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Introduction
 Rubber is an example of an elastomer type polymer,
where the polymer has the ability to return to its original
shape after being stretched or deformed.
 The rubber polymer is coiled when in the resting state.
 The elastic properties arise from the its ability to stretch
the chains apart, but when the tension is released the
chains snap back to the original position.
 The majority of rubber polymer molecules contain at least
some units derived from conjugated diene monomers.
 Such conjugated diene monomers have a constructive
backbone of at least four carbon atoms with a double-
single-double bond reactive core (C=C-C=C ).
Types of Rubber
Types
of
Rubber
Natural
Rubber
Synthetic
Rubber
NATURAL RUBBER
 Natural rubber is an addition polymer
that is obtained as a milky white fluid
known as latex from a tropical rubber
tree.
 Natural rubber is from the monomer
isoprene (2-methyl-1,3-butadiene),
which is a conjugated diene
hydrocarbon .
 It comes from latex.
 Names of the Trees: Hevea Brasiliensis
and Castilloa elástica.
 Elastic, water repellent and electric
resistent.
NATURAL RUBBER
HISTORY
 Discovered by the mayans and aztecs.
 Banned in the 15th century.
 La Condamine rediscovered it in 1735.
 It was a success in Europe.
 In 1791 it was first commercialized.
NATURAL RUBBER
RECYCLING
 Different processes to recycle it.
 Very flammable.
 It creates pollution.
 Cause of diseases.
 E.g: Rubber floors for parks.
NATURAL RUBBER
USES
 Tires.
 Wheel rims.
 Hoses.
 Conveyor belt.
SYNTHETIC RUBBER
DESCRIPTION
• Artificial elastomer:Important conjugated dienes used in
synthetic rubbers include isoprene (2-methyl-1,3-
butadiene), 1,3-butadiene.
• Polymerized 1,3-butadiene is mostly referred to simply as
polybutadiene. Polymerized chloroprene was developed
by DuPont and given the trade name Neoprene.
 Obtained mainly from petroleum.
• Elastic material.
• Good qualities and cheap.
• It is recyclable.
SYNTHETIC RUBBER
HISTORY
• Created in 1909 by Fritz Hofmann.
• Similar structure to natural rubber.
• People were very pleased.
• Cheaper than natural rubber.
• 2/3 of today’s rubber is synthetic.
SYNTHETIC RUBBER
PROPERTIES
• Solid, flexible, durable.
• It hardens when it’s cooled.
• It can be molded when heated.
• Resistant to heat, light and
chemicals.
• Heat and electrical insulator.
SYNTHETIC RUBBER
USES
• Car tires.
• Flexible rubber toys.
• Paint.
• Shoe soles.
• Rubber gloves.
• Tubes and hoses.
Neoprene:A Synthetic rubber
Properties
 Synthetic rubber.
 It’s produced by polymerization of chloroprene.
 It has good chemical stability.
 Flexible over a wide temperature range.
 It is colourless.
 Resistant to sun, climate and ozone deterioration.
Neoprene
HISTORY
 It was invented by DuPont scientist (1930).
 First name: DuPrene.
 It smelled bad and was expensive.
 Problems were solved and was a success.
 It name was changed to neoprene.
NEOPRENE
RECLYCLING
 Waste burying techniques.
 Incineration.
 Some brands do recycling processes.
 Using old neoprene to create shoes, t-shirts…
NEOPRENE
USES
 Laptop sleeves
 Wetsuits
 Small boats
 Boots
2
References
1.A text book of engineering Chemistry by shashi Chawla
2.https://www.Google.com
3. Engineering Chemistry by Jain and Jain

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B.tech. ii engineering chemistry unit 3 B rubber

  • 1.
  • 2. Introduction  Rubber is an example of an elastomer type polymer, where the polymer has the ability to return to its original shape after being stretched or deformed.  The rubber polymer is coiled when in the resting state.  The elastic properties arise from the its ability to stretch the chains apart, but when the tension is released the chains snap back to the original position.
  • 3.  The majority of rubber polymer molecules contain at least some units derived from conjugated diene monomers.  Such conjugated diene monomers have a constructive backbone of at least four carbon atoms with a double- single-double bond reactive core (C=C-C=C ).
  • 5. NATURAL RUBBER  Natural rubber is an addition polymer that is obtained as a milky white fluid known as latex from a tropical rubber tree.  Natural rubber is from the monomer isoprene (2-methyl-1,3-butadiene), which is a conjugated diene hydrocarbon .  It comes from latex.  Names of the Trees: Hevea Brasiliensis and Castilloa elástica.  Elastic, water repellent and electric resistent.
  • 6. NATURAL RUBBER HISTORY  Discovered by the mayans and aztecs.  Banned in the 15th century.  La Condamine rediscovered it in 1735.  It was a success in Europe.  In 1791 it was first commercialized.
  • 7. NATURAL RUBBER RECYCLING  Different processes to recycle it.  Very flammable.  It creates pollution.  Cause of diseases.  E.g: Rubber floors for parks.
  • 8. NATURAL RUBBER USES  Tires.  Wheel rims.  Hoses.  Conveyor belt.
  • 9. SYNTHETIC RUBBER DESCRIPTION • Artificial elastomer:Important conjugated dienes used in synthetic rubbers include isoprene (2-methyl-1,3- butadiene), 1,3-butadiene. • Polymerized 1,3-butadiene is mostly referred to simply as polybutadiene. Polymerized chloroprene was developed by DuPont and given the trade name Neoprene.
  • 10.  Obtained mainly from petroleum. • Elastic material. • Good qualities and cheap. • It is recyclable.
  • 11. SYNTHETIC RUBBER HISTORY • Created in 1909 by Fritz Hofmann. • Similar structure to natural rubber. • People were very pleased. • Cheaper than natural rubber. • 2/3 of today’s rubber is synthetic.
  • 12. SYNTHETIC RUBBER PROPERTIES • Solid, flexible, durable. • It hardens when it’s cooled. • It can be molded when heated. • Resistant to heat, light and chemicals. • Heat and electrical insulator.
  • 13. SYNTHETIC RUBBER USES • Car tires. • Flexible rubber toys. • Paint. • Shoe soles. • Rubber gloves. • Tubes and hoses.
  • 14. Neoprene:A Synthetic rubber Properties  Synthetic rubber.  It’s produced by polymerization of chloroprene.  It has good chemical stability.  Flexible over a wide temperature range.  It is colourless.  Resistant to sun, climate and ozone deterioration.
  • 15. Neoprene HISTORY  It was invented by DuPont scientist (1930).  First name: DuPrene.  It smelled bad and was expensive.  Problems were solved and was a success.  It name was changed to neoprene.
  • 16. NEOPRENE RECLYCLING  Waste burying techniques.  Incineration.  Some brands do recycling processes.  Using old neoprene to create shoes, t-shirts…
  • 17. NEOPRENE USES  Laptop sleeves  Wetsuits  Small boats  Boots 2
  • 18. References 1.A text book of engineering Chemistry by shashi Chawla 2.https://www.Google.com 3. Engineering Chemistry by Jain and Jain