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1.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 03 Issue: 02 | Feb-2016 www.irjet.net p-ISSN: 2395-0072 © 2016, IRJET | Impact Factor value: 4.45 | ISO 9001:2008 Certified Journal | Page 907 IMPACT OF DYEING INDUSTRIAL EFFLUENT ON GROUNDWATER QUALITY IN AND AROUND AYYAMPETTAI R.Sumathi1 Asst.Professor –II, Civil and Structural Engineering, SCSVMV University, Enathur, Kanchipuram, TamilNadu, India ---------------------------------------------------------------------***--------------------------------------------------------------------- Abstract - Dyeing and printing of textile being a traditional industry of Kancheepuram town, a good number of textile industries along with dyeing and printing clusters have come up in the area. The dyeing units in Kancheepuram municipality and the surrounding villages are under constant threat of ground water contamination with chemicals of dyes. The present study evaluates the groundwater quality in and around Ayyampettai, Kancheepuram town of Tamil Nadu with reference to drinking and irrigation purposes. Ten groundwater samples were collected from various parts of the dyeing industrial region and the samples were analyzed with standard analytic methods. The results show that, the groundwater quality in the present study area can be categorized under ‘good’ for irrigation purpose and ‘average’ for drinking purpose. Access to safe drinking water supply is one of the basic needs of society and hence a comprehensive plan of action is sought to curb groundwater contamination in the studied region. Key Words: Dyeing,Groundwater,Parameters, Quality Analysis, Potable ,Irrigation 1.INTRODUCTION Water is very essential for human survival. It is an essential ingredient for animal and plant life too. Kanchipuram which has a traditional history of dyeing is located on the northern bank of the river “Vegavathy”. Actually, dyeing is a process of adding color to textile products like fiber, yarns. It is normally done in a special solution containing dyes and particular chemical materials. Dye is a colored substance that has an affinity to the substrate to which it is being applied. Dyes can be removed by process called “Stripping”. There are nearly 40 dyeing industries in Ayyampettai and Muthailpet villages of Kancheepuram. The ground water get contaminated due to impact of dyeing industrial effluent which has biodegradable nature of the dyes along with strong presence of toxic trace metals, acids, alkalis and carcinogenic aromatic amines. 1.1 STUDY AREA Kanchipuram town is located at a distance of 76Km from Chennai on the northern bank of the river Vegavathi, a tributary of the river Palar in TamilNadu, India. It is situated at 12°50’ north latitude and 79°42’ east longitude, (Fig - 1). Kanchipuram District is made up of hardrocks and sedimentary formations overlaid by alluvium and laterite. The average rainfall of the district is 1212mm and occurs mostly due to the north – east monsoon and also not having any perennial rivers. Fig -1: Location of the groundwater samples collected
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International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 03 Issue: 02 | Feb-2016 www.irjet.net p-ISSN: 2395-0072 © 2016, IRJET | Impact Factor value: 4.45 | ISO 9001:2008 Certified Journal | Page 908 Table -1: Groundwater Sample Sites Fig -2: Sample from Tap Water-PuduPettai 2. METHODOLOGY Ten representative groundwater samples were collected in the dyeing industrial areas of ayyampettai village of Kancheepuram town during December 2014. The locations of the groundwater sample sites were listed in table 1 and Fig 2. The samples were analyzed for the parameters turbidity, electrical conductivity (EC @ 25 C), total dissolved solids (TDS), pH , alkalinity, sulphate ( ), chloride (Cl), nitrate ( ), total hardness (TH), calcium (Ca), iron (Fe), magnesium (Mg), sodium (Na), faecal coliform bacteria count (F.Coli.), biochemical oxygen demand (BOD5 and chemical oxygen demand (COD) by standard analytic methods (APHA, 1995). All the groundwater samples were found to be colorless and odourless. The temperature