Thermochemistry is the study of heat changes in chemical reactions. Exothermic reactions evolve heat while endothermic reactions absorb heat. The enthalpy of a reaction is the quantity of heat absorbed or evolved. Standard enthalpy of reaction is measured under standard conditions. Hess's law states that the enthalpy change of a reaction is the same regardless of the reaction pathway. Thermochemistry is applied in pyrometallurgy which involves processes like calcination, roasting, smelting, and refining to extract metals from ores.
Lecture materials for the Introductory Chemistry course for Forensic Scientists, University of Lincoln, UK. See http://forensicchemistry.lincoln.ac.uk/ for more details.
Topic Contains:
What is Thermo Chemistry ?
Define Origin of Heat of Reaction..
Exothermic Reaction..
Endothermic Reaction..
Graphical representation of Exothermic
and Endothermic reactions..
Different type of heat reactions..
Hess’s law..
Need of thermodynamics and the Laws of Thermodynamics.
Important principles and definitions of thermochemistry.
Concept of standard state and standard enthalpies of formations,
Integral and differential enthalpies of solution and dilution.
Calculation of bond energy, bond dissociation energy and resonance energy from thermochemical data.
Variation of enthalpy of a reaction with temperature – Kirchhoff’s equation.
Statement of Third Law of thermodynamics and calculation of absolute entropies of substances.
JFI -just for information
Lecture materials for the Introductory Chemistry course for Forensic Scientists, University of Lincoln, UK. See http://forensicchemistry.lincoln.ac.uk/ for more details.
Topic Contains:
What is Thermo Chemistry ?
Define Origin of Heat of Reaction..
Exothermic Reaction..
Endothermic Reaction..
Graphical representation of Exothermic
and Endothermic reactions..
Different type of heat reactions..
Hess’s law..
Need of thermodynamics and the Laws of Thermodynamics.
Important principles and definitions of thermochemistry.
Concept of standard state and standard enthalpies of formations,
Integral and differential enthalpies of solution and dilution.
Calculation of bond energy, bond dissociation energy and resonance energy from thermochemical data.
Variation of enthalpy of a reaction with temperature – Kirchhoff’s equation.
Statement of Third Law of thermodynamics and calculation of absolute entropies of substances.
JFI -just for information
scanning electron microscope for analysisM Ali Mohsin
SEM stands for scanning electron microscope. The SEM is a microscope that uses electrons instead of light to form an image. Since their development in the early 1950's, scanning electron microscopes have developed new areas of study in the medical and physical science communities.
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CFD Simulation of By-pass Flow in a HRSG module by R&R Consult.pptxR&R Consult
CFD analysis is incredibly effective at solving mysteries and improving the performance of complex systems!
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R&R and Tetra Engineering Group Inc. were asked to solve the issue with reduced steam production.
An inspection had shown that a significant amount of hot flue gas was bypassing the boiler tubes, where the heat was supposed to be transferred.
R&R Consult conducted a CFD analysis, which revealed that 6.3% of the flue gas was bypassing the boiler tubes without transferring heat. The analysis also showed that the flue gas was instead being directed along the sides of the boiler and between the modules that were supposed to capture the heat. This was the cause of the reduced performance.
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It is always satisfying when we can help solve complex challenges like this. Do your systems also need a check-up or optimization? Give us a call!
Work done in cooperation with James Malloy and David Moelling from Tetra Engineering.
More examples of our work https://www.r-r-consult.dk/en/cases-en/
Quality defects in TMT Bars, Possible causes and Potential Solutions.PrashantGoswami42
Maintaining high-quality standards in the production of TMT bars is crucial for ensuring structural integrity in construction. Addressing common defects through careful monitoring, standardized processes, and advanced technology can significantly improve the quality of TMT bars. Continuous training and adherence to quality control measures will also play a pivotal role in minimizing these defects.
Vaccine management system project report documentation..pdfKamal Acharya
The Division of Vaccine and Immunization is facing increasing difficulty monitoring vaccines and other commodities distribution once they have been distributed from the national stores. With the introduction of new vaccines, more challenges have been anticipated with this additions posing serious threat to the already over strained vaccine supply chain system in Kenya.
