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Hazardous Materials for
    First Responders
         4th Edition

Chapter 1 — Introduction to
    Hazardous Materials
What is a Haz Mat ?

 Any material that possesses an unreasonable risk to
the health and safety of persons and/or environment if
not properly controlled during
handling, storage, manufacturing, processing, packagin
g, use, disposal, or transport.

When used as weapons – WMD

Millions of tons produced, stored and transported yearly


                           1–1
What makes a hazardous
     materials incident different?




  Click
image to
  play




                     1–2
REVIEW QUESTION




 How are hazardous materials incidents
 different from other types of
 emergencies?




                      1–3
First Responder Roles




               1–4
There are six levels of training
  according to NFPA® standards.




                                            Haz Mat      Haz Mat     Private
                          Haz Mat
Awareness   Operations                      Branch       Incident    Sector
                         Technician
                                             Officer   Commander    Specialist




                                      1–5
There are five levels of training
according to OSHA standards.




                                       Haz Mat     On Scene
                           Haz Mat
 Awareness   Operations                Branch       Incident
                          Technician
                                        Officer   Commander




                           1–6
First responder roles vary by
         training level.



 Click for
next slide




                        1–7
Health Hazards

• Chemicals can affect
  – One or more organs
  – An entire body system, such as the central
    nervous system




                     1–8
There are two main definitions
of hazardous exposure.


Acute               Chronic



        Acute                 Chronic
        health                health
        effects               effects

                  1–9
TRACEM

•   Thermal
•   Radiological
•   Asphyxiation
•   Chemical
•   Etiological
•   Mechanical



                   Haz Mat for First Responders
                               1–10
Thermal

• Temperature Extremes
   low temp.
   Elevated temp.




             Haz Mat for First Responders
                         1–11
Cold temperatures can present
unique dangers when working with
cryogenic and liquefied gases.


Liquefied
                        Cryogen
   gas

            Instantly
             freeze
            materials
                             (Continued)


               1–12
Cryogenic and liquefied gases
can boil into a much larger
vapor cloud.




               Courtesy of Steve Irby, Owasso Fire Department


               1–14
WARNING!

 Any clothing saturated with a cryogenic
 material may be removed immediately.
 This actions is particularly important if
 the vapors are flammable or oxidizers.
 A first responder could not escape
 flames from clothing-trapped vapors if
 they were to ignite.


                       1–15
Elevated temperature materials
can ignite flammable and
combustible materials.



             Require    Increase
 Examples    extreme      heat
             caution     effects




              1–16
The U.S. DOT definition of
         elevated-temperature material.



 Click for
next slide




                       1–17
Radiological Hazards
Radiological Hazards exist at
specific types of incidents.




               1–19
Types of Ionizing Radiation

• Alpha                     • Beta
  positive particle           + or – electron
  lose energy rapidly          from manufactured
  very harmful if           and natural sources
ingested or inhaled            less damaging than
  can be stopped by         alpha over same dist.
paper                          can be stopped by
                            clothing
                        Haz Mat
                         1–20
Types

 Gamma                                 Neutron
  high energy photons                   ultra high energy no
  natural and industrial               electrical charge
sources                                 fission reactions
  easily passes through the             labs and nuclear power
human body                             plants
  no protection with ppe,
needs 2ft of concrete, thick
earth or 2inches of lead
i.e x-ray
                         Haz Mat for First
                           Responders
                              1–21
Each type of ionizing radiation has
a different penetrating power.




               1–22
Exposure or Contamination

• Exposure                         • Contamination
 occurs while you are                material remains on
near a radiological                a person after coming
source and biological              into contact with
damage occurs                      material – can be
                                   external, internal or
                                   both


                    Haz Mat for First
                      Responders
                         1–23
Radiation Health Effects

• Acute dose                         • Chronic dose
   short term exposure                 small amounts over
   can be permissible                time
   most no health                       the body is better
effects                              equipped to handle
   others are deadly                 this type
 i.e. nuclear bomb                      can cause cancer


                     Haz Mat for First
                       Responders
                         1–24
Asphyxiation Hazards

• Two Classes
  Simple – Gases that replace oxygen

  Chemical – substances that prohibit the
body from using oxygen




                   1–25
Chemical Hazards

•   Toxicity of chemical
•   Route of exposure
•   Nature of exposure
•   Other factors i.e. age, health




                 Haz Mat for First Responders
                             1–26
Toxins

• Local
• Systemic




             Haz Mat for First Responders
                         1–27
Corrosives comprise the largest
usage class in the industry.




