In this study, the improvement in mechanical properties and abrasion resistance of natural rubber/bromobutyl rubber (NR/BIIR) blends were investigated when using different types of layered silicates as secondary fillers. Moreover, the effects of organophillic surface treatments and their synergistic effects with ENR compatibilizer were also studied. These fillers include montmorillonite clay, kaolin, bleaching clay, and talcum. We found that the secondary fillers could improve the properties of the rubber composites differently. Bleaching clay contributed to a dramatic increase in crosslink density, which could also increase the modulus and hardness of the composite. Montmorillonite clay could provide dramatic increase in abrasion resistance with low compression set, while kaolin was excellent in terms of tensile strength. With organophillic surface treatments, the silane-treated kaolin led to dramatic improvement in all aspects. Conversely, montmorillonite clay treated with octadecylamine contributed to significantly higher modulus and hardness, while losing its abrasion resistance and resilience. These results were opposite for bleaching clay. In this case, even though the composites of silane-treated kaolin obtained improved abrasion resistance and lower compression set, they suffered the drop in crosslink density, modulus, hardness and tensile strength.
Effect of Nanoclay on the Structure and Properties of High Density Polyethyle...iosrjce
In this study we prepared high density polyethylene (HDPE)/ clay nanocomposites by melt
compounding in a twin screw extruder with rotational speed of 50rpm and the temperatures of the zones are set
to 180-210°C.Different screw configuration have been used to study the effect of screw elements on the
properties of nanocomposites. screw configuration changed from dispersive to distributive type. Cloisite 15A
was used as the filler and weight percent of clay was fixed to 3wt%. Maleated polyethylene grafted polyolefins
supplied from Reliance ltd. A new combination of maleic anhydride grafted polyethylene prepared in our lab
through grafting also taken as compatibilizer.the samples were then characterized by XRD,FTIR and DSC. The
results showed that PE/clay nanocomposites provide better exfoliation with high dispersive screw
configuration. The addition of clay also increased the dispersion and crystallinity of the composite. The clay
particles helped the nanocomposites to develop toruos path that prevent the leakage of gas through it.
Rheological results indicated an increase in the viscosity with the addition of nano clay to PE. wide angle x-ray
diffraction shows the better exfoliation of nano particle clays in the polymer matrix. The mechanical, thermal
and rheological characteristics were measured by using differential scanning calorimetry (DSC), X-ray
diffraction (XRD). XRD indicates that Compatibilizer –nanoclay ratio plays an important role in the exfoliation
of clay in the polyethylene.
Effect of Nanoclay on the Structure and Properties of High Density Polyethyle...iosrjce
In this study we prepared high density polyethylene (HDPE)/ clay nanocomposites by melt
compounding in a twin screw extruder with rotational speed of 50rpm and the temperatures of the zones are set
to 180-210°C.Different screw configuration have been used to study the effect of screw elements on the
properties of nanocomposites. screw configuration changed from dispersive to distributive type. Cloisite 15A
was used as the filler and weight percent of clay was fixed to 3wt%. Maleated polyethylene grafted polyolefins
supplied from Reliance ltd. A new combination of maleic anhydride grafted polyethylene prepared in our lab
through grafting also taken as compatibilizer.the samples were then characterized by XRD,FTIR and DSC. The
results showed that PE/clay nanocomposites provide better exfoliation with high dispersive screw
configuration. The addition of clay also increased the dispersion and crystallinity of the composite. The clay
particles helped the nanocomposites to develop toruos path that prevent the leakage of gas through it.
Rheological results indicated an increase in the viscosity with the addition of nano clay to PE. wide angle x-ray
diffraction shows the better exfoliation of nano particle clays in the polymer matrix. The mechanical, thermal
and rheological characteristics were measured by using differential scanning calorimetry (DSC), X-ray
diffraction (XRD). XRD indicates that Compatibilizer –nanoclay ratio plays an important role in the exfoliation
of clay in the polyethylene.
Dental composite /certified fixed orthodontic courses by Indian dental academy Indian dental academy
The Indian Dental Academy is the Leader in continuing dental education , training dentists in all aspects of dentistry and offering a wide range of dental certified courses in different formats.
EXPERIMENTAL STUDY OF STRENGTH BEHAVIOUR ON CEMENT MORTAR Chandan Kumar.D
EXPERIMENTAL STUDY OF STRENGTH BEHAVIOUR ON CEMENT MORTAR BY PARTIAL REPLACEMENT OF CEMENT WITH GRANITE WASTE, ALUMINIUM HYDROXIDE AND FULLY REPLACEMENT OF FINE AGGREGATE BY CRUSHED STONE DUST
A Literature Review on the Role of Zycotherm as an Additive used in Bitumenijtsrd
Water is one of the prominent damaging elements in asphalt pavement due to its enormous detrimental effects on pavement performance. Moisture damage induced by the actions of water reduces the strength as well as durability of asphalt mixtures, tends to cause various types of distress such as potholes, stripping, and others to the pavement, formed by lack of cohesion and adhesion. To sort out this problem, the modification of bitumen is needed to enhance its properties for pavement surface. Ergo, the current paper introduces the findings of prior research studies on Zycotherms effect as an anti stripping agent, recently developed, chemically reactive nanomaterial that imparts strength to the surface of the pavement. In this study, optimum bitumen content by Marshal Mix Design, without and with necessary dosages of Zycotherm upgraded from Zycosoil and alterations in properties are reported through various tests. Dr. Maninder Singh | Dr. Kunal Jain | Sukhjinder Singh Kahlon "A Literature Review on the Role of Zycotherm as an Additive used in Bitumen" Published in International Journal of Trend in Scientific Research and Development (ijtsrd), ISSN: 2456-6470, Volume-4 | Issue-6 , October 2020, URL: https://www.ijtsrd.com/papers/ijtsrd33650.pdf Paper Url: https://www.ijtsrd.com/engineering/transport-engineering/33650/a-literature-review-on-the-role-of-zycotherm-as-an-additive-used-in-bitumen/dr-maninder-singh
IJERA (International journal of Engineering Research and Applications) is International online, ... peer reviewed journal. For more detail or submit your article, please visit www.ijera.com
The Indian Dental Academy is the Leader in continuing dental education , training dentists in all aspects of dentistry and
offering a wide range of dental certified courses in different formats.for more details please visit
www.indiandentalacademy.com
The Influence of Partial Replacement of Some Selected Pozzolans on the Drying...Scientific Review SR
Concrete is prone to cracking and one of the major causes of cracking is drying shrinkage of the hardened concrete. This research work was carried out to study the influence of partial replacement of some selected pozzolans on the drying shrinkage of concrete. Four pozzolans used in this study, were made to replace cement at various percentages resulting in various concrete mixes. Setting time test was conducted for the various cement mixes using Vicat’s apparatus and drying shrinkage test was done for the concrete test specimens. The results of the setting time indicate that partial replacement of pozzolans with ordinary Portland cement increases both the initial and final setting time of cement as the percentage replacement increases. Similarly, drying shrinkage results show that concrete made with Groundnut Shell Ash (GSA) and Locust Bean Pod Ash (LBA) at 12% replacement will have a stable and better shrinkage resistance than the control at both 56 days and 90 days. Meanwhile, the control concrete gives a better drying shrinkage at 28 days curing. In conclusion, the results show that pozzolanas [Bamboo Leaves Ash (BLA), Locust Bean Pod Ash (LBA), Sugarcane Bagasse Ash (SBA) and Groundnut Shell Ash (GSA)] can successfully replace cement up to 12% without necessarily affecting the shrinkage ability of the produced concrete. It also shows that Groundnut Shell Ash (GSA), Locust Bean Pod Ash (LBA) and Bamboo Leaves Ash (BLA) are more resistance to drying shrinkage than the control.
