Hydrogenation is a chemical reaction between hydrogen gas and another compound or element in the presence of a catalyst such as nickel, palladium or platinum. It involves the addition of hydrogen atoms to reduce double or triple bonds. There are three types of reductions that differ in how hydrogen is added. The reaction rate depends on factors like temperature, pressure, catalyst surface area, time, and the ratio of hydrogen to the compound being hydrogenated. In general, higher temperatures and pressures increase the reaction rate.
Hydrogenation- definition, catalytic hydrogenation, homogeneous and heterogeneous catalytic hydrogenation, mechanism of catalytic hydrogenation, advantages and disadvantages of catalytic hydrogenation, applications of catalytic hydrogenation
Hydrogenation- definition, catalytic hydrogenation, homogeneous and heterogeneous catalytic hydrogenation, mechanism of catalytic hydrogenation, advantages and disadvantages of catalytic hydrogenation, applications of catalytic hydrogenation
I hope You all like it. I hope It is very beneficial for you all. I really thought that you all get enough knowledge from this presentation. This presentation is about materials and their classifications. After you read this presentation you knowledge is not as before.
catalysis and heterogeneous catalysis,
types of catalysis; difference between homo and hetero catalysis;
heterogeneous catalysis; preparation, characterization, supported catalysts, deactivation and regeneration of catalysts, example of drug synthesis
Determination of the order of reaction between potassium persulphate & potass...PRAVIN SINGARE
This presentation is based on the experimental demonstration of "Determination of the order of reaction between potassium persulphate & potassium iodide by fractional change method". The presentation is for chemistry Undergraduate student of Mumbai University.
Reduction using catalytic hydrogenationScifySolution
Catalytic hydrogenation is one of the most convenient available for the reduction of organic compounds. compounds. The reduction is carried out easily by stirring or shaking the substrate with the catalyst in a suitable solvent
I hope You all like it. I hope It is very beneficial for you all. I really thought that you all get enough knowledge from this presentation. This presentation is about materials and their classifications. After you read this presentation you knowledge is not as before.
catalysis and heterogeneous catalysis,
types of catalysis; difference between homo and hetero catalysis;
heterogeneous catalysis; preparation, characterization, supported catalysts, deactivation and regeneration of catalysts, example of drug synthesis
Determination of the order of reaction between potassium persulphate & potass...PRAVIN SINGARE
This presentation is based on the experimental demonstration of "Determination of the order of reaction between potassium persulphate & potassium iodide by fractional change method". The presentation is for chemistry Undergraduate student of Mumbai University.
Reduction using catalytic hydrogenationScifySolution
Catalytic hydrogenation is one of the most convenient available for the reduction of organic compounds. compounds. The reduction is carried out easily by stirring or shaking the substrate with the catalyst in a suitable solvent
I hope You all like it. I hope It is very beneficial for you all. I really thought that you all get enough knowledge from this presentation. This presentation is about materials and their classifications. After you read this presentation you knowledge is not as before.
In this chapter we will discuss about the hydrogen and the properties why the hydrogen is considered as the first group first place and they are having allotropes also they are having metal property as well as nonmetall also and mettalloid
Formulation and operation of a Nickel based methanation catalystSakib Shahriar
The objective of this experiment was to get a firsthand experience of the preparation of a catalyst for methanation reaction and to evaluate the performance of the catalyst in a fixed bed tubular reactor. In the first part of the experiment a nickel-based catalyst was synthesized. The catalyst will have nickel as the active component and alumina as the support. the catalyst precursor was prepared by co-precipitation from a solution of nitrate salts of nickel and aluminum. The precipitate was filtered out, washed, dried and calcined to obtain the catalyst. In the second part, the catalyst was activated and performance analysis was done alone with loaded in a fixed bed reactor. The percentage conversion of CO to CH4 was 96.38% and the selectivity of CH4 production to CO2 production was 3.348.
