Carbohydrates




AP Biology
CH2OH

                     H           O
                                         H
                         H
                         OH      H
                    HO                   OH

                         H        OH



             Carbohydrates
                 energy
                molecules


AP Biology                   2006-2007
Carbohydrates
     Carbohydrates are composed of C, H, O
                       carbo - hydr - ate
                            CH2O
                    (CH2O)x
                      (CH O)      C C6H12O6
                                    HO
                            2   x       6   12   6

      Function:
          energy                     energy storage
          raw materials              structural materials
      Monomer: sugars
      ex: sugars, starches, cellulose
AP Biology   sugar sugar sugar sugar sugar sugar sugar sugar
Sugars
     Most names for sugars end in -ose
     Classified by number of carbons
            6C = hexose (glucose)
            5C = pentose (ribose)

            3C = triose (glyceraldehyde)              H       O
               CH2OH          CH2OH                        C

       H           O                   O        H     H    C    OH
                        H
             H
             OH   6H              H   5    HO                  3OH
     HO                 OH   HO                 H     H    C

             H     OH             OH       H               H
AP Biology   Glucose              Ribose            Glyceraldehyde
Functional groups determine function


   carbonyl

   aldehyde




   carbonyl
   ketone

AP Biology
Sugar structure
    5C & 6C sugars form rings in solution




                Where do
             you find solutions
                in biology?
                  In cells!
AP Biology
                                  Carbons are numbered
Numbered carbons
                         C 6'
                      5' C      O


               4' C                   C1'
             energy stored in C-C bonds
                       C3'      C2'
AP Biology
CH2OH

   Simple & complex sugars                                        H         O
                                                                                 H
                                                                       H
     Monosaccharides                                            HO
                                                                       OH   H
                                                                                 OH
          simple 1 monomer sugars                                     H    OH
          glucose
                                                                      Glucose
      Disaccharides
          2 monomers
          sucrose

      Polysaccharides
          large polymers
          starch                      QuickTime™ and a
                            TIFF (Uncompressed) decompressor
                               are needed to see this picture.




AP Biology
Building sugars
     Dehydration synthesis
        monosaccharides           disaccharide




                 H2O
          |               |               |
       glucose         glucose        maltose
                                 glycosidic linkage



AP Biology
Building sugars
     Dehydration synthesis
                                                                QuickTime™ and a
                                                     TIFF (Uncompressed) decompressor
                                                        are needed to see this picture.




        monosaccharides              disaccharide




                    H2O
          |                   |             |
       glucose            fructose      sucrose
                                     (table sugar)


             Let’s go to the
               videotape!
AP Biology
Polysaccharides
    Polymers of sugars
         costs little energy to build
         easily reversible = release energy

     Function:
            energy storage                          QuickTime™ and a
                                          TIFF (Uncompressed) decompressor
                                             are needed to see this picture.




               starch (plants)
               glycogen (animals)
                   in liver & muscles
             structure
                                                                                          QuickTime™ and a
                                                                               TIFF (Uncompressed) decompressor



        
                                                                                  are needed to see this picture.




               cellulose (plants)
               chitin (arthropods & fungi)
AP Biology
Linear vs. branched polysaccharides
     slow release


      starch
      (plant)

                                      What does
    energy                          branching do?
    storage


    glycogen
    (animal)
                        Let’s go to the
      fast
AP Biology   release      videotape!
Polysaccharide diversity
     Molecular structure determines function
             in starch           in cellulose




          isomers of glucose
          structure determines function…
AP Biology
Digesting starch vs. cellulose

 starch
 easy to
 digest                       enzyme



cellulose
hard to
digest
                              enzyme

AP Biology
Cellulose
    Most abundant organic
      compound on Earth
        herbivores have evolved a mechanism to
         digest cellulose
        most carnivores have not

              that’s why they
               eat meat to get
               their energy &
               nutrients
              cellulose = undigestible roughage
                But it tastes
                   like hay!
                Who can live
AP Biology     on this stuff?!
Cow
                     can digest cellulose well;
                     no need to eat other sugars

                  Gorilla
                     can’t digest cellulose well;
                     must add another sugar
                     source, like fruit to diet




Regents Biology
Helpful bacteria
      How can herbivores digest cellulose so well?
            BACTERIA live in their digestive systems & help digest
             cellulose-rich (grass) meals




                                                                     QuickTime™ and a
                                                          TIFF (Uncompressed) decompressor
                                                             are needed to see this picture.




                                                        Caprophage

                                        Tell I eat
                                             me about                                QuickTime™ and a
                                                                          TIFF (Uncompressed) decompressor



                                         the rabbits,
                                                                             are needed to see this picture.




Ruminants
Regents Biology
                                         WHAT     !
                                       again, George!
EAT
                         X
                  Let’s build some

             Carbohydrates!