Dental composite /certified fixed orthodontic courses by Indian dental academy Indian dental academy
The Indian Dental Academy is the Leader in continuing dental education , training dentists in all aspects of dentistry and offering a wide range of dental certified courses in different formats.
EXPERIMENTAL STUDY OF STRENGTH BEHAVIOUR ON CEMENT MORTAR Chandan Kumar.D
EXPERIMENTAL STUDY OF STRENGTH BEHAVIOUR ON CEMENT MORTAR BY PARTIAL REPLACEMENT OF CEMENT WITH GRANITE WASTE, ALUMINIUM HYDROXIDE AND FULLY REPLACEMENT OF FINE AGGREGATE BY CRUSHED STONE DUST
A Literature Review on the Role of Zycotherm as an Additive used in Bitumenijtsrd
Water is one of the prominent damaging elements in asphalt pavement due to its enormous detrimental effects on pavement performance. Moisture damage induced by the actions of water reduces the strength as well as durability of asphalt mixtures, tends to cause various types of distress such as potholes, stripping, and others to the pavement, formed by lack of cohesion and adhesion. To sort out this problem, the modification of bitumen is needed to enhance its properties for pavement surface. Ergo, the current paper introduces the findings of prior research studies on Zycotherms effect as an anti stripping agent, recently developed, chemically reactive nanomaterial that imparts strength to the surface of the pavement. In this study, optimum bitumen content by Marshal Mix Design, without and with necessary dosages of Zycotherm upgraded from Zycosoil and alterations in properties are reported through various tests. Dr. Maninder Singh | Dr. Kunal Jain | Sukhjinder Singh Kahlon "A Literature Review on the Role of Zycotherm as an Additive used in Bitumen" Published in International Journal of Trend in Scientific Research and Development (ijtsrd), ISSN: 2456-6470, Volume-4 | Issue-6 , October 2020, URL: https://www.ijtsrd.com/papers/ijtsrd33650.pdf Paper Url: https://www.ijtsrd.com/engineering/transport-engineering/33650/a-literature-review-on-the-role-of-zycotherm-as-an-additive-used-in-bitumen/dr-maninder-singh
IJERA (International journal of Engineering Research and Applications) is International online, ... peer reviewed journal. For more detail or submit your article, please visit www.ijera.com
The Indian Dental Academy is the Leader in continuing dental education , training dentists in all aspects of dentistry and
offering a wide range of dental certified courses in different formats.for more details please visit
www.indiandentalacademy.com
The Influence of Partial Replacement of Some Selected Pozzolans on the Drying...Scientific Review SR
Concrete is prone to cracking and one of the major causes of cracking is drying shrinkage of the hardened concrete. This research work was carried out to study the influence of partial replacement of some selected pozzolans on the drying shrinkage of concrete. Four pozzolans used in this study, were made to replace cement at various percentages resulting in various concrete mixes. Setting time test was conducted for the various cement mixes using Vicat’s apparatus and drying shrinkage test was done for the concrete test specimens. The results of the setting time indicate that partial replacement of pozzolans with ordinary Portland cement increases both the initial and final setting time of cement as the percentage replacement increases. Similarly, drying shrinkage results show that concrete made with Groundnut Shell Ash (GSA) and Locust Bean Pod Ash (LBA) at 12% replacement will have a stable and better shrinkage resistance than the control at both 56 days and 90 days. Meanwhile, the control concrete gives a better drying shrinkage at 28 days curing. In conclusion, the results show that pozzolanas [Bamboo Leaves Ash (BLA), Locust Bean Pod Ash (LBA), Sugarcane Bagasse Ash (SBA) and Groundnut Shell Ash (GSA)] can successfully replace cement up to 12% without necessarily affecting the shrinkage ability of the produced concrete. It also shows that Groundnut Shell Ash (GSA), Locust Bean Pod Ash (LBA) and Bamboo Leaves Ash (BLA) are more resistance to drying shrinkage than the control.
OPTIMIZATION OF DRY SLIDING WEAR BEHAVIOUR OF ZIRCONIUM FILLED BISMALEIMIDE N...IAEME Publication
The mechanical properties and dry sliding wear behavior of bismaleimide BMI) nanocomposites with varying weight percentage of zirconium dioxide (ZrO2) filler have been studied in the present work. The influence of independent
parameters such as sliding velocity (A), normal load (B), filler content (C), and sliding distance (D) on dry sliding wear
behaviour has been considered using Taguchi's L27 orthogonal array. The results showed that the coefficient of friction of ZrO2 filled BMI nanocomposites decreased with the ZrO2 content increased. The specific wear rate of the BMI and ZrO2 filled BMI nano composites decreased as the sliding distance increased and a clear transition in friction and wear behavior was observed in neat BMI and their nano composites.
compressive strength of concrete containing milled glass as partial substitut...IJAEMSJORNAL
This work reports the outcome of an experiment carried out by using milled glass (MG) of varying percentages (20%, 40% and 60% by weight)of cement in concrete making. MG was sourced for and milled to required fineness. The concrete was batched with mix ratio of 1։2։ 4. Concrete Cube specimens produced were allowed to cure for 7-28 days and compressive strength, slump and setting time tests were carried out and were compared with those of conventional concrete (0% MG). Results obtained showed that compressive strength of the concrete increased with increase in length of curing age, but decreased as the percentage of MG increased. However, the strength still remained in the allowable range of workability for concrete in line with British standard. MG replacement of 20% was found to be the most suitable mix considering the strength and safe use of the concrete. It was concluded that MG replacement of 20% showed no significant loss in strength compared to the control sample and is stable and could be acceptable in most concrete. At the long run. Waste glass that currently constitutes waste concern in built environment in Nigeria can best be managed through alternative use in concrete production.
11(4) 2020 ITJEMAST Multidisciplinary Research Articlesdrboon
Research papers 2020 Behavioral finance; Personality traits; Behavioral factors; Overconfidence bias; Locus of control; Decision-making; Biased behavior Carbon (CO2) emissions; Economic Growth; Energy consumption; Trade; ARDL Approach; Granger Causality; Energy use Pedestrian start-up time; Street crosswalk, Pedestrian traffic signals; Pedestrians traffic lights; zebra crossings; Intersection crossings Service Attributes; Relationship quality; Relationship outcomes; Banking services; Electronic Customer Relationship Management; Virtual relationships; eBanking; eCRM College town landscape; College town character; Campus community; Urban identity; College town space; Sense of a place; Public Space; University gardens; Cultural identity; Campus identity; Businesses in college towns Emotional quotient; Self-emotional appraisal; Workplace Advice Network (WAN) Centrality; Service Sector Organizations; Sociometric matrix; Interconnectivity of nodes
11(3) 2020 ITJEMAST Multidisciplinary Research Articles drboon
Non-destructive testing method Heat loss Thermal conductivity Specific heat Know-how Psychological contract breach Employees' Workplace behaviour Workplace spirituality Human resource management (HRM) Power sector Positive classroom Male teachers Classroom management system Public primary schools Private primary school Positive motivation students Quality primary education Grout rheology Construction workings High-precision lining Tunneling complex Cement slurry Reinforcement solutions Smart building systems Green architecture Green roof Green design Sustainable environmental architecture Smart energy management Architecture technology Neo-Functionalism Trade integration CPEC agreement Economic integration Regional cooperation Pak-China relations Pak-Iran relations Central Asia Republics Sino-Pakistan Agreement
11(2)2020 International Transaction Journal of Engineering, Management, & Ap...drboon
Multidisciplinary Management, Journalism and Mass Communication Science (Information and Media Sciences), Political Sciences (International Affairs), Global Studies), Animal Sciences, Feeding Technology, Healthcare Management.
