The document discusses various nanofabrication techniques. Photolithography has limitations based on the optical diffraction limit. Electron beam lithography allows for higher resolution down to 5 nm but is slow and expensive. Soft lithography uses elastomeric stamps to transfer self-assembled monolayers in a parallel, low-cost manner via techniques like nanoimprint lithography and microcontact printing. Scanned probe techniques like atomic force microscopy and scanning tunneling microscopy can directly oxidize surfaces on the nanoscale.
Different types of Nanolithography technique.
Types: Electron beam lithography, Photolithography, electron-beam writing, ion- lithography, X-ray lithography, and related images, concepts and graphical views.
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Northwestern University Professor Chad Mirkin is the inventor of DiP-Pen Nanolithography. He is a world renowned nanoscience expert and is also a member of President Obama’s Council of Advisors for Science and Technology.
This presentation includes basis of lithography i.e. (photo-lithography e-beam lithography) in nano-lithography includes (AFM, Soft, NIL and DPN lithography)
Different types of Nanolithography technique.
Types: Electron beam lithography, Photolithography, electron-beam writing, ion- lithography, X-ray lithography, and related images, concepts and graphical views.
I hope this presentation helpful for you.
https://www.linkedin.com/in/preeti-choudhary-266414182/
https://www.instagram.com/chaudharypreeti1997/
https://www.facebook.com/profile.php?id=100013419194533
https://twitter.com/preetic27018281
Please like, share, comment and follow.
stay connected
If any query then contact:
chaudharypreeti1997@gmail.com
Thanking-You
Preeti Choudhary
Northwestern University Professor Chad Mirkin is the inventor of DiP-Pen Nanolithography. He is a world renowned nanoscience expert and is also a member of President Obama’s Council of Advisors for Science and Technology.
This presentation includes basis of lithography i.e. (photo-lithography e-beam lithography) in nano-lithography includes (AFM, Soft, NIL and DPN lithography)
Nanoimprint Lithography head points:
Approaches: thermal and UV NIL
Properties of NIL
Overview. of NIL
Thermal NIL resists.
Residual layer after NIL.
NIL for large features (more difficult than small one).
Room temperature NIL, reverse NIL, inking.
NIL of bulk resist (polymer sheet, pellets).
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https://www.instagram.com/chaudharypreeti1997/
https://www.facebook.com/profile.php?id=100013419194533
https://twitter.com/preetic27018281
Please like, share, comment and follow.
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If any query then contact:
chaudharypreeti1997@gmail.com
Thanking-You
Preeti Choudhary
Designing a low cost UV-Exposure System for Optical MicrolithographySushenDhali
Designing a low cost (about 52 $) UV-Exposure system for lithography and other UV-ray induced chemical reactions. These slides also describes detail process of photolithography.
Lithography is the process of transferring patterns of geometric shapes in a mask to a radiation sensitive material called resist,which cover the surface of semiconductor wafer.
Lecture on Introduction of Semiconductor at North South University as the undergraduate course (ETE411)
=======================
Dr. Mashiur Rahman
Assistant Professor
Dept. of Electrical Engineering and Computer Science
North South University, Dhaka, Bangladesh
http://mashiur.biggani.org
Nanoimprint Lithography head points:
Approaches: thermal and UV NIL
Properties of NIL
Overview. of NIL
Thermal NIL resists.
Residual layer after NIL.
NIL for large features (more difficult than small one).
Room temperature NIL, reverse NIL, inking.
NIL of bulk resist (polymer sheet, pellets).
https://www.linkedin.com/in/preeti-choudhary-266414182/
https://www.instagram.com/chaudharypreeti1997/
https://www.facebook.com/profile.php?id=100013419194533
https://twitter.com/preetic27018281
Please like, share, comment and follow.
stay connected
If any query then contact:
chaudharypreeti1997@gmail.com
Thanking-You
Preeti Choudhary
Designing a low cost UV-Exposure System for Optical MicrolithographySushenDhali
Designing a low cost (about 52 $) UV-Exposure system for lithography and other UV-ray induced chemical reactions. These slides also describes detail process of photolithography.
Lithography is the process of transferring patterns of geometric shapes in a mask to a radiation sensitive material called resist,which cover the surface of semiconductor wafer.
