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IJSRD - International Journal for Scientific Research & Development| Vol. 2, Issue 07, 2014 | ISSN (online): 2321-0613
All rights reserved by www.ijsrd.com 377
Experimental Investigation on Performance, Emission and Combustion
Characteristics of Single Cylinder Diesel Engine Running on Fish Oil
Biodiesel
Shivaraj1
Harichandra.V.Astagi2
Omprakash.D.Hebbal3
1
M.Tech Student 2
Assistant Professor 3
Professor
1
Department of Thermal Power engineering 2,3
Department of Mechanical engineering
1,2,3
Poojya Doddappa Appa College of Engineering, Gulbarga, Karnataka, India
Abstract— Continuous rise in the conventional fuel prices
and shortage of its supply have increased the interest in the
field of the alternative sources for petroleum fuels. In this
present work, experimentation was carried out to study the
performance, emission and combustion characteristics of
desert date biodiesel and its blends. For this experiment a
single cylinder, four strokes, naturally aspired, direct
injection, water cooled, eddy current dynamometer
Kirloskar diesel engine at 1500 rpm for variable loads.
Initially, desert date biodiesel and its blends were chosen.
The physical and chemical properties of desert date
biodiesel were determined. The tests were carried out over
entire range of engine operation at varying conditions of
load. The engine performance parameters studied were
brake horse power, brake specific fuel consumption, brake
thermal efficiency, exhaust temperature and mechanical
efficiency. The emission characteristics studied are CO, HC,
NOx and smoke opacity. These results are compared to
those of pure diesel. These results are again compared to the
other results of neat oils available in the literature for
validation. By analyzing the graphs, it was observed that
performance characteristics are reduced and emission
characteristics are lowered compare to the diesel. This is
mainly due to lower calorific value, higher viscosity and
delayed combustion process. From the analysis of graphs it
is observed that B10 and B20 blends are best suited for
diesel engine. The present experimental results show that
fish oil biodiesel and its blends can be used as an alternative
fuel in diesel engine.
Keywords: Biodiesel, fish oil biodiesel, alternative fuel
Ethanol Performance Emissions, combustion.
I. INTRODUCTION
In Energy is very important for life quality, welfare level
and social development of people as well as economic
growth. Fossil fuels have been an important traditional
energy source for years. Energy demand around the world is
increasing rapidly as a result of ongoing trends in
modernization and industrialization. In the scenario of
increase of vehicle population at an alarming rate due to
advancement of civilization, use of diesel fuel in not only
transport sector but also in agriculture sector leading to fast
depletion of diesel fuels and increase of pollution levels with
these fuels, the search for alternate fuels on has become
pertinent for the engine manufacturers, users and researchers
involved in the combustion research. To meet tough
automotive competition and stringent government
regulations, more efficient engine components, improved
engine oils, and high performance coating materials have
been developed within the automotive industry [2].
Energy consumption is increased globally in various
purposes. The intensity of consumption is directly
proportional to society’s development. Today, more and
more developing countries are prospering through economic
reforms and are industrially advanced. Fuel is critical to any
strategic plan for economic development and national
security. In developing countries like India which is about to
emerge as world power, the fuel has assumed serious
economic consequences in the forms of budget deficits
caused by oil imports and ecological degradation caused by
pollution. The possibility of substituting cleaner burning
alternatives for gasoline and diesel has drawn the attention
of automobile industry over the past decade. [3]
Many of the alternative fuels have been
experimented. Among them is the bio-fuel. As bio-diesel
has certain similarity for the conventional fuels,slowly they
have been introduced in the CI-Engine. Bio fuels have
become a matter of global importance because of the need
for an alternative energy at a cheaper price and with less
pollution. Biodiesel is a domestic, renewable fuel for diesel
engine comprised of mono-alkyl esters of long chain fatty
acids derived from natural oil vegetable oils/animal fats.
A. The Properties of Diesel and Fish Oil Biodiesel
The different properties of diesel fuel and neem kernel
biodiesel are determined and given in Table.1. After
transesterification process the fuel properties like kinematic
viscosity, calorific value, and density, flash and fire point
get improved in case of biodiesel. The calorific value of fish
oil biodiesel is lower than that of diesel because of oxygen
content. The flash and fire point temperature of biodiesel is
higher than the pure diesel fuel this is beneficial by safety
considerations which can be stored and transported without
any risk.
Properties Diesel BD 10 BD 20
BD
100
Equipment
Calorific
value
(kJ/kg)
42000 41716.7 41433.4 39167
Bomb
calorimeter
Kinematics
viscosity at
400
C (Cst)
2.54 2.84 3.14 5.55
Red wood
viscometer
Density
(kg/m3
)
830 832.6 835.2 856 Hydrometer
Flash Point
(o
C)
54 63.6 73.2 150
Pensky
marten’s
Fire Point
(o
C)
64 73.6 83.2 160
Pensky
marten’s
Table 1: Fuel properties
Experimental Investigation on Performance, Emission and Combustion Characteristics of Single Cylinder Diesel Engine Running on Fish Oil Biodiesel
(IJSRD/Vol. 2/Issue 07/2014/083)
All rights reserved by www.ijsrd.com 378
II. EXPERIMENTATION
A. Transesterification
It is most commonly used and important method to reduce
the viscosity of vegetable oils. In this process triglyceride
reacts with three molecules of alcohol in the presence of a
catalyst producing a mixture of fatty acids, alkyl ester and
glycerol. The process of removal of all the glycerol and the
fatty acids from the vegetable oil in the presence of a
catalyst is called esterification. This esterifies vegetable oil
is called bio-diesel. Biodiesel properties are similar to diesel
fuel. It is renewable, non-toxic, bio-degradable and
environment friendly transportation fuel. After esterification
of the vegetable oil its density, viscosity, cetane number,
calorific value, atomization and vaporization rate, molecular
weight, and fuel spray penetration distance are improved
more. So these improved properties give good performance
in CI engine.
