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Prof. Sohaib Hasnain
Punjab Group of Colleges, Faisalabad
CHEMISTRY
VOLUMETIC
ANALYSIS
“It is a quantitative analysis in which amount of
substance is determined in the solution. For this
purpose, we titrate the solution against the other
solution whose concentration is known”
SOME IMPORTANT TERMS:
STANDARD SOLUTION :
The solution whose concentration is already known
Concentration :
It is relative amount of solute in a solution
STRENGTH :
when the amount of substance dissolved in a solution is expressed in gram per
dm3
WHAT IS TITRATION
“IT IS THE PROCESS OF FINDING THE CONCENTRATION OF
UNKNOWN SOLUTION”
Types
• Acid Base titration
• Redox titration
• Compelxometric titration
APPARATUS
• Burette
• Pipette
• Conical flask
• Burette stand
• Pipette sucker
• Beaker
• Measuring Flask
DIFFERENCE B/W TITRANT AND
TITRAND
Titrant : The solution which is taken in burette
Titrand : The solution which is taken in Conical Flask
PROCEDURE
• Fill the titrant in burette
• take 10 cm3 titrand in conical flask
• Add 2-3 drops of indicator to the flask
• Now add the solution from burette to the flask drop wise
• End point shows some change in color
• Note the final reading
• Repeat the experiment for three time
CALCULATION
Avarage =
10+10+10
3
= 10 cm3
No. of Obs Initial value Final value Volume used
1 0.0 10.0 10.0 cm3
2 10.0 20.0 10.0 cm3
3 20.0 30.0 10.0 cm3
CHEMICAL EQUATION
ACID + BASE → SALT + WATER
HCl + NaOH → NaCl + H2O
MOLAR RATIO
For acid n1= 1 mol
For base n2 = 1 mol
MOLARITY FORMULA
𝑀1𝑉1
𝑛1
=
𝑀2𝑉2
𝑛2
Strength = Molarity ×Molar mass
PRECAUTIONS
• Use lab coat and gloves
• Wash the apparatus before and after use
• Always use funnel for adding solution in burette
• Always use sucker for pipetting out the solution
•
Volumetric Analysis Techniques and Calculations

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Volumetric Analysis Techniques and Calculations

  • 1.
  • 2. Prof. Sohaib Hasnain Punjab Group of Colleges, Faisalabad CHEMISTRY
  • 3. VOLUMETIC ANALYSIS “It is a quantitative analysis in which amount of substance is determined in the solution. For this purpose, we titrate the solution against the other solution whose concentration is known”
  • 4. SOME IMPORTANT TERMS: STANDARD SOLUTION : The solution whose concentration is already known Concentration : It is relative amount of solute in a solution STRENGTH : when the amount of substance dissolved in a solution is expressed in gram per dm3
  • 5. WHAT IS TITRATION “IT IS THE PROCESS OF FINDING THE CONCENTRATION OF UNKNOWN SOLUTION” Types • Acid Base titration • Redox titration • Compelxometric titration
  • 6. APPARATUS • Burette • Pipette • Conical flask • Burette stand • Pipette sucker • Beaker • Measuring Flask
  • 7.
  • 8.
  • 9.
  • 10. DIFFERENCE B/W TITRANT AND TITRAND Titrant : The solution which is taken in burette Titrand : The solution which is taken in Conical Flask
  • 11. PROCEDURE • Fill the titrant in burette • take 10 cm3 titrand in conical flask • Add 2-3 drops of indicator to the flask • Now add the solution from burette to the flask drop wise • End point shows some change in color • Note the final reading • Repeat the experiment for three time
  • 12. CALCULATION Avarage = 10+10+10 3 = 10 cm3 No. of Obs Initial value Final value Volume used 1 0.0 10.0 10.0 cm3 2 10.0 20.0 10.0 cm3 3 20.0 30.0 10.0 cm3
  • 13. CHEMICAL EQUATION ACID + BASE → SALT + WATER HCl + NaOH → NaCl + H2O MOLAR RATIO For acid n1= 1 mol For base n2 = 1 mol
  • 15. PRECAUTIONS • Use lab coat and gloves • Wash the apparatus before and after use • Always use funnel for adding solution in burette • Always use sucker for pipetting out the solution •