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Islamic University of Gaza  ‐Environmental Engineering Department
Water TreatmentWater Treatment
EENV 4331
Lecture 2:   Aeration
Dr.   Fahid Rabah
1
2.1 Purpose of Aeration in water Treatment
Aeration is used for many purposes in water Treatment theAeration is used for many purposes in water Treatment , the
main uses are:
1. Increase the dissolved oxygen concentration in water.1. Increase the dissolved oxygen concentration in water.
2. Decrease CO2 concentration thereby reduce its
corrosiveness.corrosiveness.
3. Reduce taste and odor caused by dissolved gases such as
Hydrogen sulphide (H2S) and methane (CH4) that areHydrogen sulphide (H2S) and methane (CH4) that are
removed during aeration.
4. Oxidize iron and manganese from their soluble to4. Oxidize iron and manganese from their soluble to
insoluble states and cause them to precipitate so that they
maybe removed by sedimentation and filtration processes.
2
5. Remove certain volatile organic compounds.
2.2 Types of aerators used in water Treatment
The most common aerators used in water treatment are :The most common aerators used in water treatment are :
1. Gravity Aerators: In gravity aerators, water is allowed to fall
by gravity such that a large area of water is exposed toby gravity such that a large area of water is exposed to
atmosphere, sometimes aided by turbulence. Cascade
aerators and Multi‐tray aerators are two examples of this
type.
2. Fountain Aerators : These are also known as spray aerators
with special nozzles to produce a fine spray.
3. Injection or Diffused Aerators : It consists of a tank with
perforated pipes, tubes or diffuser plates, fixed at the
b tt t l fi i b bbl f itbottom to release fine air bubbles from compressor unit.
4. Mechanical Aerators : Mixing paddles as in flocculation are
d P ddl b ith b d t th f
3
used. Paddles may be either submerged or at the surface.
Cascade AeratorCascade Aerator
4
Cascade AeratorCascade Aerator
5
Cascade AeratorCascade Aerator
6
7
Cascade Aerator
8
Cascade Aerator
9
Cascade Aerator
10Cascade Aerator
Cascade Aerator
11
Cascade Aerator
Multi Tray Aerators
12
Multi Tray Aerators
13
Multi Tray Aerators
14
Multi Tray Aerators
Spray Aerators: Nozzles
15
Spray Aerators: Nozzles
Spray Aerators: Nozzles
16
Spray Aerators: Nozzles
Spray Aerators: Nozzles
17
Spray Aerators: Nozzles
Diffused Air System
18
19
Diffused Air System
Mechanical AeratorsMechanical Aerators
20
Cascade AeratorCascade Aerator
Cw,e =  gas concentration in the effluent water, mg/L
Cw,0 =  gas concentration in the influent water, mg/L
21
,
Cs =  gas  saturation concentration in water at specific temperature , mg/L
h      =  height of one step,  m
Cascade AeratorCascade Aerator
22
Cascade AeratorCascade Aerator
3
10*
*)( ggas
a
V
CMW
C 
Ca = gas concentration in air, mg/L
(MW)gas = molecular weight of gas, gram
C i i i
10*airV
Cg = gas concentration in air, ppm
Vair  = volume of  1 mole of air at a given pressure and temperature,  L
nRT
P
nRT
Vair 
n             = number of air  moles, ( in this case n =1)
R             = universal gas constant, 0.08285 (atm.L)/(mole.K)
T             = temperature in degrees Kelven.
P             = air pressure , atm
Typical values of Cg :
CH4 = 1.5‐2.00 ppp
H2S     =  20‐30  ppm
23
CO2 = 350‐450 ppm
Cascade AeratorCascade Aerator
Example:
Calculate the saturation concentration of H2S in water at  air temperature  of 20 0C 
Solution:
(MW) 2+32 1 34 1 g
and a pressure of 1 atm if its concentration in air is  30 ppm. 
(MW)gas = 2+32.1 = 34.1 g
LVair 29.24
1
)15.27320(*08285.0*1



LmgCa /042.0
10*29.24
30*1.34
3

From the Table , kD for H2S at 20 oC = 2.87
1
From the Table , kD for H2S at 20  C   2.87
Cs = KD* Ca =   2.87 * 0.042 = 0.1205 mg/L
You can calculate CS for CO2, O2, CH4 in the same procedure of this example.   S 2, 2, 4 p p
24
Cascade AeratorCascade Aerator
Example:
C d i b d h f d h d hCascade is to be used to remove methane from ground water. The cascade has 
5 steps each 0.40 m. The initial concentration of methane in the ground water is 
0.80 mg/L and its  saturation concentration (CS ) in water under atmospheric pressure 
i i l t 0 /Lis  is close to 0 mg/L. 