B. Separation of glycerol from bio- diesel
Fig. 1: Seperation of glycerin
The fig 1. Shows the separation of glycerin from
the bio- diesel. After reaction the oil is kept in a settling
funnel for the process of separation. In which biodiesel,
glycerin and catalyst are separated
C. Experimental Set-Up
Experiments were performed in the internal combustion
engine laboratory, Department of mechanical engineering,
PDA College of engineering, Gulbarga. The experimental
setup consists of single cylinder, four strokes, diesel engine
connected to eddy current dynamometer for variable
loading. The set as stand- alone type independent panel box
consisting of air box, fuel tank, manometer etc. The set up
enables study of engine for brake power, BMEP, brake
thermal efficiency, mechanical efficiency, specific fuel
consumption, volumetric efficiency, A/F ratio, and emission
characteristics like CO, CO2, HC and NOX.
Fig. 2: Schematic diagram of experimental setup
PT Pressure
transducer
T1 Jacket water inlet
temperature
N Rotary encoder T2 Jacket water outlet
temperature
F1 Fuel flow T3 Calorimeter water inlet
temperature = T1
F2 Air flow T4 Calorimeter water outlet
temperature
F3 Jacket water flow T5 Exhaust gas to calorimeter
temperature
F4 Calorimeter water
flow
T6 Exhaust gas from
calorimeter temperature
The various components of experimental set up are
described. Fig 2. shows the schematic diagram of
experimental setup and fig 3. Shows the photograph of the
experimental set up. The important components of the
system are,
 The engine
 Dynamometer
 Exhaust emission testing machine
 Calorimeter
 Fuel measuring unit
 Pressure sensor
 Temperature sensor
 Rotameter
 Software
Fig. 3: Photograph of experimental setup
Table 1 shows the technical specification of the engine.
Manufacturer Kirloskar Oil Engines Ltd., India
Model TV–SR II, naturally Aspirated
Engine Single cylinder, DI, 4 strokes
Bore/stroke 87.5mm/110mm
Compression ratio 17.5:1
Speed 1500 r/min, constant
Rated power 5.2 kW
Injection pressure 240 bar/23° BTDC
Type of sensor Piezo electric
Crank angle sensor 1-degree crank angle
Table 1: Technical specifications of the engine.
Experimental Investigation on Performance, Emission and Combustion Characteristics of Single Cylinder Diesel Engine Running on Fish Oil Biodiesel
(IJSRD/Vol. 2/Issue 07/2014/083)
All rights reserved by www.ijsrd.com 379
Fig. 4: Emission testing machine
The emissions test is are done with AVL DITEST
MDS 350 Exhaust Gas Analyzer. It is designed with
sophisticated measurement modules. The product has
additional features to save a vehicle and customer database,
radio-connected diesel measuring chamber up to the option
of designing the protocols individually. Due to the
robustness and intuitive application of the device, the tester
can be used to get sophisticated and accurate emission
measurements. This provides for motivation and
satisfaction. Fig.4 shows the emission testing machine
III. RESULT AND DISCUSSIONS
A. Introduction
The experimental results obtained from the tests carried out
on engine performance, combustion and emission
characteristics are presented in this section. These include
results at constant speeds with different loads for the
different fuels i.e. standard diesel fuel and the three multi-
blend biodiesel products. The results are discussed from the
viewpoint of using multi-blend biodiesel as an alternative
fuel for compression ignition engines.
B. Characteristics of fuels
1) Performance characteristic
Fig 4.1: Variation of brake thermal efficiency with brake
power
The variation of brake thermal efficiency with
brake power for diesel, fish oil biodiesel and their blends are
shown in fig 4.1. Brake thermal efficiency is increasing with
increasing brake power for all multi-blends of biodiesel and
diesel. It may be due to reduction in heat loss and increase in
power with increase in load. Brake thermal efficiency of
10% blend is very close to diesel for entire range of
operation. Maximum brake thermal efficiency of 10% blend
is 34.44% against, 34.93% of diesel oil, which is lower by
0.49%. We can say that brake thermal efficiency of 10%
blend is very well comparable with diesel. The maximum
brake thermal efficiency of 20% and neat fish oil are 31.5%
and 31.1% against 34.93% of diesel.
Fig. 4.2: Variation of specific fuel consumption with brake
power
The variation of brake specific fuel consumption
(BSFC) with brake power for diesel, fish oil biodiesel and
its blends shown in fig 4.2.BSFC of 10% blend closely
matches with diesel, followed by 20% blend. Minimum
BSFC of 10% blend and 20% blend are 0.359 kg/kW-h and
0.424 kg/kW-h against 0.374 kg/kW-h of fish oil. BSFC of
neat fish oil biodiesel is 0.105 kg/kW-h higher than of
diesel oil.
Fig. 4.3: Variation of air-fuel ratio with brake power
The variation of air fuel ratio with brake power for
diesel and fish oil biodiesel blends is shown in fig 4.3. It can
be observed that air fuel ratio of pure diesel is higher than
other fish oil biodiesel and its blends, and we can also
seemthat the air fuel ratio decreases as the load
increases.
