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Chemistry I Unit III The atom & the periodic table 
Ms. Claudia Barahona 
October 2014
Stage 3 
•Development of atomic theories 
•Subatomic particles 
•Electron configuration 
•Organization of elements on the 
periodic table 
•Periodic properties (trends): 
–Atomic size 
–Ionization energy 
–Electronegativity
Activity 3.1 The atom 
•What is the atom composed of? 
•Composed by subatomic particles: 
•Protons : p+ 
•Electrons: e- 
•Neutrons: n
Subatomic particles 
•Particles that are smaller than the atom. 
•Protons and neutrons make up the nucleus of an atom. 
Note: Amu (Atomic Mass Unit) is defined as one-twelfth of the mass of the carbon atom with six protons and six neutrons. 
Name 
Symbol 
Elctrical charge 
Mass (amu) 
Proton 
Electron 
Neutron 
n 
Name 
Symbol 
Elctrical charge 
Mass (amu) 
Proton 
p+ 
+1 
1 
Electron 
e- 
-1 
0.000549 
Neutron 
n 
0 
1
•Atomic number: 
Is equal to the number of p+ in an atom. 
•Mass number: 
Is equal to the number of p+ and n in 
the nucleus of an atom. 
•Atomic mass or atomic weight: 
Weight average mass of all the 
natural occuring isotopes of an element 
Information in the periodic table
Smallest particle of an element that retains the characteristis of the element. 
Atom 
Atomic theories: Theories that try to explain the structure of the atom: 
•Dalton 
•Thomson 
•Bohr 
•Ruhtherford 
•Schrodinger
•Decomposition process in which unstable atomic nuclei will spontaneously decompose to form nuclei with a higher stability, resulting in a release of high energy radiation. Radioactivity
Radioactivity 
Benefits 
Risk 
Used in nuclear medicine. 
Radiotheraphy 
Irradiation 
Can burn the surface of the skin. 
In contact with cells in the body may cause genetics mutations. 
Fire detective systems 
Generates wastes which we do not know how to manage or destroy. 
Nuclear power stations 
•Ex: P-32 (Tx of Leukemia), C-14 (Radiocarbon dating), Au-198 (Liver imaging and carcinoma), I-123 (Thyroid, brain and porstate cancer).
Modern periodic table 
•Period: Each horizontal row. 
•Group/family: Each vertical column, this elements will have similar properties.
Modern periodic table
Representative elements Transition Metals
Periodic trends
Representative elements Transition Metals
Acquisition of knowledge
•Isotopes: 
Are atoms of the same element that have different mass number but the same chemical behavior. 
Atomic symbol for writing Isotopes: AZX X= chemical symbol for the element Z= Atomic number A= Mass number
•Atomic mass or atomic weight: Weight average 
mass of all the natural occuring isotopes 
of an element 
•Atomic number: Is equal to the number 
of protons in an atom. Information in the periodic table
Representative elements 
Transition 
Metals
Exercise # 1 Subatomic particles 
•Is each of the following statements true or false? 
If false, explain your reason. 
a.Protons are heavier than electrons. 
True 
b. Protons are attracted to neutrons. 
False. p+ are attracted to e- 
c. Electrons are so small that they have no electrical charge. 
False. e- have a -1 charge 
d. The nucleus contains all the protons and neutrons of an atom. 
True
Exercise # 2 Subatomic particles 
•Using the periodic table, state the atomic number, number of protons, and number of electrons for an atom of each of the following elements: 
Element 
Atomic number 
p+ 
e- 
Nitrogen 
Magnesium 
Bromine
Representative elements Transition Metals
Subatomic particles 
•Using the periodic table, state the atomic number, number of protons, and number of electrons for an atom of each of the following elements: 
Element 
Atomic number 
p+ 
e- 
Nitrogen 
7 
7 
7 
Magnesium 
12 
12 
12 
Bromine 
35 
35 
35
Exercise # 3 Subatomic particles 
•Consider an atom that has 79 electrons. 
a.How many protons are in its nucleus? 
b.What is its atomic number? 
c.What is its name, and what is its symbol?
Representative elements Transition Metals
Subatomic particles 
•Consider an atom that has 79 electrons. 
a.How many protons are in its nucleus? 
79 
a.What is its atomic number? 
79 
a.What is its name, and what is its symbol?
Subatomic particles 
•The number of protons gives atoms their identity. 
•Atomic number (Z) 
#of protons 
•Mass number (A) 
•#protons + #neutrons
Information in the periodic table 
•Atomic mass or atomic weight: Weight average 
mass of all the natural occuring isotopes 
of an element.