of the groundwater samples was found about 30 C. 3.RESULTS AND DISCUSSION All the samples are satisfied with colour, odour, turbidity.TDS, Electrical conductivity ,pH,Total and Phenolphthalein Alkalinity as CaCO3,Total Hardness, Calcium, Magnesium, Sodium, Pottasium, Iron, FreeAmmonia, Nitrite, Nitrate, Chloride, Flouride, Phosphate as per BIS 10500:2012 except samples B, F, J. All The samples are not satisfied with BOD, COD Tidy ‘Test 4-hrs as O2 as per BIS 10500:2012 (Table 2 and Table 3). The samples collected at B is not satisfying colour, turbidity, Total Alkalinity, Total Hardness, Iron, Flouride and Sulphate. Turbidity, colour, Total Alkalinity,Iron are not satisfied for the samples collected at F and J. Free Ammonia and Nitrite are not satisfied in C and Phosphate in E. (Table 4). Sample Source Location A BW Kaliyanur B BW Olaiyur C BW Karur D BW Kuttamur E BW Siva Temple (Ayyampettai) F BW Thimmaiyan Pettai G Tap water Rani Amman temple H BW Kurrukkupattai I Tap water Pudupettai J BW Satya nagar, Ayyampettai
3.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 03 Issue: 02 | Feb-2016 www.irjet.net p-ISSN: 2395-0072 © 2016, IRJET | Impact Factor value: 4.45 | ISO 9001:2008 Certified Journal | Page 909 Table -2: Quality Standards As Per BIS-10500:2012 BIS 10500:2012 Acceptable Limit MaximumPermissible Limit Physical Examination Appearance - - Color (pt.co-scale) 5 15 Odour Agreeable Agreeable Turbidity NT units 1 5 Total Dissolved Solids mg/l 500 2000 Electrical Conductivity micro mho/cm - - Chemical Examination pH 6.5-8.5 6.5-8.5 Ph. Alkalinity as - - Total Alkalinity as 200 600 Total Hardness as 200 600 Calcium as Ca 75 200 Magnesium as Mg 30 100 Sodium as Na - - Potassium as K - - Iron as Fe 0.3 0.3 Manganese 0.1 0.3 Free Ammonia as 0.5 0.5 Nitrite as - - Nitrate as 45 45 Chloride as Cl 250 1000 Fluoride as 1.0 1.5 Sulphate as 200 400 Phosphate as - - Tidy’s Test 4 hrs. as - - BOD - - COD - - Biological Examination FAECAL CALIFORM - -
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International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 03 Issue: 02 | Feb-2016 www.irjet.net p-ISSN: 2395-0072 © 2016, IRJET | Impact Factor value: 4.45 | ISO 9001:2008 Certified Journal | Page 910 Table -3: Quality Standards For Effluent Irrigation As Per Is: 3307-1965 SL.NO PARAMETERS LIMIT AS PER IS:3307 – 1965 (mg/l) 1. BOD 500 2. PH 5.5 TO 9 3. TDS 2100 4. OIL AND GREASE 30 5. CHLORIDES 600 6. BORON 2 7. SULPHATES 1000 8. % OF Na wrt, TOTAL CONTENT OF Na, Ca, Mg & K. 60% 9. ARSENIC 0.2 10. CYANIDE 0.2 Table -4: Analytical Results of Groundwater Samples PARAMETERS A B C D E F G H I J COLOR - YELLOW - - - - YELLOW - - TURBID ODOUR - - - - - - - - - - TURBIDITY 3 30 1 1 3 34 1 2 2 24 TDS 1300 1688 557 1282 940 2100 1000 1200 1686 1300 EC 2800 4100 1159 2700 2000 4600 2200 2500 4100 2800 PH 7.71 7.30 7.68 7.63 7.02 7.01 8.14 7.34 7.36 7.11 PH. AL 0 0 0 0 0 0 0 0 0 0 TOTAL AL 472 736 336 440 352 720 328 408 416 424 TOTAL HARDNESS 280 528 124 272 240 384 296 424 736 448 Ca 64 116 28 60 52 84 64 92 160 99 Mg 29 57 13 29 26 42 33 47 81 48 Na - - - - - - - - - - K - - - - - - - - - - Fe 0 2.08 0.26 0 0.65 2.34 0 0.26 0 2.08 MANGANESE 0 0 0 0 0 0 0 0 0 0 FREE AMMONIA 0 0 2 0 0.5 0.1 0 0 0.3 0 NITRITE 0 0 0.4 0 0 0 0 0 0 0 NITRATE 30 40 10 28 20 42 20 20 40 24 CHLORIDE 480 600 106 464 236 744 300 368 800 388
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International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 03 Issue: 02 | Feb-2016 www.irjet.net p-ISSN: 2395-0072 © 2016, IRJET | Impact Factor value: 4.45 | ISO 9001:2008 Certified Journal | Page 911 FLUORIDE 1 1.6 0.6 0.4 0.2 0.8 0.2 0.6 0.6 0 SULPHATE 200 550 130 180 220 300 225 250 350 300 PHOSPHATE 0 0 0.4 0.4 2.4 0 2.8 0 0.4 2 TIDYS TEST 0.6 0.7 0.7 0.6 0.7 0.7 0.7 0.6 0.7 0.8 FAECAL COLIFORM 60 0 80 40 60 0 60 0 0 80 COD 37.1 45.8 29.2 56.4 62.8 9.3 30.5 46.4 35.5 27.8 BOD 12.4 15.2 6.9 17.4 20.9 3.1 7.4 15.5 12.3 9.3 The bar charts have been given only for the parameters which were not satisfied the permissible limits for all the samples collected from different sites (Chart 1 to 4). 0 0 0.6 0.7 0.7 0.6 0.7 0.7 0.7 0.6 0.7 0.8 0 0.2 0.4 0.6 0.8 1 TIDYS TEST TIDYS TEST 4HRS AS O2 mg/l ACCEPTIBLE LIMIT PERMISSIBLE LIMIT KALIYANUR OLAIYUR KARUR KUTTAMUR AYYAMPETTAI THIMMAIYAN PETTAI RANI AMMAN TMEPLE KURRUKKUPETTAI PUDUPETTAI SATYA NAGAR Chart1: TIDYS TEST 4HRS AS O2 mg/l 0 0 60 0 80 40 60 0 60 0 0 80 0 20 40 60 80 100 faecol caliform FAECAL COLIFORM counts/100ml ACCEPTIBLE LIMIT PERMISSIBLE LIMIT KALIYANUR OLAIYUR KARUR KUTTAMUR AYYAMPETTAI THIMMAIYAN PETTAI RANI AMMAN TMEPLE KURRUKKUPETTAI PUDUPETTAI SATYA NAGAR Chart2: FAECAL COLIFORM counts/100ml