0
5
10
15
20
25
30
35
40
0 2 4 6
BreakThermalEffiecency
in%
Brake Power, kW
B10
B20
B100
D100
0
1
2
3
4
5
0 2 4 6
BSFCKg/kW-h Brake Power, kW
B10
B20
B100
D100
0
10
20
30
40
50
60
70
0 2 4 6
AFRatioin%
Brake Power,kW
B10
B20
B100
D100
Experimental Investigation on Performance, Emission and Combustion Characteristics of Single Cylinder Diesel Engine Running on Fish Oil Biodiesel
(IJSRD/Vol. 2/Issue 07/2014/083)
All rights reserved by www.ijsrd.com 380
Fig. 4.4: Variation of exhaust gas temperature
With brake power
Fig 4.4 shows the variation of Exhaust
Temperature (ET) with brake power output for fish oil
biodiesel and its blends with diesel in the test engine. The
exhaust temperature of 10% blend of fish oil biodiesel has
lower values compared with all other blends and is well
comparable with diesel, the exhaust temperature of all
blends and diesel increases with increase of operating load.
The 10% blend of fish oil biodiesel has higher performance
than other blends due to reduction in exhaust loss.
Fig. 4.5: Variation of mechanical efficiency with respect to
brake power
The variation of mechanical efficiency with brake
power, for diesel and fish oil biodiesel blends is shown in
fig 4.5. The mechanical efficiency of diesel is slightly higher
than the fish oil biodiesel. Mechanical efficiency of 20%
blend is very close to diesel, followed by 10% blend for
entire range of operation. Maximum mechanical efficiency
of 20% and 10% blend is 88.99% and 89.65% against,
92.91% of diesel oil. The maximum mechanical efficiency
of neat fish oil biodiesel is 88.12%. From the graph it is
evident that with increase in concentration of fish oil
biodiesel in neat diesel oil decreases the mechanical
efficiency. This may be due to better lubricating property of
the diesel which reduces frictional losses.
The variation of pressure with crank angle for
diesel fish oil biodiesel and their blends are shown in fig.4.5.
In a CI engine the cylinder pressure is depends on fuel
burning rate during the premixed burning phase, which in
turn leads better combustion and heat release. It can be seen
from fig 4.6. That neat fish oil biodiesel had a higher peak
pressure than that of neat diesel.
2) Combustion characteristics
Fig. 4.6: Variation of pressure with crank angle
Fig. 4.7: Variation of net HRR with crank angle
The variation of net heat release rate with crank
angle for diesel, fish oil biodiesel and their blends are shown
in fig 4.7. The heat release rate for all other tested fuel was
slightly less than that of diesel this may be attributed to low
vaporization, high viscosity and low peak pressure of blends
as compared to that of diesel. Heat release rate of neat
biodiesel is very close to diesel for entire range of operation,
followed by 10% blend. The maximum heat release rate for
neat biodiesel and 10% blend is 43.15 J/deg and 41.25 J/deg
against 46.05 J/deg of diesel oil.
The variation of cumulative release rate with crank
angle for diesel, fish oil biodiesel and their blends are shown
in fig 4.8. The maximum cumulative heat release for neat
biodiesel has same value of diesel oil i.e. 0.67 kJ. Maximum
cumulative heat release rate for 10% and 20% blends are
0.65 kJ and 0.61 kJ, against the diesel of 0.69 kJ. This may
be due to once the ignition delay period is passed, the
premixed fuel air mixture burns very fast, releasing the heat
very rapidly and then diffusion combustion takes place.
During the latter it is possible to control the burning rate by
regulating the quantity of available air-fuel mixture
0 2 4 6
Exhaustgas
temperature,c
Brake Power, kW
B10 B20 B100 D100
0
20
40
60
80
100
0 2 4 6
mechanicalefficincy,%
Brake Power, kW
B10
B20
B100
D100
0
10
20
30
40
50
60
70
80
1 201 401 601
Pressur(bar)
Crank angle (deg)
B10
B20
B10
0
-10
0
10
20
30
40
50
301 341 381
Netheatreleaserate(J/deg)
Crank angle (degree)
B10
B20
B100
D100
Experimental Investigation on Performance, Emission and Combustion Characteristics of Single Cylinder Diesel Engine Running on Fish Oil Biodiesel
(IJSRD/Vol. 2/Issue 07/2014/083)
All rights reserved by www.ijsrd.com 381
Fig. 4.8: Variation of cumulative heat release rate with
3) Emission Characteristics
Fig. 4.9: Variation of carbon monoxide with brake power
Fig.4.9 shows the variation of carbon monoxide
emission with brake power for fish oil biodiesel and its
blends in the test engine. The CO emission depends upon
the strength of the mixture, availability of oxygen and
viscosity of fuel. CO emission of all blends is higher than
that of diesel. Among the blends 10% blend has a lower CO
emission followed by 20% blend. CO emission of 10% and
20% blends at maximum load is 0.03% and 0.042% volume
against 0.028% volume of diesel. CO emission of neat fish
oil biodiesel is higher than all other blends for entire
operating range and maximum of 0.05% occurs at the rated
load. This due to incomplete combustion at higher loads
which results in higher CO emissions.
Fig. 4.10: Variation NOx of with brake power
Fig. 4.10 shows the variation of nitrogen oxides
emission with brake power output for fish oil biodiesel and
its blends with diesel in the test ring. The NOx emission for
biodiesel and its blends is higher than that of diesel. The
NOx of 10% blend is very close to diesel for entire range of
operation followed by the neat biodiesel. The maximum
NOx emission of 10% and neat biodiesel is 289ppm and
295ppm against 278ppm of diesel. The maximum NOx
emission for the 20% blend is 295ppm.
