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UAIPD 08-0019
Dr. Dan Daly, Dr. Rachel Frazier,
Dr. Scott Spear
Process for Preparing Conductive Cellulose and
Cotton Using Ionic Liquids
Current Problems
• Intrinsic conducting polymers (ICPs) have immense
variety in physical and electronic/conductive
properties
• Polypyrrole (PPy) consist of five membered
heterocyclic rings
– Low resistance, redox properties, environmental stability
• Conductive polymers into nanostructure
– Oxidation process is unsafe and uses harsh chemicals
– Significant degradation in mechanical properties
• Novel process fabricating nanostructure conductive
polypyrrolecellulose fiber composites using Ionic
Liquid (IL) solvent
• IL acts as a solvent for the polymerization of pyyrole
and can dissolve as cellulose
– Combination of both properties lead to effectively
impregnate cellulose fibers as well as effectively
polymerize pyrrole
• Resulting in electrically conductive cellulose fiber composites
Technology
• Enhancement
– Mechanical and conductive properties
• Fe(III) absorption peaks at 65mg/g around 10 minutes
– Indications of significant improvement compared to other
processing routes
• Increased amounts of nanostructure polypyrrole particles
• Resistance of conductive cellulose fiber composite reduced
significantly with increased pyrrole concentration
• Degradation of strength and stiffness
Advantages
• Dr. Dan Daly
– Director
– 1 Patent
– 15 Patent Applications
• Department
– Alabama Innovation
and Mentoring of
Entrepreneurs
Inventors
• Dr. Rachel Frazier
– Research Engineer
– 1 Patent
– 6 Patent Applications
• Department
– Alabama Innovation
and Mentoring of
Entrepreneurs
• Dr. Scott Spear
– Research Engineer
– 1 Patent
– 7 Patent Applications
• Department
– Alabama Innovation
and Mentoring of
Entrepreneurs
dandaly@ua.edu rmfrazier@bama.ua.edu sspear@bama.ua.edu
Office for Technology Transfer
720 2nd Ct E
Tuscaloosa, AL 35401
UAIPD 08-0019
OTT@UA.edu
www.OTT.UA.edu

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UAIPD 08-0019

  • 1. UAIPD 08-0019 Dr. Dan Daly, Dr. Rachel Frazier, Dr. Scott Spear Process for Preparing Conductive Cellulose and Cotton Using Ionic Liquids
  • 2. Current Problems • Intrinsic conducting polymers (ICPs) have immense variety in physical and electronic/conductive properties • Polypyrrole (PPy) consist of five membered heterocyclic rings – Low resistance, redox properties, environmental stability • Conductive polymers into nanostructure – Oxidation process is unsafe and uses harsh chemicals – Significant degradation in mechanical properties
  • 3. • Novel process fabricating nanostructure conductive polypyrrolecellulose fiber composites using Ionic Liquid (IL) solvent • IL acts as a solvent for the polymerization of pyyrole and can dissolve as cellulose – Combination of both properties lead to effectively impregnate cellulose fibers as well as effectively polymerize pyrrole • Resulting in electrically conductive cellulose fiber composites Technology
  • 4. • Enhancement – Mechanical and conductive properties • Fe(III) absorption peaks at 65mg/g around 10 minutes – Indications of significant improvement compared to other processing routes • Increased amounts of nanostructure polypyrrole particles • Resistance of conductive cellulose fiber composite reduced significantly with increased pyrrole concentration • Degradation of strength and stiffness Advantages
  • 5. • Dr. Dan Daly – Director – 1 Patent – 15 Patent Applications • Department – Alabama Innovation and Mentoring of Entrepreneurs Inventors • Dr. Rachel Frazier – Research Engineer – 1 Patent – 6 Patent Applications • Department – Alabama Innovation and Mentoring of Entrepreneurs • Dr. Scott Spear – Research Engineer – 1 Patent – 7 Patent Applications • Department – Alabama Innovation and Mentoring of Entrepreneurs dandaly@ua.edu rmfrazier@bama.ua.edu sspear@bama.ua.edu
  • 6. Office for Technology Transfer 720 2nd Ct E Tuscaloosa, AL 35401 UAIPD 08-0019 OTT@UA.edu www.OTT.UA.edu

Editor's Notes

  1. Should read like Wikipedia entry. Try to focus on the high points.
  2. Closing slide. Make sure to add in UAIPD# then change font back to black.