1. Disinfection is the destruction of pathogenic microorganisms. Common disinfection methods include chemical disinfection using chlorine or ozone, and non-chemical methods like heat or UV radiation.
2. Chlorine is the most widely used disinfectant. It reacts with water to form hypochlorous acid and hydrochloric acid. Hypochlorous acid then dissociates to form hypochlorite ion, both of which are effective disinfectants.
3. The CT concept is used to determine chlorination efficiency, where C is the chlorine concentration and T is the contact time. Higher CT values are needed to achieve greater levels of pathogen inactivation.
water supply engineering, raw water treatment, disinfection, sterilization, killing of micro organism, chlorination, break point chlorination, ozonization, Ultraviolet rays, Iodine and Bromine
water supply engineering, raw water treatment, disinfection, sterilization, killing of micro organism, chlorination, break point chlorination, ozonization, Ultraviolet rays, Iodine and Bromine
Industrial wastewater treatment describes the processes used for treating wastewater that is produced by industries as an undesirable by-product. After treatment, the treated industrial wastewater (or effluent) may be reused or released to a sanitary sewer or to a surface water in the environment. Some industrial facilities generate wastewater that can be treated in sewage treatment plants. Most industrial processes, such as petroleum refineries, chemical and petrochemical plants have their own specialized facilities to treat their wastewaters so that the pollutant concentrations in the treated wastewater comply with the regulations regarding disposal of wastewaters into sewers or into rivers, lakes or oceans.
Lecture notes of Environmental Engineering-II as per Solapur university syllabus of TE CIVIL.
Prepared by
Prof S S Jahagirdar,
Associate Professor,
N K Orchid college of Engg and Technology,
Solapur
Chlorination is the process of adding the element chlorine to water as a method of water purification to make it fit for human consumption as drinking water.
Lecture note of Industrial Waste Treatment (Elective -III) as per syllabus of Solapur university for BE Civil
Prepared by
Prof S S Jahagirdar,
Associate Professor,
N K ORchid College of Engg and Tech,
Solapur
Industrial wastewater treatment describes the processes used for treating wastewater that is produced by industries as an undesirable by-product. After treatment, the treated industrial wastewater (or effluent) may be reused or released to a sanitary sewer or to a surface water in the environment. Some industrial facilities generate wastewater that can be treated in sewage treatment plants. Most industrial processes, such as petroleum refineries, chemical and petrochemical plants have their own specialized facilities to treat their wastewaters so that the pollutant concentrations in the treated wastewater comply with the regulations regarding disposal of wastewaters into sewers or into rivers, lakes or oceans.
Lecture notes of Environmental Engineering-II as per Solapur university syllabus of TE CIVIL.
Prepared by
Prof S S Jahagirdar,
Associate Professor,
N K Orchid college of Engg and Technology,
Solapur
Chlorination is the process of adding the element chlorine to water as a method of water purification to make it fit for human consumption as drinking water.
Lecture note of Industrial Waste Treatment (Elective -III) as per syllabus of Solapur university for BE Civil
Prepared by
Prof S S Jahagirdar,
Associate Professor,
N K ORchid College of Engg and Tech,
Solapur
It deals with biological water quality improvement through disinfection, disinfectants and disinfection kinetics, chlorine and other commonly used disinfectants, breakpoint chlorination and chlorination system
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2. 7. Disinfection in water Treatment
f f f7.1 Definition of Disinfection :
Disinfection is the destruction of pathogenic microorganisms.Disinfection is the destruction of pathogenic microorganisms.
7.2 Disinfection methods :
A. Chemical disinfection:
Chlorination Chlorination
Ozonation
B. Non chemical disinfection:
Heat
Ultra Violet radiation (UV)
2
( )
5. 7.4 Disinfection by chlorinationy
7.4.2 Chemistry of Chlorine in water:
Chlorine gas reacts readily with water to form hypochlorous acid andChlorine gas reacts readily with water to form hypochlorous acid and
hydrochloric acid:
Cl2+H2O → HOCl + HCl
Th d d h hl id h di i i ld h hl i iThe produced hypochlorous acid then dissociates to yield hypochlorite ion:
HOCl → H+ + OCl‐
The relative distribution of HOCl and OCl‐ is a function of pH and temperature
see (Fig 7.1). Both HOCl and OCl‐ are excellent disinfectants but HOCl is
more effective.