Lecture on Introduction of Semiconductor at North South University as the undergraduate course (ETE411)
=======================
Dr. Mashiur Rahman
Assistant Professor
Dept. of Electrical Engineering and Computer Science
North South University, Dhaka, Bangladesh
http://mashiur.biggani.org
Lecture on Introduction of Semiconductor at North South University as the undergraduate course (ETE411)
=======================
Dr. Mashiur Rahman
Assistant Professor
Dept. of Electrical Engineering and Computer Science
North South University, Dhaka, Bangladesh
http://mashiur.biggani.org
Lecture on Introduction of Semiconductor at North South University as the undergraduate course (ETE411)
=======================
Dr. Mashiur Rahman
Assistant Professor
Dept. of Electrical Engineering and Computer Science
North South University, Dhaka, Bangladesh
http://mashiur.biggani.org
A brief overview of the processes involved in nanolithography & nanopatterning. It mainly discusses the steps, mechanism & instrumentation of the electron beam lithography in detail. It also gives a small view on other technologies as well.
MODELING STUDY OF LASER BEAM SCATTERING BY DEFECTS ON SEMICONDUCTOR WAFERSjmicro
Accurate modeling of light scattering from nanometer scale defects on Silicon wafersiscritical for enabling
increasingly shrinking semiconductor technology nodes of the future. Yet, such modeling of defect
scattering remains unsolved since existing modeling techniques fail to account for complex defect and
wafer geometries. Here, we present results of laser beam scattering from spherical and ellipsoidal
particles located on the surface of a silicon wafer. A commercially available electromagnetic field solver
(HFSS) was deployed on a multiprocessor cluster to obtain results with previously unknown accuracy
down to light scattering intensity of -170 dB. We compute three dimensional scattering patterns of silicon
nanospheres located on a semiconductor wafer for both perpendicular and parallel polarization and show
the effect of sphere size on scattering. We further computer scattering patterns of nanometer scale
ellipsoidal particles having different orientation angles and unveil the effects of ellipsoidal orientation on
scattering.
MODELING STUDY OF LASER BEAM SCATTERING BY DEFECTS ON SEMICONDUCTOR WAFERSjmicro
Accurate modeling of light scattering from nanometer scale defects on Silicon wafersiscritical for enabling
increasingly shrinking semiconductor technology nodes of the future. Yet, such modeling of defect
scattering remains unsolved since existing modeling techniques fail to account for complex defect and
wafer geometries. Here, we present results of laser beam scattering from spherical and ellipsoidal
particles located on the surface of a silicon wafer. A commercially available electromagnetic field solver
(HFSS) was deployed on a multiprocessor cluster to obtain results with previously unknown accuracy
down to light scattering intensity of -170 dB. We compute three dimensional scattering patterns of silicon
nanospheres located on a semiconductor wafer for both perpendicular and parallel polarization and show
the effect of sphere size on scattering. We further computer scattering patterns of nanometer scale
ellipsoidal particles having different orientation angles and unveil the effects of ellipsoidal orientation on
scattering.
A Study of Pulse by Pulse Microscale Patch Transfer Using Picosecond LaserIJERA Editor
The shape restoring capability of Ti/Ni has potential to overcome the shrinkage of polymer in mould cavity, which has potential of solving the demoulding problems and helps dimension accuracy in micro/nano injection molding. However, the deposition of Ti/Ni film precisely and securely on specific location of the micro mould cavity present difficulties with conventional deposition methods. In this paper, the use of photonic impact forward transfer method to deposit Ti/Ni film patches on specific locations of a substrate is demonstrate using a picosecond laser. Pulse by pulse deposition control parameters affecting position accuracy and spot size were studied in this paper. It was found that although laser power, and distance between donor films and the substrate all influence the spot sizes of pulse by pulse deposited patches, adjusting spot size by changing laser power is better than changing distance due to separated particles being found around the deposited film patches. Results of this study proved the feasibility of depositing Ti/Ni film patches on specific location using pico-second laser with high position accuracy. The potential of using photonic impact forward transfer as a complementing method to laser powder 3D printing of difficult to process material to produce better surface quality microproducts such as micro moulds for micro-injection molding is tremendous.
2. Limitations of Photolithography Current photolithography techniques used in microelectronics manufacturing use a projection printing system (known as a stepper). In this system, the image of the mask is reduced and projected, via a high numerical aperture lens system, onto a thin film of photoresist that has been spin coated onto a wafer. The resolution that the stepper is capable of is based on optical diffraction limits set in the Rayleigh equation . In the Rayleigh equation, k1 is a constant that is dependent on the photoresist, λ is the wavelength of the light source, and NA is the numerical aperture of the lens. The minimum feature size that can be achieved with this technique is approximately the wavelength of the light used, λ; although theoretically, the lower limit is λ /2. So, in order to produce micro- or nanoscaled patterns and structures, light sources with shorter wavelengths must be used. This also makes manufacturing more difficult and expensive.
3. Nano Fabrication Electron Beam Lithography Soft Lithography Scanned Probe Techniques Self-Assembly and Template Manufacturing
4. Nano Fabrication Electron Beam Lithography Soft Lithography Scanned Probe Techniques Self-Assembly and Template Manufacturing
12. Suspended AuPd wires made by standard e-beam lithography and etching techniques. The inset is a blowup view of one of the wires. The scale bar is 1 micron.