V8(3) 2017:: International Transaction Journal of Engineering, Management, & ...drboon
Research articles published in V8(3) 2017:: International Transaction Journal of Engineering, Management, & Applied Sciences & Technologies ==>
Awareness of Passive Design on Apartment Façade Designs in Putrajaya, Malaysia
127
Comparative Analysis of Low-Cost Housing Policies in Malaysia and Nigeria
139
A Study on Kevin Lynch’s Urban Design Elements: Precinct 9 East Putrajaya
153
Investigating Urban Design Elements of Bandar Baru Sentul, Kuala Lumpur
169
A Study on Sharing Home Ownership Schemes in Malaysia
183
The Impact of Window to Wall Ratio (WWR) and Glazing Type on Energy Consumption in Air-Conditioned Office Buildings
197
Competitiveness Factors of Thai Construction Industry within the AEC Context: A Qualitative Approach
209
Application of Confirmatory Factor Analysis in Government Construction Procurement Problems in Thailand
221
In a world of rapidly increasing urbanization, striving to develop more livable cities, the city’s streets designing and planning should be high on the agenda for policymakers, city planners and other practitioners, as well as researchers. Designing streets is not as easy as it might originally seem, however, done correctly it means that one third of the city was designed successfully with an immense impact on the rest of the city. The key challenge in developing sustainable and fulfilling streets is to develop an integrated approach in planning them, where it is necessary to consider all aspects involved. Meanwhile, efforts devoted to this topic vary considerably from place to place. Thus, this paper aims at discussing the main elements involved in designing streets for a livable city, in a comprehensive approach including pedestrians, vehicles, and parking areas.
Impact of Building Envelope Modification on Energy Performance of High-Rise A...drboon
In residential buildings, providing comfortable living environment for building occupants is a major challenge for architects, engineers and those who involved in the building industry. It is reported that considerable energy is consumed to provide and maintain acceptable indoor conditions for thermal comfort in residential buildings in hot-humid climate. The observable increase in energy consumption is chiefly resulting from the growing use of air conditioning system. There are various energy conservation measures which can be applied to reduce energy consumption and among these measures are passive envelope design measures. This paper addresses the energy performance of selected high-rise apartments in Kuala Lumpur. Energy Plus software is utilized in measuring the performance because of its availability, validity and accuracy. Possible energy savings due to passive envelope design measures integration are investigated. This includes investigating the effect of thermal insulation and glazing type on potential energy savings.
Enhancement of Space Environment Via Healing Gardendrboon
Green nature, sunlight and fresh air have been known as important component of healing in healthcare facilities. This paper presents the finding of an exploratory study on healing garden elements in healthcare facilities. The purpose of the paper is to find the elements of healing gardens and its healing factors in the existing garden design. In conducting this research study, site observation and informal interview at selected healthcare facilities have been performed. The study reveals the elements of existing garden design, the interactivity and the end users expectation on a garden. The finding shows that lacking some of the elements of garden design lead to less user friendliness and interactivity in the garden. It also shows that the visibility, accessibility, quietness and comfortable condition in the garden give impact to the utilization of the garden.
Design of Quadruped Walking Robot with Spherical Shelldrboon
We propose a new quadruped walking robot with a spherical shell, called "QRoSS." QRoSS is a transformable robot that can store its legs in the spherical shell. The shell not only absorbs external forces from all directions, but also improves mobile performance because of its round shape. In rescue operations at a disaster site, carrying robots into a site is dangerous for operators because doing so may result in a second accident. If QRoSS is used, instead of carrying robots in, they are thrown in, making the operation safe and easy. This paper reports details of the design concept and development of the prototype model. Basic experiments were conducted to verify performance, which includes landing, rising and walking through a series of movements.
Motion Analysis of Pitch Rotation Mechanism for Posture Control of Butterfly-...drboon
We developed a small flapping robot on the basis of movements made by a butterfly with a low flapping frequency of approximately 10 Hz, a few degrees of freedom of the wings, and a large flapping angle. In this study, we clarify the pitch rotation mechanism that is used to control its posture during takeoff for different initial pitch and flapping angles by the experiments of both manufactured robots and simulation models. The results indicate that the pitch angle can be controlled by altering the initial pitch angle at takeoff and the flapping angles. Furthermore, it is suggested that the initial pitch angle generates a proportional increase in the pitch angle during takeoff, and that certain flapping angles are conducive to increasing the tendency for pitch angle transition. Thus, it is shown that the direction of the flight led by periodic changing in the pitch angle can be controlled by optimizing control parameters such as initial pitch and flapping angles.
Analysis of Roll Rotation Mechanism of a Butterfly for Development of a Small...drboon
In this paper, we investigated the aerodynamic characteristics during roll rotation of a butterfly based on computational fluid dynamics using a three-dimensional high-speed camera information. This method allows to create a numerical model of a butterfly from the camera images and to analyze the flow field corresponding to the captured behavior. We photographed two behaviors different in rotational axis and analyzed the roll rotational mechanism. In a typical pitch rotational flight, the differential pressure was concentrated on the tip of fore wings. The magnitudes of reaction forces on left and right wings were roughly matched each other. On the other hands, the differential pressure of the roll rotational flight was distributed in the whole of wings. The magnitude of the right reaction force was twice greater than that of left at the first down stroke. The roll angle changed largely at the same time. These results show that a butterfly rotates about roll by changing the reaction forces on each side.
Effect of Oryzalin on Growth of Anthurium andraeanum In Vitrodrboon
Apical shoots and lateral buds of Anthurium andraeanum about 0.5 cm grew very well when cultured on MS medium supplemented with NAA, kinetin, sucrose and gelrite. When brought young plantlets (the same sized) of A. andraeanum soaked in various concentrations of oryzalin with different duration times. The A. andraeanum plantlets were subcultured into the same medium every 4 weeks for 3 times. It was found that 5.0 mg/l oryzalin with 24 and 72 hours gave the best average number of leaves per bunch, plant height and diameter of bunch. These parameters were reverse proportion, when increased concentration of oryzalin, the growth rate in each parameter was decreased with thick and pale green leaves.
Role of 2,4-D on Callus Induction and Shoot Formation to Increase Number of S...drboon
Stem node of Miniature Rose with axillary bud were used as explants. These explants cultured on MS medium supplemented with different concentrations of 2,4-D. It was found that MS medium supplemented with 0.5 mg/l 2,4-D gave the highest number of green callus. The callus cultured on MS medium supplemented with different combinations of NAA and BA to form new shoot and root. From the result, we are able to find the highest number of young shoots that were induced from callus when cultured callus on MS medium supplemented with NAA and BA. When subcultured all new shoots with the same size to MS medium supplemented with different concentrations of NAA and BA, and 2,4- D for six weeks. The result was significant difference (P≤0.5) when compared the average height of plant and percentage of root formation, but their duration time for flowering were not significant different.
Seismic Capacity Comparisons of Reinforced Concrete Buildings Between Standar...drboon
Earthquakes are cause of serious damage through the building. Therefore, moment resistant frame buildings are widely used as lateral resisting system. Generally three types of moment resisting frames are designed namely Special ductile frames (SDF), Intermediate ductile frames (IDF) and Gravity load designed (GLD) frames, each of which has a certain level of ductility. Comparative studies on the seismic performance of three different ductility of building are performed in this study. The analytical models are considered about failure mode of column (i.e. shear failure, flexural to shear failure and flexural failure); beam-column joint connection, infill wall and flexural foundation. Concepts of incremental dynamic analysis are practiced to assess the required data for performance based evaluations. This study found that the lateral load capacity of GLD, IDF, and SDF building was 19.25, 27.87, and 25.92 %W respectively. The average response spectrum at the collapse state for GLD, IDF, and SDF are 0.75 g, 1.19 g, and 1.33 g, respectively. The results show that SDF is more ductile than IDF and the initial strength of SDF is close to IDF. The results indicate that all of frames are able to resistant a design earthquake.