Hierarchical Digital Twin of a Naval Power SystemKerry Sado
A hierarchical digital twin of a Naval DC power system has been developed and experimentally verified. Similar to other state-of-the-art digital twins, this technology creates a digital replica of the physical system executed in real-time or faster, which can modify hardware controls. However, its advantage stems from distributing computational efforts by utilizing a hierarchical structure composed of lower-level digital twin blocks and a higher-level system digital twin. Each digital twin block is associated with a physical subsystem of the hardware and communicates with a singular system digital twin, which creates a system-level response. By extracting information from each level of the hierarchy, power system controls of the hardware were reconfigured autonomously. This hierarchical digital twin development offers several advantages over other digital twins, particularly in the field of naval power systems. The hierarchical structure allows for greater computational efficiency and scalability while the ability to autonomously reconfigure hardware controls offers increased flexibility and responsiveness. The hierarchical decomposition and models utilized were well aligned with the physical twin, as indicated by the maximum deviations between the developed digital twin hierarchy and the hardware.
Cosmetic shop management system project report.pdfKamal Acharya
Buying new cosmetic products is difficult. It can even be scary for those who have sensitive skin and are prone to skin trouble. The information needed to alleviate this problem is on the back of each product, but it's thought to interpret those ingredient lists unless you have a background in chemistry.
Instead of buying and hoping for the best, we can use data science to help us predict which products may be good fits for us. It includes various function programs to do the above mentioned tasks.
Data file handling has been effectively used in the program.
The automated cosmetic shop management system should deal with the automation of general workflow and administration process of the shop. The main processes of the system focus on customer's request where the system is able to search the most appropriate products and deliver it to the customers. It should help the employees to quickly identify the list of cosmetic product that have reached the minimum quantity and also keep a track of expired date for each cosmetic product. It should help the employees to find the rack number in which the product is placed.It is also Faster and more efficient way.
Welcome to WIPAC Monthly the magazine brought to you by the LinkedIn Group Water Industry Process Automation & Control.
In this month's edition, along with this month's industry news to celebrate the 13 years since the group was created we have articles including
A case study of the used of Advanced Process Control at the Wastewater Treatment works at Lleida in Spain
A look back on an article on smart wastewater networks in order to see how the industry has measured up in the interim around the adoption of Digital Transformation in the Water Industry.
CFD Simulation of By-pass Flow in a HRSG module by R&R Consult.pptxR&R Consult
CFD analysis is incredibly effective at solving mysteries and improving the performance of complex systems!
Here's a great example: At a large natural gas-fired power plant, where they use waste heat to generate steam and energy, they were puzzled that their boiler wasn't producing as much steam as expected.
R&R and Tetra Engineering Group Inc. were asked to solve the issue with reduced steam production.
An inspection had shown that a significant amount of hot flue gas was bypassing the boiler tubes, where the heat was supposed to be transferred.
R&R Consult conducted a CFD analysis, which revealed that 6.3% of the flue gas was bypassing the boiler tubes without transferring heat. The analysis also showed that the flue gas was instead being directed along the sides of the boiler and between the modules that were supposed to capture the heat. This was the cause of the reduced performance.
Based on our results, Tetra Engineering installed covering plates to reduce the bypass flow. This improved the boiler's performance and increased electricity production.
It is always satisfying when we can help solve complex challenges like this. Do your systems also need a check-up or optimization? Give us a call!
Work done in cooperation with James Malloy and David Moelling from Tetra Engineering.
More examples of our work https://www.r-r-consult.dk/en/cases-en/
Saudi Arabia stands as a titan in the global energy landscape, renowned for its abundant oil and gas resources. It's the largest exporter of petroleum and holds some of the world's most significant reserves. Let's delve into the top 10 oil and gas projects shaping Saudi Arabia's energy future in 2024.
Immunizing Image Classifiers Against Localized Adversary Attacksgerogepatton
This paper addresses the vulnerability of deep learning models, particularly convolutional neural networks
(CNN)s, to adversarial attacks and presents a proactive training technique designed to counter them. We
introduce a novel volumization algorithm, which transforms 2D images into 3D volumetric representations.
When combined with 3D convolution and deep curriculum learning optimization (CLO), itsignificantly improves
the immunity of models against localized universal attacks by up to 40%. We evaluate our proposed approach
using contemporary CNN architectures and the modified Canadian Institute for Advanced Research (CIFAR-10
and CIFAR-100) and ImageNet Large Scale Visual Recognition Challenge (ILSVRC12) datasets, showcasing
accuracy improvements over previous techniques. The results indicate that the combination of the volumetric
input and curriculum learning holds significant promise for mitigating adversarial attacks without necessitating
adversary training.