•Isotopes: 
Are atoms of the same element that have different mass number but the same chemical behavior. 
Atomic symbol for writing Isotopes: AZX X= chemical symbol for the element Z= Atomic number A= Mass number
Identify protons and neutron in isotopes 
State the number of p+, e- and n in each of the following isotopes of Carbon (C). 
Exercise# 4 
Isotopes 
Isotope 
Protons 
Electrons 
Neutrons 
6 
6 
6 
6 
6 
7 
6 
6 
8
Identify protons and neutron in isotopes 
Write the symbol for each of the following isotopes: 
a)A nitrogen atom with 8 neutrons. 
b)An atom with 20 protons and 22 neutrons. 
c)An atom with mass number 27 and 14 neutrons. 
Exercise# 5 Isotopes
Representative elements Transition Metals
Write the symbol for each of the following isotopes: 
a)A nitrogen atom with 8 neutrons. 
157N 
a)An atom with 20 protons and 22 neutrons. 
4220Ca 
a)An atom with mass number 27 and 14 neutrons. 
2713Al 
Exercise# 5 Isotopes
Review activity 3.2
Atomic theories 
•Theories that try to explain the 
structure of the atom. 
–John Dalton 
–J. J. Thomson 
–Ernest Rutherford 
–Niels Bohr 
–Erwin Schrodinger
Evolution of the atomic theories 
Billiard ball model- a small, solid sphere
Evolution of the atomic theories 
Law of Conservation of mass: 
States that the total mass present before a chemical reaction is the same as the total mass present after the chemical reaction; thus, mass is conserved. The law of conservation of mass was formulated by Antoine Lavoisier (1743-1794). This law was a result of his combustion.
Evolution of the atomic theories 
Law of Constant composition or Law of definite proportions: 
Formulated by Joseph Proust (1754-1826). 
States that if a compound is broken down into its constituent elements, the masses of the constituents will always have the same proportions, regardless of the quantity or source of the original substance.
Evolution of the atomic theories Law of Constant composition or Law of definite proportions: Jon Berzelius did experiments with about 2000 compounds Berzelius prepared and purified the necessary reagents, developed the techniques to perform the analyses, and collected data on the relative weights of atoms of 43 elements. That confirmed John Dalton's atomic theory as well as Proust's law showing that separate elements always combined in whole-number proportions. *Also introduced the symbolism with which chemical formulas are still written
Evolution of the atomic theories 
How was Dalton wrong in his proposal? 
Not all atoms of the same element are exactly alike (isotopes). 
Atoms are made up of subatomic particles.
J.J. Thomson 
•Discovered the electron in a series of experiments using cathode-ray tube. 
•In 1904 Thomson suggested a model of the atom as a sphere of positive matter in which electrons are positioned by electrostatic forces. 
“Plum-pudding” 
model
Ernest Rutherford 
•Rutherford performed a series of experiments with radioactive alpha particles. 
• He found that while most of the alpha particles passed right through the gold foil, a small number of alpha particles passed through at an angle (as if they had bumped up against 
something) and some bounced straight 
back 
•Rutherford's experiments suggested 
that gold foil, and matter in general, had 
holes in it!
Niels Bohr 
•Devised the atom as a small, positively charged nucleus surrounded by electrons that travel in circular orbits around the nucleus— similar in structure to the solar system.
Erwin Schrodinger 
•Schrödinger model describes the probability that an electron can be found in a given region of space at a given time. This model no longer tells us where the electron is; it only tells us where it might be. 
•Introduced “wave 
mechanics” as a 
mathematical model.
Evolution of the atomic theories
Evolution of the atomic theories
Electronic configuration 
Energy level: Specific energy that an electron has (bound by the electric field of the nucleus). 
e- in the lower energy levels are usually closer to the nucleus. 
Sublevel: Group of orbitals of equal energy within principal energy level. 
Orbital: Region around the nucleus where e-s of a certain energy are more likely to be found. (s, p,d and f)
Electronic configuration 
List of the number of electrons in each sublevel within an atom, arranged by increasing energy.
Electronic configuration 
Orbital´s maximum number of e- 
•S= 2 
•P= 6 
•d= 10 
•f = 14
Electronic configuration
Representative elements Transition Metals
Electronic configuration 
•To contruct the electronic configuration of an atom do the following: 
1.Determine the number of electrons in the atom. 
2.Put electrons moving from the lowest energy levels to the highest energy orbital available, starting with 1s (holds a maximum of two electrons). 
3.Fill in the orbitals according to the number of electrons in the atom.
Electronic configuration 
•Example: Write the electronic configuration of Lithium atom. 