13. SEM images of multi-layer line-array structures made of electron-beam sensitive polymers. These structure can serve as 3D photonic crystals (upper-left image) and quasi-3D suspending slab photonic crystals (lower-right image). The structures were fabricated by e-beam lithography with single- step 100keV-exposure, and multiple-development steps.
14. Scanning electron microscopy image of a regular and homogeneous assembly of GaAsnanowires. The nanowire growth is catalyzed by a 2D array of Au dots defined by e-beam lithography.
15. Electron BeamWrite An electron gun or electron source that supplies the electrons. An electron column that 'shapes' and focuses the electron beam. A mechanical stage that positions the wafer under the electron beam. A wafer handling system that automatically feeds wafers to the system and unloads them after processing. A computer system that controls the equipment.
16. Electron energy deposition in matter Electron trajectories in resist: An incident electron (purple) produces secondary electrons (blue). Sometimes, the incident electron may itself be backscattered as shown here and leave the surface of the resist (amber).
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18. Sensitivity (C/cm^2)PMMA has extremely high resolution, and its ultimate resolution has been demonstrated to be less than 10 nm. But its major problems are its relatively poor sensitivity, poor dry etch resistance, and moderate thermal stability. Electron beam exposure breaking the polymer into fragments Recent progress in electron-beam resists for advanced mask-making by D.R.Medeiros, A.Aviram, C.R.Guarnieri, W.S.Huang, R.Kwong, C.K.Magg, A.P.Mahorowala, W.M.Moreau, K.E.Petrillo, and M.Angelopoulos
19. Advantages High resolution down to 5 nm Useful design tool direct write allows for quick pattern changes (no masks are needed)
20. Limitation Cost (up to $6 –10 million for hardware) Direct write has low throughput slow and expensive E-beam lithography is not suitable for high-volume manufacturing because of its limited throughput. The serial nature of electron beam writing makes for very slow pattern generation compared with a parallel technique like photolithography (the current standard) in which the entire surface is patterned at once. To pattern a single wafer with an electron beam lithography system for sub-100 nm resolution, it would typically take days, compared to the few minutes it would take with a photolithography system. Currently an optical maskless lithographytool is much faster than an electron beam tool used at the same resolution for photomask patterning.
21. Nano Fabrication Electron Beam Lithography Soft Lithography Scanned Probe Techniques Self-Assembly and Template Manufacturing
23. Introduction Soft lithography is called ‘‘soft’’ because an elastomeric stamp or mold is the part that transfers patterns to the substrate and this method uses flexible organic molecules and materials rather than the rigid inorganic materials commonly used during the fabrication of microelectronic systems. This process, developed by George Whitesides, does not depend on a resist layer to transfer a pattern onto the substrate. Soft lithography can produce micropatterns of self-assembled monolayers (SAMs) through contact printing or form microstructures in materials through imprinting (embossing) or replica molding.
24. Nanoimprint lithography (NIL) Nanoimprint lithography (NIL) has primarily been used to emboss hard thermoplastic polymers. The micromolding and embossing of elastomers has attracted considerable interest as these materials have found important applications in softlithographic techniques such as microcontact printing (µCP). In this technique, a monolayer of a material is printed off an elastomeric stamp [made of poly(dimethylsiloxane) (PDMS)] after forming conformal contact between stamp and substrate. Sub-micron surface relief structures can easily be introduced in PDMS by curing the polymers against a lithographically prepared master. Feature sizes in the 10–100 nm size range. After imprinting the polymer film, further etching can transfer the pattern into the underlying substrate. Alternatively, metal evaporation and lift-off of the polymer mask produces nanopattern metal features.
25. Advantages Nanoimprint lithography (NIL) has the potential of high-throughput due to the parallel processing, does not require sophisticated tools, and allows nanoscale replication for data storage. NIL is also compatible with conventional device processing techniques. The quality of the nanoimprinting process depends on a number of experimental parameters like T, viscosity in the melt, adhesion of the polymer to the mold, etc.
29. Micro contact printing (μCP) Micro contact printing (or μCP) uses the relief patterns on a PDMS stamp to form patterns of self-assembled monolayers (SAMs) of inks on the surface of a substrate through conformal contact. Micro contact printing differs from other printing methods, like inkjet printing or 3D printing, in the use of self-assembly (especially, the use of SAMs) to form micro patterns and microstructures of various materials. The advantage of µCP is the ability to pattern surfaces chemically at the sub-micron level.