‐What  is the efficiency of methane removal after  the 5 steps?
‐What is the effluent methane concentration?
l iSolution:
From the  table in a previous slide:   kCH4 = 27 % 
K = 1‐ (1‐k)n = 1‐ (1‐ 0.27)5 = 0.793
,0,, wew
CC
CC
K



80000
80.0
793.0 ,


 ewC
Cw,e = (CCH4) effluent = 0.166 mg CH4/L.
0,ws CC 80.00.0
25
Cascade AeratorCascade Aerator
Example:
h i h l h f h C d i h i l if i iWhat is the length of the Cascade aerator in the previous example if its capacity
is 35 m3/h per 1 m length of the step. The total water flow to be treated is 625 m3/h.
What is the total surface area of the cascade if the width to height ratio of the steps
i 1 1?is 1:1?
Solution:
 L cascade = 625/35 = 17.86 m
 Acascade = (number of steps ‐1)*step width*Lcascade
= (5‐1)*0 40*17 86 = 28 58 m2 (5 1) 0.40 17.86   28.58 m
26
Multiple tray aerator
This is an economical solution that occupies little space. 
It consists of three to eight trays with perforated bottoms. The 
p y
holes are 5 to 13 mm in diameter and spaced at 75 mm center to 
center.  
 The trays are  placed one on top of another with a 30‐50cm space e ays a e p aced o e o op o a o e a 30 50c space
between them. 
 The water is evenly distributed in the first tray through porous 
pipes or by stopping the gush with a bar (as shown in the figure) sopipes, or by stopping the gush with a bar (as shown in the figure), so 
that the water trickles into the tray at a rate of 40‐200 L/min per 
square meter of the tray’s surface. 
Small droplets are then sprayed into the next traySmall droplets are then sprayed into the next tray. 
To obtain a finer spray, the aerator trays can be filled with thick 
gravel approximately 10cm deep  (50‐150 mm) in diameter. 
27
Multiple tray aeratorp y
The removal of carbon dioxide by multiple tray aerators  is represented by 
h f ll ( )the following equation ( AWWA,1990):
kn
e
C 
 e
C 0
C = effluent concentration, mg/l
C0 = influent concentration, mg/l
k removal rate constant from 0 28 to 0 37 for COk    =  removal rate constant,  from 0.28  to 0.37  for CO2.
n    =  number of trays 
28
Multiple tray aeratorp y
Example:
A ground water containing 8 mg/L of CO2 is to be degasified using multiple trayA ground water containing 8 mg/L of CO2 is to be degasified using multiple tray 
aerator  with three steps. The groundwater flow rate is  990 L/min.  The k value
is 0.33 and the hydraulic loading rate of the trays is 400 L/(min.m2)
1 What is the CO concentration in the treated effluent?1. What is the CO2 concentration in the treated effluent?
2. What is the size of the trays  if the length to width ratio is 2:1?
Solution:
1. C = C0 * e –kn = C0 * e –0.33X3 = 8*0.3716 = 2.98 mg CO2/L
2. Area of each tray = (990 L/min)/[(400L/(min.m2)] = 2.47 m22. Area of each tray = (990 L/min)/[(400L/(min.m )] = 2.47 m
Dimensions of the tray : L = 2 W
L* W = 2.47 m2
2W*W = 2.47 m2
W = 1.57 m
L = 3 14 m
29
L = 3.14 m
Removal of Iron and Manganese from water by Aeration:Removal of Iron and Manganese from water by Aeration:
 Iron and manganese  in excess of 0.30 mg/L and  0.05 mg/L , respectively ,should be 
removed according to secondary standards of EPA. They cause staining of laundry and 
plumbing fixtures, produce unacceptable taste and color.
Aeration provides the dissolved oxygen needed to convert the iron and manganese 
from their ferrous and manganous forms to their insoluble oxidized ferric and manganic 
forms.  The produced precipitates of ferric hydroxide and manganic oxide are then 
d b di t ti f ll d b id d filt tiremoved by sedimentation  followed by  rapid sand filtration.
 It takes 0.14 mg/L of O2 to oxidize 1 mg/L of iron; and 0.29 mg/L of O2 to oxidize 1 mg/L 
of manganeseof manganese. 
