the viscometer from the bath and place it in an inverted position in an oven maintained at 135 ± 5°C until asphalt is drained off thoroughly from the viscometer. 4.2.3 CALORIFIC VALUE TEST Prepare the sample in the bomb. The sample is put in the crucible together with a piece of cotton wool.Aknown length of fuse wire is passed through the sample with both ends of the wire being attached to the 2 electrodes of the bomb. Closing the bomb. Care must be taken not to disturb the sample when moving the bomb head to the bomb cylinder. Check the sealing ring to be sure that it is in good condition and moisten it with a bit of water so that it will slide freely into the cylinder; then slide the head into the cylinder and push it down as far as it will go. For easy insertion, push the head straight down without twistingand leave the gas release valve open during this operation. Set
  • 4. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 5092 the screw cap on the cylinder and turn it down firmly by hand to a solid stop. When properlyclosed,nothreadson the cylinder should be exposed. Filling the bomb. Connect the oxygen supply to the bomb and close the gas release valve. Open the filling connection control valve slowly and watch the gauge as the bomb pressure rises to the desired filling pressure (usually 30 atm., but never more than 40atm)then close the control valve. Fill the calorimeter bucket. Put the bomb inside the calorimeter bucket by attaching the lifting handle to the screw cap and lowering the bomb with its feet spanning the circular boss in the bottom of the bucket. Handle the bomb carefully during this operation so that the sample will not be disturbed. Remove the lifting handle and add 1.2 liters of water inside the bucket. Final settings. Connect the power source to the bomb and put the thermometer inside the bucket. Set the cover on the jacket and start the stirrer. Read and record temperatures. Let the stirrer run for 5 minutes to reachequilibriumbeforestarting a measured run. At the end of this period start a timer and read the temperature. Read and recordtemperaturesatone- minute intervals for 5 minutes. Then, at the start of the 5th minute. Recording change in temperature. The bucket temperature will start to rise within 30 seconds after firing. This rise will be rapid during the first few minutes, measuring the energy content of sample using the Bomb Calorimeter then it will become slower as the temperature approaches a stable maximum as shown by the typical temperature rise curve. Record temperatures at one minute intervals until the difference between successive readings have been constant for 3 minutes. Usually the temperature will reach a maximum; then drop very slowly. But this is not always true since a low starting temperature may result in a slow continuous rise without reaching a maximum. As stated above, the difference between successive readings must be noted and the readings continued at one-minute intervals until the rate of the temperature change becomes constant over a period of 3 minutes.Openingthebomb.After the last temperature reading, stop the motor and lift the cover from the calorimeter. Lift the bomb out of the bucket and open the gas release valve on the bomb head to release the gas pressure before attempting to remove the cap. After all pressure has been released, unscrew the cap and lift the head out of the cylinder. Examine the interior of the bomb for soot or other evidence of incomplete combustion. If such evidence is found, the test will have to be discarded. Fuse wire burnt. Remove all unburned pieces of fuse wire from the bomb electrodes; straighten them and measure their combined length in centimeters. Subtract this length from the initial length of fuse wire used and enter this quantity on the data sheet as the net amount of wire burned. 4.2.4 ASH CONTENT TEST When determining the ash content of asphalt cement, the reference to the dry residue from the determination of residue by evaporation in section 10 are referring to asphalt cement. Incinerate the content of the crucible for 2 hours and remove the crucible from the furnace to cool to room temperature. Once the crucible is at room temperature, the sample weight shall be determined and recorded to the nearest 1 ml. Return the crucible to the muffle furnace and heat the sample for an additional 30 minutes. After heating, cool the crucible again to room temperature. Once at room temperature, determine and record the sample weight to the nearest 1 ml. If a constant weight has not been achieved, repeat step 3 until a constant weight is reached. Calculate the ash content of a sample as a percent of the asphalt cement or residue by evaporation as applicable. Report the ash content to the nearest 0.1 percentage. 