Both HOCl & OCl‐ react with ammonia if exists in water to produce chloramines:p
NH3 + HOCl → NH2Cl + H2O (monochloramine)
NH2Cl + 2HOCl → NHCl2 + H2O (dichloramine)
NHCl2 + 3HOCl → NCl3 + H2O (Trichloramine)NHCl2 + 3HOCl → NCl3 + H2O (Trichloramine)
Note: Chloramines are good disinfectants
Both HOCl & OCl‐ react with reducing compounds such as Fe+2, Mn+2, NO‐2 ,
and the chlorine will be reduced to the non effective chlorid ion Cl‐
5
and the chlorine will be reduced to the non effective chlorid ion Cl .
7. Both HOCl & OCl‐ react with reducing natural organic maters producing
trihalomethanes (THMs) including:
*Chloroform (CHCl3) ,
*Bromoform (CHBr3),
* bromodichloromethane (CHCl2Br), b o od c o o e a e ( 2 ),
*dibromochloromethane (CHClBr2).
The THMs are carcinogenic compounds andThe THMs are carcinogenic compounds and
their total concentration in drinking water should not be more than 0.1 mg/l.
THMs are one of the disinfection by products DBPs that should be minimized orTHMs are one of the disinfection by products DBPs that should be minimized or
removed before supplying the water to the consumers.
Another dangerous DBPs is the halogenated acetic acids HAAs as it may cause
cancer.
THMs and HAAs can be minimized by removing the organic matter before
disinfection. THMs and HAAs can be removed from water by GAC.
7
8. 7.4 Disinfection by chlorinationy
7.4.3 Break point chlorination :
‐As illustrated in the previous section, chlorine reacts with the substances existing
in water. Figure 7.2 shows the stages of these reactions.
‐On Fig 7.2, The chlorine dosage is presented on the x‐axis and the residualO g , e c o e dosage s p ese ed o e a s a d e es dua
chlorine is presented on the y‐axis.
‐When chlorine is added it reacts first with the reducing compounds such as
Fe+2 Mn+2 NO‐2 and the chlorine will be reduced to the none effectiveFe , Mn , NO , and the chlorine will be reduced to the none effective
chloride ion Cl‐ (from zero to point A on the figure).
‐ When adding more chlorine it will react with NH3 to form chloramines as shown
in the chlorine chemistry ( from point A to B)in the chlorine chemistry ( from point A to B).
‐When adding more chlorine some chloramines are oxidized to nitrogen gas and
the chlorine is reduced to the none effective Cl‐ ion.( from point B to C).
d dd f hl ll d d f l bl hl ( )‐Continued addition of chlorine will produced free available chlorine (at point C).
point C is called the break point.
8
10. 7.4 Disinfection by chlorinationy
‐The chlorine added is called the dosage.
The amount used to oxidize the materials existing in water is called the demand‐ The amount used to oxidize the materials existing in water is called the demand.
‐ The Free residual = dosage – demand
‐The residual between points A to C is called combined residual because the
hl i i i h f f hl i d hl ichlorine is in the form of chloramines and chloro‐organics.
‐From point C and up a free residual chlorine start to appear.
in water in addition to the combined residual.
‐The free Chlorine residual is composed of un‐reacted forms of
chlorine HOCl and OCl‐.
‐The total residual after the break point = free + combined. p
‐Since the free residual is much more effective in disinfection, all the regulations
require a free residual of at least 0.20 mg/l at the farthest tap in the system. The
residual chlorine in the produced water is typically 2 – 5 mg/l just at the outletresidual chlorine in the produced water is typically 2 5 mg/l just at the outlet
of the treatment .