Fig. 4.11: Variation of hydrocarbon with brake power
Fig 4.11 shows the variation of hydrocarbons with
the break power and it evident those biodiesel blends B100
have high emission characteristics of hydrocarbons. The
blends B10, B20 follows the blend B100 and have less
emission of hydrocarbons that blend B100. Diesel emits less
HC compound to the blends hydrocarbons emissions varies
almost constant and increases instantly. Maximum HC
emission is by fish oil biodiesel is recorded as 444PPM and
minimum HC from diesel as 435 PPM.
IV. CONCLUSIONS
A. Introduction
The purpose of this concluding chapter is to summaries the
results of the experiments and makes recommendations for
future work. The following section contains specific
conclusions that can be drawn from the experimental
analysis.
B. Summarized results
Experimental investigations are carried out on a single
cylinder diesel engine to examine the suitability of fish oil
biodiesel as an alternate fuel. The performance, combustion
and emission characteristics of blends are evaluated and
compared with diesel. No difficulty was faced at the time of
starting the engine and the engine ran smoothly over the
range of engine speed. From the above investigation, the
following conclusions are drawn.
 The properties viz; density, viscosity, flash point
and fire point of fish oil biodiesel is higher and
calorific value is 0.92 times that of diesel.
 Performance, combustion and emission
characteristics of 10% blend are better than other
blends, followed by 20% blend. And efficiency of
10% blend is well compare with the diesel. The
maximum brake thermal efficiency of 10% and
0
0.1
0.2
0.3
0.4
0.5
0.6
261 321 381 441
Cumulativeheatrelease
rate,kJ
Crank angle (deg)
B10
B20
B100
D100
0
0.01
0.02
0.03
0.04
0.05
0.06
0.07
0 2 4 6
Carbonmonoxide%
Brake Power kW
B
1
0
0
50
100
150
200
250
300
350
0 2 4 6
NO(PPM)
Brake Power kW
B
1
0
0
50
100
150
200
250
300
350
400
450
500
0 5 10
UnburntHCinPPM
Break Power kW
B10
B20
B100
D100
Experimental Investigation on Performance, Emission and Combustion Characteristics of Single Cylinder Diesel Engine Running on Fish Oil Biodiesel
(IJSRD/Vol. 2/Issue 07/2014/083)
All rights reserved by www.ijsrd.com 382
20% are respectively 34.44% and 31.1% against,
34.93% of diesel.
 The maximum brake thermal efficiency of neat fish
oil biodiesel is 31.1% against 34.93% of diesel.
 The minimum BSFC of neat biodiesel is 0.0412
kg/kW-h higher compared with diesel.
 Unburnt HC, CO and NOx emissions at maximum
load for neat fish oil biodiesel compared with
diesel are higher by 1ppm, 0.022 vol %, and
435ppm, respectively.
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[3] O.D. Hebbal, K.Vijaykumar Reddy and K.Rajagopal
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[4] Heywood, J. B.(1988).“Internal combustion engine
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[6] Narinder Singh, Narinder Kumar and SK Mahla
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using Mahua Oil and Ethanol Blends” ISSN: 2319–
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[7] Hariram.V, 2 Shanil George Chandy “ Influence of
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[8] D H ; Lee C.Fjia C.C; Wang ‘ Experimental
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[9] A. Swarna Kumari1 *, Ch. Penchalayya, A.V. Sita
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[13]J.F. Costa, M.F. Almeida, M.C.M. Alvim-Ferraz,
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[18]A. Horel, S. Schiewer conducted experiment on
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[21]Ivana B. Banković-Ilić, Olivera S. Stamenković,
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[23]R. Vallinayagam, S. Vedharaj, W.M. Yang, V.
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524

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Experimental Investigation on Performance, Emission and Combustion Characteristics of Single Cylinder Diesel Engine Running on Fish Oil Biodiesel

  • 1. IJSRD - International Journal for Scientific Research & Development| Vol. 2, Issue 07, 2014 | ISSN (online): 2321-0613 All rights reserved by www.ijsrd.com 377 Experimental Investigation on Performance, Emission and Combustion Characteristics of Single Cylinder Diesel Engine Running on Fish Oil Biodiesel Shivaraj1 Harichandra.V.Astagi2 Omprakash.D.Hebbal3 1 M.Tech Student 2 Assistant Professor 3 Professor 1 Department of Thermal Power engineering 2,3 Department of Mechanical engineering 1,2,3 Poojya Doddappa Appa College of Engineering, Gulbarga, Karnataka, India Abstract— Continuous rise in the conventional fuel prices and shortage of its supply have increased the interest in the field of the alternative sources for petroleum fuels. In this present work, experimentation was carried out to study the performance, emission and combustion characteristics of desert date biodiesel and its blends. For this experiment a single cylinder, four strokes, naturally aspired, direct injection, water cooled, eddy current dynamometer Kirloskar diesel engine at 1500 rpm for variable loads. Initially, desert date biodiesel and its blends were chosen. The physical and chemical properties of desert date biodiesel were determined. The tests were carried out over entire range of engine operation at varying conditions of load. The engine performance parameters studied were brake horse power, brake specific fuel consumption, brake thermal efficiency, exhaust temperature and mechanical efficiency. The emission characteristics studied are CO, HC, NOx and smoke opacity. These results are compared to those of pure diesel. These results are again compared to the other results of neat oils available in the literature for validation. By analyzing the graphs, it was observed that performance characteristics are reduced and emission characteristics are lowered compare to the diesel. This is mainly due to lower calorific value, higher viscosity and delayed combustion process. From the analysis of graphs it is observed that B10 and B20 blends are best suited for diesel engine. The present experimental results show that fish oil biodiesel and its blends can be used as an alternative fuel in diesel engine. Keywords: Biodiesel, fish oil biodiesel, alternative fuel Ethanol Performance Emissions, combustion. I. INTRODUCTION In Energy is very important for life quality, welfare