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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 203
Partial Replacement of Aggregates in Geopolymer Concrete
Balaji K1 andMs.D.Shanthini2
1UG Student, Department of Civil Engineering, Sri Ramakrishna Institute of Technology, Coimbatore,
Tamilnadu, India.
2Assistant Professor, Department of Civil Engineering, Sri Ramakrishna Institute of Technology, Coimbatore,
Tamilnadu, India.
--------------------------------------------------------------------***-----------------------------------------------------------------------
Abstract- Global warming is a major concern in the
present day. The main reason for global warming is the
emission of CO2. The sustainable concept of development is
unavoidable that has become more relevant because the
greater people of this world are breathing the same
polluted air as the rest of us. We can reduce the ill effects
on environment, by increasing the usage of industrial
waste products in the construction industry. Geopolymer
concrete is a industrial waste product based material that
is used in the present study, to produce the geopolymer
concrete with partial aggregate replacement, the ordinary
Portland cement is completely replaced with fly ash, the
fine aggregate is partially replaced with charcoal powder
and coconut shells in crushed form is used as a partial
replacement to the coarse aggregates. Different
replacement proportions of aggregates (i.e) 0%, 10% and
20% are prepared for determining the strength
characteristics of each mix proportion. The Geopolymer
concrete specimens are tested for their strength
characteristics at 7th day and 28th day.
Key Words: Geopolymer concrete, tensile strength,
compressive strength, flexural strength, charcoal
powder, coconut shells.
1. INTRODUCTION
For constructing any structure, concrete is the main
material. The concrete that is used for construction is the
most extensively used material next to water in the
world. The quality of urban environment is at stake,
energy efficient buildings can reduce the emission of
hazardous gases such as CO2 and SO2. One of the
prominent materials used in concrete is the cement.
Production of 1 ton of cement emits 1 ton of carbon
dioxide due to combustion processes that requires high
temperatures in the order of 1200°C-1500°C, this
constitutes about 7% of total man made greenhouse
emissions and it is the second most cause for carbon
dioxide emissions after pollution caused due to
automobiles and 17% of the total discharge of harmful
gas related to construction and building field. In the
present day where the availability of energy resources is
less, it becomes a major concern and hence reduction in
the usage of cement will bring reduction in energy
utilized and also the emission of highly dangerous
greenhouse gases. Other than cement, the production of
concrete involves the usage of sand and aggregates.
Earlier these aggregates were available at nominal prices
with very good qualities due to abundant availability.
But due to the continuous excavation of aggregates it has
caused depletion at an exponential rate which has
increased the cost and demand. The quarrying
operations that are done for the extraction of aggregates
are highly energy intensive and they release large
quantities of wastes. The coarse aggregate used is the
crushed granite stones. These are natural resources
which are non-renewable and these are excessively
mined which will have a greater ecological impact hence
some alternate material has to be found that is either a
waste material or available at lesser cost. Generally, the
density of the aggregates is high which increases the
weight of the concrete and also the impact resistance
property is also low. Thus, usage of light weight
aggregates makes it ideal for prefabricated structural
elements. This weightless concrete is also suitable for
reinforced concrete construction.
2. MATERIALS AND METHODS
By using alternate binding material in concrete other
than cement, environment friendly concrete can be
obtained. The usage of industrial by products as binders
can reduce the problem. In this aspect a new technology
geopolymer concrete is a promising technique, in terms
of reducing the CO2 emissions to the atmosphere due to
cement and aggregates. If the industrial wastes are used
properly it can reduce the problem in disposal. The
industrial coal that is manufactured by the burning of
coal in an electrostatic precipitator which has Fly ash as
a by-product . The cementitious properties of fly ash
were discovered in late 19th century and it has been used
widely in cement manufacturing for over 100 years. It
generally replaces the Portland cement between 20%
and 80%.
Coconut shell is an agricultural waste product that is
extensively grown in the tropics. When coconut shells
are used as the coarse aggregate in concrete it gives
medium strength to the concrete with high impact
resistance. It was observed that coconut shell concrete is
very suitable for low cost and it can be used as a
replacement to the natural coarse aggregate up to
certain limits. This serves as a counter measure for the
scarcity. It is one of the most common agricultural solid
wastes in many tropical countries like India, Malaysia….
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072
Table-1: Material properties of coconut shells
Charcoal powder is an agricultural by product that is
obtained after the combustion of coconut shells. The
particle size of the powder is very much similar to the
fine aggregate that is used in the concrete. Charcoal
powder can be effectively used as an alternate material
to fine aggregate due to the excess availability and
cheaper cost.