ITJEMAST5(2): Latest Research from International Transaction Journal of Engin...drboon
An After-Stay Satisfaction Survey of Residents Living in Prefabricated Concrete Structures in Thailand
Hydrothermal Assisted Microwave Pyrolysis of Water Hyacinth for Electrochemical Capacitors Electrodes
Group Technology Paves the Road for Automation
Effect of Laser Priming on accumulation of Free Proline in Spring Durum Wheat (Triticum turgidum L.) under Salinity Stress
Livable Public Open Space for Citizen’s Quality of Life in Medan, Indonesia
ITJEMAST5(1): Latest Research from International Transaction Journal of Engin...drboon
Latest Research from International Transaction Journal of Engineering, Management, & Applied Sciences & Technologies ITJEMAST5(1):
Effects of Calcination Treatment of Diatomite on Dimethyl Ether Synthesis from Methanol
Effect of Blend Ratio on Cure Characteristics, Mechanical Properties, and Aging Resistance of Silica-filled ENR/SBR Blends
An Efficient Formulation of Off-line Model Predictive Control for Nonlinear Systems Using Polyhedral Invariant Sets
Effect of Modeling Parameters on System Hydrodynamics of Air Reactor in Chemical Looping Combustion Using CFD Simulation
Flow Behavior of Geldart A and Geldart C Particles in a Co-current Downflow Circulating Fluidized Bed Reactor
Optimization of Enzymatic Clarification from Corncob
Synthesis of Alkali Metal/CaO Sorbent for CO2 Capture at Low Temperature
Effect of Exchangeable Cations on Bentonite Swelling Characteristics of Geosy...drboon
Geosynthetic clay liners (GCLs) are thin hydraulic barriers which contain the bentonite sandwiched between geotextiles or geomembrane. Bentonite swelling is a very common phenomenon observed in GCLs. It is one of the major causes for permeability reduction in hydraulic barriers. The aim of this study is to characterize the swelling behavior of bentonite in GCLs by exchangeable cations. X-ray diffraction test and scanning electron microscopy were used to quantify the swelling characteristics of this bentonite under contact with salt solutions, as in the hydraulic barriers. The results from X-ray diffraction test showed that the presence of clay minerals was swelling montmorillonite. The swell volume of bentonite decreases with increasing valence of cations. In the case of the same valence the free swell volume of bentonite increased with decreasing concentration of permeant liquids. From another test, the scanning electron microscopy, it can be seen that the bentonite appears as corn flake like crystals for air-dried bentonite. However, specimen permeated with salt solutions, the clay has become more porous and fluffy and porous size seemed to be diminished.
Effect of Exchangeable Cations on Bentonite Swelling Characteristics of Geosy...
Effects of Layered Silicate Fillers and Their Surface Treatments in NR/BIIR Blend
1. 2012 International Transaction Journal of Engineering, Management, & Applied Sciences & Technologies.
International Transaction Journal of Engineering,
Management, & Applied Sciences & Technologies
http://TuEngr.com, http://go.to/Research
Effects of Layered Silicate Fillers and Their
Surface Treatments in NR/BIIR Blend
a*
Cattaleeya Pattamaprom , and Karoon Jiamjitsiripong a
a
Center of Excellence on Natural Rubber Technology, Department of
Chemical Engineering, Thammasat University, THAILAND
ARTICLEINFO ABSTRACT
Article history: In this study, the improvement in mechanical properties
Received 29 May 2012
Received in revised form and abrasion resistance of natural rubber/bromobutyl rubber
05 July 2012 (NR/BIIR) blends were investigated when using different types of
Accepted 11 July 2012 layered silicates as secondary fillers. Moreover, the effects of
Available online
12 July 2012 organophillic surface treatments and their synergistic effects with
Keywords: ENR compatibilizer were also studied. These fillers include
bromobutyl rubber; montmorillonite clay, kaolin, bleaching clay, and talcum. We
natural rubber; found that the secondary fillers could improve the properties of
talcum, clay; the rubber composites differently. Bleaching clay contributed to
surface modification. a dramatic increase in crosslink density, which could also
increase the modulus and hardness of the composite.
Montmorillonite clay could provide dramatic increase in abrasion
resistance with low compression set, while kaolin was excellent
in terms of tensile strength. With organophillic surface
treatments, the silane-treated kaolin led to dramatic improvement
in all aspects. Conversely, montmorillonite clay treated with
octadecylamine contributed to significantly higher modulus and
hardness, while losing its abrasion resistance and resilience.
These results were opposite for bleaching clay. In this case, even
though the composites of silane-treated kaolin obtained improved
abrasion resistance and lower compression set, they suffered the
drop in crosslink density, modulus, hardness and tensile strength.
2012 International Transaction Journal of Engineering, Management, &
Applied Sciences & Technologies.
*Corresponding author (C. Pattamaprom). Tel/Fax: +66-2-5643001 Ext.3125. E-mail address:
cattalee@engr.tu.ac.th. 2012. International Transaction Journal of Engineering,
Management, & Applied Sciences & Technologies. Volume 3 No.4 ISSN 2228-9860 381
eISSN 1906-9642. Online Available at http://TuEngr.com/V03/381-399.pdf
2. 1. Introduction
Due to its low air permeability, butyl rubber (IIR) has been used in various applications
including footballs, tire inner liners and insulators of air-conditioned tubes, etc [1].
Nevertheless, as the cost of butyl rubber is considerably high compared to natural rubber
(NR), NR is potentially blended with IIR to reduce cost. However, since the cure time of IIR
is inconsistent with NR, inhomogeneous curing may cause phase separation inside these
blends. In this regard, bromobutyl rubber (BIIR) has replaced IIR for the blends with NR [2].
The outstanding characteristics of NR are its high toughness and resilience; nevertheless, the
drawback of NR is that it can be easily degraded by heat and ozone. Moreover, it also
possessed low oil resistance and high gas permeability, which is undesirable in some gas
storage applications. Generally, the presence of methyl groups serves to reduce the gas
permeability of polymers. Butyl rubber is more saturated and has more methyl groups than
natural rubber causing it to be twenty times less permeable to air [3]. Therefore, by blending
NR with BIIR, some modifications should be incorporated to improve the properties of the
NR/BIIR blends. To improve mechanical strengths of rubber, reinforcing fillers are
commonly incorporated. Good choices of reinforcing fillers for abrasion resistance and gas
barrier purpose are those with platelet structures. Among different kinds of platelet fillers,
talcum and kaolinite are commonly used in rubber compounding formulation due to their
abundance and low cost. Talcum is a hydrated magnesium silicate sheets with the chemical
formula Mg3Si4O10(OH)2. The surfaces of these elementary sheets do not contain hydroxyl
groups or active ions making it hydrophobic and inert [4]. This filler is generally used as
processing aid, UV resistance, insulator and liquid barrier of rubber products [5]. On the
other hand, kaolin consists of non-expandable and hydrophilic alumino–silicate layers. An
individual kaolin particle has the shape of a hexagonal plate. In nature, these plates occur in
stacks or “books” that exhibit varying degrees of stacking regularity. It is generally used as a
semi–reinforcing filler and to reduce cost [6]. Beside talcum and kaolinite, montmorillonite
clay has become of increasing interest especially in nanocomposite applications. This is
mainly due to its ion-exchange capability and its expandability, which can create tremendous
increase in the filler’s surface area [4, 7]. Since the advent of nanocomposites,
montmorillonite clays were widely investigated for their applications as nanofillers in
polymers. Several reports were found on the applications of montmorillonite clay in natural
rubber [8-12]. By melt compounding, even though the degree of exfoliation or intercalation
382 Karoon Jiamjitsiripong, Cattaleeya Pattamaprom
3. was limited, its applications as abrasion resistance, gas barrier or in terms of property
improvement still worth investigation. Bleaching clay, another type of layered silicate
generally used for bleaching application was also considered here. In this paper, we
investigate the effects of different layered silicates stated earlier as well as their surface
modification on various properties of the natural rubber/bromobutyl rubber blend composites.