level and social development of people as well as economic growth. Fossil fuels have been an important traditional energy source for years. Energy demand around the world is increasing rapidly as a result of ongoing trends in modernization and industrialization. In the scenario of increase of vehicle population at an alarming rate due to advancement of civilization, use of diesel fuel in not only transport sector but also in agriculture sector leading to fast depletion of diesel fuels and increase of pollution levels with these fuels, the search for alternate fuels on has become pertinent for the engine manufacturers, users and researchers involved in the combustion research. To meet tough automotive competition and stringent government regulations, more efficient engine components, improved engine oils, and high performance coating materials have been developed within the automotive industry [2]. Energy consumption is increased globally in various purposes. The intensity of consumption is directly proportional to society’s development. Today, more and more developing countries are prospering through economic reforms and are industrially advanced. Fuel is critical to any strategic plan for economic development and national security. In developing countries like India which is about to emerge as world power, the fuel has assumed serious economic consequences in the forms of budget deficits caused by oil imports and ecological degradation caused by pollution. The possibility of substituting cleaner burning alternatives for gasoline and diesel has drawn the attention of automobile industry over the past decade. [3] Many of the alternative fuels have been experimented. Among them is the bio-fuel. As bio-diesel has certain similarity for the conventional fuels,slowly they have been introduced in the CI-Engine. Bio fuels have become a matter of global importance because of the need for an alternative energy at a cheaper price and with less pollution. Biodiesel is a domestic, renewable fuel for diesel engine comprised of mono-alkyl esters of long chain fatty acids derived from natural oil vegetable oils/animal fats. A. The Properties of Diesel and Fish Oil Biodiesel The different properties of diesel fuel and neem kernel biodiesel are determined and given in Table.1. After transesterification process the fuel properties like kinematic viscosity, calorific value, and density, flash and fire point get improved in case of biodiesel. The calorific value of fish oil biodiesel is lower than that of diesel because of oxygen content. The flash and fire point temperature of biodiesel is higher than the pure diesel fuel this is beneficial by safety considerations which can be stored and transported without any risk. Properties Diesel BD 10 BD 20 BD 100 Equipment Calorific value (kJ/kg) 42000 41716.7 41433.4 39167 Bomb calorimeter Kinematics viscosity at 400 C (Cst) 2.54 2.84 3.14 5.55 Red wood viscometer Density (kg/m3 ) 830 832.6 835.2 856 Hydrometer Flash Point (o C) 54 63.6 73.2 150 Pensky marten’s Fire Point (o C) 64 73.6 83.2 160 Pensky marten’s Table 1: Fuel properties
  • 2. Experimental Investigation on Performance, Emission and Combustion Characteristics of Single Cylinder Diesel Engine Running on Fish Oil Biodiesel (IJSRD/Vol. 2/Issue 07/2014/083) All rights reserved by www.ijsrd.com 378 II. EXPERIMENTATION A. Transesterification It is most commonly used and important method to reduce the viscosity of vegetable oils. In this process triglyceride reacts with three molecules of alcohol in the presence of a catalyst producing a mixture of fatty acids, alkyl ester and glycerol. The process of removal of all the glycerol and the fatty acids from the vegetable oil in the presence of a catalyst is called esterification. This esterifies vegetable oil is called bio-diesel. Biodiesel properties are similar to diesel fuel. It is renewable, non-toxic, bio-degradable and environment friendly transportation fuel. After esterification of the vegetable oil its density, viscosity, cetane number, calorific value, atomization and vaporization rate, molecular weight, and fuel spray penetration distance are improved more. So these improved properties give good performance in CI engine. B. Separation of glycerol from bio- diesel Fig. 1: Seperation of glycerin The fig 1. Shows the separation of glycerin from the bio- diesel. After reaction the oil is kept in a settling funnel for the process of separation. In which biodiesel, glycerin and catalyst are separated C. Experimental Set-Up Experiments were performed in the internal combustion engine laboratory, Department of mechanical engineering, PDA College of engineering, Gulbarga. The experimental setup consists of single cylinder, four strokes, diesel engine connected to eddy current dynamometer for variable loading. The set as stand- alone type independent panel box consisting of air box, fuel tank, manometer etc. The set up enables study of engine for brake power, BMEP, brake thermal efficiency, mechanical efficiency, specific fuel consumption, volumetric efficiency, A/F ratio, and emission characteristics like CO, CO2, HC and NOX. Fig. 2: Schematic diagram of experimental setup PT Pressure transducer T1 Jacket water inlet temperature N Rotary encoder T2 Jacket water outlet temperature F1 Fuel flow T3 Calorimeter water inlet temperature = T1 F2 Air flow T4 Calorimeter water outlet temperature F3 Jacket water flow T5 Exhaust gas to calorimeter temperature F4 Calorimeter water flow T6 Exhaust gas from calorimeter temperature The various components of experimental set up are described. Fig 2. shows the schematic diagram of experimental setup and fig 3. Shows the photograph of the experimental set up. The important components of the system are,  The engine  Dynamometer  Exhaust emission testing machine  Calorimeter  Fuel measuring unit  Pressure sensor  Temperature sensor  Rotameter  Software Fig. 3: Photograph of experimental setup Table 1 shows the technical specification of the engine. Manufacturer Kirloskar Oil Engines Ltd., India Model TV–SR II, naturally Aspirated Engine Single cylinder, DI, 4 strokes Bore/stroke 87.5mm/110mm Compression ratio 17.5:1 Speed 1500 r/min, constant Rated power 5.2 kW Injection pressure 240 bar/23° BTDC Type of sensor Piezo electric Crank angle sensor 1-degree crank angle Table 1: Technical specifications of the engine.