‐ since free residual appears only after the breakpoint, so we need to decide the
breakpoint dosage Thus the required dosage = breakpoint dosage + free residual
10
breakpoint dosage. Thus the required dosage = breakpoint dosage + free residual
11. Example 7.1:
Referring to the Figure, if a dosage of 1.8 mg/L is applied, determine:
(1 ) The amount free chlorine residual (2 )The amount of combined residual(1. ) The amount free chlorine residual (2. )The amount of combined residual,
(3. )The amount of total residual, (4.) What is the chlorine demand?
Destruction of Chloramines and Presence of
0.5
chlorine residual
by reducing
compounds
Chloramines and
chloro-organic
compounds
Presence of
chloro-organic
compounds not
destroyed
0.4
g/L)
Formation of chloro-organic
0.3
sidual(mg
compounds and chloramines free residual
0.2
hlorineres
Breakpoint
Combined residual
0.1
0
C
Combined residual
0 0.8 1.0 1.2 1.4 1.6 1.8 2.00.60.40.2
Chlorine added (mg/L)
12. From the figure:
1. The of free chlorine residual at a dosage of 1.80 mg/L= 0.40 mg/L.
2. The combined residual at the breakpoint = 0.21 mg/L.
3. The Total residual = 0.40 + 0.21 mg/L = 0.61 mg/L.g g
4. Chlorine demand = 1.40 mg/L
13. 7.4 Disinfection by chlorinationy
7.4.4 CT concept :
h hl ff d d h lThe chlorination efficiency is determined using the CT value.
C = Free residual chlorine concentration in the chlorination tank, mg/L
T = contact time in the storage tank, min.
The chlorination efficiency is determined according to the value C*T
See the USEPA Table for the required values of CT to achieve certain
value of microorganisms inactivation.g
for example, a CT value of 67 (min*mg/L) is needed at 20 oC and a pH
of 7.5 and a residual chlorine of 1 mg/L to achieve 3 log inactivation of
Giardia cysts In this case T = (67/1) = 67 minGiardia cysts. In this case T (67/1) 67 min.
The disinfection is achieved inside the chlorination tank. To increase the
contact time or (the detention time) in the tank, baffle walls are usually
used This will increase the CT value available in the tank and achieve theused. This will increase the CT value available in the tank and achieve the
design CT value.
13
15. Example 7.2
The Initial number of Gardia cycts in water is = 106 Cell/100 ml. Calculate
the nlog inactivation for the given remaining concentration at each
inactivation logs.
A ) N = 104A ) Nr = 10
n Log Inactivation = log N0 – Log Nr
= log106 – log 104
= 6‐4 = 2 log inactivation
B ) Nr = 2.3 X 103
L I i i l N L NnLog Inactivation = log N0 – Log Nr
= log106 – log (2.3X103 )
= 6‐3.362 = 2.638 log inactivation 6 3.362 2.638 log inactivation
17. 7.4 Disinfection by chlorination
7.4.5 Predicting chlorination efficiency:7.4.5 Predicting chlorination efficiency:
Example 7.3 :
The concentration of Giardia cysts in drinking water is 104/ 100 ml. A free chlorine
Residual of 1 2 mg/L has been created in the chlorination tank The detention time in theResidual of 1.2 mg/L has been created in the chlorination tank. The detention time in the
chlorination tank is 57 min. What is the final concentration of Giardia cysts ? What is the
Inactivation percent and the Log‐ inactivation in this case? . Take n = 1.0 , and k = 0.103.
lC llN
e
100/71010*071*10
10*07.1e
N
N
34
3684.057*2.1*10.0
0
t
N
NN
oninactivatiPercent
mlCellsN
t
t
%9.99999.0
10
7.1010
100/7.1010*07.1*10
4
4
0
34
mlCellNNN
oninactivatiLogoninactivatin
N
100/998971010
97.27.10log10loglog
10
4
4
0
mlCellNN
mlCellNNN
oninactivatinremoved
tremoved
100/9989
10
1
110
10
1
1
100/99897.1010
97.2
4
log0
0
17