6.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 03 Issue: 02 | Feb-2016 www.irjet.net p-ISSN: 2395-0072 © 2016, IRJET | Impact Factor value: 4.45 | ISO 9001:2008 Certified Journal | Page 912 0 0 37.1 45.8 29.2 56.4 62.8 9.3 30.5 46.4 35.5 27.8 0 20 40 60 80 COD COD ACCEPTIBLE LIMIT PERMISSIBLE LIMIT KALIYANUR OLAIYUR KARUR KUTTAMUR AYYAMPETTAI THIMMAIYAN PETTAI RANI AMMAN TMEPLE KURRUKKUPETTAI PUDUPETTAI SATYA NAGAR Chart 3: COD in mg/l Chart 4: BOD in mg/l
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International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395 -0056 Volume: 03 Issue: 02 | Feb-2016 www.irjet.net p-ISSN: 2395-0072 © 2016, IRJET | Impact Factor value: 4.45 | ISO 9001:2008 Certified Journal | Page 913 Table -5: Water Quality Index Classifications CONCLUSION From the above discussions, it can be said that the quality of groundwater in the study area is fair or satisfactory for drinking purposes and good for irrigation purposes. All the samples contain high BOD and CODand samples A, C, D, E, G and J are bacteriologically contaminated. Also few have objectionable color, high content of turbidity, totalalkalinity, iron, sulphate and phosphate which shows the impact of dyeing industries.As per the quality standards, the sampling places are classified as average , poor and they are used only for irrigation but for drinking purposes after giving proper treatment (Table 5). REFERENCES [1] N. Kannan and K. Thavamani, “Assessment of Industrial groundwater pollution potential from correlation of parametric ratios-Dye Industry”. Indian J. Environ. Prot. 13(5), 346-348. 8, 1993 [2] G. Kesavan and R.Parameswari, “Evaluation of groundwater quality in Kancheepuram”. Indian J. Environ. Prot. 25(3), 235-239, 2005 [3] Neetu Saxena and Harinder Kaur, “Evaluation of groundwater quality of Bareilly City”. J. Industrial Poll. Control, 19(2), 169- 174, 2003 [4] K.V. Sastry , Vineeta Shukla and Sharda Abusaria, “ Impact assessment of industrial pollution on groundwater”. Indian J. Environ. Prot. 23(3), 250-255. 2003 [5] Dr. C.Gajendran, S.Jayapriya, Diana Yohannan, OshinVictor and Christina Jacob, “Assessment of groundwater quality in Tirunelveli District, Tamil Nadu, India”. School of Civil Engineering, Karunya University, Coimbatore, Tamil Nadu, 2013. [6] Debabrata Mazumder , “Process Evaluation and treatability study of wastewater in a textile dyeing industry” , Civil Engineering Department, Bengal Engineering and Science University, Shibpur, P.O. – Botanic Garden, Howrah, West Bengal India, 2011 [7] Malik Bhawna, H.S. Dwivedi and P.Dwivedi, “Effect of Textile, Dyeing and Printing industrial effluents on river Kshipra Bherugarh Ujjain, M.P., and India, 2014. [8] Ikbal HUSAIN, Jakir HUSAIN, Mohammed ARIF, “Environmental impact of dyeing and printing industry of Sanganer”, Rajasthan (India) ,Public Health Engineering Department Laboratory, Bhilwara, Rajasthan, India, Feb 2014. [9] B. K. BHADRA, SUPARN PATHAK and J. R. SHARMA, “Impact of Industrial Effluents on Groundwater around Pali City”, Rajasthan Using Field and Satellite Data Regional Remote Sensing Centre (West), NRSC/ISRO, CAZRI Campus, and Jodhpur, 2013. [10] M. Balakrishnan, S. Arul Antony, S. Gunasekaran and R.K. Natarajan, “Impact of dyeing industrial effluents on the groundwater quality in Kancheepuram,India” 2008. Sample Quality Kaliyanur [A] Average Olaiyur [B] Poor Karur [C] Average Kuttamur [D] Average Siva Temple (Ayyampettai) [E] Average Thimmaiyan Pettai[F] Poor Rani Amman temple [G] Poor Kurrukkupattai [H] Average Pudupettai [I] Average Satya near, Ayyampettai [J] Poor
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