Table-2: Material properties of charcoal powder
Properties Charcoal Powder
Fineness Modulus 1.93
Specific Gravity 2.18
3. EXPERIMENTAL WORK
The conventional method of making normal concrete is
adopted in the preparation geopolymer concrete. First,
M-sand, Charcoal powder, Coarse aggregate, Crushed
coconut shells and Fly-ash are mixed in dry condition for
about 2-3 minutes and then alkaline solutions (Sodium
silicate and Sodium hydroxide) is added and mixing is
done evenly for effective bonding of all the materials in
the mix. After the mixing, the cubes, cylinders and prisms
are casted and compacted well. The sizes of the moulds
are:
Cubes – 150mmx150mmx150mm
Cylinders – 150mmx300mm
Prisms – 500mmx100mmx100mm
Table-3: Geopolymer concrete mix proportion
Material Mass(Kg/m3)
Coarse aggregate 1294
Fine aggregate 554
Fly ash 409
Sodium silicate 102
Sodium hydroxide 41
Fig-1 Casting of Geopolymer concrete
For the curing of geopolymer concrete specimens, the
specimens are placed in direct sunlight. In this dry
curing, after 24 hours of casting the specimens are
demoulded and are subjected to dry curing.
4. OBSERVATIONS AND RESULTS
The test results of the mixes are shown in the Table 4-6.
Table-4: Compressive strengths in N/mm2
S.No. % of
Aggregate
replacement
7 Days 28 Days
1. 0% 11.70 24.9
2. 10% 8.89 25.63
3. 20% 7.41 23.26
Table-5: Tensile strengths in N/mm2
S.No. % of
Aggregate
replacement
7 Days 28 Days
1. 0% 1.46 2.5
2. 10% 1.08 2.26
3. 20% 0.90 1.79
Table-6: Flexural strengths in N/mm2
S.No. % of
Aggregate
replacement
7 Days 28 Days
1. 0% 2.5 5
2. 10% 1.75 3.25
3. 20% 1 2.88
5. CONCLUSIONS
1) The compressive strength of the geopolymer concrete
of proportions such as 0%, 10% and 20% are found to be
24.9 N/mm2, 25.63 N/mm2 and 23.26 N/mm2
respectively.
2)From the compressive strength test results it is
observed that the 10% replacement mix has high
strength than the other mixes in the 28th day test.
Properties Coconut shells
Specific Gravity 1.31
Impact Value 20.12%
Crushing Value 24.51%
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 204
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072
3)The tensile strength of the geopolymer concrete of
proportions such as 0%, 10% and 20% are observed to
be 2.5 N/mm2, 2.26 N/mm2 and 1.79 N/mm2
respectively.
4)From the tensile strength test results it can be
observed that the 0% replacement mix has higher
strength compared to other mix proportions but the
10% mix proportion almost has similar strength of the
former.
5)The flexural strength of the geopolymer concrete of
proportions such as 0%, 10% and 20% are found to be 5
N/mm2, 3.25 N/mm2 and 2.88 N/mm2 respectively.
6)From the flexural strength test results it can be stated
that the 0% mix proportion has high strength than the
other mix proportions. It is clearly observed that
increase in replacement proportion greatly affects the
flexural strength.
7)The fresh geopolymer concrete is easy to handle for
first few minutes without any sign of setting but after
few minutes it sets rapidly.
8)We observe that the strength parameters of the
concrete are reduced with increase in replacement
proportion of the aggregates.
9)With increase in replacement proportion the weight of
the geopolymer concrete decreases. Thus it can be used
for light weight concreting.
REFERENCES
[1] Abdul Aleem M.I.,P.D. Arumairaj,” Geo polymer concrete-
A review”, International Journal of Engineering Sciences
& Emerging Technologies, Volume 1,Issue 2, February
2012.
[2] Afia Sharmin, Johnson Alengaram U., Mohd Zamin
Jumaat, S.M. Alamgir Kabir, Iftekhair Ibnul Bashar,
“Engineering properties of light weight geo polymer
concrete with oil palm shell and palm oil clinker”,
Rev.Tec.Ing.Zulia, Volume 38, 2015.
[3] Chandran K. P.,Dr.M.Natarajan,Dr.C.Meiaraj,” Impact
resistance of fly ash based Geo polymer concrete using
coconut shell aggregate”,International Journal of Civil
Engineering and Technology, Volume 7, Issue 5,
September 2016.
[4] Chandran K.P.,Dr.M.Natarajan,Dr.C.Meiaraj “Fly ash
based Geo polymer concrete using coconut shell
aggregate”, International Journal of Engineering,
Management & Sciences , Volume 3, Issue 8, August
2016.