30. μCP process An elastomeric stamp is inked with small molecules (thiols or silanes) and pressed against a clean substrate (gold or silicon wafer). Where the stamp is in contact with the surface, a monolayer of material is transferred to the substrate. A second thiol or silane is used to fill in the background to provide a chemically patterned surface.
31. ODT from the solution settles down onto the PDMS stamp. Stamp now has ODT attached to it which acts as the ink. "Inking" a stamp. PDMS stamp with pattern is placed in Ethanol and ODT solution The PDMS stamp with the ODT is placed on the gold substrate. When the stamp is removed, the ODT in contact with the gold stays stuck to the gold. Thus the pattern from the stamp is transferred to the gold via the ODT "ink." Sarfus image of streptavidin deposited by soft lithography with PDMS stamp.
33. Nano Fabrication Electron Beam Lithography Soft Lithography Scanned Probe Techniques Self-Assembly and Template Manufacturing
34. Scanned Probe Techniques SPM systems are capable of controlling the movement of an atomically sharp tip in close proximity to or in contact with a surface with subnanometer accuracy. Scanning Probe Induced Oxidation Dip Pen Lithography
37. In 1993 it was demonstrated that local oxidation experiments could be performed with an atomic force microscope.Local oxidation nanolithography (LON) is sometimes called scanning probe oxidation, nano-oxidation, local anodic oxidation or generically AFM lithography.
38. Examples of local oxidation nanopatterns. (a) Periodic array of 10 nm silicon oxide dots. The lattice spacing is 40 nm. (b) Alternating insulating (bright) and semiconducting rings. (c) First paragraph of Don Quixote .
39. Scanning Probe Induced Oxidation Nanometer-scale local oxidation of various materials can be achieved using scanning probes operated in air and biased at a sufficiently high voltage. Tip bias of −2 to −10V is normally used with writing speeds of 0.1–100μm/s in an ambient humidity of 20–40%. It is believed that the water meniscus formed at the contact point serves as an electrolyte such that the biased tip anodically oxidizes a small region of the surface.
40. Scanning Probe Resist Exposure and Lithography Electrons emitted from a biased SPM tip can be used to expose a resist the same way e-beam lithography does. Various systems have been used for this lithographic technique. These include constant current STM, noncontact AFM, and AFM with constant tip-resist force and constant current.
41. Dip Pen Lithography Dip pen lithography is a type of scanning probe lithography. In this lithographic technique, the tip of an atomic force microscope (AFM) is used to create micro- and nanoscaled structures by depositing material onto a substrate. The AFMtip delivers the molecules to the substrate surface using a solvent meniscus that forms in ambient atmospheres. Structures with features ranging from several hundreds of nanometers to sub-50 nm can be generated using this technique
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45. This image was written using Dip-Pen Nanolithography, and imaged using lateral force microscopy mode of an atomic force microscope. Courtesy the Mirkin Group, Northwestern University. From "There's Plenty of Room at the Bottom" By Professor Richard P. Feynman, December 29th, 1959.
46. Nano Fabrication Electron Beam Lithography Soft Lithography Scanned Probe Techniques Self-Assembly and Template Manufacturing
47. Self-Assembly and Template Manufacturing Nanopatterning of self-assembled monolayers Template growth of organic and biological structures onto nanopatterns
48. Nanopatterning of self-assembled monolayers Self-assembly, chemical functionality and nanopatterning are concepts very akin to nanotechnology, so it is not surprising to discover various approaches to modify self-assembled monolayers or to induce a selective self assembly process by LON. Sugimura and co-workers pioneered the protocol to generated coplanar nanostructures consisting of two different types of self-assembled monolayers (SAM).
49. Scheme of the hierarchical self-assembled approach developed by Sagivet al. SAM on Si substrate. Patterned SAM by local oxidation of methyl terminated groups. and (d) Different steps in the formation of a second monolayer in the patterned region. The transformation of the vinyl-terminated overlayer in amino-terminated requires the reaction of NTS groups with formamide and its further reduction with BH3.THF.
50. Template growth of organic and biological structures onto nanopatterns Developing methods that allow the deposition of small functional molecules at pre-determined positions on a substrate is one of the exciting challenges for alternative nanolithographies. In this section we illustrate the potential of LON in this topic by describing three applications, fabrication of gold patterns and nanowires onto SAM templates, patterning of proteins (ferritin) and fabrication of conjugated molecular tracks and nanowires.
51. Template-guided self-assembly of gold nanoparticles on a organosilanebilayer template fabricated according to the scheme of (a) Template bilayer. (b) Deposition of water-soluble (Au-citrate) colloidal particles on amino-terminated template patterns. (c) Fabrication of gold electrodes and wires. (d) Patterning of a Picasso drawing. The patterning was carried out with a 800 × 800 raster-scanned points at 3.3 ms per point and by applying a tip-surface voltage of 8.5 V.