                             (Continued)


               1–28
Irritant

• Non-corrosive
• Causes irritation
  – Eyes
  – Respiratory tract
• Easily reversed by fresh air



                Haz Mat for First Responders
                            1–29
Convulsants

• Causes involuntary muscle movement
  death occurs from asphyxiation or
exhaustion




              Haz Mat for First Responders
                          1–30
Carcinogens

• Refers to a material with cancer-causing
  potential.
• Most commonly used category.
• Two categories
     –Known
       –52 chemicals
     –Suspected (majority)
       –176 chemicals
               Haz Mat for First Responders
                           1–31
Sensitizer/Allergens

• Causes an effect like an allergic reaction




               Haz Mat for First Responders
                           1–32
Etiological/Biological




                1–34
Microorganisms that may cause
                         severe, disabling disease or illness.
  Health Image Library
Courtesy of CDC Public




                                                             Courtesy of CDC Public
                                                               Health Image Library
                               Virus




                                                  Bacteria

                                Ricin

                                         1–35
Etiological

• Viruses - simplest microorganisms, can only replicate
  in a living host
• Bacteria – single celled, most do not cause disease,
  the ones that do invade tissue or produce toxins
• Rickettsia – specialized bacteria live in intestinal
  tracked of a host
• Biological – produced by living organisms, usually not
  harmful , altered by man as a weapon



                   Haz Mat for First Responders
                               1–36
Biological Hazards

• Found at: Med. Labs, human carriers,
  crime scenes, terrorist incidents
• Infectious diseases may or may not be
  contagious




              Haz Mat for First Responders
                          1–37
Biological Weapons

•   Ricin
•   Smallpox
•   Anthrax
•   Botulism




               Haz Mat for First Responders
                           1–38
Mechanical Hazards




           Haz Mat for First
             Responders

                1–39
Courtesy of U.S. Department of Defense,




                                            Click for
                                           next slide
 photo by Ken Drylle, civilian

                                                        hazards.




1–40
                                                        Explosions present specific
Mechanical Hazard

Four Hazards
• Shock Wave
• Shrapnel Fragmentation
• Seismic Effect
• Incendiary Thermal Effect



              Haz Mat for First Responders
                          1–41
Routes of Entry

CDC and NIOSH
Use three routes of entry.




                   1–43
Inhalation




             1–44
Ingestion




            1–46
Skin Contact




               1–47
Routes Of Entry

NYS and Others
 In place of skin contact use:
   Injection
   Absorption




                   1–49
Injection

• Body fluids.
• Most common exposure.
• Fluid pushed into skin by air.




               Haz Mat for First Responders
                           1–50
Absorption

• Entry is via skin, the body's largest
  organ.
• Skin absorption is relatively low when
  wearing PPE.
• Bunker gear slows absorption, but does
  not stop it.


               Haz Mat for First Responders
                           1–51
Haz Mat Regulations and
      Definitions
United States Haz-Mat
Regulations

• Department of Transportation (DOT)
• Environmental Protection Agency (EPA)
• Comprehensive, Environmental Response,
  Compensation and Liability Act (CERCLA)
• Superfund Amendments and
  Reauthorization Act (SARA)

                                    (Continued)


                  1–53
United States Haz-Mat
Regulations

• Environmental Planning and Community
  Right-to-Know Act (EPCRA)
• Resource Conservation and Recovery
  Act (RCRA)
• Toxic Substances Control Act (TSCA)
• Department of Labor (DOL)

                                    (Continued)


                  1–54
United States Haz-Mat
Regulations

• Nuclear Regulatory Commission (NRC)
• Department of Homeland Security
  (DHS)
• Consumer Product Safety Commission
  (CPSC)
• Department of Energy (DOE)
                                  (Continued)


                  1–56
United States Haz-Mat
Regulations

• Department of Defense Explosives
  Safety Board (DDESB), Department of
  Defense (DoD)
• Bureau of Alcohol, Tobacco, Firearms,
  and Explosives (ATF), Department of
  Treasury
• Department of Justice (DOJ)

                   1–57
Haz Mat Regulation Agencies

• Four main
 DOT
 EPA
 DOL (OSHA)
 NRC



              Haz Mat for First Responders
                          1–59
DOT

• Title 49 CFR – Hazardous Materials
 Regulations (HMR)- Transportation




              Haz Mat for First Responders
                          1–60
EPA




      Haz Mat for First
        Responders
           1–61
CERCLA (Superfund Act)