[5] Chandran K.P.,Dr.M.Natarajan,Dr.C.Meiaraj,” Eco friendly
light weight geo polymer concrete for sustainable
development ”, International Journal of Civil Engineering
and Technology, Volume 8, Issue 8, August 2017.
[6] Gokulakannan S.,N.Sakthieswaran, “Experimental
investigation of geo polymer concrete with ternary
blends of steatite powder, metakaolin, rice husk ash and
coconut shell for coarse aggregate replacement”,
International Journal of Engineering Research, Volume 3,
Issue 3, 2015.
[7] Harianto Hardjasaputra, Ivan Fernando, Judith Indrajaya,
Melanie Cornelia and Rachmansyah, “ The Effect of Using
Palm Kernel Shell Ash and Rice Husk Ash on Geopolymer
Concrete.”, MATEC Web of Conference 251(2018).
[8] Keerthi M.,K.Prasanthi, “Experimental study of coir fiber
reinforced fly ash based geo polymer concrete ”, ”,
International Journal of Civil Engineering and
Technology, Volume 8, Issue 1, January 2017.
[9] Lee Yee Loon, Dr.R.N. Krishna, “ Biomass Aggregate
Geopolymer Concrete- Malaysia Experience”,
International Journal of Civil Engineering and
Technology(IJCIET), Volume 5 Issue 3 March(2014).
[10] Lloyd N.A ,B.V. Rangan, “Geo polymer concrete: A
review of development and opportunities”, 35th
Conference on OUR WORLD IN CONCRETE &
STRUCTURES: 25-27 August 2010, Singapore.
[11] Michael Yong Jing Liu,Choon Peng Chua,U.Johnson
Alengaram,Mohd Zamin Jumaat, “Utilization of palm oil
fuel ash as binder in light weight oil palm shell
geopolymer concrete ”, Micheael Yong Jing Liu et al./
Advances in Material Science and Engineering (2014).
[12] Michael Yong Jing Liu,U.Johnson Alengaram,Manu
Santhanam,Mohd Zamin Jumaat,Kim Hung Mo,
“Microstructural investigations of palm oil fuel ash and
fly ash based binders in lightweight aggregate foamed
geopolymer concrete”, M.Y.J. Liu et al./Construction and
Building Materials 120 (2016).
[13] Michael Yong Jing Liu,U.Johnson Alengaram,Manu
Santhanam,Mohd Zamin Jumaat,Kim Hung Mo, “
Evaluation of thermal conductivity, mechanical and
transport properties of lightweight aggregate foamed
geopolymer concrete”, M.Y.J. Liu et al./Construction and
Building Materials 120 (2016)
[14] Priya B., Dr.K.Nirmalkumar, “ Combination of
GGBS/GLSS/Bio Additives/ OPC with Flyash in
Geopolymer Concrete cured at Ambient Temparature-
Review”, International Journal of Innovative Research in
Science, Enginnering and Technology, Volume 6 Issue 10,
October 2017.
[15] Renuka P, Ashik Mohamed M, “ Experimental study
on strength properties of geopolymer concrete”,
International Research Journal of Engineering and
Technology(IRJET), Volume 4 Issue 3 March 2017.
[16] Sonia T., R.Subashini, “ Experimental Investigation
on Mechanical Properties of Light Weight Concrete Using
Leca International Journal of Science and
Research(IJSR),Volume 5 Issue 11, November 2016.
[17] Tjokorde Walmiki Samadhi, Winny Wulandari,
Muhammad Iqbal Prasetyo, Muhammad Rizki Fernando,
Aprilina Purbasari, “ Synthesis of Geopolymer from
Biomass- Coal Ash Blends ”, AIP Confernce Proceedings
2017.
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 205
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072
[18] Tjokorde Walmiki Samadhi, Winny Wulandari,
Muhammad Iqbal Prasetyo, Muhammad Rizki Fernando,”
Reuse of Coconut Shell, Rice Husk and Coal Ash Blends in
Geopolymer Synthesis”, ICSMME 2017.
[19] Yashida Nadir, Sujatha A. ,” Durability properties of
Coconut shell Aggregate concrete ”, KSCE Journal of Civil
Engineering, September 15, 2017.
[20] Zuhua Zhang,John L. Provis,Andrew Reid,Hao Wang,
“Mechanical, thermal insulation, thermal resistance and
acoustic absorption properties of geopolymer foam
concrete”,Z.Zhang et al./Cement & Concrete 62(2015).
