GreenDAO is an ORM (Object Relational Mapping) library that uses code generation to provide a faster alternative to reflection-based ORMs for Android. It works by mapping Java objects to SQLite database tables to allow for CRUD (create, read, update, delete) operations on the data. The library includes a schema definition and code generator that automatically generates DAO classes to manage database access and queries. This avoids the performance overhead of reflection and allows for compiler checks of the database schema.