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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7022
A STUDY ON MECHANICAL PROPERTIES OF GEOPOLYMER CONCRETE
P. Naveen kumar1, CH. Sai kumar2, M. Hupendra babu3, K. Rakesh4, B. Priyanka5, G. Priyanka6
1,2,3,4,5B.tech final year students, department of civil engineering, Dhanekula institute of engineering and technology
6Assistant professor ,Department of Civil Engineering, Dhanekula Institute Of Engineering &Technology,
Andhra Pradesh, India
---------------------------------------------------------------------***---------------------------------------------------------------------
Abstract – The major problem the world is facing today is the
environmental pollution. In the constructionindustrymainly the
production of Portland cement will causes the emission of
pollutants results in environmentalpollution.Wecanreducethe
pollution effect on environment by increasing the usage of
industrial byproducts in our construction industry. Fly ashisone
of the major waste material obtained from thermal power
plants. Geopolymer concrete is such a one and in the present
study, to produce the geopolymer concretethePortlandcement
is fully replaced with fly ash and alkaline liquids are used for the
binding of materials. The alkaline liquids used in this study for
the polymerizationarethesolutionsofsodium hydroxide(NaOH)
and sodium silicate(Na2SiO3).Different molarities of sodium
hydroxide solution i.e, 16M,18M,20M are taken to prepare
different mixes. The geopolymer concrete is designed for a
grade of M30 in this study. The geopolymer concretespecimens
are subjected to sunlight curing and tested for their mechanical
properties(compressive strength, split tensile strength, flexure
strength)at the age of 7days,28 days. Mixes of varying sodium
hydroxide molarities i.e, 16M, 18M and 20M are prepared.
Key Words: fly ash, geopolymer, sunlightcuring,sodium
hydroxide, sodium silicate
1 .INTRODUCTION
For the construction of any structure, Concrete is
the main material. . The main ingredienttoproduceconcrete
is Portland cement. The production of cement means the
production of pollution because of the emission of CO2
during its production Thecementindustrycontributesabout
5% of total global carbon dioxide emissions. And also, the
cement is manufactured by using the raw materials such as
lime stone, clay and other minerals. . Quarrying of these raw
materials is also causes environmental degradation. So to
overcome this problem, the concrete to be used should be
environmental friendly.
Geopolymer concrete was introduced to reduce
environmental pollution that causes by production of
Portland cement. In 1978, Professor Joseph Davidovits
introduced the development of mineral binders with an
amorphous structure, named geopolymers.Davidovits
(1988; 1994) proposed that an alkaline liquid couldbe
used to react with the silicon (Si) and the aluminium(Al)ina
source material of geological origin or in by-product
materials such as fly ash and rice husk ash to produce
binders.
2.MATERIALS USED
 Fly ash (class F)
 Alkaline liquids: Sodium hydroxide (NaOH)
Sodium silicate (Na2SiO3)
 Coarse aggregates
 Fine aggregates
2.1 Fly ash
Fly ash is manufactured by the burning of coal in an
electrostatic precipitator, a byproduct of industrial coal.The
cementitious properties of fly ash were discovered in late
19th century and it has been widely used in cement
manufacture for over 100 years. fly ash is supplied as a
separate component for concrete and is added at the
concrete at the mixer. It generally replaces between 20 and
80 per cent of the normal Portland cement. Two types of fly
ash are commonly used in concrete:ClassCandClassF.Class
C are often high calcium fly ashes with carbon content less
than 2%; whereas, Class F are generally low-calcium fly
ashes with carbon contents less than 5% but sometimes as
high as 10%.In this present study, class F fly ash is used.
2.2 ALKALINE LIQUIDS
Sodium hydroxide(NaOH) was acquired intheform
of pellets which are used for commercial purpose and
sodium silicate(Na2SiO3) is used in the form of gel.
2.3 COARSE AGGREGATES
Locally available 10mm and 20mm crushed
aggregates are used as coarse aggregates.
2.4 FINE AGGREGATES
Locally available river sand is used as fine
aggregate.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7023
3. PREPARATION OF ACTIVATOR SOLUTION
In this project the compressive strength of geo-
polymer concrete is examined for the mixes of varying
molarities of Sodium hydroxide (16M, 18M, and 20M). The
molecular weight of sodiumhydroxideis40.Toprepare 16M
i.e. 16 molar sodium hydroxide solution, 640g of sodium
hydroxide flakes are weighed and they can be dissolved in
distilled water to form 1 liter solution. For this, volumetric
flask of 1 liter capacity is taken, sodium hydroxide flakes are
added slowly to distilled water to prepare 1litre solution.