Regents Biology                      2006-2007

Carbs

  • 1.
  • 2.
    CH2OH H O H H OH H HO OH H OH Carbohydrates energy molecules AP Biology 2006-2007
  • 3.
    Carbohydrates  Carbohydrates are composed of C, H, O carbo - hydr - ate CH2O (CH2O)x (CH O) C C6H12O6 HO 2 x 6 12 6  Function:  energy energy storage  raw materials structural materials  Monomer: sugars  ex: sugars, starches, cellulose AP Biology sugar sugar sugar sugar sugar sugar sugar sugar
  • 4.
    Sugars  Most names for sugars end in -ose  Classified by number of carbons  6C = hexose (glucose)  5C = pentose (ribose)  3C = triose (glyceraldehyde) H O CH2OH CH2OH C H O O H H C OH H H OH 6H H 5 HO 3OH HO OH HO H H C H OH OH H H AP Biology Glucose Ribose Glyceraldehyde
  • 5.
    Functional groups determinefunction carbonyl aldehyde carbonyl ketone AP Biology
  • 6.
    Sugar structure 5C & 6C sugars form rings in solution Where do you find solutions in biology? In cells! AP Biology Carbons are numbered
  • 7.
    Numbered carbons C 6' 5' C O 4' C C1' energy stored in C-C bonds C3' C2' AP Biology
  • 8.
    CH2OH Simple & complex sugars H O H H  Monosaccharides HO OH H OH  simple 1 monomer sugars H OH  glucose Glucose  Disaccharides  2 monomers  sucrose  Polysaccharides  large polymers  starch QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. AP Biology
  • 9.
    Building sugars  Dehydration synthesis monosaccharides disaccharide H2O | | | glucose glucose maltose glycosidic linkage AP Biology
  • 10.
    Building sugars  Dehydration synthesis QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. monosaccharides disaccharide H2O | | | glucose fructose sucrose (table sugar) Let’s go to the videotape! AP Biology
  • 11.
    Polysaccharides  Polymers of sugars  costs little energy to build  easily reversible = release energy  Function:  energy storage QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture.  starch (plants)  glycogen (animals)  in liver & muscles structure QuickTime™ and a TIFF (Uncompressed) decompressor  are needed to see this picture.  cellulose (plants)  chitin (arthropods & fungi) AP Biology
  • 12.
    Linear vs. branchedpolysaccharides slow release starch (plant) What does energy branching do? storage glycogen (animal) Let’s go to the fast AP Biology release videotape!
  • 13.
    Polysaccharide diversity  Molecular structure determines function in starch in cellulose  isomers of glucose  structure determines function… AP Biology
  • 14.
    Digesting starch vs.cellulose starch easy to digest enzyme cellulose hard to digest enzyme AP Biology
  • 15.
    Cellulose  Most abundant organic compound on Earth  herbivores have evolved a mechanism to digest cellulose  most carnivores have not  that’s why they eat meat to get their energy & nutrients  cellulose = undigestible roughage But it tastes like hay! Who can live AP Biology on this stuff?!
  • 16.
    Cow can digest cellulose well; no need to eat other sugars Gorilla can’t digest cellulose well; must add another sugar source, like fruit to diet Regents Biology
  • 17.
    Helpful bacteria  How can herbivores digest cellulose so well?  BACTERIA live in their digestive systems & help digest cellulose-rich (grass) meals QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. Caprophage Tell I eat me about QuickTime™ and a TIFF (Uncompressed) decompressor the rabbits, are needed to see this picture. Ruminants Regents Biology WHAT ! again, George!
  • 18.
    EAT X Let’s build some Carbohydrates! Regents Biology 2006-2007

Editor's Notes

  • #4 carb = carbon hydr = hydrogen ate = oxygen compound
  • #10 maltose
  • #11 sucrose = table sugar
  • #12 Polysaccharides are polymers of hundreds to thousands of monosaccharides
  • #13 Can you see the difference between starch & glycogen? Which is easier to digest? Glycogen = many branches = many ends Enzyme can digest at multiple ends. Animals use glycogen for energy storage == want rapid release. Form follows function. APBio/TOPICS/Biochemistry/MoviesAP/05_07Polysaccharides_A.swf
  • #15 Starch = all the glycosidic linkage are on same side = molecule lies flat Cellulose = cross linking between OH (H bonds) = rigid structure
  • #16 Cross-linking between polysaccharide chains: = rigid & hard to digest The digestion of cellulose governs the life strategy of herbivores. Either you do it really well and you’re a cow or an elephant (spend a long time digesting a lot of food with a little help from some microbes & have to walk around slowly for a long time carrying a lot of food in your stomach) Or you do it inefficiently and have to supplement your diet with simple sugars, like fruit and nectar, and you’re a gorilla.
  • #17 The digestion of cellulose governs the life strategy of herbivores. Either you do it really well and you’re a cow or an elephant (spend a long time digesting a lot of food with a little help from some microbes & have to walk around slowly for a long time carrying a lot of food in your stomach) Or you do it inefficiently and have to supplement your diet with simple sugars, like fruit and nectar, and you’re a gorilla. APBioTOPICS/20Biochemistry/MoviesAP/Macromolecule-Lifewire.swf