Oxidation reaction of iron is:
4 Fe(HCO3)2 + 2H2O + O2 > 4 Fe(OH) 3 ↓ + 8CO23 2 2 2 3 2
Oxidation reaction of iron is:
2MnSO4 + 2H2O + O2 > 2MnO2 ↓ +  2H2SO4
30
2Mn(HCO3)2 + O2 > 2MnO2 ↓ + 2H2O + 4CO2

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Water treatment-lecture-2-eenv

  • 2. 2.1 Purpose of Aeration in water Treatment Aeration is used for many purposes in water Treatment theAeration is used for many purposes in water Treatment , the main uses are: 1. Increase the dissolved oxygen concentration in water.1. Increase the dissolved oxygen concentration in water. 2. Decrease CO2 concentration thereby reduce its corrosiveness.corrosiveness. 3. Reduce taste and odor caused by dissolved gases such as Hydrogen sulphide (H2S) and methane (CH4) that areHydrogen sulphide (H2S) and methane (CH4) that are removed during aeration. 4. Oxidize iron and manganese from their soluble to4. Oxidize iron and manganese from their soluble to insoluble states and cause them to precipitate so that they maybe removed by sedimentation and filtration processes. 2 5. Remove certain volatile organic compounds.
  • 3. 2.2 Types of aerators used in water Treatment The most common aerators used in water treatment are :The most common aerators used in water treatment are : 1. Gravity Aerators: In gravity aerators, water is allowed to fall by gravity such that a large area of water is exposed toby gravity such that a large area of water is exposed to atmosphere, sometimes aided by turbulence. Cascade aerators and Multi‐tray aerators are two examples of this type. 2. Fountain Aerators : These are also known as spray aerators with special nozzles to produce a fine spray. 3. Injection or Diffused Aerators : It consists of a tank with perforated pipes, tubes or diffuser plates, fixed at the b tt t l fi i b bbl f itbottom to release fine air bubbles from compressor unit. 4. Mechanical Aerators : Mixing paddles as in flocculation are d P ddl b ith b d t th f 3 used. Paddles may be either submerged or at the surface.
  • 15. Spray Aerators: Nozzles 15 Spray Aerators: Nozzles
  • 16. Spray Aerators: Nozzles 16 Spray Aerators: Nozzles
  • 17. Spray Aerators: Nozzles 17 Spray Aerators: Nozzles
  • 21. Cascade AeratorCascade Aerator Cw,e =  gas concentration in the effluent water, mg/L Cw,0 =  gas concentration in the influent water, mg/L 21 , Cs =  gas  saturation concentration in water at specific temperature , mg/L h      =  height of one step,  m
  • 23. Cascade AeratorCascade Aerator 3 10* *)( ggas a V CMW C  Ca = gas concentration in air, mg/L (MW)gas = molecular weight of gas, gram C i i i 10*airV Cg = gas concentration in air, ppm Vair  = volume of  1 mole of air at a given pressure and temperature,  L nRT P nRT Vair  n             = number of air  moles, ( in this case n =1) R             = universal gas constant, 0.08285 (atm.L)/(mole.K) T             = temperature in degrees Kelven. P             = air pressure , atm Typical values of Cg : CH4 = 1.5‐2.00 ppp H2S     =  20‐30  ppm 23 CO2 = 350‐450 ppm
  • 24. Cascade AeratorCascade Aerator Example: Calculate the saturation concentration of H2S in water at  air temperature  of 20 0C  Solution: (MW) 2+32 1 34 1 g and a pressure of 1 atm if its concentration in air is  30 ppm.  (MW)gas = 2+32.1 = 34.1 g LVair 29.24 1 )15.27320(*08285.0*1    LmgCa /042.0 10*29.24 30*1.34 3  From the Table , kD for H2S at 20 oC = 2.87 1 From the Table , kD for H2S at 20  C   2.87 Cs = KD* Ca =   2.87 * 0.042 = 0.1205 mg/L You can calculate CS for CO2, O2, CH4 in the same procedure of this example.   S 2, 2, 4 p p 24
  • 25. Cascade AeratorCascade Aerator Example: C d i b d h f d h d hCascade is to be used to remove methane from ground water. The cascade has  5 steps each 0.40 m. The initial concentration of methane in the ground water is  0.80 mg/L and its  saturation concentration (CS ) in water under atmospheric pressure  i i l t 0 /Lis  is close to 0 mg/L.  ‐What  is the efficiency of methane removal after  the 5 steps? ‐What is the effluent methane concentration? l iSolution: From the  table in a previous slide:   kCH4 = 27 %  K = 1‐ (1‐k)n = 1‐ (1‐ 0.27)5 = 0.793 ,0,, wew CC CC K    80000 80.0 793.0 ,    ewC Cw,e = (CCH4) effluent = 0.166 mg CH4/L. 0,ws CC 80.00.0 25