Water scarcity is the lack of fresh water resources to meet the standard water demand. There are two type of water scarcity. One is physical. The other is economic water scarcity.
2. Hydrogenation
Hydrogenation – to treat with hydrogen – is a chemical
reaction between molecular hydrogen (H2) and another
compound or element, usually in the presence of
a catalyst such as nickel, palladium or platinum.
The process is commonly employed to reduce or saturate
organic compounds.
Hydrogenation typically constitutes the addition of pairs
of hydrogen atoms to a molecule, often an alkene.
Catalysts are required for the reaction
non-catalytic hydrogenation takes place only at very high
temperatures.
Hydrogenation reduces double and triple bonds
in hydrocarbons
3. Hydrogenation
Hydrogenation reaction is basically a reduction
reaction
Various reduction reaction takes place. For example
reduction of alkenes, reduction of alkynes.
In hydrogenation H2 is added as reducing agents in
one of three ways.
4. 4
• There are three types of reductions differing in how H2 is
added.
• The simplest reducing agent is H2. Reductions using H2 are
carried out with a metal catalyst.
• A second way is to add two protons and two electrons to a
substrate—that is, H2 = 2H+ + 2e-.
Reductions of this sort use alkali metals as a source of
electrons, and liquid ammonia as a source of protons.
These are called dissolving metal reductions.
Reducing Agents
5. 5
• The third way to add H2 is to add hydride (H¯) and a proton
(H+).
• The most common hydride reducing agents contain a hydrogen
atom bonded to boron or aluminum. Simple examples include
sodium borohydride (NaBH4) and lithium aluminum hydride
(LiAlH4).
• NaBH4 and LiAlH4 deliver H¯ to the substrate, and then a
proton is added from H2O or an alcohol.
6. 6
• Reduction takes place by addition of H2 as a reducing agent.
• The addition of H2 occurs only in the presence of a metal catalyst, and
thus it is called catalytic hydrogenation.
• The catalyst consists of a metal—usually Pd, Pt, or Ni, adsorbed onto a
finely divided inert solid, such as charcoal.
• H2 adds in
a syn fashion.
Reduction of Alkenes—Catalytic Hydrogenation
7. 7
• The Ho of hydrogenation, also known as the heat of hydrogenation,
can be used as a measure of the relative stability of two different alkenes
that are hydrogenated to form the same alkane.
• When hydrogenation of two alkenes gives the same alkane, the more
stable alkene has the smaller heat of hydrogenation.
12. 12
• Palladium metal is too reactive to allow hydrogenation of an
alkyne to stop after one equivalent of H2 adds.
• To stop at a cis alkene, a less active Pd catalyst is used—Pd
adsorbed onto CaCO3 with added lead(II) acetate and quinoline.
This is called Lindlar’s catalyst.
• Compared to Pd metal, the Lindlar catalyst is deactivated or
“poisoned”.
• With the Lindlar catalyst, one equivalent of H2 adds to an alkyne
to form the cis product. The cis alkene product is unreactive to
further reduction.
Reduction of an Alkyne to a Cis Alkene
13. 13
• Reduction of an alkyne to a cis alkene is a stereoselective reaction,
because only one stereoisomer is formed.
14. 14
• In a dissolving metal reduction (such as Na in NH3), the elements
of H2 are added in an anti fashion to form a trans alkene.
Reduction of an Alkyne to a Trans Alkene
16. 16
Summary of Alkyne Reductions
Figure 12.5
Summary: Three methods to
reduce a triple bond
17. Thermodynamics and kinetics of
hydrogenation
Factors affect the hydrogenation reaction are;
• Temperature
• Pressure
• Catalyst surface
• Time
• Ratio of hydrogen to substance being hydrogenated
18. Temperature effect
For the most part, the temperature for hydrogenation
reactions is usually below 400°C, except in reactions where
pyrolytic decomposition occurs concurrently with the
hydrogenation reactions
Temperature is one of the most important variables
affecting a reaction
hydrogenation reaction can be reversed by increasing
temperature.