1.Electrons involved: 
atomic number 3 
2.Begin with the 1s sublevel. 
1s2 
3. Fill in the needed orbitals, until all the electrons are being positioned. 
1s2 2s1
Electronic configuration 
•Write the electron configuration for : 
a.Nitrogen atom 
b.Silicon atom 
c. Chlorine atom
Representative elements Transition Metals
Electronic configuration 
•Write the electron configuration for : 
a.Nitrogen atom 
1s2 2s2 2p3 
b.Silicon atom 
1s2 2s2 2p6 3s2 3p2 
c. Chlorine atom 
1s2 2s2 2p6 3s2 3p5
Electronic configuration 
•List of the number of electrons in each sublevel within an atom, arranged by increasing energy. 
•Chemistry book chapter 3 Pg 81 
Orbital diagram 
•Boxes represent the orbitals and half arrows represent electrons.
Electronic configuration 
Maximum number of e- 
•S= 2 
•P= 6 
•d= 10 
•f = 14
Aufbau´s principle 
•e-s fill orbitals starting at the lowest available energy state before filling higher states (1s before 2s).
Pauli exclusion principle 
•States the an orbital can hold up to maximum of 2 e-´s, which are seeing as spinning on its axis, which generates a magnetic field. 
•An orbital can hold 0, 1, or 2 electrons only, and if there are two electrons in the orbital, they must have opposite (paired) spins.
Hund´s rule 
•When filling sublevels other than s, electrons are placed in individual orbitals before they are paired up.
Representative elements Transition Metals
Blocks in the periodic table
Valence electrons 
•Electrons in the outermost energy level. 
•Given by the group number (representative elements).
Valence electrons 
•Electrons in the outermost energy level. 
•Given by the group number (representative elements).
Oxidation number 
•Shows the total number of e-´s which have been removed from an element (+) or added to an element (-).
Periodic trends 
•Elctron configuration of atoms are an important factor in physical and chemical properties of the elements. 
•Periodic properties increases or decreases across a period, and then the trend is repeated again in each successive group.
Periodic trends 
•Electron afinity: The ability of an atom to attract additional electrons. 
•Electronegativity: The relative ability of an element to attract electrons in a bond. 
•Ionization energy: Energy needed to remove the least tight bound electron from an atom in gaseous (g) state. 
•Atomic radius: Distance from the nucleus to the energy level that contains the valence (outermost) electrons.
Periodic trends
Writing formulas 
1.Identify the cation and anion or polyatomic ion. 
2.Balance the charge. 
3.Write the formula, cation first, using the subscript from the charge balance.
Subscripts in formulas 
•The subscripts in the formula represent the number of positive and negative ions that give an overall charge of zero.
Check activity 3.3
Check End of chapter

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Unit iii the atom and the prediodic table (2)

  • 1. Chemistry I Unit III The atom & the periodic table Ms. Claudia Barahona October 2014
  • 2. Stage 3 •Development of atomic theories •Subatomic particles •Electron configuration •Organization of elements on the periodic table •Periodic properties (trends): –Atomic size –Ionization energy –Electronegativity
  • 3. Activity 3.1 The atom •What is the atom composed of? •Composed by subatomic particles: •Protons : p+ •Electrons: e- •Neutrons: n
  • 4. Subatomic particles •Particles that are smaller than the atom. •Protons and neutrons make up the nucleus of an atom. Note: Amu (Atomic Mass Unit) is defined as one-twelfth of the mass of the carbon atom with six protons and six neutrons. Name Symbol Elctrical charge Mass (amu) Proton Electron Neutron n Name Symbol Elctrical charge Mass (amu) Proton p+ +1 1 Electron e- -1 0.000549 Neutron n 0 1
  • 5. •Atomic number: Is equal to the number of p+ in an atom. •Mass number: Is equal to the number of p+ and n in the nucleus of an atom. •Atomic mass or atomic weight: Weight average mass of all the natural occuring isotopes of an element Information in the periodic table
  • 6. Smallest particle of an element that retains the characteristis of the element. Atom Atomic theories: Theories that try to explain the structure of the atom: •Dalton •Thomson •Bohr •Ruhtherford •Schrodinger
  • 7. •Decomposition process in which unstable atomic nuclei will spontaneously decompose to form nuclei with a higher stability, resulting in a release of high energy radiation. Radioactivity
  • 8. Radioactivity Benefits Risk Used in nuclear medicine. Radiotheraphy Irradiation Can burn the surface of the skin. In contact with cells in the body may cause genetics mutations. Fire detective systems Generates wastes which we do not know how to manage or destroy. Nuclear power stations •Ex: P-32 (Tx of Leukemia), C-14 (Radiocarbon dating), Au-198 (Liver imaging and carcinoma), I-123 (Thyroid, brain and porstate cancer).