The properties include tensile strength, surface hardness, compression set, abrasion resistance
and gas permeability. In the past, epoxidized natural rubber has been used in various aspects
including intercalation and exfoliation of organoclay in natural rubber or in natural rubber
blend matrices [13-15], improving of blend compatibility [16], mechanical strengths [17-18],
and gas permeability [19] In our previous study [20], the role of epoxidized natural rubber
(ENR) was investigated as a compatibilizer in NR/BIIR blend. Here, we investigated the
synergistic effects of surface treatment together with the use of ENR compatibilizer on
improving several properties of NR/BIIR blend composites.
2. Experimental
2.1 Raw Materials
The natural rubber used in this experiment was STR-5L grade supplied by Yong Thai
Rubber Co., Ltd. (Thailand). Bromobutyl rubber, MBTS and TMTD were provided by Multi-
chemical Engineering, Co., Ltd. (Thailand), and the epoxidized natural rubber with 50 mol%
epoxidation was obtained from San-Thap International Co., Ltd. Montmorillonite clay with
the cation exchange capacity of 100 meq./100g. of clay, and kaolinite clay (kaolin) were
kindly supplied by Kunimine (Japan) and Kentucky-Tennessee Clay (U.S.A.), respectively.
Other chemicals (talcum, phenolic resin, paraffinic oil, paraffin wax, stearic acid, and zinc
oxide) were kindly donated by Petch Thai Chemical Co., Ltd, Thailand.
2.2 Surface Modification of Layered Silicates
In this study, organophillic surface treatment of montmorillonite clay was carried out by
cation-exchange reaction with octadecylamine, while those of kaolin and bleaching clay were
carried out by silylation reaction. The procedures for both surface treatment methods are
described below.
*Corresponding author (C. Pattamaprom). Tel/Fax: +66-2-5643001 Ext.3125. E-mail address:
cattalee@engr.tu.ac.th. 2012. International Transaction Journal of Engineering,
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eISSN 1906-9642. Online Available at http://TuEngr.com/V03/381-399.pdf
4. (a) Cation–exchange reaction of montmorillonite clay [21]
First, montmorillonite clay was swollen in deionized water at room temperature with
continuous stirring overnight. Prior to the reaction, the dispersion was heated up to 70 °C for
1/2 hour. In a separate container, the protonated form of octadecylammonium ion was
prepared by dissolving the octadecylamine (8% of clay) into 2.9 ml of HCl and 500 ml of
water at 70 °C. The mixture was then poured into the clay dispersion under vigorous stirring
for 4 hours at 70 °C to produce organoclay. The organoclay then underwent 3 cycles of
consecutive centrifuging and washing by hot water at 70 °C and dried in a vacuum oven at
110 °C for 24 hrs.
(b) Silylation of kaolin and bleaching clay [22]
In this study, tetrasulfane silane (Si-69) was selected for silylation reactions of kaolin and
bleaching clay due to the fact that Si-69 has already found applications as a compatibilizer for
natural rubber with inorganic fillers. The structure of Si-69, shown in Figure 1, is composed
of symmetric ethoxy groups, which were converted to silanol groups on hydrolysis, and
nonhydrolyzable organic and sulphur groups that enables the coupling agent to bond with
rubbers.
Figure 1: Structure of Bis(3–triethoxylpropyl)–tetrasulfane (Si-69).
First, Si-69 in the amount of 8% of the reinforcing fillers was hydrolyzed under
continuous stirring for 1 hour in a mixture of 90% ethanol and 10% water. Acetic acid was
used as a catalyst. Then, the silylation reaction was carried out by pouring the hydrolyzed Si-
69 mixture into the clay dispersion under vigorous stirring for 24 hours at room temperature
to produce organoclay. The organoclay were then washed and dried in a vacuum oven at 110
°C for 24 hrs.
2.3 NR/BIIR Composite Preparation
The compounding formulations of the NR/BIIR composites were listed in Table 1.
Formulation A and B are for composites without and with ENR compatibilizer, respectively.
The rubber compounds prepared according to formulas A and B were compounded in an open
384 Karoon Jiamjitsiripong, Cattaleeya Pattamaprom
5. two-roll mill at 70°C. During compounding, the rubbers were first masticated for 5–10
minutes before adding activators (stearic acid and zinc oxide). Then, the fillers were added
together with DEG, paraffinic oil, paraffin wax, and phenolic resins. Curatives (MBTS,
TMTD, and sulphur) were added last to prevent precuring. After compounding, the samples
were then vulcanized in compression molds at 180oC.
Table 1: Formulations of the rubber compounds used in this study.
Ingredient (phr)a A B
Natural Rubber, NR 25 25
Bromobutyl Rubber, BIIR 75 75
Epoxidised Natural Rubber, ENR - 10
Secondary Filler (treated/untreated) 10 10
Stearic acid 3 3
Zinc oxide 2 2
Silica 40 40
Phenolic resin 2 2
Paraffinic oil 7.5 7.5
Paraffin wax 2.5 2.5
b
DEG 3.5 3.5
MBTSc 2 2
d
TMTD 0.8 0.8
Sulfur 1 1
a
Parts per hundred parts of rubber
b
Diethylene glycol
c
Dibenzothiazole Disulphide
d
Tetramethyl thiuramdisulphide
2.4 Characterization
The surface areas of fillers were determined by the Brunauer-Emmett-Teller (BET)
method on the Quantachrome (AUTOSORB-1) following ASTM D 3037-1978 standard test
method, whereas the average particle sizes were measured by Mastersizer MS2000 (model
APA2000) particle sizer. The X-ray diffraction patterns and the elemental compositions of the
fillers were obtained from JEOL-LDX 3530 X-ray diffractometer and the Philips PW2404
XRF, respectively. The cure characteristics of the composites were measured using a
Monsanto Moving Die Rheometer (Model MDR 2000) at 180°C. The presence of functional
groups on the surfaces of both the montmorillonite clay and kaolin was verified by FTIR
Perkin Elmer System 2000. The light source is in the mid-infrared range (4,000 – 400 cm-1)
with the resolution of 4 cm-1 using triglycine sulphate (TGS) detector. The inorganic
compositions of the clays were analyzed by Philips PW2404 (wavelength dispersive) X–Ray
Fluorescence Spectrometer (XRF).
*Corresponding author (C. Pattamaprom). Tel/Fax: +66-2-5643001 Ext.3125. E-mail address:
cattalee@engr.tu.ac.th. 2012. International Transaction Journal of Engineering,
Management, & Applied Sciences & Technologies. Volume 3 No.4 ISSN 2228-9860 385
eISSN 1906-9642. Online Available at http://TuEngr.com/V03/381-399.pdf
6. The tensile stress–strain properties were measured according to ISO 37–1977(E) by Mini-
tech Universal Testing machine, with type-1 dumbbell test specimens. Shore hardness and
abrasion tests were measured by using Durometer Shore A according to ASTM 2240 and
Hampden Abrasion Tester according to DIN 53516, respectively. Compression set
measurement was performed following ASTM D395 and the gas permeability tests were
carried out based on ASTM D 3985 using oxygen as the model gas.
The micrographs of the fractured surfaces of the composites were taken by a Joel
scanning electron microscope (SEM). The fractured surfaces were coated with gold to prevent
electrostatic charging during examination.