4.2.5 PERFORMANCE TEST The useful power available at the crank shaft of the engine is called brake power (BP). Torque is a measure of the force that can cause an object to rotate aboutanaxis.Just as force is what causes an object to accelerate in linear kinematics, torque is what causes an object to acquire angular acceleration. Total fuel consumption is the mass of fuel consumed at particularloadconsumedatparticularload per hour .It is expressed in kg / hr. Specific fuel consumption is defined as the mass of the fuel consumed per hour per brake power of the engine. The indicated power actually developed inside the cylinder due to the combustion of fuel are called indicated power (IP) Brake thermal efficiency is defined as the ratio of brake power to heat supplied by the combustion of fuel Indicated thermal efficiency is defined as the ratio of indicated power to heat supplied by the combustion of fuel Mechanical efficiency is defined as the ratio of Brake power to indicated power Calculate the maximum load that can be applied on the given engine. Check the engine for fuel availability, lubricant and cooling water connection. Release the load on the engine and start the engine with no load condition. Allow the engine to run for few minute to attain rated speed. Note the speed of the engine and time taken for consumption of 10 cc of fuel. Increase the load on the engine and note the speed of the engine and time taken for 10cc of fuel consumption Repeat the procedure up to 75 percentage of the maximumloadand tabulate the readings. 4.2.6. EMISSION TEST The first emissions testing was done in California in 1966. Emissions testingdeterminesthelevel ofairpollutants emitted from the exhaust of a motor vehicle. Since then, many states began requiring testing for all registered vehicles. If a vehicle fails the emissions test, repairs must be done and the vehicle retested. An emission test cycle is a protocol contained in an emission standard to allow repeatable and comparable measurement of exhaust emissions for different engines or vehicles. Test cycles specify the specific conditions under which the engine or vehicle is operated during the emissiontest. Therearemany different test cycles issued by various national and international governments and working groups. Specified parameters in a test cycle include a range of operating
  • 5. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 5093 temperature, speed, and load. Ideally these are specified so as to accurately and realistically represent the range of conditions under which the vehicle or engine will be operated in actual use. Because it is impractical to test an engine or vehicle under everypossiblecombinationofspeed, load, and temperature, this may not actually be the case. 4.2.6.1. SMOKE TEST The smoke emitted from all diesel engine heavy goods vehicles and buses is assessed for its density. It is carried out by the use of an approved and calibrated smoke meter. The engine will be accelerated up to governed speed and the density of the smoke measured. After the third acceleration the average readingisrecorded.Ifthereadingis below 2.5m1 for non-turbocharged engines or 3.0m1 for turbocharged engines the vehicle will pass. Diesel vehicles first used from 1 July 2008 to 1 January 2014 must have a reading of 1.50, and those vehicles first used on or after 1 January 2014 must have a reading of below 0.7ml. However if the average is higher, a further acceleration is carried out and the average of the last three readings are used, this will continue until a maximum of six accelerations have been carried out. If the average of the fourth, fifth and sixth acceleration is higher than the right level the vehicle will not pass the test. Also, any of the following will result in the vehicle being refused a certificate:  exhaust emits too much smoke or vapour of any color, to an extent likely to obscure vision  emissions cannot be measured because a tail pipeis damaged or an accessory is fitted which prevents the insertion of the smoke meter probe  insufficient oil in the engine or low oil pressure which could cause engine damage if engine is accelerated  obvious signs of an engine defectsuchasanunusual noise or emission of smoke  The emissions of CO increase with increasing load. Higher the load, richer fuel–air mixture is burned, and thus more CO is produced due tolack ofoxygen. At lower loads, CO emissions for biodiesel blends are close to mineral diesel.  