Green chemistry is the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products.
Study and prediction of persistent organochlorine and organophosphorous pesti...iosrjce
The indiscriminate use of toxic pesticides had created an environment that without this poison the
plant life is unfruitful leading to the farmer’s life miserable. For several years, this phenomenon was continuing
and the ecosystem is protecting the environment and the life of human being from high risk of toxicity. But, how
long it will continue or weather a paradigm change in the agricultural field is required? With this objective a
field study was conducted in the cardamom plantations of Idukki district in South India to estimate and predict
the persistence of pesticide residue in the soil environment. It is observed that residues of endosulfan, DDT and
organophosphorous pesticides were present in soil samples at 31.6 %, 29 % and 21 % respectively. The present
study gives a prediction of the concentration of persistent pesticide residues in the soil if the present dose and
frequency of application is continued. The study also highlighted the adsorption capacity of soil in the study
area and low water solubility of pesticides used in cardamom plantations which is referred as partition
coefficient. The soil properties such as pH, organic content and microbial concentration which determine the
fate of degradation of pesticides and formation of its metabolites are also been discussed in this context. Based
on the observations and analysis, it is concluded that the formation of degradation products and bound residues
decrease at higher concentration of pesticide applications but the concentration of persistent pesticides
increases and the biodegradation reduced in such cases due to bound residues and reduced biological activity.
The predicted values on multiple applications where the concentrations in soil may build up and reach a
plateau, are 2.559,0.2559, 1.7324 and 0.659 mgKg-1
in the case of endosulfan, DDT, organophosphorous and
total pesticides respectively.
Green chemistry is the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products.
Study and prediction of persistent organochlorine and organophosphorous pesti...iosrjce
The indiscriminate use of toxic pesticides had created an environment that without this poison the
plant life is unfruitful leading to the farmer’s life miserable. For several years, this phenomenon was continuing
and the ecosystem is protecting the environment and the life of human being from high risk of toxicity. But, how
long it will continue or weather a paradigm change in the agricultural field is required? With this objective a
field study was conducted in the cardamom plantations of Idukki district in South India to estimate and predict
the persistence of pesticide residue in the soil environment. It is observed that residues of endosulfan, DDT and
organophosphorous pesticides were present in soil samples at 31.6 %, 29 % and 21 % respectively. The present
study gives a prediction of the concentration of persistent pesticide residues in the soil if the present dose and
frequency of application is continued. The study also highlighted the adsorption capacity of soil in the study
area and low water solubility of pesticides used in cardamom plantations which is referred as partition
coefficient. The soil properties such as pH, organic content and microbial concentration which determine the
fate of degradation of pesticides and formation of its metabolites are also been discussed in this context. Based
on the observations and analysis, it is concluded that the formation of degradation products and bound residues
decrease at higher concentration of pesticide applications but the concentration of persistent pesticides
increases and the biodegradation reduced in such cases due to bound residues and reduced biological activity.
The predicted values on multiple applications where the concentrations in soil may build up and reach a
plateau, are 2.559,0.2559, 1.7324 and 0.659 mgKg-1
in the case of endosulfan, DDT, organophosphorous and
total pesticides respectively.
The use of nanoparticles and nanotechnology to enhance the microbial activity to remove pollutants, they also enhance bioremediation.
NanoBioremediation has the potential not only to reduce the overall costs of cleaning up large-scale contaminated sites, but it can also reduce clean up time.
Green synthesis of Nanoparticles using plants utsav dalal
Slide contains basic definition of Plant mediated nanoparticles. This route is environmentally friendly and widely accepted. For better understanding you can contact me.
The main methods of producing nanoparticles are often cost effective and harmful to the environment. The green synthesis of nanoparticles has been proposed as a cost-effective and eco-friendly alternative of the previous methods. At present the metal nanoparticle synthesis using plant extracts has become a major focus of researchers.
Removal of heavy metal lead (pb) from electrochemical industry waste water us...eSAT Journals
Abstract Electrochemical industries generates a wastewater that has a potential hazard for our environment as it contains various heavy metals such as Lead, Cadmium, Nickel etc. If this wastewater left untreated, will pollute soil and water resources. Out of the above heavy metals, in this project work, only removal of Lead (Pb) from electrochemical industrial wastewater has been investigated by using low cost adsorbent such as charcoal along with coconut shell powder as a natural adsorbent. The project is a bench scale experimental type i.e. Batch mode technique and analyses have performed by using different amounts of adsorbent in solutions with different concentrations of Lead metal. Beside the effect of various amounts of adsorbent used in adsorption efficiency experiments has been investigated. Result indicates that the maximum removal efficiency for Lead is about 94% by using 0.25 gm/L amount of activated coconut shell carbon powder (ACSCP) and charcoal powder (ACP) mixed in equal amount for particular pH and contact time. Keywords: Adsorption, batch mode technique, battery industry waste water, Coconut shell powder, Charcoal carbon powder, Economic, Heavy Metal.