3. Results and Discussion
3.1 Filler characterizations
Table 2 reports the average particle sizes and BET surface area of fillers used in this
study. As can be seen, the average particle size of montmorillonite clay is the smallest with
the highest surface area, whereas talcum has the largest particle size with the lowest surface
area. The elemental compositions of fillers used here were tested by X-ray Fluorescence
(XRF). As reported in Table 3, major compositions of these fillers were consistent with their
chemical structures reported in literature, where talcum was composed mainly of SiO2 and
MgO, and the clays, which were alumino-silicate in nature, consisted primarily of SiO2 and
Al2O3. Moreover, majority of the trace components in montmorillonite clay were Na+ and
Mg2+, corresponding to the ion-exchangeable species reportedly found in the interlayer
spacing of expandable montmorillonite clays. [4, 12]. On the other hand, the majority of trace
components in bleaching clay is potassium (K+). The XRD analyzes of the clays are shown
in Figure 2. As can be seen, the diffraction pattern of montmorillonite clay indicated the
characteristic peak of montmorillonite at 2θ = 7.10° (interlayer spacing = 12.45 Å), whereas
the pattern of kaolin revealed the obvious characteristic peak for kaolinite clay at 2θ = 12.47°
(interlayer spacing = 7.09 Å). On the other hand, the pattern of bleaching clay indicated that
the clay consisted of illite (2θ = 8.96° and 17.91°) and a smaller portion of kaolinite (2θ =
12.48°). The interlayer space of illite is mainly occupied by potassium cations (K+) consistent
with the XRF result of the bleaching clay.
386 Karoon Jiamjitsiripong, Cattaleeya Pattamaprom
7. Table 2: Average particle sizes and BET specific surface areas of fillers
Average Diameter Specific Surface Area
Types of filler
(μm) (m2/g)
Talc 16.66 3.18
Montmorillonite Clay 4.81 25.85
Kaolinite Clay 11.23 21.32
Bleaching Clay 5.74 4.22
Table 3: Oxide Analysis of Fillers by X-ray Fluorescence (XRF)
Composition ( % by weight)
Compound Montmorillonite Bleaching
Talcum Kaolin
Clay Clay
SiO2 61.4 64.33 53.20 75.20
Al2O3 0.14 23.95 43.70 18.30
Fe2O3 0.03 2.30 1.10 0.85
MgO 38.10 3.53 - 1.60
Na2O - 4.65 0.08 0.28
SO3 - 0.30 0.31 -
CaO 0.31 0.59 0.02 0.07
TiO2 - 0.18 1.10 0.07
K2O - 0.12 0.35 3.60
P2O5 0.02 - 0.10 -
Intensity (a.u.)
(a)
(b)
(c)
2 4 6 8 10 12 14 16 18 20
2θ (Theta)
Figure 2: XRD patterns of (a) montmorillonite clay, (b) kaolin and
(c) bleaching clay used in this study.
From the FTIR spectra of the three types of clays in Figure 3, the broad absorbance peaks
at 900-1100 cm-1 of montmorillonite and bleaching clays are similar indicating similar
rearrangement of Si-O and Al-O bonds of alumino-silicates. The differences are the
absorbance peaks of adsorbed water at 3,400 – 3,500 cm-1 and 1,600 cm-1 appeared in
montmorillonite clay but not in bleaching clay indicating the absence of adsorbed water in
*Corresponding author (C. Pattamaprom). Tel/Fax: +66-2-5643001 Ext.3125. E-mail address:
cattalee@engr.tu.ac.th. 2012. International Transaction Journal of Engineering,
Management, & Applied Sciences & Technologies. Volume 3 No.4 ISSN 2228-9860 387
eISSN 1906-9642. Online Available at http://TuEngr.com/V03/381-399.pdf
8. bleaching clay. On the other hand, the absorbance pattern at 3,600 and 3,700 cm-1 of
bleaching clay is similar to that of kaolin indicating similar pattern of surface hydroxyl
groups. The characteristic perpendicular and in–plane Si–O stretchings of kaolin appeared at
1,100 cm-1 and 1,000 – 1,050 cm-1, respectively, whereas the Al2OH deformation occurred at
900 cm-1 [23].
% of Clay
Montmorillonite Clay
Kaolinite Clay
Bleaching Clay
3900 3400 2900 2400 1900 1400 900 400
Wavenumber (cm-1)
Figure 3: FTIR spectra of the same clays as in Figure 2
3.2 Organoclay characterization
After surface treatment, the expansion of the clay interlayer and the %coverage of
coupling agents on the clay surfaces were determined by X-Ray diffraction and
thermogravimetric analysis. The XRD patterns of the clays before and after surface treatment
are shown in Figure 4. In Figure 4(a) the primary silicate of the pristine montmorillonite clay
presents a diffraction peak at 2θ = 7.097°, corresponding to an interlayer distance (d) of 12.45
Å. After treated with octadecylamine, the diffraction peak was shifted to 2θ = 5.003° (d =
17.65 Å), indicating an enlargement of the interlayer spacing due to the insertion of
octadecylammonium ions between the interlayer. In Figure 4(b) and (c), on the other hand,
after kaolin and bleaching clay were treated with silane, the diffraction peaks were at the same
locations as those of the pristine clays but with much lower intensity. This insignificant
expansion of the clays implies no insertion of the silane couling agent into the interlayer
spaces. However, the lower intensity indicated that the dispersion of the aggregated structure
might be improved.
388 Karoon Jiamjitsiripong, Cattaleeya Pattamaprom
9. 1400 1400
1200 (b.) (a.) Montmorillonite Clay
1200 ( ( (a.)
MontmorilloniteKaolinite Clay
Clay
b a Treated Kaolinite Clay
1000
Treated Montmorillonite Clay 1000
.) .) Treated Montmorillonite Clay
Intensity (a.u.)
Intensity (a.u.)
Intensity (a.u.)
Intensity (a.u.)
800 800
600 600
400 400
200 200 (b.)
0 0
2 4 6 8 10 12 14 16 18 20
2θ (Theta) 2 4 6 8 10 12
2θ (Theta)
14 16 18 20
2θ (Theta) 2θ (Theta)
Montmorillonite Clay Kaolin
1400
( (
1200
b a
(a.) Montmorillonite Clay Clay
Bleaching
Intensity (a.u.)
Treated Bleaching Clay
1000
.) .) Treated Montmorillonite Clay
Intensity (a.u.)
800
600
(b.)
400
200
0
2 4 6 8 10 12 14 16 18 20
2θ (Theta)
2θ (Theta)
Bleaching Clay
Figure 4: XRD patterns (a) before and (b) after surface modification of montmorillonite clay
(top-left), kaolin (top-right) and bleaching clay (bottom)
The TGA thermograms of the same set of clays were used to calculate the %coverage of
the organophillic compound on the clay surface/interfaces. We found that the %coverage of
organophillic compound on montmorillonite clay was 26.5 %, whereas the %coverages of
silane on kaolin and bleaching clay were almost undetectable by TGA. These results agree
well with the XRD patterns. The high surface coverage of montmorillonite clay was because
the coating of octadecylamine by cation-exchange reaction covered not only the outer surface
of the clay but also the interlayer spaces. On the other hand, the low surface coverage of the
silane-coated clays was due to the limited coating only on the outer surfaces.
*Corresponding author (C. Pattamaprom). Tel/Fax: +66-2-5643001 Ext.3125. E-mail address:
cattalee@engr.tu.ac.th. 2012. International Transaction Journal of Engineering,
Management, & Applied Sciences & Technologies. Volume 3 No.4 ISSN 2228-9860 389
eISSN 1906-9642. Online Available at http://TuEngr.com/V03/381-399.pdf
10. 3.3 The effects of clay types and surface treatments on the properties of
NR/BIIR composites
The surface structures and the organophillic surface treatment of clays affected both the
cure characteristics and mechanical properties of the NR/BIIR blends. The cure characteristics
in table 4 are shown in terms of scorch time (ts2), cure time (tc90), and the maximum torque
difference (ΔTmax). The cure time (tc90) is denoted by the time when the torque value reaches
90% of the maximum torque and the maximum torque difference (ΔTmax), is the differences
between the maximum torque (Tmax) and the minimum torque (Tmin). The magnitude of ΔTmax
indicates the degree of crosslinking of the vulcanized rubber composites [24].