At higher load the biodiesel blends show significant reduction in CO emission. All the biodiesel blends exhibit lower HC emissions compared to mineral diesel. This may be due to better combustion of biodiesel blends due to presence of oxygen.  Increase in the emission of NO was observed in comparison with diesel for the biodiesel fueled engines. The smoke opacity for biodiesel blend fueled engines was lower than diesel at all loads. 5. RESULTS AND DISCUSSIONS Bio-fuel and Diesel blending ratio - 3:7 [B30] 5.1 FLAS AND FIRE POINT FLASH POINT OBTAINED - 75℃ FIRE POINT OBTAINED - 84℃ 5.2 VISCOSITY TEST TABLE 1 – VISCOSITY OF THE BIODIESEL S.NO TEMPERATURE (℃) TIME (Sec.) QUANTITY (ml) 1 40 32 50 2 45 30 50 3 50 28 50 4 55 25 50 5 60 21 50 5.3. CALORIFIC VALUE Calorific value of Diesel - 45.5 MJ/kg Calorific value of Bio-Diesel - 39.6 MJ/kg 5.4 ASH CONTENT Ash content of Diesel - 0.1% to 0.2% Ash content of Bio-Diesel - 0.2% to 0.5% 5.5 PERFORMANCE TEST TABLE 2 – PERFORMANCE OF BIODIESEL VS DIESEL S.NO PERFORNAMNCE CHARECTERISTICS DIESEL B30 1 BP (KW) 1.9025 1.9027 3 TFC (Kg/hr) 0.3678 0.3641 4 SFC (Kg/hr) 0.134 0.132 5 Heat supplied (KW) 4.4955 4.2785 6 Induction power (KW) 3.0025 2.5052 7 BTE (percentage) 37.19 45.28 8 IPE (percentage) 62.89 32.71 9 ME (percentage) 50.37 59.47 FIG 2 – PERFORMANCE GRAPH OF BIODIESEL VS DIESEL
  • 6. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 5094 5.6 EMISSION TEST TABLE 2 – EMISSION OF BIODIESEL VS DIESEL S.NO EMISSION B100 B30 1 HC -67 percentage -20 percentage 2 CO -48 percentage -12 percentage 3 NOX +10 percentage +2 percentage to -2 percentage 4 PM -47 percentage -12 percentage -80 -60 -40 -20 0 20 HC CO NOX PM E M I S S I ON B100 B30 FIG 3 –EMISSION OF BIODIESEL VS DIESEL 5.7 DISCUSSIONS From the figure 2, comparing normal diesel with biodiesel is obtained very nearest value of various performance test. From the figure 3 the emission of biodiesel blend is less compared to normal diesel and also due to less soot formation, absence of black smoke occurs during emission test. 6. CONCLUSIONS It is a simple, eco-friendly, fast and green methodto synthesize Biodiesel from peanut oil. In the present study it was found that peanut oil could be a good source for the synthesis of Biodiesel with several advantages. The synthesized Biodiesel was confirmed by FlashandFirepoint test. The Emission test of the synthesized Biodiesel showed nearby values of standard emission tests. REFERENCES [1] Bari, S., Yu, et al. [2004] Effect of fuel injection timing with waste cooking oil as a fuel in a direct injection diesel engine. Proc.InstnMech.Engrs,Part D: J. Automobile Engineering, 218, 93–104. [2] Bari, S., et al. [2002] Filter clogging and power loss issues while running a diesel engine with waste cooking oil. Proc. Instn Mech. Engrs, Part D: J. Automobile Engineering, 216, 993–1001. [3] Bian, Y.-Z, et al. [2003] New automobile energy technology, (China CommunicationsPress,Beijing). [4] Carraretto, C., et al. [2004] Biodiesel as alternative fuel: experimental analysis and energetic evaluations. Energy, 29, 2195–2211. [5] Demirbas A, et al. [2005] Biodiesel productionfrom vegetable oils via catalytic and noncatalytic supercritical methanol transesterificationmethods. Prog Energy Combus Sci;31:466–87. [6] Demirbas A, et al. [2006] Biodiesel production via non-catalytic SCF method and biodiesel fuel characteristics. Energy Convers Manage;47:2271– 82. [7] Gandhi, A.P., et al. [1992] Status of Soymeal Production and Its Utilization for Human Food in India, Souvenir SOPA convention, Indore,India,,pp. 24–34. BIOGRAPHIES SANTHOSH SHIVAN D B.E. Automobile Engineering RVS Technical Campus-Coimbatore RANJITH S B.E. Automobile Engineering RVS Technical Campus-Coimbatore SHYAM PRAKASH K J B.E. Automobile Engineering RVS Technical Campus-Coimbatore Prof. A. GOWRISANKAR Associate Professor Department of Automobile Engineering RVS Technical Campus-Coimbatore