  • 26. Cascade AeratorCascade Aerator Example: h i h l h f h C d i h i l if i iWhat is the length of the Cascade aerator in the previous example if its capacity is 35 m3/h per 1 m length of the step. The total water flow to be treated is 625 m3/h. What is the total surface area of the cascade if the width to height ratio of the steps i 1 1?is 1:1? Solution:  L cascade = 625/35 = 17.86 m  Acascade = (number of steps ‐1)*step width*Lcascade = (5‐1)*0 40*17 86 = 28 58 m2 (5 1) 0.40 17.86   28.58 m 26
  • 27. Multiple tray aerator This is an economical solution that occupies little space.  It consists of three to eight trays with perforated bottoms. The  p y holes are 5 to 13 mm in diameter and spaced at 75 mm center to  center.    The trays are  placed one on top of another with a 30‐50cm space e ays a e p aced o e o op o a o e a 30 50c space between them.   The water is evenly distributed in the first tray through porous  pipes or by stopping the gush with a bar (as shown in the figure) sopipes, or by stopping the gush with a bar (as shown in the figure), so  that the water trickles into the tray at a rate of 40‐200 L/min per  square meter of the tray’s surface.  Small droplets are then sprayed into the next traySmall droplets are then sprayed into the next tray.  To obtain a finer spray, the aerator trays can be filled with thick  gravel approximately 10cm deep  (50‐150 mm) in diameter.  27
  • 28. Multiple tray aeratorp y The removal of carbon dioxide by multiple tray aerators  is represented by  h f ll ( )the following equation ( AWWA,1990): kn e C   e C 0 C = effluent concentration, mg/l C0 = influent concentration, mg/l k removal rate constant from 0 28 to 0 37 for COk    =  removal rate constant,  from 0.28  to 0.37  for CO2. n    =  number of trays  28
  • 29. Multiple tray aeratorp y Example: A ground water containing 8 mg/L of CO2 is to be degasified using multiple trayA ground water containing 8 mg/L of CO2 is to be degasified using multiple tray  aerator  with three steps. The groundwater flow rate is  990 L/min.  The k value is 0.33 and the hydraulic loading rate of the trays is 400 L/(min.m2) 1 What is the CO concentration in the treated effluent?1. What is the CO2 concentration in the treated effluent? 2. What is the size of the trays  if the length to width ratio is 2:1? Solution: 1. C = C0 * e –kn = C0 * e –0.33X3 = 8*0.3716 = 2.98 mg CO2/L 2. Area of each tray = (990 L/min)/[(400L/(min.m2)] = 2.47 m22. Area of each tray = (990 L/min)/[(400L/(min.m )] = 2.47 m Dimensions of the tray : L = 2 W L* W = 2.47 m2 2W*W = 2.47 m2 W = 1.57 m L = 3 14 m 29 L = 3.14 m
  • 30. Removal of Iron and Manganese from water by Aeration:Removal of Iron and Manganese from water by Aeration:  Iron and manganese  in excess of 0.30 mg/L and  0.05 mg/L , respectively ,should be  removed according to secondary standards of EPA. They cause staining of laundry and  plumbing fixtures, produce unacceptable taste and color. Aeration provides the dissolved oxygen needed to convert the iron and manganese  from their ferrous and manganous forms to their insoluble oxidized ferric and manganic  forms.  The produced precipitates of ferric hydroxide and manganic oxide are then  d b di t ti f ll d b id d filt tiremoved by sedimentation  followed by  rapid sand filtration.  It takes 0.14 mg/L of O2 to oxidize 1 mg/L of iron; and 0.29 mg/L of O2 to oxidize 1 mg/L  of manganeseof manganese.  Oxidation reaction of iron is: 4 Fe(HCO3)2 + 2H2O + O2 > 4 Fe(OH) 3 ↓ + 8CO23 2 2 2 3 2 Oxidation reaction of iron is: 2MnSO4 + 2H2O + O2 > 2MnO2 ↓ +  2H2SO4 30 2Mn(HCO3)2 + O2 > 2MnO2 ↓ + 2H2O + 4CO2