Table 4: Cure characteristics of the composites with different types of secondary fillers at
180°C
Sample ts2 tc90 Tmax Tmin ΔTmax
No Plate–like Filler 0.48 2.59 7.06 2.08 4.98
Talc 1.24 3.00 8.95 3.53 5.42
Mont. 1.15 3.29 9.29 3.78 5.51
(Treated Mont.) (1.13) (2.30) (8.79) (3.50) (5.29)
Kaolin 1.19 3.29 9.43 4.10 5.33
(Treated Kaolin) (1.33) (5.26) (9.50) (4.20) (5.30)
Bleaching Clay 0.55 3.06 11.39 3.90 7.49
(Treated B. Clay) (1.21) (4.20) (10.14) (3.25) (6.89)
With secondary fillers (except for bleaching clay), the scorch times (ts2) of the
composites were roughly twice as long as those without a secondary filler. This was probably
due to the obstruction from the platy fillers to form crosslink network within the rubber
matrices. After surface treatments, the cure time of kaolin and bleaching clay were much
longer than without surface treatment. This is most likely because the surface coverage of
clays by silane partly deactivated the acceleration effects of metal oxides naturally presented
in the clays. [25] On the other hand, the cure time of treated montmorillonite clay was shorter
than that of the pristine clay since the ammonium ion present in the coupling agent also
helped accelerating the curing reaction.[26] Nevertheless, the ΔTmax in Table 4 indicated that
the crosslink density of all blend composites using treated secondary fillers were lower than
those using the untreated fillers.
The mechanical properties of the same composites are shown in figure 5(a-c) in terms of
modulus, tensile strength and elongation at break, respectively. As can be seen, without
390 Karoon Jiamjitsiripong, Cattaleeya Pattamaprom
11. surface treatment, the composite of bleaching clay provided the highest modulus. However,
with surface treatment, the modulii of the bleaching clay composite dropped significantly
consistent with the drop in crosslink density. On the other hand, for kaolin and
montmorillonite, surface treatments of those composites provided improved tensile modulus,
where the highest modulus belongs to the composite of treated montmorillonite clay. The
adverse effect of this high modulus was the drop in tensile strength and elongation at break.
(This could be improved by lowering the clay loading.) Therefore, when considering the
improvement in terms of tensile strength and elongation at break, the composite of treated
kaolin could provide improved tensile strength, modulus, and elongation at break. The values
of surface hardness of the composites in Figure 6(a) were roughly in proportion to the tensile
moduli.
4.0 12
3.63
3.45 10.41
3.5 10.12
3.25 10 9.69
Tensile strength (N/m m2 )
Modulus @ 300% (N/mm2)
3.02 9.13 9.02 8.95 8.99
3.0 2.84 8.46
2.72
2.52 8
2.5 2.31
2.0 6
1.5
4
1.0
2
0.5
0.0
0
No Talc Mont. Treated Kaolin Treated Bleaching Treated
No Plate–like Talc Mont. Treated Kaolin Treated Bleaching Treated
Plate–like Mont. Kaolin Bleaching
Filler Mont. Kaolin Bleaching
Filler
Types of filler Types of filler
1000
900 858.06
816.00
779.89 764.52 779.76 764.83
800
% E lo n g a tio n @ b re a k
686.59
700 667.99
600
500
400
300
200
100
0
No Plate–like Talc Mont. Treated Mont. Kaolin Treated Bleaching Treated
Filler Kaolin Bleaching
Types of filler
Figure 5: (top-left) Tensile modulus at 300% strain, (top-right) tensile strength and (bottom)
elongation at break of NR/BIIR blend composites, where talcum, and pristine/treated
montmorillonite clay, kaolin and bleaching clay were used as secondary fillers
*Corresponding author (C. Pattamaprom). Tel/Fax: +66-2-5643001 Ext.3125. E-mail address:
cattalee@engr.tu.ac.th. 2012. International Transaction Journal of Engineering,
Management, & Applied Sciences & Technologies. Volume 3 No.4 ISSN 2228-9860 391
eISSN 1906-9642. Online Available at http://TuEngr.com/V03/381-399.pdf
12. 160
148.14
140
124.01
Volume loss (mm )
3
120 113.45
107.48 105.59
99.21
100 91.76
87.64
80
60
40
20
0
No Talc Mont. Treated Kaolin Treated Bleaching Treated
Plate–like Mont. Kaolin Bleaching
Filler
Type of filler
(a)
60
52.5
50 48.1
46.5 45.5
45.2 44.3 44.5
42.6
Hardness (Shore A)
40
30
20
10
0
No Talc Mont. Treated Kaolin Treated Bleaching Treated
Plate–like Mont. Kaolin Bleaching
Filler
Types of filler
(b)
Figure 6: (a) Surface hardness and (b) abrasion loss of the same NR/BIIR blend
composites as in Figure 5
Another interesting property is wear or abrasion resistance. It is quite clear in Figure 6(b)
that the addition of any of these plate-like fillers could improve wear/abrasion resistance,
where montmorillonite clay was outstanding in this aspect, followed by bleaching clay.
Abrasion resistance of kaolin composite was not very good but was improved after surface
treatment.
The dispersions of clays in the rubber blend matrices are indicated by the SEM images of
fractured surfaces shown in figure 7 for montmorillonite and kaolin before and after surface
treatment. It was noticeable that the clays were more compatible with the rubber matrices
after surface treatments.
3.4 The synergistic effects of ENR compatibilizer and filler surface
modification
The approach in improving filler/matrix compatibility could be carried out by using
compatibilizer as well as chemically modifying the filler surfaces. Here, the synergistic
392 Karoon Jiamjitsiripong, Cattaleeya Pattamaprom
13. effects of using 10 phr of ENR compatibilizer and filler surface treatment will be investigated.
These effects were reported in terms of crosslink density, mechanical strength, abrasion
resistance and gas permeability.
(a.) (b.)
(c.) (d.)
Figure 7: SEM micrographs of the NR/BIIR blend composites using (a) montmorillonite clay
(b) surface-treated montmorilonite clay (c) kaolin (d) surface-treated kaolin as secondary filler
6 10 No Compatibilizer
No Compatibilizer 5.26 ENR Compatibilizer
9 8.49
5 ENR Compatibilizer
8 7.55 7.49
7.37
4.20 7.08 6.95 6.896.90
7 6.71
Cure Time (Min)
4
ΔT max (dNm)
3.29 3.29 6 5.42 5.51
5.38 5.29 5.33 5.30
3.00 3.06 4.98
3 5
2.59
2.37 2.28 2.30
2.01 2.08 4
2
1.57 1.55 1.49 3
1.44
2
1
1
0 0
No Talc Mont. Treated Kaolin Treated Bleaching Treated No Talc Mont. Treated Kaolin Treated Bleaching Treated
Plate–like Mont. Kaolin Bleaching Plate–like Mont. Kaolin Bleaching
Filler Filler
Types of filler Types of filler
(a) (b)
Figure 8: (a) Cure time and (b) ΔTmax of the same NR/BIIR blend composites as in Figure 5
with and without 10 phr of ENR compatibilizer
*Corresponding author (C. Pattamaprom). Tel/Fax: +66-2-5643001 Ext.3125. E-mail address:
cattalee@engr.tu.ac.th. 2012. International Transaction Journal of Engineering,
Management, & Applied Sciences & Technologies. Volume 3 No.4 ISSN 2228-9860 393
eISSN 1906-9642. Online Available at http://TuEngr.com/V03/381-399.pdf
14. With ENR compatibilizer, the cure characteristic changed in 2 aspects, which were the
cure time and the crosslink density. Figure 8 showed that ENR compatibilizer could
significantly shorten cure times, especially for the composites of silane-treated clays, and
increased the crosslink density for most of the blend composites. This is because the epoxy
ring in ENR activates the transformation of adjacent double bonds in the rubber molecules
into free radicals. These radicals can quickly react and form additional crosslinks with
sulphur. [27] The increase in crosslink density due to the addition of 10 phr ENR
compatibilizer significantly outweighed the effects of filler surface treatment. This increase
led in overall to higher modulus and lower tensile strength and elongation at break as shown
in Figure 9 (a-c).