  • 3. Experimental Investigation on Performance, Emission and Combustion Characteristics of Single Cylinder Diesel Engine Running on Fish Oil Biodiesel (IJSRD/Vol. 2/Issue 07/2014/083) All rights reserved by www.ijsrd.com 379 Fig. 4: Emission testing machine The emissions test is are done with AVL DITEST MDS 350 Exhaust Gas Analyzer. It is designed with sophisticated measurement modules. The product has additional features to save a vehicle and customer database, radio-connected diesel measuring chamber up to the option of designing the protocols individually. Due to the robustness and intuitive application of the device, the tester can be used to get sophisticated and accurate emission measurements. This provides for motivation and satisfaction. Fig.4 shows the emission testing machine III. RESULT AND DISCUSSIONS A. Introduction The experimental results obtained from the tests carried out on engine performance, combustion and emission characteristics are presented in this section. These include results at constant speeds with different loads for the different fuels i.e. standard diesel fuel and the three multi- blend biodiesel products. The results are discussed from the viewpoint of using multi-blend biodiesel as an alternative fuel for compression ignition engines. B. Characteristics of fuels 1) Performance characteristic Fig 4.1: Variation of brake thermal efficiency with brake power The variation of brake thermal efficiency with brake power for diesel, fish oil biodiesel and their blends are shown in fig 4.1. Brake thermal efficiency is increasing with increasing brake power for all multi-blends of biodiesel and diesel. It may be due to reduction in heat loss and increase in power with increase in load. Brake thermal efficiency of 10% blend is very close to diesel for entire range of operation. Maximum brake thermal efficiency of 10% blend is 34.44% against, 34.93% of diesel oil, which is lower by 0.49%. We can say that brake thermal efficiency of 10% blend is very well comparable with diesel. The maximum brake thermal efficiency of 20% and neat fish oil are 31.5% and 31.1% against 34.93% of diesel. Fig. 4.2: Variation of specific fuel consumption with brake power The variation of brake specific fuel consumption (BSFC) with brake power for diesel, fish oil biodiesel and its blends shown in fig 4.2.BSFC of 10% blend closely matches with diesel, followed by 20% blend. Minimum BSFC of 10% blend and 20% blend are 0.359 kg/kW-h and 0.424 kg/kW-h against 0.374 kg/kW-h of fish oil. BSFC of neat fish oil biodiesel is 0.105 kg/kW-h higher than of diesel oil. Fig. 4.3: Variation of air-fuel ratio with brake power The variation of air fuel ratio with brake power for diesel and fish oil biodiesel blends is shown in fig 4.3. It can be observed that air fuel ratio of pure diesel is higher than other fish oil biodiesel and its blends, and we can also seemthat the air fuel ratio decreases as the load increases. 0 5 10 15 20 25 30 35 40 0 2 4 6 BreakThermalEffiecency in% Brake Power, kW B10 B20 B100 D100 0 1 2 3 4 5 0 2 4 6 BSFCKg/kW-h Brake Power, kW B10 B20 B100 D100 0 10 20 30 40 50 60 70 0 2 4 6 AFRatioin% Brake Power,kW B10 B20 B100 D100
  • 4. Experimental Investigation on Performance, Emission and Combustion Characteristics of Single Cylinder Diesel Engine Running on Fish Oil Biodiesel (IJSRD/Vol. 2/Issue 07/2014/083) All rights reserved by www.ijsrd.com 380 Fig. 4.4: Variation of exhaust gas temperature With brake power Fig 4.4 shows the variation of Exhaust Temperature (ET) with brake power output for fish oil biodiesel and its blends with diesel in the test engine. The exhaust temperature of 10% blend of fish oil biodiesel has lower values compared with all other blends and is well comparable with diesel, the exhaust temperature of all blends and diesel increases with increase of operating load. The 10% blend of fish oil biodiesel has higher performance than other blends due to reduction in exhaust loss. Fig. 4.5: Variation of mechanical efficiency with respect to brake power The variation of mechanical efficiency with brake power, for diesel and fish oil biodiesel blends is shown in fig 4.5. The mechanical efficiency of diesel is slightly higher than the fish oil biodiesel. Mechanical efficiency of 20% blend is very close to diesel, followed by 10% blend for entire range of operation. Maximum mechanical efficiency of 20% and 10% blend is 88.99% and 89.65% against, 92.91% of diesel oil. The maximum mechanical efficiency of neat fish oil biodiesel is 88.12%. From the graph it is evident that with increase in concentration of fish oil biodiesel in neat diesel oil decreases the mechanical efficiency. This may be due to better lubricating property of the diesel which reduces frictional losses. The variation of pressure with crank angle for diesel fish oil biodiesel and their blends are shown in fig.4.5. In a CI engine the cylinder pressure is depends on fuel burning rate during the premixed burning phase, which in turn leads better combustion and heat release. It can be seen from fig 4.6. That neat fish oil biodiesel had a higher peak pressure than that of neat diesel. 