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Indigenized remote control interface card suitable for MAFI system CCR equipment. Compatible for IDM8000 CCR. Backplane mounted serial and TCP/Ethernet communication module for CCR remote access. IDM 8000 CCR remote control on serial and TCP protocol.
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Indigenized remote control interface card suitable for MAFI system CCR equipment. Compatible for IDM8000 CCR. Backplane mounted serial and TCP/Ethernet communication module for CCR remote access. IDM 8000 CCR remote control on serial and TCP protocol.
• Remote control: Parallel or serial interface
• Compatible with MAFI CCR system
• Copatiable with IDM8000 CCR
• Compatible with Backplane mount serial communication.
• Compatible with commercial and Defence aviation CCR system.
• Remote control system for accessing CCR and allied system over serial or TCP.
• Indigenized local Support/presence in India.
Application
• Remote control: Parallel or serial interface.
• Compatible with MAFI CCR system.
• Compatible with IDM8000 CCR.
• Compatible with Backplane mount serial communication.
• Compatible with commercial and Defence aviation CCR system.
• Remote control system for accessing CCR and allied system over serial or TCP.
• Indigenized local Support/presence in India.
• Easy in configuration using DIP switches.
Welcome to WIPAC Monthly the magazine brought to you by the LinkedIn Group Water Industry Process Automation & Control.
In this month's edition, along with this month's industry news to celebrate the 13 years since the group was created we have articles including
A case study of the used of Advanced Process Control at the Wastewater Treatment works at Lleida in Spain
A look back on an article on smart wastewater networks in order to see how the industry has measured up in the interim around the adoption of Digital Transformation in the Water Industry.
Saudi Arabia stands as a titan in the global energy landscape, renowned for its abundant oil and gas resources. It's the largest exporter of petroleum and holds some of the world's most significant reserves. Let's delve into the top 10 oil and gas projects shaping Saudi Arabia's energy future in 2024.
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4. Heat of a reaction
In a chemical reaction, the energy in the form of heat will either be evolved or
absorbed and this is called Heat of Reaction.
Heat is denoted by the symbol q.
• The sign of q is +ve if heat is Absorbed by the system.
• The sign of q is -ve if heat is Evolved by the system.
5. Exothermic Reactions
In all chemical changes energy, when heat is evolved by the reaction is
called Exothermic Reaction.
C + O2 CO2 ∆H = -393.7 kj/mol
Endothermic Reactions
In all chemical changes energy, when heat is absorbed by the reaction is
called Endothermic Reaction.
N2 + O2 2NO ∆H = +180.51 kj/mol
6. Heat of Reaction
Exothermicity
“out of” a system
Dq < 0
Endothermicity
“into” a system
Dq > 0
Energy
System
Surroundings
Energy
System
Surroundings
7. Spontaneous Reaction
A process which takes place on its own without any outside assistance and
moves from a non-equilibrium state towards an equilibrium state is termed
as Spontaneous Process or Natural Process.
Water flows from Higher level to lower level.
Neutralization of a strong acid with a strong base.
NaOH +HCl NaCl +H2O
8. Non Spontaneous Reaction
A process which doesn’t take place on its own and take place with
external assistance is termed as Non Spontaneous Reaction.
Pumping of water uphill.
Transfer of heat from cold interior part of the refrigerator to the hot
surroundings.
When nitrogen reacts with oxygen, nitric oxide is formed. This
reaction takes place by the absorbance of heat.
N2 + O2 2NO
9. Enthalpy
To take account of increase in internal energy and accompanying work done by
the gas, there is another property of the system is called Enthalpy or Heat
Content.
It is represented by H.
H = E + PV
Enthalpy is a State Function.
It is measured in Joules.
It is not possible, to measure the enthalpy of a system in a given state. however
change in enthalpy can be measured.
10. Enthalpy of a Reaction
The standard enthalpy of reaction is enthalpy of change which occurs when the certain
number of moles of reactants as indicated by the balanced chemical equation, react
together completely to give the products under standard condition, i.e 25◦C (298K) and one
atmospheric pressure.
2H2 + O2 2H2O ∆H = -285.8 KJ/mol
Enthalpy of Formation
The standard enthalpy of formation of a compound is the amount of heat absorbed or
evolved when one mole of the compound is formed from its elements.