The weights to be added to get required molarity are given
in Table.1
Required
molarity
Weight of
sodium
hydroxide in gm
16M 640
18M 720
20M 800
4.TRAIL MIX PROPORTION
As there is no proper mix design and codal
provisions, a trial mix design is adopted and the density of
geopolymer concrete is assumed as 2400Kg/m3. The mix
proportion is shown below
CONSTITUENTS DENSITY (Kg/m3)
FLYASH 380
FINE AGGREGATES 680.2
COARSE AGGREGATES 1263
NaOH 44.33
Na2SiO3 88.66
ADDITIONAL WATER 23.66
5. EXPERIMENTAL PROCEDURE
5.1 CASTING
The fly ash and aggregates werefirst mixedtogether
for about 3 to 4 minutes and then the prepared activator
solutions with required additional water are added to the
mix. The mixing is continued for another 3-4 minutes.
The fresh concrete is immediately cast into the moulds in
3layers by doing proper compaction. Each layer should be
compacted for 25 times with the tamping rod.
5.2 CURING
The concrete specimens are then placed in sunlight
for curing and they were tested after the curing period is
over.
FIG-Specimens Subjected To Sunlight Curing
6. TESTS CONDUCTED
 COMPRESSIVE STRENGTH
 SPLIT TENSILE STRENGTH
 FLEXURE STRENGTH
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7024
6.1 COMPRESSIVE STRENGTH TEST
The cubes are tested for their compressivestrength
as per IS specifications IS(519:1959).The obtained results
are shown below
S.NO MOLARITY
COMPRESSIVE
STRENGTH
(N/mm2)
7 DAYS 28 DAYS
1. 16M 7.77 10.64
2. 18M 8.28 12.15
3. 20M 9.62 13.24
Table -1:COMPRESSIVESTRENGTHOFCONCRETE
0
2
4
6
8
10
12
14
7 Days 28 Days
16 M
18 M
20 M
6.2 SPLIT TENSILE STRENGTH TEST
The concrete specimens are tested for their tensile
strength on compression testing machine as per
IS(5816:1999).The obtained results are shown below:
S.NO MOLARITY
TENSILE
STRENGTH (N/mm2)
7DAYS 28DAYS
1 16M 0.85 1.23
2 18M 1.03 1.38
3 20M 1.45 1.74
Table-2: SPLITTENSILESTRENGTHOFCONCRETE
0
0.5
1
1.5
2
7 Days 28 Days
16 M
18 M
20 M
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7025
6.3 FLEXURE STRENGTH TEST
The flexure strength of the concrete
specimens are tabulated below
S.NO MOLARITY
FLEXURAL
STRENGTH N/mm2
7 DAYS 28 DAYS
1 16M 0.52 1.44
2 18M 0.62 1.51
3 20M 0.73 1.63
Table-3: FLEXURAL STRENGTH OF CONCRETE
0
0.2
0.4
0.6
0.8
1
1.2
1.4
1.6
1.8
7 days 28 Days
16 M
18 M
20 M
7. CONCLUSIONS
On the basis of the results obtained during the
experimental investigations, following conclusions were
drawn:
 The compressive strength, split tensile strength,
flexure strength of geo polymerconcretespecimens
increases with increase in the molarity of sodium
hydroxide solution.
 The mix with 18M solution gives higher strengths
because increase in the molarity of sodium
hydroxide increases the strength of concrete.
 The fresh fly ash based geo polymer concrete is
easily handled up to 120 minutes without any sign
of setting and without any degradation in the
compressive strength.
 Increase in curing temperaturegives morestrength
to concrete.
 As there is increase in curing time, strength of the
specimens will improve.
 Sunlight curing is not preferable for geo polymer
concrete as it requires high temperature.
REFERENCES
[1].Zhu Pan , Jay G. Sanjayan , B. V. Rangan,(2007) “An
investigation of the mechanisms for strength gain or loss of
geopolymer mortar after exposure to elevatedtemperature”
, published in J Matera Science (2009)44:1873–1880.
[2].Davidovits, J. (1988b). Geopolymer Chemistry and
Properties. Paper presented at the Geopolymer ’88,First
European Conference on Soft Mineralurgy, Compiegne,
France.