  • 9. Modern periodic table •Period: Each horizontal row. •Group/family: Each vertical column, this elements will have similar properties.
  • 15. •Isotopes: Are atoms of the same element that have different mass number but the same chemical behavior. Atomic symbol for writing Isotopes: AZX X= chemical symbol for the element Z= Atomic number A= Mass number
  • 16. •Atomic mass or atomic weight: Weight average mass of all the natural occuring isotopes of an element •Atomic number: Is equal to the number of protons in an atom. Information in the periodic table
  • 18. Exercise # 1 Subatomic particles •Is each of the following statements true or false? If false, explain your reason. a.Protons are heavier than electrons. True b. Protons are attracted to neutrons. False. p+ are attracted to e- c. Electrons are so small that they have no electrical charge. False. e- have a -1 charge d. The nucleus contains all the protons and neutrons of an atom. True
  • 19. Exercise # 2 Subatomic particles •Using the periodic table, state the atomic number, number of protons, and number of electrons for an atom of each of the following elements: Element Atomic number p+ e- Nitrogen Magnesium Bromine
  • 21. Subatomic particles •Using the periodic table, state the atomic number, number of protons, and number of electrons for an atom of each of the following elements: Element Atomic number p+ e- Nitrogen 7 7 7 Magnesium 12 12 12 Bromine 35 35 35
  • 22. Exercise # 3 Subatomic particles •Consider an atom that has 79 electrons. a.How many protons are in its nucleus? b.What is its atomic number? c.What is its name, and what is its symbol?
  • 24. Subatomic particles •Consider an atom that has 79 electrons. a.How many protons are in its nucleus? 79 a.What is its atomic number? 79 a.What is its name, and what is its symbol?
  • 25. Subatomic particles •The number of protons gives atoms their identity. •Atomic number (Z) #of protons •Mass number (A) •#protons + #neutrons
  • 26. Information in the periodic table •Atomic mass or atomic weight: Weight average mass of all the natural occuring isotopes of an element.
  • 27. •Isotopes: Are atoms of the same element that have different mass number but the same chemical behavior. Atomic symbol for writing Isotopes: AZX X= chemical symbol for the element Z= Atomic number A= Mass number
  • 28. Identify protons and neutron in isotopes State the number of p+, e- and n in each of the following isotopes of Carbon (C). Exercise# 4 Isotopes Isotope Protons Electrons Neutrons 6 6 6 6 6 7 6 6 8
  • 29. Identify protons and neutron in isotopes Write the symbol for each of the following isotopes: a)A nitrogen atom with 8 neutrons. b)An atom with 20 protons and 22 neutrons. c)An atom with mass number 27 and 14 neutrons. Exercise# 5 Isotopes
  • 31. Write the symbol for each of the following isotopes: a)A nitrogen atom with 8 neutrons. 157N a)An atom with 20 protons and 22 neutrons. 4220Ca a)An atom with mass number 27 and 14 neutrons. 2713Al Exercise# 5 Isotopes
  • 33. Atomic theories •Theories that try to explain the structure of the atom. –John Dalton –J. J. Thomson –Ernest Rutherford –Niels Bohr –Erwin Schrodinger
  • 34. Evolution of the atomic theories Billiard ball model- a small, solid sphere
  • 35. Evolution of the atomic theories Law of Conservation of mass: States that the total mass present before a chemical reaction is the same as the total mass present after the chemical reaction; thus, mass is conserved. The law of conservation of mass was formulated by Antoine Lavoisier (1743-1794). This law was a result of his combustion.
  • 36. Evolution of the atomic theories Law of Constant composition or Law of definite proportions: Formulated by Joseph Proust (1754-1826). States that if a compound is broken down into its constituent elements, the masses of the constituents will always have the same proportions, regardless of the quantity or source of the original substance.
  • 37. Evolution of the atomic theories Law of Constant composition or Law of definite proportions: Jon Berzelius did experiments with about 2000 compounds Berzelius prepared and purified the necessary reagents, developed the techniques to perform the analyses, and collected data on the relative weights of atoms of 43 elements. That confirmed John Dalton's atomic theory as well as Proust's law showing that separate elements always combined in whole-number proportions. *Also introduced the symbolism with which chemical formulas are still written
  • 38. Evolution of the atomic theories How was Dalton wrong in his proposal? Not all atoms of the same element are exactly alike (isotopes). Atoms are made up of subatomic particles.