2) Combustion characteristics Fig. 4.6: Variation of pressure with crank angle Fig. 4.7: Variation of net HRR with crank angle The variation of net heat release rate with crank angle for diesel, fish oil biodiesel and their blends are shown in fig 4.7. The heat release rate for all other tested fuel was slightly less than that of diesel this may be attributed to low vaporization, high viscosity and low peak pressure of blends as compared to that of diesel. Heat release rate of neat biodiesel is very close to diesel for entire range of operation, followed by 10% blend. The maximum heat release rate for neat biodiesel and 10% blend is 43.15 J/deg and 41.25 J/deg against 46.05 J/deg of diesel oil. The variation of cumulative release rate with crank angle for diesel, fish oil biodiesel and their blends are shown in fig 4.8. The maximum cumulative heat release for neat biodiesel has same value of diesel oil i.e. 0.67 kJ. Maximum cumulative heat release rate for 10% and 20% blends are 0.65 kJ and 0.61 kJ, against the diesel of 0.69 kJ. This may be due to once the ignition delay period is passed, the premixed fuel air mixture burns very fast, releasing the heat very rapidly and then diffusion combustion takes place. During the latter it is possible to control the burning rate by regulating the quantity of available air-fuel mixture 0 2 4 6 Exhaustgas temperature,c Brake Power, kW B10 B20 B100 D100 0 20 40 60 80 100 0 2 4 6 mechanicalefficincy,% Brake Power, kW B10 B20 B100 D100 0 10 20 30 40 50 60 70 80 1 201 401 601 Pressur(bar) Crank angle (deg) B10 B20 B10 0 -10 0 10 20 30 40 50 301 341 381 Netheatreleaserate(J/deg) Crank angle (degree) B10 B20 B100 D100
  • 5. Experimental Investigation on Performance, Emission and Combustion Characteristics of Single Cylinder Diesel Engine Running on Fish Oil Biodiesel (IJSRD/Vol. 2/Issue 07/2014/083) All rights reserved by www.ijsrd.com 381 Fig. 4.8: Variation of cumulative heat release rate with 3) Emission Characteristics Fig. 4.9: Variation of carbon monoxide with brake power Fig.4.9 shows the variation of carbon monoxide emission with brake power for fish oil biodiesel and its blends in the test engine. The CO emission depends upon the strength of the mixture, availability of oxygen and viscosity of fuel. CO emission of all blends is higher than that of diesel. Among the blends 10% blend has a lower CO emission followed by 20% blend. CO emission of 10% and 20% blends at maximum load is 0.03% and 0.042% volume against 0.028% volume of diesel. CO emission of neat fish oil biodiesel is higher than all other blends for entire operating range and maximum of 0.05% occurs at the rated load. This due to incomplete combustion at higher loads which results in higher CO emissions. Fig. 4.10: Variation NOx of with brake power Fig. 4.10 shows the variation of nitrogen oxides emission with brake power output for fish oil biodiesel and its blends with diesel in the test ring. The NOx emission for biodiesel and its blends is higher than that of diesel. The NOx of 10% blend is very close to diesel for entire range of operation followed by the neat biodiesel. The maximum NOx emission of 10% and neat biodiesel is 289ppm and 295ppm against 278ppm of diesel. The maximum NOx emission for the 20% blend is 295ppm. Fig. 4.11: Variation of hydrocarbon with brake power Fig 4.11 shows the variation of hydrocarbons with the break power and it evident those biodiesel blends B100 have high emission characteristics of hydrocarbons. The blends B10, B20 follows the blend B100 and have less emission of hydrocarbons that blend B100. Diesel emits less HC compound to the blends hydrocarbons emissions varies almost constant and increases instantly. Maximum HC emission is by fish oil biodiesel is recorded as 444PPM and minimum HC from diesel as 435 PPM. IV. CONCLUSIONS A. Introduction The purpose of this concluding chapter is to summaries the results of the experiments and makes recommendations for future work. The following section contains specific conclusions that can be drawn from the experimental analysis. B. Summarized results Experimental investigations are carried out on a single cylinder diesel engine to examine the suitability of fish oil biodiesel as an alternate fuel. The performance, combustion and emission characteristics of blends are evaluated and compared with diesel. No difficulty was faced at the time of starting the engine and the engine ran smoothly over the range of engine speed. From the above investigation, the following conclusions are drawn.  The properties viz; density, viscosity, flash point and fire point of fish oil biodiesel is higher and calorific value is 0.92 times that of diesel.  Performance, combustion and emission characteristics of 10% blend are better than other blends, followed by 20% blend. And efficiency of 10% blend is well compare with the diesel. The maximum brake thermal efficiency of 10% and 0 0.1 0.2 0.3 0.4 0.5 0.6 261 321 381 441 Cumulativeheatrelease rate,kJ Crank angle (deg) B10 B20 B100 D100 0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0 2 4 6 Carbonmonoxide% Brake Power kW B 1 0 0 50 100 150 200 250 300 350 0 2 4 6 NO(PPM) Brake Power kW B 1 0 0 50 100 150 200 250 300 350 400 450 500 0 5 10 UnburntHCinPPM Break Power kW B10 B20 B100 D100