[3].XiaoluGuo, HuishengShi , Warren A. Dick (2009)
“Compressivestrengthandmicrostructural characteristicsof
class C fly ash Geopolymer” published in Elsevier .Ltd,
Cement & Concrete Composites32 (2010) 142–147
www.elsevier.com/locate/cemconcomp
[4].Smith Songpiriyakij, TeinsakKubprasit , Chai
Jaturapitakkul , Prinya Chindaprasirt(2010) “Compressive
strength and degree of reaction of biomass- and fly ash-
based Geo polymer” published in Elsevier .Ltd,Construction
and Building Materials 24 (2010) 236–240.
[5].Shuguang Hu, Hongxi Wang, GaozhanZhang ,Qingjun
Ding(2007) “Bonding and abrasion resistance of geo
polymeric repair material made with steel slag”publishedin
Elsevier .Ltd ,Cement&ConcreteComposites30(2007)239–
244.
[6].C.A. Hendriks1, “Emission Reduction of Greenhouse
Gases from the Cement Industry” Greenhouse gas control
technologies conference paper.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7026
[7].Ernst Worerell. Lynn Price, et al. “CO2 emission from the
global cement industry”, Annual review ofenergy and the
environment. Vol 26: p-303-32
[8].Christina K. Yip, Grant C. Lukey, John L. Provis, Jannie S.J.
van Deventer (2008), “Effect of calcium silicate sources on
geopolymerisation” published in Elsevier .Ltd, Cement and
Concrete Research 38 (2008) 554–564.
[9].Wee, T. H., Suryavanshi, A. K., Wong, S. F., &Rahman, A. K.
M. A. (2000) Sulfate Resistance of Concrete Containing
Mineral Admixtures.ACIMaterials Journal, 97(5), 536-549.
[10] Aleem M I A,Arumairaj P D Optimum Mix For The
Geopolymer Concrete.Indian Journal Of Science And
Technology. 2012; 5(3), 2299-2301
[11] G.Yamini And Dr.S.Siddiraju, An Experimental Research
On Strength Properties Of Concrete By Influence Of Fly Ash
And Nano Silica As A Partial Replacement Of Cement.
International Journal Of Civil Engineering And Technology
,7(3), 2016, Pp.306-315
[12] IS code 2386-1963(part I to part VIII) Indian standard
methods of test for aggregate of concrete.

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IRJET- A Study on Mechanical Properties of Geopolymer Concrete

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7022 A STUDY ON MECHANICAL PROPERTIES OF GEOPOLYMER CONCRETE P. Naveen kumar1, CH. Sai kumar2, M. Hupendra babu3, K. Rakesh4, B. Priyanka5, G. Priyanka6 1,2,3,4,5B.tech final year students, department of civil engineering, Dhanekula institute of engineering and technology 6Assistant professor ,Department of Civil Engineering, Dhanekula Institute Of Engineering &Technology, Andhra Pradesh, India ---------------------------------------------------------------------***--------------------------------------------------------------------- Abstract – The major problem the world is facing today is the environmental pollution. In the constructionindustrymainly the production of Portland cement will causes the emission of pollutants results in environmentalpollution.Wecanreducethe pollution effect on environment by increasing the usage of industrial byproducts in our construction industry. Fly ashisone of the major waste material obtained from thermal power plants. Geopolymer concrete is such a one and in the present study, to produce the geopolymer concretethePortlandcement is fully replaced with fly ash and alkaline liquids are used for the binding of materials. The alkaline liquids used in this study for the polymerizationarethesolutionsofsodium hydroxide(NaOH) and sodium silicate(Na2SiO3).Different molarities of sodium hydroxide solution i.e, 16M,18M,20M are taken to prepare different mixes. The geopolymer concrete is designed for a grade of M30 in this study. The geopolymer concretespecimens are subjected to sunlight curing and tested for their mechanical properties(compressive strength, split tensile strength, flexure strength)at the age of 7days,28 days. Mixes of varying sodium hydroxide molarities i.e, 16M, 18M and 20M are prepared. Key Words: fly ash, geopolymer, sunlightcuring,sodium hydroxide, sodium silicate 1 .INTRODUCTION For the construction of any structure, Concrete is the main material. . The main ingredienttoproduceconcrete is Portland cement. The production of cement means the production of pollution