Designed in a very easy manner so that u all are able to understand each and everything easily. Gillespie & Nyholm proposed this theory ion 1957 and its is based on the direction of bonds in a polyatomic molecule. Based on this there are several postulate that are very necessary to know before any molecule to study.

2. VALENCE SHELL ELECTRON PAIR
REPULSION THEORY
PRESENTED
BY
ALTAMAS ALI
B.Sc – MICROBIOLOGY
SEM. – 2ND
SCHOOL OF LIFE AND ALLIED
HEALTH SCIENCE
THE GLOCAL UNIVERSITY

3. CONTENTS
• ABBREVIATION USED
• INTRODUCTION
• VSEPR THEORY : MAIN POSTULATES OF VSEPR
• REPULSION STRENGTHS
• CAUSE OF ALTERNATION IN SHAPE
• EFFCT OF ELECTRONEGATIVITY
• SHAPE OF MOLECULES CONTAINING lp & bp
• REFERENCES

4. ABBREVIATION USED
• VSEPR THEORY – VALENCE SHARE ELECTRON PAIR REPULSION
THEORY
• lp – lone pair
• bp - bond pair
• max. – maximum
• min. - minimum

5. INTRODUCTION
• VSEPR theory was suggested by Sidgwick and Powell [1940]
• It was further improved by Gillespie and Nyholm in 1957.
• Based on that in a polyatomic molecule the direction bonds around the
central atom depends on the total number of bonding &non-bonding
electron pairs in its valance shell.

6. VSEPR THEORY
MAIN POSTULATES OF VSEPR :
• The shape of the molecule is determined by repulsions between all
of the electron present in the valance shell.
• Electron pairs in the valence shell of the central atom repel each
other and align themselves to minimize this repulsion.

7. • Lone pair electrons takes up more space round the central
atom than a bond pair.
• Lone pair attracted to one nucleus, but bond pair is shared by
two nuclei.
• The minimum repulsions to the state minimum energy and
maximum stability of the molecule.

8. REPULSION STRENGTHS
• Lone pair -Lone pair  Lone pair -Bond pair
 Bond pair-Bond pair
• Triple bond >double bond >single bond

9. CAUSE OF ALTERNATION IN
SHAPE
• Presence of lone pairs on the central atom causes slight
distortion of the bond angles from the ideal shape.
• The magnitude of repulsions between bonding pairs of
electrons depends on the electronegativity difference
between the central atom & the other atoms .

10. EFFCT OF ELECTRONEGATIVITY
Five electrons in the valance shell of
Nitrogen. [1s2 2s2 2p3]
Molecular geometry- Tetrahedral [e-pairs arrangement]
or Trigonal Pyramidal [VSEPR]
Presence of lone pair causes slight distortion from 109⁰28′ to 107⁰48′ to 102⁰30′
Repulsion between bondpair-bondpair is less in NF3 than in NH3

11. Valence Electron Pair
Geometry
Number of
Orbitals
Hybrid
Orbitals
Linear 2 sp
Trigonal Planar 3 sp2
Tetrahedral 4 sp3
Trigonal Bipyramidal 5 sp3d
Octahedral 6 sp3d2

12. SHAPE OF MOLECULES CONTAINING
lp & bp

15. REFERENCES
• J.D Lee, WILEY INDIA EDITION, Concise Inorganic, Vol. 5 @ Pg. 74-80.
• Atkins, Rourke, Weller & Armstrong. Shriver & Atkins, OXFORD South Asia edition,
Inorganic Chemistry, Vol. 5. Topic 2.3 @ Pg. 36-39.
• Pictures From www.oxfordtextbooks.co.uk/orc/ichem5e/
• Pictures from Wikipedia- free encyclopedia- www. Wikipedia.org.

16. THANKS TO RESPECTED
TEACHERS AND STUDENTS
THEEND