• Requirements for closed and abandoned waste site
• Liability of persons responsible for waste releases at
  these sites
• Trust fund for cleanup when responsible parties go
  unidentified
• Authorized 2 response actions
   1. Quick removal when prompt action is required
   2. long term actions to permanently remove or
reduce hazard


                   Haz Mat for First Responders
                               1–62
SARA

•   Stressed permanent remedies
•   New enforcement and settlement tools
•   Increased state involvement
•   Increased focus on human health problems
•   Encouraged citizen participation on site cleanup
•   Increased the size of trust fund




                     Haz Mat for First Responders
                                 1–63
EPCRA (Title III SARA)

• State Emergency Response Commission (SERC)
   Emergency Planning Districts
    Local Emergency Planning Committee (LEPC)




                 Haz Mat for First Responders
                             1–64
Resource Conservation and
Recovery Act (RCRA)

• Gave the EPA authority to control
 hazardous waste and hold parties
 accountable for what they produce
 (cradle to grave)




              Haz Mat for First Responders
                          1–65
DOL

• Created OSHA
• Created Title 29 CFR – HAZWOPER
 regulations and others




             Haz Mat for First Responders
                         1–66
NRC

• Regulates power plants as well as commercial and
  civilian use of nuclear material
• Dose limits for workers
• Monitoring and labeling of radioactive material
• Requirements for theft or loss




                   Haz Mat for First Responders
                               1–67
Other Agencies

• DOE – nuclear research and defense
• DHS – 3 missions; prevent terrorist attacks, reduce
    our vulnerability to attacks, minimize damage from
    potential attacks and natural disasters
•   Consumer Product Safety Commission (CPSC)
•   Department of Defense Explosives Safety Board
    (DDESB), Department of Defense (DOD)
•   ATF, Dept. of Treasury
•   DOJ


                    Haz Mat for First Responders
                                1–68
Canadian Regulations and
Definitions

•   Transport Canada (TC)
•   Environment Canada
•   Health Canada
•   Canadian Nuclear Safety Commission
    (CNSC)




                    1–69
Mexican Regulations and
Definitions

• Secretaría de Comunicaciones y
  Transportes (SCT)
• Secretaría de Medio Ambiente y
  Recursos Naturales (SEMARNAT)
• Secretaría del Trabajo y Previsión Social
  (STPS)



                    1–70
Hazardous Materials Incident
Statistics




              1–72
Hazardous materials incidents
         trends can be measured.(rt. click to play)




 Click for
next slide




                       1–73
DISCUSSION QUESTION




 Which mode of transportation is MOST
 likely to have a haz mat transportation
 incident?




                      1–74
Summary

• First responders must understand their
  roles and limitations at haz mat
  emergencies.
• Numerous government agencies and
  government regulations play important
  roles in how hazardous materials are
  manufactured, used, transported, and
  disposed of.                      (Continued)



                     1–75
Summary

• Haz mat incidents typically involve
 certain types of materials, but first
 responders must be prepared to deal
 with any emergencies.




