This document discusses half-life for coordination complexes reactions. It describes that the half-life of a substance is the time it takes for its concentration to reduce to half of the initial value. There are two main types of coordination complex reactions: ligand substitution reactions, where one ligand is exchanged for another without changing the metal's oxidation state; and redox reactions, where electrons are transferred between complexes. Ligand substitution reaction rates can be used to determine if a complex is labile or inert based on whether its half-life is less than or greater than one minute. Some metal complexes like [99mTcO4]- have particular half-lives that make them useful in medical applications like imaging.