  • 39. J.J. Thomson •Discovered the electron in a series of experiments using cathode-ray tube. •In 1904 Thomson suggested a model of the atom as a sphere of positive matter in which electrons are positioned by electrostatic forces. “Plum-pudding” model
  • 40. Ernest Rutherford •Rutherford performed a series of experiments with radioactive alpha particles. • He found that while most of the alpha particles passed right through the gold foil, a small number of alpha particles passed through at an angle (as if they had bumped up against something) and some bounced straight back •Rutherford's experiments suggested that gold foil, and matter in general, had holes in it!
  • 41. Niels Bohr •Devised the atom as a small, positively charged nucleus surrounded by electrons that travel in circular orbits around the nucleus— similar in structure to the solar system.
  • 42. Erwin Schrodinger •Schrödinger model describes the probability that an electron can be found in a given region of space at a given time. This model no longer tells us where the electron is; it only tells us where it might be. •Introduced “wave mechanics” as a mathematical model.
  • 43. Evolution of the atomic theories
  • 44. Evolution of the atomic theories
  • 45. Electronic configuration Energy level: Specific energy that an electron has (bound by the electric field of the nucleus). e- in the lower energy levels are usually closer to the nucleus. Sublevel: Group of orbitals of equal energy within principal energy level. Orbital: Region around the nucleus where e-s of a certain energy are more likely to be found. (s, p,d and f)
  • 46. Electronic configuration List of the number of electrons in each sublevel within an atom, arranged by increasing energy.
  • 47. Electronic configuration Orbital´s maximum number of e- •S= 2 •P= 6 •d= 10 •f = 14
  • 50. Electronic configuration •To contruct the electronic configuration of an atom do the following: 1.Determine the number of electrons in the atom. 2.Put electrons moving from the lowest energy levels to the highest energy orbital available, starting with 1s (holds a maximum of two electrons). 3.Fill in the orbitals according to the number of electrons in the atom.
  • 51. Electronic configuration •Example: Write the electronic configuration of Lithium atom. 1.Electrons involved: atomic number 3 2.Begin with the 1s sublevel. 1s2 3. Fill in the needed orbitals, until all the electrons are being positioned. 1s2 2s1
  • 52. Electronic configuration •Write the electron configuration for : a.Nitrogen atom b.Silicon atom c. Chlorine atom
  • 54. Electronic configuration •Write the electron configuration for : a.Nitrogen atom 1s2 2s2 2p3 b.Silicon atom 1s2 2s2 2p6 3s2 3p2 c. Chlorine atom 1s2 2s2 2p6 3s2 3p5
  • 55. Electronic configuration •List of the number of electrons in each sublevel within an atom, arranged by increasing energy. •Chemistry book chapter 3 Pg 81 Orbital diagram •Boxes represent the orbitals and half arrows represent electrons.
  • 56. Electronic configuration Maximum number of e- •S= 2 •P= 6 •d= 10 •f = 14
  • 57. Aufbau´s principle •e-s fill orbitals starting at the lowest available energy state before filling higher states (1s before 2s).
  • 58. Pauli exclusion principle •States the an orbital can hold up to maximum of 2 e-´s, which are seeing as spinning on its axis, which generates a magnetic field. •An orbital can hold 0, 1, or 2 electrons only, and if there are two electrons in the orbital, they must have opposite (paired) spins.
  • 59. Hund´s rule •When filling sublevels other than s, electrons are placed in individual orbitals before they are paired up.
  • 61. Blocks in the periodic table
  • 62. Valence electrons •Electrons in the outermost energy level. •Given by the group number (representative elements).
  • 63. Valence electrons •Electrons in the outermost energy level. •Given by the group number (representative elements).
  • 64. Oxidation number •Shows the total number of e-´s which have been removed from an element (+) or added to an element (-).
  • 65. Periodic trends •Elctron configuration of atoms are an important factor in physical and chemical properties of the elements. •Periodic properties increases or decreases across a period, and then the trend is repeated again in each successive group.
  • 66. Periodic trends •Electron afinity: The ability of an atom to attract additional electrons. •Electronegativity: The relative ability of an element to attract electrons in a bond. •Ionization energy: Energy needed to remove the least tight bound electron from an atom in gaseous (g) state. •Atomic radius: Distance from the nucleus to the energy level that contains the valence (outermost) electrons.
  • 68. Writing formulas 1.Identify the cation and anion or polyatomic ion. 2.Balance the charge. 3.Write the formula, cation first, using the subscript from the charge balance.
  • 69. Subscripts in formulas •The subscripts in the formula represent the number of positive and negative ions that give an overall charge of zero.
  • 71. Check End of chapter