                    1–76

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Chapter 01

  • 1. Hazardous Materials for First Responders 4th Edition Chapter 1 — Introduction to Hazardous Materials
  • 2. What is a Haz Mat ? Any material that possesses an unreasonable risk to the health and safety of persons and/or environment if not properly controlled during handling, storage, manufacturing, processing, packagin g, use, disposal, or transport. When used as weapons – WMD Millions of tons produced, stored and transported yearly 1–1
  • 3. What makes a hazardous materials incident different? Click image to play 1–2
  • 4. REVIEW QUESTION How are hazardous materials incidents different from other types of emergencies? 1–3
  • 6. There are six levels of training according to NFPA® standards. Haz Mat Haz Mat Private Haz Mat Awareness Operations Branch Incident Sector Technician Officer Commander Specialist 1–5
  • 7. There are five levels of training according to OSHA standards. Haz Mat On Scene Haz Mat Awareness Operations Branch Incident Technician Officer Commander 1–6
  • 8. First responder roles vary by training level. Click for next slide 1–7
  • 9. Health Hazards • Chemicals can affect – One or more organs – An entire body system, such as the central nervous system 1–8
  • 10. There are two main definitions of hazardous exposure. Acute Chronic Acute Chronic health health effects effects 1–9
  • 11. TRACEM • Thermal • Radiological • Asphyxiation • Chemical • Etiological • Mechanical Haz Mat for First Responders 1–10
  • 12. Thermal • Temperature Extremes low temp. Elevated temp. Haz Mat for First Responders 1–11
  • 13. Cold temperatures can present unique dangers when working with cryogenic and liquefied gases. Liquefied Cryogen gas Instantly freeze materials (Continued) 1–12
  • 14. Cryogenic and liquefied gases can boil into a much larger vapor cloud. Courtesy of Steve Irby, Owasso Fire Department 1–14
  • 15. WARNING! Any clothing saturated with a cryogenic material may be removed immediately. This actions is particularly important if the vapors are flammable or oxidizers. A first responder could not escape flames from clothing-trapped vapors if they were to ignite. 1–15
  • 16. Elevated temperature materials can ignite flammable and combustible materials. Require Increase Examples extreme heat caution effects 1–16
  • 17. The U.S. DOT definition of elevated-temperature material. Click for next slide 1–17
  • 19. Radiological Hazards exist at specific types of incidents. 1–19
  • 20. Types of Ionizing Radiation • Alpha • Beta positive particle + or – electron lose energy rapidly from manufactured very harmful if and natural sources ingested or inhaled less damaging than can be stopped by alpha over same dist. paper can be stopped by clothing Haz Mat 1–20
  • 21. Types Gamma Neutron high energy photons ultra high energy no natural and industrial electrical charge sources fission reactions easily passes through the labs and nuclear power human body plants no protection with ppe, needs 2ft of concrete, thick earth or 2inches of lead i.e x-ray Haz Mat for First Responders 1–21
  • 22. Each type of ionizing radiation has a different penetrating power. 1–22
  • 23. Exposure or Contamination • Exposure • Contamination occurs while you are material remains on near a radiological a person after coming source and biological into contact with damage occurs material – can be external, internal or both Haz Mat for First Responders 1–23
  • 24. Radiation Health Effects • Acute dose • Chronic dose short term exposure small amounts over can be permissible time most no health the body is better effects equipped to handle others are deadly this type i.e. nuclear bomb can cause cancer Haz Mat for First Responders 1–24
  • 25. Asphyxiation Hazards • Two Classes Simple – Gases that replace oxygen Chemical – substances that prohibit the body from using oxygen 1–25
  • 26. Chemical Hazards • Toxicity of chemical • Route of exposure • Nature of exposure • Other factors i.e. age, health Haz Mat for First Responders 1–26
  • 27. Toxins • Local • Systemic Haz Mat for First Responders 1–27
  • 28. Corrosives comprise the largest usage class in the industry. (Continued) 1–28
  • 29. Irritant • Non-corrosive • Causes irritation – Eyes – Respiratory tract • Easily reversed by fresh air Haz Mat for First Responders 1–29
  • 30. Convulsants • Causes involuntary muscle movement death occurs from asphyxiation or exhaustion Haz Mat for First Responders 1–30
  • 31. Carcinogens • Refers to a material with cancer-causing potential. • Most commonly used category. • Two categories –Known –52 chemicals –Suspected (majority) –176 chemicals Haz Mat for First Responders 1–31
  • 32. Sensitizer/Allergens • Causes an effect like an allergic reaction Haz Mat for First Responders 1–32
  • 34. Microorganisms that may cause severe, disabling disease or illness. Health Image Library Courtesy of CDC Public Courtesy of CDC Public Health Image Library Virus Bacteria Ricin 1–35
  • 35. Etiological • Viruses - simplest microorganisms, can only replicate in a living host • Bacteria – single celled, most do not cause disease, the ones that do invade tissue or produce toxins • Rickettsia – specialized bacteria live in intestinal tracked of a host • Biological – produced by living organisms, usually not harmful , altered by man as a weapon Haz Mat for First Responders 1–36
