Non-defining relative clauses provide extra information about a person or thing being referred to that is not essential for identifying them. They are usually separated from the main clause by commas. Relative pronouns like 'who', 'which', 'whom', and 'that' are used to begin non-defining relative clauses, with 'who' and 'whom' used for people and 'which' used for things. 'When' and 'where' can also be used in non-defining relative clauses after expressions of time and place.