Green synthesis of silver nanoparticles: The reasons for and against Aspergil...Nanomedicine Journal (NMJ)
Abstract
Objective(s):
The enzymatic activity of fungi has recently inspired the scientists with re-explore the fungi as potential biofactories rather than the causing agents of humans and plants infections. In very recent years, fungi are considered as worthy, applicable and available candidates for synthesis of smaller gold, silver and other nano-sized particles.
Materials and Methods:
A standard strain of Aspergillus parasiticus was grown on a liquid medium containing mineral salt. The cell-free filtrate of the culture was then obtained and subjected to synthesize SNPs while expose with 1mM of AgNO3. Further characterization of synthesized SNPs was performed afterward. In addition, antifungal activity of synthesized SNPs was evaluated against a standard strain of Candida albicans. The reduction of Ag+ ions to metal nanoparticles was investigated virtually by tracing the color of the solution which turned into reddish-brown after 72h.
Results:
The UV-vis spectra demonstrated a broad peak centering at 400nm which corresponds to the particle size much less than 70nm. The results of TEM demonstrated that the particles were formed fairly uniform, spherical, and small in size with almost 90% in 5-30nm range. The zeta potential of silver nanoparticles was negative and equal to -15.0 which meets the quality and suggested that there was not much aggression. Silver nanoparticles synthesized by A. parasiticus showed antifungal activity against yeast strain tested and exhibited MIC value of 4 μg/mL.
Conclusion:
The filamentous fungus, A. parasiticus has successfully demonstrated potential for extra cellular synthesis of fairly monodispersed, tiny silver nanoparticles.
Kinetics and Thermodynamic Studies of Biosorption of Cadmium (ii) from Aqueous Solution onto Garden Grass (GAG)
Original Research Article
Journal of Chemistry and Materials Research Vol. 1 (1), 2014, 12–22
B.O. Evbuomwan, M.M. Atuka
The major challenge in municipal solid waste management using landfills is
leachate, which causes a significant threat to subsurface resources. Leachate is the
liquid that passes through soil and has extracted dissolved and suspended solids from
it. Municipal solid waste landfills are one of the severe environmental impacts on the
urban environment. Landfills are one of the practices of disposal of municipal solid
waste in the Indian scenario. Understanding the leachate composition is an equally
important and critical factor in terms of environmental production. When the
municipal solid waste is buried in a landfill, physical, chemical and biological
reactions occur, and the refuse reacts with the moisture present in the soil. Studying
leachate characteristics and its treatment is essential as it could threaten the
ecosystem. Rapid urbanization is one of the major contributions to the generation of
municipal solid waste. The present study reviews the different applications available
to treat the leachate generated from municipal solid waste landfills. Nano-particles
are recently gaining great interest in the protection of the environment, which will
ensure sustainable development.
The use of nanoparticles and nanotechnology to enhance the microbial activity to remove pollutants, they also enhance bioremediation.
NanoBioremediation has the potential not only to reduce the overall costs of cleaning up large-scale contaminated sites, but it can also reduce clean up time.
Green synthesis of Nanoparticles using plants utsav dalal
Slide contains basic definition of Plant mediated nanoparticles. This route is environmentally friendly and widely accepted. For better understanding you can contact me.
The main methods of producing nanoparticles are often cost effective and harmful to the environment. The green synthesis of nanoparticles has been proposed as a cost-effective and eco-friendly alternative of the previous methods. At present the metal nanoparticle synthesis using plant extracts has become a major focus of researchers.
Removal of heavy metal lead (pb) from electrochemical industry waste water us...eSAT Journals
Abstract Electrochemical industries generates a wastewater that has a potential hazard for our environment as it contains various heavy metals such as Lead, Cadmium, Nickel etc. If this wastewater left untreated, will pollute soil and water resources. Out of the above heavy metals, in this project work, only removal of Lead (Pb) from electrochemical industrial wastewater has been investigated by using low cost adsorbent such as charcoal along with coconut shell powder as a natural adsorbent. The project is a bench scale experimental type i.e. Batch mode technique and analyses have performed by using different amounts of adsorbent in solutions with different concentrations of Lead metal. Beside the effect of various amounts of adsorbent used in adsorption efficiency experiments has been investigated. Result indicates that the maximum removal efficiency for Lead is about 94% by using 0.25 gm/L amount of activated coconut shell carbon powder (ACSCP) and charcoal powder (ACP) mixed in equal amount for particular pH and contact time. Keywords: Adsorption, batch mode technique, battery industry waste water, Coconut shell powder, Charcoal carbon powder, Economic, Heavy Metal.
Green synthesis of silver nanoparticles: The reasons for and against Aspergil...Nanomedicine Journal (NMJ)
Abstract
Objective(s):
The enzymatic activity of fungi has recently inspired the scientists with re-explore the fungi as potential biofactories rather than the causing agents of humans and plants infections. In very recent years, fungi are considered as worthy, applicable and available candidates for synthesis of smaller gold, silver and other nano-sized particles.