  • 36. Biological Hazards • Found at: Med. Labs, human carriers, crime scenes, terrorist incidents • Infectious diseases may or may not be contagious Haz Mat for First Responders 1–37
  • 37. Biological Weapons • Ricin • Smallpox • Anthrax • Botulism Haz Mat for First Responders 1–38
  • 38. Mechanical Hazards Haz Mat for First Responders 1–39
  • 39. Courtesy of U.S. Department of Defense, Click for next slide photo by Ken Drylle, civilian hazards. 1–40 Explosions present specific
  • 40. Mechanical Hazard Four Hazards • Shock Wave • Shrapnel Fragmentation • Seismic Effect • Incendiary Thermal Effect Haz Mat for First Responders 1–41
  • 41. Routes of Entry CDC and NIOSH Use three routes of entry. 1–43
  • 42. Inhalation 1–44
  • 43. Ingestion 1–46
  • 44. Skin Contact 1–47
  • 45. Routes Of Entry NYS and Others In place of skin contact use: Injection Absorption 1–49
  • 46. Injection • Body fluids. • Most common exposure. • Fluid pushed into skin by air. Haz Mat for First Responders 1–50
  • 47. Absorption • Entry is via skin, the body's largest organ. • Skin absorption is relatively low when wearing PPE. • Bunker gear slows absorption, but does not stop it. Haz Mat for First Responders 1–51
  • 48. Haz Mat Regulations and Definitions
  • 49. United States Haz-Mat Regulations • Department of Transportation (DOT) • Environmental Protection Agency (EPA) • Comprehensive, Environmental Response, Compensation and Liability Act (CERCLA) • Superfund Amendments and Reauthorization Act (SARA) (Continued) 1–53
  • 50. United States Haz-Mat Regulations • Environmental Planning and Community Right-to-Know Act (EPCRA) • Resource Conservation and Recovery Act (RCRA) • Toxic Substances Control Act (TSCA) • Department of Labor (DOL) (Continued) 1–54
  • 51. United States Haz-Mat Regulations • Nuclear Regulatory Commission (NRC) • Department of Homeland Security (DHS) • Consumer Product Safety Commission (CPSC) • Department of Energy (DOE) (Continued) 1–56
  • 52. United States Haz-Mat Regulations • Department of Defense Explosives Safety Board (DDESB), Department of Defense (DoD) • Bureau of Alcohol, Tobacco, Firearms, and Explosives (ATF), Department of Treasury • Department of Justice (DOJ) 1–57
  • 53. Haz Mat Regulation Agencies • Four main DOT EPA DOL (OSHA) NRC Haz Mat for First Responders 1–59
  • 54. DOT • Title 49 CFR – Hazardous Materials Regulations (HMR)- Transportation Haz Mat for First Responders 1–60
  • 55. EPA Haz Mat for First Responders 1–61
  • 56. CERCLA (Superfund Act) • Requirements for closed and abandoned waste site • Liability of persons responsible for waste releases at these sites • Trust fund for cleanup when responsible parties go unidentified • Authorized 2 response actions 1. Quick removal when prompt action is required 2. long term actions to permanently remove or reduce hazard Haz Mat for First Responders 1–62
  • 57. SARA • Stressed permanent remedies • New enforcement and settlement tools • Increased state involvement • Increased focus on human health problems • Encouraged citizen participation on site cleanup • Increased the size of trust fund Haz Mat for First Responders 1–63
  • 58. EPCRA (Title III SARA) • State Emergency Response Commission (SERC) Emergency Planning Districts Local Emergency Planning Committee (LEPC) Haz Mat for First Responders 1–64
  • 59. Resource Conservation and Recovery Act (RCRA) • Gave the EPA authority to control hazardous waste and hold parties accountable for what they produce (cradle to grave) Haz Mat for First Responders 1–65
  • 60. DOL • Created OSHA • Created Title 29 CFR – HAZWOPER regulations and others Haz Mat for First Responders 1–66
  • 61. NRC • Regulates power plants as well as commercial and civilian use of nuclear material • Dose limits for workers • Monitoring and labeling of radioactive material • Requirements for theft or loss Haz Mat for First Responders 1–67
  • 62. Other Agencies • DOE – nuclear research and defense • DHS – 3 missions; prevent terrorist attacks, reduce our vulnerability to attacks, minimize damage from potential attacks and natural disasters • Consumer Product Safety Commission (CPSC) • Department of Defense Explosives Safety Board (DDESB), Department of Defense (DOD) • ATF, Dept. of Treasury • DOJ Haz Mat for First Responders 1–68
  • 63. Canadian Regulations and Definitions • Transport Canada (TC) • Environment Canada • Health Canada • Canadian Nuclear Safety Commission (CNSC) 1–69
  • 64. Mexican Regulations and Definitions • Secretaría de Comunicaciones y Transportes (SCT) • Secretaría de Medio Ambiente y Recursos Naturales (SEMARNAT) • Secretaría del Trabajo y Previsión Social (STPS) 1–70
  • 66. Hazardous materials incidents trends can be measured.(rt. click to play) Click for next slide 1–73
  • 67. DISCUSSION QUESTION Which mode of transportation is MOST likely to have a haz mat transportation incident? 1–74
  • 68. Summary • First responders must understand their roles and limitations at haz mat emergencies. • Numerous government agencies and government regulations play important roles in how hazardous materials are manufactured, used, transported, and disposed of. (Continued) 1–75
  • 69. Summary • Haz mat incidents typically involve certain types of materials, but first responders must be prepared to deal with any emergencies. 1–76