because of the emission of CO2 during its production Thecementindustrycontributesabout 5% of total global carbon dioxide emissions. And also, the cement is manufactured by using the raw materials such as lime stone, clay and other minerals. . Quarrying of these raw materials is also causes environmental degradation. So to overcome this problem, the concrete to be used should be environmental friendly. Geopolymer concrete was introduced to reduce environmental pollution that causes by production of Portland cement. In 1978, Professor Joseph Davidovits introduced the development of mineral binders with an amorphous structure, named geopolymers.Davidovits (1988; 1994) proposed that an alkaline liquid couldbe used to react with the silicon (Si) and the aluminium(Al)ina source material of geological origin or in by-product materials such as fly ash and rice husk ash to produce binders. 2.MATERIALS USED  Fly ash (class F)  Alkaline liquids: Sodium hydroxide (NaOH) Sodium silicate (Na2SiO3)  Coarse aggregates  Fine aggregates 2.1 Fly ash Fly ash is manufactured by the burning of coal in an electrostatic precipitator, a byproduct of industrial coal.The cementitious properties of fly ash were discovered in late 19th century and it has been widely used in cement manufacture for over 100 years. fly ash is supplied as a separate component for concrete and is added at the concrete at the mixer. It generally replaces between 20 and 80 per cent of the normal Portland cement. Two types of fly ash are commonly used in concrete:ClassCandClassF.Class C are often high calcium fly ashes with carbon content less than 2%; whereas, Class F are generally low-calcium fly ashes with carbon contents less than 5% but sometimes as high as 10%.In this present study, class F fly ash is used. 2.2 ALKALINE LIQUIDS Sodium hydroxide(NaOH) was acquired intheform of pellets which are used for commercial purpose and sodium silicate(Na2SiO3) is used in the form of gel. 2.3 COARSE AGGREGATES Locally available 10mm and 20mm crushed aggregates are used as coarse aggregates. 2.4 FINE AGGREGATES Locally available river sand is used as fine aggregate.
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7023 3. PREPARATION OF ACTIVATOR SOLUTION In this project the compressive strength of geo- polymer concrete is examined for the mixes of varying molarities of Sodium hydroxide (16M, 18M, and 20M). The molecular weight of sodiumhydroxideis40.Toprepare 16M i.e. 16 molar sodium hydroxide solution, 640g of sodium hydroxide flakes are weighed and they can be dissolved in distilled water to form 1 liter solution. For this, volumetric flask of 1 liter capacity is taken, sodium hydroxide flakes are added slowly to distilled water to prepare 1litre solution. The weights to be added to get required molarity are given in Table.1 Required molarity Weight of sodium hydroxide in gm 16M 640 18M 720 20M 800 4.TRAIL MIX PROPORTION As there is no proper mix design and codal provisions, a trial mix design is adopted and the density of geopolymer concrete is assumed as 2400Kg/m3. The mix proportion is shown below CONSTITUENTS DENSITY (Kg/m3) FLYASH 380 FINE AGGREGATES 680.2 COARSE AGGREGATES 1263 NaOH 44.33 Na2SiO3 88.66 ADDITIONAL WATER 23.66 5. EXPERIMENTAL PROCEDURE 5.1 CASTING The fly ash and aggregates werefirst mixedtogether for about 3 to 4 minutes and then the prepared activator solutions with required additional water are added to the mix. The mixing is continued for another 3-4 minutes. The fresh concrete is immediately cast into the moulds in 3layers by doing proper compaction. Each layer should be compacted for 25 times with the tamping rod. 5.2 CURING The concrete specimens are then placed in sunlight for curing and they were tested after the curing period is over. FIG-Specimens Subjected To Sunlight Curing 6. TESTS CONDUCTED  COMPRESSIVE STRENGTH  SPLIT TENSILE STRENGTH  FLEXURE STRENGTH