The enthalpy of formation, for MgO is -692kJ/mol
Mg + 1/2O2 MgO ∆Hf=-692kj/mol
11. Enthalpy of Atomization
The amount of heat absorbed when one mole of gaseous atoms are formed
from the elements under standard conditions.
For example, the standard enthalpy of atomization of hydrogen under
standard conditions is given:
½ H2 H ∆Hat=218 kj/mol
Enthalpy of Combustion
The amount of heat evolved when one mole of a substance is completely burnt in
excess of oxygen under standard conditions.
For example, standard enthalpy of combustion of ethanol is ∆Hc = -1368 kj/mol.
C2H5OH + 3O2 2CO2 +3H2O ∆Hc = -1368 kj/mol
12. Enthalpy of Neutralization
The amount of heat evolved when one mole of hydrogen ions from an acid, react with one mole of
hydroxide ions from a base react to form one mole of water, is called enthalpy of neutralization.
For example, the enthalpy of neutralization of sodium hydroxide by hydrochloric acid is -57.4
Kj/mol.
HCl H+ (aq) + Cl-
NaOH Na+ + OH- (aq) ∆Hn = -57.4 Kj/mol
Enthalpy of Solution
The amount of heat absorbed or evolved when one ole of a substance is dissolved in so much
solvent that further dilution results in no detectable heat change.
For example , the enthalpy of solution of ammonium chloride is +16.2kj/mol and sodium carbonate
is -25.0kj/mol.
13. Measurement of Enthalpy of a Reaction
1. Glass Calorimeter
An ordinary glass calorimeter is used to find the value of ∆H for various
purposes. It consists of:
(a) Insulated container
(b) Thermometer
(c) Stirrer
Working
Reactants are placed in calorimeter.
When the reaction proceeds, the heat energy evolved or absorbed will
either warm or cool the system.
The temperature of the system is recorded before and after the chemical
reaction.
Knowing the change in temperature, mass of reactants & specific heat
of the reaction
Q = m × s × ∆T
14. 2. Bomb Calorimeter
A bomb calorimeter is used for the accurate determination of the enthalpy of
combustion for food, fuel and other compounds.
It consists of a strong cylindrical steel vessel usually lined with enamel to prevent
corrosion.
WORKING
A known mass is placed in a platinum crucible inside the Bomb.
The lid is screwed & oxygen is provided to maintain the
Pressure around about 20atm.
The initial temperature is measured
The enthalpy of combustion can be calculated from this formula
q = c x ∆T
15. Hess's Law Of Constant Heat Summation
“If a chemical change takes place by several different routes, the overall
enthalpy change is the same, regardless of the route by which the
chemical change occurs (provided the initial and final conditions are the
same).”
Single Step Process
2NaOH + CO2 Na2CO3+H2O ∆H=-89.08kJ
Two Step Process
NaOH+CO2 NaHCO3 ∆H1=-48.06kJ
NaHCO3+NaOH Na2CO3+H2O ∆H2=-41.02kJ
According to Hess’s law:
∆H=∆H1+∆H2
-89.08=-48.06-41.02
-89.08=-89.08
16. Application of Thermochemistry
Pyrometallurgy:
Pyrometallurgy is a branch of Extractive Metallurgy. It consists of the
thermal treatment of minerals and metallurgical ores and concentrates to
bring about physical and chemical transformations in the materials to enable
recovery of valuable metals
Pyrometallurgical processes are generally grouped into one or more of the
following categories:
1. Calcination,
2. Roasting,
3. Smelting,
4. Refining.
17. 1. Calcination:
The process of calcining - heating a substance to a high temperature, but
below its melting point, to bring about thermal decomposition.
2. Roasting:
Roasting is a process of heating of sulphide ore to a high temperature in
presence of air.
This process is similar like the reaction happening with Blast Furnace.
18. 3. Smelting:
Smelting involves thermal reactions in which at least one product is a molten
phase.
Metal oxides can then be smelted by heating with coke or charcoal (forms of
carbon), a reducing agent that liberates the oxygen as carbon dioxide leaving
a refined mineral.
4. Refining:
Refining is the removal of impurities from materials by a thermal process.
This covers a wide range of processes, involving different kinds of furnace or
other plant.