So hydrogenation reaction necessary occurs at low
temperature, where the reaction is satisfactory
Catalyst affect the speed and course of reaction, while
temperature affects the equilibrium, speed, path or course
of reaction.
19. Temperature effect
increasing temperature adversely affects the equilibrium
position,
so that the maximum ultimate yield is decreased;
but it affects favorably the speed of a reaction, so that in a
given time a greater quantity of product can be obtained.
Fortunately in recent years knowledge of catalysis is
extended so satisfactory reactions are possible at lower
temperature. Where more satisfactory equilibirium
position is prevailed.
In some cases increasing temperature has adverse effect on
catalyst,
so the catalyst activity decreases and resultant rate of
reaction decreases.
This type of case is known sintering of catalyst
20. Temperature effect
In general, the noble-metal catalysts, such as platinum
or palladium, are used from room temperatures to
150°C
catalysts of the nickel and copper type, from 150-
250°C
various combinations of metals and metal oxides, from
250-400°C.
21. Pressure effect
Pressure, like temperature, can affect the rate of
reaction.
The rate of reaction is generally increased by
increasing pressure, because a gas phase is usually
present, and increased pressure gives increased
concentration.
Pressure increases the equilibrium yield in a
hydrogenation reaction when there is a decrease in the
volume of the reaction as it proceeds.
This is the simple application of the mass-action law,
or Le Chatelier's principle.
22. Pressure effect
In general, however, increased pressure will result in
an increased reaction rate.
Thus, Brochet observed that phenol is hydrogenated
very slowly at 150°C at atmospheric pressure using a
nickel catalyst but that at 15 atm at the same
temperature the reaction was complete and rapid.
Armstrong reported hydrogenation of acetone to
isopropyl alcohol with identical batches of a copper
chromite catalyst and observed the following as shown
in table.
23. Pressure effect
EFFECT OF PRESSURE IN THE HYDROGENATION OF ACETONE
Pressure(atm) Conversion%
35 17
148 70
212 95
24. Catalyst surface
For the most part, hydrogenation catalysts are solids
consisting of metals and metal oxides
. The hydrogenation is effected at the surface of the
catalyst; so a highly extended surface is essential.
Taking a piece of bar nickel or copper and subdividing
it mechanically to pass, say, a 50-mesh sieve would not
produce an active nickel or copper catalyst.
Usually, the preparation of a catalyst is associated with
some chemical reaction whereby a highly extended,
porous, and honeycombed surface is produced so that
the density of the surface metal is far less than that of
the bulk metal.
25. Catalyst surface
Certain surface atoms may become so removed from other
adjoining ones that they may approach a gasified state, at
conditions far removed from the normal vaporization of the
metal.
These surface atoms, having varying degrees of unsaturation
compared with the bulk metal or metal oxide, will strongly
adsorb other substances with which they may come in
contact, and active catalysts usually have high absorptive
powers.
Although absorption is closely related to the successful
performance of a catalyst
Thus speed of a hydrogenation will depend on the type and
amount of active surface available. Increasing the ratio of
catalyst to the substance undergoing hydrogenation usually
increases the speed of the hydrogenation
26. Time
The time necessary for a hydrogenation reaction may
vary from a few seconds to several hours, depending
on the materials being hydrogenated, the catalyst, the
temperature, and the pressure.
In general, the more reactive the compound, the faster
the hydrogenation reaction.
Thus, simple aldehydes are hydrogenated very readily,
whereas the reduction of aromatic rings to saturated
cyclic compounds is a or of esters to alcohols is a
slower reaction.
27. Ratio of Hydrogen to the
Substances Being Hydrogenated
The ratio of hydrogen to the substance being
hydrogenated is conveniently expressed in terms of
partial pressures.
It frequently happens that the speed or path of a
certain hydrogenation can be affected by the
proportion of hydrogen to the substance
it has been found that ethyl lactate and malonate are
reduced to the corresponding alcohols in good yields
in a flow system at pressures of about 1,300 psig, where
practically the entire pressure is hydrogen and the
partial pressure of the esters is only a few centimeters.
28. Ratio of Hydrogen to the
Substances Being Hydrogenated
In the examples previously cited, the higher total
pressure was lessened, and a higher ratio of hydrogen
pressure to the partial pressure of the substance being
hydrogenated was employed.