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7024 6.1 COMPRESSIVE STRENGTH TEST The cubes are tested for their compressivestrength as per IS specifications IS(519:1959).The obtained results are shown below S.NO MOLARITY COMPRESSIVE STRENGTH (N/mm2) 7 DAYS 28 DAYS 1. 16M 7.77 10.64 2. 18M 8.28 12.15 3. 20M 9.62 13.24 Table -1:COMPRESSIVESTRENGTHOFCONCRETE 0 2 4 6 8 10 12 14 7 Days 28 Days 16 M 18 M 20 M 6.2 SPLIT TENSILE STRENGTH TEST The concrete specimens are tested for their tensile strength on compression testing machine as per IS(5816:1999).The obtained results are shown below: S.NO MOLARITY TENSILE STRENGTH (N/mm2) 7DAYS 28DAYS 1 16M 0.85 1.23 2 18M 1.03 1.38 3 20M 1.45 1.74 Table-2: SPLITTENSILESTRENGTHOFCONCRETE 0 0.5 1 1.5 2 7 Days 28 Days 16 M 18 M 20 M
  • 4. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7025 6.3 FLEXURE STRENGTH TEST The flexure strength of the concrete specimens are tabulated below S.NO MOLARITY FLEXURAL STRENGTH N/mm2 7 DAYS 28 DAYS 1 16M 0.52 1.44 2 18M 0.62 1.51 3 20M 0.73 1.63 Table-3: FLEXURAL STRENGTH OF CONCRETE 0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 7 days 28 Days 16 M 18 M 20 M 7. CONCLUSIONS On the basis of the results obtained during the experimental investigations, following conclusions were drawn:  The compressive strength, split tensile strength, flexure strength of geo polymerconcretespecimens increases with increase in the molarity of sodium hydroxide solution.  The mix with 18M solution gives higher strengths because increase in the molarity of sodium hydroxide increases the strength of concrete.  The fresh fly ash based geo polymer concrete is easily handled up to 120 minutes without any sign of setting and without any degradation in the compressive strength.  Increase in curing temperaturegives morestrength to concrete.  As there is increase in curing time, strength of the specimens will improve.  Sunlight curing is not preferable for geo polymer concrete as it requires high temperature. REFERENCES [1].Zhu Pan , Jay G. Sanjayan , B. V. Rangan,(2007) “An investigation of the mechanisms for strength gain or loss of geopolymer mortar after exposure to elevatedtemperature” , published in J Matera Science (2009)44:1873–1880. [2].Davidovits, J. (1988b). Geopolymer Chemistry and Properties. Paper presented at the Geopolymer ’88,First European Conference on Soft Mineralurgy, Compiegne, France. [3].XiaoluGuo, HuishengShi , Warren A. Dick (2009) “Compressivestrengthandmicrostructural characteristicsof class C fly ash Geopolymer” published in Elsevier .Ltd, Cement & Concrete Composites32 (2010) 142–147 www.elsevier.com/locate/cemconcomp [4].Smith Songpiriyakij, TeinsakKubprasit , Chai Jaturapitakkul , Prinya Chindaprasirt(2010) “Compressive strength and degree of reaction of biomass- and fly ash- based Geo polymer” published in Elsevier .Ltd,Construction and Building Materials 24 (2010) 236–240. [5].Shuguang Hu, Hongxi Wang, GaozhanZhang ,Qingjun Ding(2007) “Bonding and abrasion resistance of geo polymeric repair material made with steel slag”publishedin Elsevier .Ltd ,Cement&ConcreteComposites30(2007)239– 244. [6].C.A. Hendriks1, “Emission Reduction of Greenhouse Gases from the Cement Industry” Greenhouse gas control technologies conference paper.
  • 5. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 03 | Mar 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 7026 [7].Ernst Worerell. Lynn Price, et al. “CO2 emission from the global cement industry”, Annual review ofenergy and the environment. Vol 26: p-303-32 [8].Christina K. Yip, Grant C. Lukey, John L. Provis, Jannie S.J. van Deventer (2008), “Effect of calcium silicate sources on geopolymerisation” published in Elsevier .Ltd, Cement and Concrete Research 38 (2008) 554–564. [9].Wee, T. H., Suryavanshi, A. K., Wong, S. F., &Rahman, A. K. M. A. (2000) Sulfate Resistance of Concrete Containing Mineral Admixtures.ACIMaterials Journal, 97(5), 536-549. [10] Aleem M I A,Arumairaj P D Optimum Mix For The Geopolymer Concrete.Indian Journal Of Science And Technology. 2012; 5(3), 2299-2301 [11] G.Yamini And Dr.S.Siddiraju, An Experimental Research On Strength Properties Of Concrete By Influence Of Fly Ash And Nano Silica As A Partial Replacement Of Cement. International Journal Of Civil Engineering And Technology ,7(3), 2016, Pp.306-315 [12] IS code 2386-1963(part I to part VIII) Indian standard methods of test for aggregate of concrete.