Materials and Methods:
A standard strain of Aspergillus parasiticus was grown on a liquid medium containing mineral salt. The cell-free filtrate of the culture was then obtained and subjected to synthesize SNPs while expose with 1mM of AgNO3. Further characterization of synthesized SNPs was performed afterward. In addition, antifungal activity of synthesized SNPs was evaluated against a standard strain of Candida albicans. The reduction of Ag+ ions to metal nanoparticles was investigated virtually by tracing the color of the solution which turned into reddish-brown after 72h.
Results:
The UV-vis spectra demonstrated a broad peak centering at 400nm which corresponds to the particle size much less than 70nm. The results of TEM demonstrated that the particles were formed fairly uniform, spherical, and small in size with almost 90% in 5-30nm range. The zeta potential of silver nanoparticles was negative and equal to -15.0 which meets the quality and suggested that there was not much aggression. Silver nanoparticles synthesized by A. parasiticus showed antifungal activity against yeast strain tested and exhibited MIC value of 4 μg/mL.
Conclusion:
The filamentous fungus, A. parasiticus has successfully demonstrated potential for extra cellular synthesis of fairly monodispersed, tiny silver nanoparticles.
Kinetics and Thermodynamic Studies of Biosorption of Cadmium (ii) from Aqueous Solution onto Garden Grass (GAG)
Original Research Article
Journal of Chemistry and Materials Research Vol. 1 (1), 2014, 12–22
B.O. Evbuomwan, M.M. Atuka
The major challenge in municipal solid waste management using landfills is
leachate, which causes a significant threat to subsurface resources. Leachate is the
liquid that passes through soil and has extracted dissolved and suspended solids from
it. Municipal solid waste landfills are one of the severe environmental impacts on the
urban environment. Landfills are one of the practices of disposal of municipal solid
waste in the Indian scenario. Understanding the leachate composition is an equally
important and critical factor in terms of environmental production. When the
municipal solid waste is buried in a landfill, physical, chemical and biological
reactions occur, and the refuse reacts with the moisture present in the soil. Studying
leachate characteristics and its treatment is essential as it could threaten the
ecosystem. Rapid urbanization is one of the major contributions to the generation of
municipal solid waste. The present study reviews the different applications available
to treat the leachate generated from municipal solid waste landfills. Nano-particles
are recently gaining great interest in the protection of the environment, which will
ensure sustainable development.
Purification of Wastewater by Metal Oxide Nanoparticlesijtsrd
In todays world, nanotechnology is becoming increasingly popular for water treatment. In this review, we will summarize recent advances in the development of typical metal oxide materials TiO2, Fe3O4 Fe2O3, MnO2, CeO2, MgO and Al2O3 and the related processes for the treatment of various water resources which have been contaminated by organic solutes, inorganic anions, radionuclides, bacteria and viruses. Gajendra Kumar Tardia "Purification of Wastewater by Metal Oxide Nanoparticles" Published in International Journal of Trend in Scientific Research and Development (ijtsrd), ISSN: 2456-6470, Volume-6 | Issue-4 , June 2022, URL: https://www.ijtsrd.com/papers/ijtsrd50327.pdf Paper URL: https://www.ijtsrd.com/other-scientific-research-area/other/50327/purification-of-wastewater-by-metal-oxide-nanoparticles/gajendra-kumar-tardia
REMOVAL OF POLLUTANTS USING RADIAL AND VERTICAL FLOW REGIME REACTORSIAEME Publication
Batch and continuous processes were conducted to study the adsorption of methylene blue dye on to three adsorbent materials, commercial activated carbon, chemically activated corncob carbon with phosphoric acid and ion exchange resin (akualite). Batch processes were established to show the effects of solution pH, contact time, adsorbent dosage, agitation speed and initial dye concentration. Two isotherm models, Freundlich and Langmuir fitted with the experimental data found from batch processes, the Langmuir model fitted well than the Freundlich, with maximum adsorption capacities of 16.21, 30.95 and 77.52 mg/g and R2 of 0.952, 0.992 and 0.995 predicted by commercial activated carbon, corncob activated carbon akualite respectively.
Water scarcity is the lack of fresh water resources to meet the standard water demand. There are two type of water scarcity. One is physical. The other is economic water scarcity.
Hierarchical Digital Twin of a Naval Power SystemKerry Sado
A hierarchical digital twin of a Naval DC power system has been developed and experimentally verified. Similar to other state-of-the-art digital twins, this technology creates a digital replica of the physical system executed in real-time or faster, which can modify hardware controls. However, its advantage stems from distributing computational efforts by utilizing a hierarchical structure composed of lower-level digital twin blocks and a higher-level system digital twin. Each digital twin block is associated with a physical subsystem of the hardware and communicates with a singular system digital twin, which creates a system-level response. By extracting information from each level of the hierarchy, power system controls of the hardware were reconfigured autonomously. This hierarchical digital twin development offers several advantages over other digital twins, particularly in the field of naval power systems. The hierarchical structure allows for greater computational efficiency and scalability while the ability to autonomously reconfigure hardware controls offers increased flexibility and responsiveness. The hierarchical decomposition and models utilized were well aligned with the physical twin, as indicated by the maximum deviations between the developed digital twin hierarchy and the hardware.