6 No Compatibilizer 12 No Compatibilizer
5.32 ENR Compatilibiler
10.41 ENR Compatibilizer
10.12
5 4.78 10 9.69
Modulus @ 300% (N/mm2)
4.43 9.13 9.02 8.99
Tensile strength (N/mm 2)
4.28 4.29 8.95
8.46
4 3.83
3.71 3.63 8 7.66
3.45
3.25
3.02 6.54
2.84 6.24
3 2.71 2.72
2.52 6
5.34 5.20
2.31 5.08
4.62 4.63
2
4
1
2
0
No Talc Mont. Treated Kaolin Treated Bleaching Treated 0
Plate–like Mont. Kaolin Bleaching
No Plate–like Talc Mont. Treated Kaolin Treated Bleaching Treated
Filler
Filler Mont. Kaolin Bleaching
Types of filler Types of filler
1000 No Compatibilizer
ENR Compatibilizer
900 858.06
816.00
800 779.89 764.52 779.76 764.83
726.76
% Elongation @ break
667.99 686.59
700
600
489.07
500
423.98 438.57
417.73 417.51
392.27
400
305.85
300
200
100
0
No Plate–like Talc Mont. Treated Kaolin Treated Bleaching Treated
Filler Mont. Kaolin Bleaching
Types of filler
Figure 9: (Top-left) Modulus at 300% strain, (Top-right) Tensile strength, and (bottom)
Elongation at break of the same NR/BIIR blend composites as in Figure 8
Figure 10a showed that the addition of plate-like fillers could in overall lead to lower
compression set, where the treated bleaching clay was the best in this aspect. The addition of
ENR compatibilizer to those treated clay composites could lower the compression set even
future. For wear/abrasion resistance, as mentioned earlier, montmorillonite clay was the best
394 Karoon Jiamjitsiripong, Cattaleeya Pattamaprom
15. in this aspect but the surface treatment of the clay slightly worsen this feature (Figure 10b).
The addition of ENR compatibilizer could significantly reduce abrasion and wear of the
composite, and the wear was minimal when using ENR compatibilizer together with the
surface-treated montmorillonite clay.
80
No Compatibilizer No Compatibilizer
160 ENR Compatibilizer
ENR Compatibilizer 148.14
70
63.37 140
58.91 123.45 124.01
60
Volume loss (mm )
3
120 113.45
52.06
Comprssion set
107.48 105.59
50 46.71 99.21
45.05 100
42.37 91.76 90.91
41.72 41.81 87.64
40.16
40 78.41
34.13 80
30.79 30.46 30.95 65.07
61.73
30 25.88 26.38 60 56.72 56.59
25.13
46.71
20 40
10 20
0 0
No Talc Mont. Treated Kaolin Treated Bleaching Treated No Talc Mont. Treated Kaolin Treated Bleaching Treated
Plate–like Mont. Kaolin Bleaching Plate–like Mont. Kaolin Bleaching
Filler Filler
Types of filler Types of filler
(a) (b)
Figure 10 : (a) Compression set and (b) Abrasion loss of the same NR/BIIR blend
composites as in figure 8
In terms of gas permeability, Table 5 shows the gas permeability of some selected blend
composites. As can be seen, montmorillonite clay and kaolin, even with surface modification
and ENR compatibilizer, could not reduce the gas permeation of the blend composites as
much as talcum. In this case, though ENR could lower the gas permeability of unfilled
NR/BIIR blend, it could not improve the gas permeability of NR/BIIR-talcum composite any
further.
Table 5: Oxygen permeabilities of selected NR/BIIR blend composites.
OTR
Types of rubber composite
(CC/m3xDay)
BIIR 41.2
BIIR & NR 92.82
BIIR & NR & ENR 57.46
BIIR & NR-Talc 68.82
BIIR & NR & ENR-Talc 69.78
BIIR & NR-Treated Mont 118.32
BIIR & NR & ENR-Treated Mont 111.31
BIIR & NR-Treated Kaolin 117.31
*Corresponding author (C. Pattamaprom). Tel/Fax: +66-2-5643001 Ext.3125. E-mail address:
cattalee@engr.tu.ac.th. 2012. International Transaction Journal of Engineering,
Management, & Applied Sciences & Technologies. Volume 3 No.4 ISSN 2228-9860 395
eISSN 1906-9642. Online Available at http://TuEngr.com/V03/381-399.pdf
16. 4. Conclusion
The surface treatments of 3 types of plate-like fillers were investigated for the used as
secondary fillers in NR/BIIR blend composites for the improvement in several properties.
Those properties include tensile properties, surface hardness, abrasion resistance and
compression set. Moreover, the synergistic effects of ENR compatibilizer together with
surface treatment of the fillers were also studied. We found that the addition of plate-like
fillers could significantly reduce the compression set and abrasion loss with an increase in
modulus at high %strain. However, the different types of secondary fillers could in detail
affect the final properties of the composites differently. Montmorillonite and bleaching clays,
which were similar types of alumino-silicate, were outstanding in terms of high abrasion
resistance with low compression set, where montmorillonite clay provided the highest
abrasion resistance. The as-received bleaching clay provided high crosslink density, which led
to high modulus and surface hardness. Kaolin, the conventional plate-like filler for rubber
industries, was considered appropriate in the aspect of mechanical properties as it could
provide high tensile strength with moderate modulus. The filler surface treatments could
significantly affect the blend properties. It was found that the surface treatment of
montmorillonite clay could significantly improve the tensile modulii and surface hardness of
the blend composite with a drop in tensile strength and a slightly higher compression set. This
trade-off in properties could supposedly be fine-tuned by using lower amount of clay loading.
The silylation of kaolin could slightly improve all of the blend properties especially the
abrasion loss, where the silylation of bleaching clay led to the lowest compression set but with
lower mechanical properties. Regarding the synergistic effect of surface treatment and ENR
compatibilizer, the effects of ENR compatibilizer were found to be very strong as it could
significantly increase the blend crosslink density, lower the abrasion loss and compression set
beyond those of the surface-treated clays. However, the increase in crosslink density here had
an adverse effect on the tensile strength. Therefore, the addition of lower doses of ENR
together with surface treatment of montmorillonite clay could be an interesting pathway to
improve tensile strength, compression set and abrasion resistance of NR/BIIR blend
composites.
5. Acknowledgements
The authors are grateful to the financial support from Thammasat University and the
396 Karoon Jiamjitsiripong, Cattaleeya Pattamaprom
17. Office of Higher Education, Ministry of Education, Thailand. The material supports from
Multichemical Co. Ltd., San Thap International Co. Ltd., and Petch Thai Chemical Co Ltd.
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Dr.Cattaleeya Pattamaprom is an Associate Professor of Department of Chemical Engineering at
Thammasat University. She received her PhD from the Department of Chemical Engineering, University of
Michigan in 2001. Dr.Pattamaprom has been working extensively on theoretical modeling of polymer
rheological properties, natural rubber technology and composites. Her research interests are in polymer
rheology and composites, natural rubber technology, and more currently in heat transfer and renewable
energy.
Karoon Jiamjitsiripong earned his bachelor degree from Srinakharinwirot University and master degree in
Chemical Engineering from Thammasat University in 2010. His master thesis involved composites of natural
rubber and bromobutyl rubber. He is currently working at Thai Rayon Public Company.
Peer Review: This article has been internationally peer-reviewed and accepted for publication
according to the guidelines given at the journal’s website.
*Corresponding author (C. Pattamaprom). Tel/Fax: +66-2-5643001 Ext.3125. E-mail address:
cattalee@engr.tu.ac.th. 2012. International Transaction Journal of Engineering,
Management, & Applied Sciences & Technologies. Volume 3 No.4 ISSN 2228-9860 399
eISSN 1906-9642. Online Available at http://TuEngr.com/V03/381-399.pdf