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 206

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IRJET- Partial Replacement of Aggregates in Geopolymer Concrete

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 203 Partial Replacement of Aggregates in Geopolymer Concrete Balaji K1 andMs.D.Shanthini2 1UG Student, Department of Civil Engineering, Sri Ramakrishna Institute of Technology, Coimbatore, Tamilnadu, India. 2Assistant Professor, Department of Civil Engineering, Sri Ramakrishna Institute of Technology, Coimbatore, Tamilnadu, India. --------------------------------------------------------------------***----------------------------------------------------------------------- Abstract- Global warming is a major concern in the present day. The main reason for global warming is the emission of CO2. The sustainable concept of development is unavoidable that has become more relevant because the greater people of this world are breathing the same polluted air as the rest of us. We can reduce the ill effects on environment, by increasing the usage of industrial waste products in the construction industry. Geopolymer concrete is a industrial waste product based material that is used in the present study, to produce the geopolymer concrete with partial aggregate replacement, the ordinary Portland cement is completely replaced with fly ash, the fine aggregate is partially replaced with charcoal powder and coconut shells in crushed form is used as a partial replacement to the coarse aggregates. Different replacement proportions of aggregates (i.e) 0%, 10% and 20% are prepared for determining the strength characteristics of each mix proportion. The Geopolymer concrete specimens are tested for their strength characteristics at 7th day and 28th day. Key Words: Geopolymer concrete, tensile strength, compressive strength, flexural strength, charcoal powder, coconut shells. 1. INTRODUCTION For constructing any structure, concrete is the main material. The concrete that is used for construction is the most extensively used material next to water in the world. The quality of urban environment is at stake, energy efficient buildings can reduce the emission of hazardous gases such as CO2 and SO2. One of the prominent materials used in concrete is the cement. Production of 1 ton of cement emits 1 ton of carbon dioxide due to combustion processes that requires high temperatures in the order of 1200°C-1500°C, this constitutes about 7% of total man made greenhouse emissions and it is the second most cause for carbon dioxide emissions after pollution caused due to automobiles and 17% of the total discharge of harmful gas related to construction and building field. In the present day where the availability of energy resources is less, it becomes a major concern and hence reduction in the usage of cement will bring reduction in energy utilized and also the emission of highly dangerous greenhouse gases. Other than cement, the production of concrete involves the usage of sand and aggregates. Earlier these aggregates were available at nominal prices with very good qualities due to abundant availability. But due to the continuous excavation of aggregates it has caused depletion at an exponential rate which has increased the cost and demand. The quarrying operations that are done for the extraction of aggregates are highly energy intensive and they release large quantities of wastes. The coarse aggregate used is the crushed granite stones. These are natural resources which are non-renewable and these are excessively mined which will have a greater ecological impact hence some alternate material has to be found that is either a waste material or available at lesser cost. Generally, the density of the aggregates is high which increases the weight of the concrete and also the impact resistance property is also low. Thus, usage of light weight aggregates makes it ideal for prefabricated structural elements. This weightless concrete is also suitable for reinforced concrete construction. 2. MATERIALS AND METHODS By using alternate binding material in concrete other than cement, environment friendly concrete can be obtained. The usage of industrial by products as binders can reduce the problem. In this aspect a new technology geopolymer concrete is a promising technique, in terms of reducing the CO2 emissions to the atmosphere due to cement and aggregates. If the industrial wastes are used properly it can reduce the problem in disposal. The industrial coal that is manufactured by the burning of coal in an electrostatic precipitator which has Fly ash as a by-product . The cementitious properties of fly ash were discovered in late 19th century and it has been used widely in cement manufacturing for over 100 years. It generally replaces the Portland cement between 20% and 80%. Coconut shell is an agricultural waste product that is extensively grown in the tropics. When coconut shells are used as the coarse aggregate in concrete it gives medium strength to the concrete with high impact resistance. It was observed that coconut shell concrete is very suitable for low cost and it can be used as a replacement to the natural coarse aggregate up to certain limits. This serves as a counter measure for the scarcity. It is one of the most common agricultural solid wastes in many tropical countries like India, Malaysia….