  • 6. Experimental Investigation on Performance, Emission and Combustion Characteristics of Single Cylinder Diesel Engine Running on Fish Oil Biodiesel (IJSRD/Vol. 2/Issue 07/2014/083) All rights reserved by www.ijsrd.com 382 20% are respectively 34.44% and 31.1% against, 34.93% of diesel.  The maximum brake thermal efficiency of neat fish oil biodiesel is 31.1% against 34.93% of diesel.  The minimum BSFC of neat biodiesel is 0.0412 kg/kW-h higher compared with diesel.  Unburnt HC, CO and NOx emissions at maximum load for neat fish oil biodiesel compared with diesel are higher by 1ppm, 0.022 vol %, and 435ppm, respectively. REFERENCES [1] .K.Venkanna and C.Venkataramana Reddy “Performance, emission and combustion characteristics of direct injection diesel engine running on calophyllum inophyllum linn oil (honne oil)” Int J Agric & Biol Eng Vol. 4 No.1 March, 2011 [2] D. Ramesh and A. Sampathrajan “Investigations on Performance and Emission Characteristics of Diesel Engine with Jatropha Biodiesel and Its Blends” the CIGR Journal. Manuscript EE 07 013. Vol. X. March, 2008. [3] O.D. Hebbal, K.Vijaykumar Reddy and K.Rajagopal “Performance characteristics of a diesel engine with deccan hemp oil” Science direct fuel 85 (2006) 2187-294 [4] Heywood, J. B.(1988).“Internal combustion engine fundamentals”. ISBN0-07-100499-8. [5] Introduction to IC engine The Goodheart-Willcox Co [6] Narinder Singh, Narinder Kumar and SK Mahla “Experimental Studies on Single Cylinder CI Engine using Mahua Oil and Ethanol Blends” ISSN: 2319– 6378, Volume-1, Issue-11, September 2013 [7] Hariram.V, 2 Shanil George Chandy “ Influence of injection timing on combustion and heat release parameters using biodiesel of Neem, Rice bran and Pongamia in a direct injection compression ignition engine” Vol.2, Issue 11 (April 2013), Pp 36-43 [8] D H ; Lee C.Fjia C.C; Wang ‘ Experimental investigations of combustion and emission characteristics of rapeseed oil-diesel blends in a two cylinder agriculture diesel engine’ 2014 vol.77 pp.227-232 ISSN 0196-8904 [9] A. Swarna Kumari1 *, Ch. Penchalayya, A.V. Sita Rama Raju ‘Performance evaluation of diesel engine with safflower oil’ vol.19 (2013) no.2 [10]R. Senthil Kumar and R.Manimaran “Performance and emission characteristics on 4-stroke single cylinder c. i. engine using cottonseed bio fuels” ISSN-2319–2100 [11]Tony Piccolo “A feasibility study for fish oil bio- diesel production” Sustainable Communities Enterprise for Clayoquot Biosphere Trust. [12]R. Yahyaee, B. Ghobadian, G. Najafi conducted experiment on Waste fish oil biodiesel as a source of renewable fuel in Iran Review Article Renewable and Sustainable Energy Reviews, Volume 17, January 2013, Pages 312-319 [13]J.F. Costa, M.F. Almeida, M.C.M. Alvim-Ferraz, J.M. Dias conducted experiment on Biodiesel production using oil from fish canning industry wastes Original Research Article Energy Conversion and Management, Volume 74, October 2013, Pages 17-23 [14]Cherng-Yuan Lin, Rong-Ji Li conducted experiment on Engine performance and emission characteristics of marine fish-oil biodiesel produced from the discarded parts of marine fish Original Research Article Fuel Processing Technology, Volume 90, Issues 7–8, July–August 2009, Pages 883-888 [15]Jinlin Xue conducted experiment on Combustion characteristics, engine performances and emissions of waste edible oil biodiesel in diesel engine Review Article Renewable and Sustainable Energy Reviews, Volume 23, July 2013, Pages 350-365 [16]Sharanappa Godiganur, Ch. Suryanarayana Murthy, Rana Prathap Reddy conducted experiment on Renewable Energy, Volume 35, Issue 2, February 2010, Pages 355-359 [17]Otto Andersen, Jan-Erik Weinbach conducted experiment on Residual animal fat and fish for biodiesel production Volume 83, Issue 5, April 2011, Pages 652-660 [18]A. Horel, S. Schiewer conducted experiment on Influence of constant and fluctuating temperature on biodegradation rates of fish biodiesel blends contaminating Alaskan sand Journal of Biotechnology, Volume 118, Issue 1, Supplement, August 2 Chemosphere, A. Horel, S. Schiewer 005, Pages 1-189 [19]Niraj Kumar, Varun, Sant Ram Chauhan conducted experiment on Performance and emission characteristics of biodiesel from different origins Renewable and Sustainable Energy Reviews, Volume 21, May 2013, Pages 633-658 [20]Punyama Jayasinghe, Kelly Hawboldt conducted experiment on A review of bio-oils from waste biomass: Focus on fish processing waste Renewable and Sustainable Energy Reviews, Volume 16, Issue 1, January 2012, Pages 798-821 [21]Ivana B. Banković-Ilić, Olivera S. Stamenković, Vlada B. Veljković conducted experiment on Renewable and Sustainable Energy Reviews, Volume 16, Issue 6, August 2012, Pages 3621-3647 [22]Windmoeller, P. conducted experiment on Cement Industry Technical Conference, 2011 IEEE-IAS/PCA 53rd Digital Object , Identifier: 10.1109/CITCON. 2011. 5934560 Publication Year: 2011 , Page(s): 1 – 5 [23]R. Vallinayagam, S. Vedharaj, W.M. Yang, V. Raghavan, C.G. Saravanan, P.S. Lee, K.J.E. Chua, S.K. Chou conducted experiment on Applied Energy, Volume 115, 15 February 2014, Pages 514- 524