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1.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 03 | Mar-2018 www.irjet.net p-ISSN: 2395-0072 © 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 2513 Waste water treatment by Tea Waste, Alum, Pre-Aluminium Chloride. Nitin Singh Bhadoriya1, Anish.P.Jacob2, Krishan kumar Pathak3 1Department of Chemical Engineering, MITS Institute, Gwalior(M.P),India. 2,3 Assistant Prof. Department of chemical Engineering, MITS Institute, Gwalior(M.P),India. ---------------------------------------------------------------------***--------------------------------------------------------------------- Abstract -In the tighra reservoir heavy metalsCr,Pb,Cd,Ni etc were found immersely. The heavy metals infected the tighra reservoir which can cause the human health.An effective tea waste adsorbent were urbanized to eradicate the heavy metal. Activated carbon showing good result for purification and seperation technique.Classification of the tea waste adsorbent, Alum, and PAC showed a clear image Key Words Tea waste, Alum, Pre aluminium chloride(PAC). 1. INTRODUCTION The main reason behind getting water impure of tighra dam is is immersing the idols of god during the time of Ganesh Chaturthi and NavDurgas.The hindu community peoples worship idols of lord during the time.And ritualisperformed by muslim during the Muharram festival, and Tazias are being immersed by them. The idolsare made up of clay,POP, cloth, paper wood, thermo Cal, jute, adhesive material and synthetic paints etc. The synthetic chemical paints that arwe generally increases the hewavy metals concentration and acidity while immersing the idolsin tighradam.Leadand chromium which also adds through SINDUR in the water bodies are very dangerous even in a very small quantity for human health through the process known as Bioaccumulation.In Gwalior, lot of religious activities takes place all around the year. Health Effect of Heavy Metals Heavy metals are very dense metals or metalloid that is noted for its potential toxicity Especially in environmental context. These metals cadmium,mercury,lead,and arsenic all of appeard in W.H.O.Common sources are from mining and industrial waste , vehicalsemission, Lead acid batteries, fertilizers, paints, treated woods and ageing water supply infrastructure. (Cn, PB, Zn, Cu, As, Cd, Ni, Hg, Cr)is18.39%, 18.60%, 20.30%, 321%, 22.10%, 23.01%, 23.20%, 25.56%. 2. Material and Method In this study, life cycle assessment framework methodology provided by the International standard organization (ISO) 14040 is utilized to access the environmental impacts of sewage water treatment process of a reservoir .Tea waste were collected from an hotel ofGwalior near puranichawani and washed with boiled water until the water was colourless. This process were repeated with 15 cycle and after that it keeps in a tray drier at 1080c for 12h.The dreid substances were changed into powder and screened the sizes upto 100µm.Again the powder dreid at 1080c for 5h and dreid tea waste was chemically activated with 1.2M sulphuric acid and stored in sealed polythene bags.Now adsorbent is ready to use. 3. Result and Discussion The example of water is taken from Tighra dam and were mock up by UV- spectrophotometer. The residual focus of heavy metals were determined by its wavelength. Heavy Metals Wavelength Nickle(Ni) 385nm Copper|(Cu) 310nm Zinc(Zn) 308nm Cynaid(Cn) 280.2nm Cadmium(Cd) 379nm Lead(Pb) 382.5nm Chromium(Cr) 530nm Arsenic(As) 355nm Mercury(Hg) 390.5nm 0.3gm adsorbents were dissolved into 1000ml of Tighra water sample to make up 0.5gm/l.This sample is scum from white man filter paper to get final absorption of water sample. This experiment is experienced from UV spectrophotometer from 280nm, 285nm, 310nm, 309nm, 345nm, 390nm, 530nm wavelength respectively. Table -1: Sample Table format Preparation of Manuscript Transparency 126.71cm T.D.S 112.1mg/l ELECTRICAL CONDUCTIVITY 137.9µS/cm FREE CO2 0.18mg/l TOTAL ALKALINITY 26.73mg/l TOTAL HARDNESS 48.16mg/l CHLORIDES 27.97mg/l NITRATE- NITROGEN 0.024mg/l PHOSPHOROUS 0.006mg/l MAGNESIUM 3.46mg/l
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International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 03 | Mar-2018 www.irjet.net p-ISSN: 2395-0072 © 2018, IRJET | Impact Factor value: 6.171 | ISO 9001:2008 Certified Journal | Page 2514 Chart -1: water availability and its use India accounts for 2.45% of land area and 4% of water resources of the world but represents 16% of the world population. Total utilizable water resource in the country has been estimated to be about 1123 BCM (690 BCM from surface and 433 BCM from ground), which is just 28%of the water derived from precipitation. About 85% (688 BCM) of water usage is being diverted for irrigation (Figure1),which may increase to 1072 BCM 2050. Major source for irrigation is groundwater. Annual groundwater recharge is about 433 BCM of which 212.5 BCM used for irrigation and 18.1 BCM for domestic and industrial use (CGWB, 2011). By 2025, demand for domestic and industrial water usage may increase to 29.2 BCM. Thuswater availability forirrigationis expected to reduce to 162.3 BCM. With the present population growth-rate (1.9% per year), the population is expected to cross the 1.5 billion mark by 2050. 4. CONCLUSION Experiment result shows the max. removal of heavy metals (Cr,Pb,Zn,Cu,As,Cd,Ni,Hg,Cr) by tea waste, Alum and Pre- aluminium chloride(PAC) is 25.6% ( APPROX). ACKNOWLEDGEMENT I express my deepest thanks to Asst. Prof. ANISH.P.JACOB Department of Chemical Engineering ,MITS Institute, Gwalior for his constant encouragement, invaluable guidance, advice ,and have faith on me. I am also thankful to Dr. Shriram Prasad sir the H.O.D of chemical department for their valuable suggestion and encouragement that I got during my work. I trulyappreciate the space what I got in tighra dam plant to work in the area to keen my interest. REFERENCES [1] Gopal k. Bharagav, Shankarlal C.bhatt Land and people of Indian states and union territories. 15. Madhya pradesah Kalpaz publication 2006 ISBN81-7835-371-7 page 361 [2] .Khadag singh valdiya Geology, Environment and Society, Universities press, 2004 ISBN 81-7371-505-X, page 178. [3] Metcalf&Eddy, Waste Water Engineering: Treatment, Disposal, and Reuse 3rd ed. Boston, MA: Mc Graw- Hill,1991.
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