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072 Table-1: Material properties of coconut shells Charcoal powder is an agricultural by product that is obtained after the combustion of coconut shells. The particle size of the powder is very much similar to the fine aggregate that is used in the concrete. Charcoal powder can be effectively used as an alternate material to fine aggregate due to the excess availability and cheaper cost. Table-2: Material properties of charcoal powder Properties Charcoal Powder Fineness Modulus 1.93 Specific Gravity 2.18 3. EXPERIMENTAL WORK The conventional method of making normal concrete is adopted in the preparation geopolymer concrete. First, M-sand, Charcoal powder, Coarse aggregate, Crushed coconut shells and Fly-ash are mixed in dry condition for about 2-3 minutes and then alkaline solutions (Sodium silicate and Sodium hydroxide) is added and mixing is done evenly for effective bonding of all the materials in the mix. After the mixing, the cubes, cylinders and prisms are casted and compacted well. The sizes of the moulds are: Cubes – 150mmx150mmx150mm Cylinders – 150mmx300mm Prisms – 500mmx100mmx100mm Table-3: Geopolymer concrete mix proportion Material Mass(Kg/m3) Coarse aggregate 1294 Fine aggregate 554 Fly ash 409 Sodium silicate 102 Sodium hydroxide 41 Fig-1 Casting of Geopolymer concrete For the curing of geopolymer concrete specimens, the specimens are placed in direct sunlight. In this dry curing, after 24 hours of casting the specimens are demoulded and are subjected to dry curing. 4. OBSERVATIONS AND RESULTS The test results of the mixes are shown in the Table 4-6. Table-4: Compressive strengths in N/mm2 S.No. % of Aggregate replacement 7 Days 28 Days 1. 0% 11.70 24.9 2. 10% 8.89 25.63 3. 20% 7.41 23.26 Table-5: Tensile strengths in N/mm2 S.No. % of Aggregate replacement 7 Days 28 Days 1. 0% 1.46 2.5 2. 10% 1.08 2.26 3. 20% 0.90 1.79 Table-6: Flexural strengths in N/mm2 S.No. % of Aggregate replacement 7 Days 28 Days 1. 0% 2.5 5 2. 10% 1.75 3.25 3. 20% 1 2.88 5. CONCLUSIONS 1) The compressive strength of the geopolymer concrete of proportions such as 0%, 10% and 20% are found to be 24.9 N/mm2, 25.63 N/mm2 and 23.26 N/mm2 respectively. 2)From the compressive strength test results it is observed that the 10% replacement mix has high strength than the other mixes in the 28th day test. Properties Coconut shells Specific Gravity 1.31 Impact Value 20.12% Crushing Value 24.51% © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 204
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072 3)The tensile strength of the geopolymer concrete of proportions such as 0%, 10% and 20% are observed to be 2.5 N/mm2, 2.26 N/mm2 and 1.79 N/mm2 respectively. 4)From the tensile strength test results it can be observed that the 0% replacement mix has higher strength compared to other mix proportions but the 10% mix proportion almost has similar strength of the former. 5)The flexural strength of the geopolymer concrete of proportions such as 0%, 10% and 20% are found to be 5 N/mm2, 3.25 N/mm2 and 2.88 N/mm2 respectively. 6)From the flexural strength test results it can be stated that the 0% mix proportion has high strength than the other mix proportions. It is clearly observed that increase in replacement proportion greatly affects the flexural strength. 7)The fresh geopolymer concrete is easy to handle for first few minutes without any sign of setting but after few minutes it sets rapidly. 8)We observe that the strength parameters of the concrete are reduced with increase in replacement proportion of the aggregates. 9)With increase in replacement proportion the weight of the geopolymer concrete decreases. Thus it can be used for light weight concreting. REFERENCES [1] Abdul Aleem M.I.,P.D. Arumairaj,” Geo polymer concrete- A review”, International Journal of Engineering Sciences & Emerging Technologies, Volume 1,Issue 2, February 2012. [2] Afia Sharmin, Johnson Alengaram U., Mohd Zamin Jumaat, S.M. Alamgir Kabir, Iftekhair Ibnul Bashar, “Engineering properties of light weight geo polymer concrete with oil palm shell and palm oil clinker”, Rev.Tec.Ing.Zulia, Volume 38, 2015. [3] Chandran K. 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  • 4. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072 [18] Tjokorde Walmiki Samadhi, Winny Wulandari, Muhammad Iqbal Prasetyo, Muhammad Rizki Fernando,” Reuse of Coconut Shell, Rice Husk and Coal Ash Blends in Geopolymer Synthesis”, ICSMME 2017. [19] Yashida Nadir, Sujatha A. ,” Durability properties of Coconut shell Aggregate concrete ”, KSCE Journal of Civil Engineering, September 15, 2017. [20] Zuhua Zhang,John L. Provis,Andrew Reid,Hao Wang, “Mechanical, thermal insulation, thermal resistance and acoustic absorption properties of geopolymer foam concrete”,Z.Zhang et al./Cement & Concrete 62(2015). © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 206