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USE OF HYDROMETALLURGY IN METAL
RECOVERY FROM MINE WASTES
BY : ALI MEHRI
SUPERVISOR : DR. KARIMI
1
CONTENT
 Introduction
 Types of mine waste
 Classification of minerals wastes
 Mine waste leaching
 References
2
Aspects :
1. Economical
2. Environmental
3
THE IMPORTANCE OF RECOVERING WASTE[1]
 Creates jobs
 Growth of an industry
 Utilize smaller solid waste dumpsters
 Converting waste materials into new products
 Reduce the consumption of fresh raw materials
4
ECONOMICAL ASPECTS
 Resource conservation
 Reduce energy usage
 Air pollution, including reductions in greenhouse gas generation
 Reduce water pollution (from land filling)
5
ENVIRONMENTALASPECTS[2]
6
MINERAL EXTRACTION: FROM MINING TO METAL[3]
Mining
Mineral processing
(beneficiation)
Metallurgical
extraction
Mineral
concentrate
Metal
Waste
rock
Tailings
Slags
7
COMPARISON OF WASTE AND PRODUCT[11]
 Cut – off grade ores
 Tailings from mineral products
 Residues
8
TYPES OF MINE WASTE[4][5]
9
CLASSIFICATION OF MINERALS WASTES[4]
10
WASTE CUT OFF GRADES[6]
 “Acid mine drainage” refers to a particular process whereby low
pH mine water is formed from the oxidation of sulphide minerals
 AMD is particularly prevalent in both metallic mineral and coal
mines.
11
WHAT IS AMD[3]
12
PROCESS[7]
13
IMPACTS OF AMD
General equations for this process are:
 2FeS2 + 7O2+ 2H2O → 2Fe2+ + 4SO4
2- + 4H+
 4Fe2+ + O2 + 4H+  4Fe3+ + 2H2O
 4Fe3+ + 12H2O  4Fe(OH)3 + 12H+
 FeS2 + 14Fe3+ + 8H2O → 15Fe2++ 2SO4
2- + 16H+
14
WHAT IS AMD[8]
 Aluminum
1. Gibbsite
2. Bohmite
3. Diaspore
15
MINE WASTE LEACHING[9]
RED MUD
16
50 % of bauxite is red-mud:- a waste-product from the Bayers
Process:
 Fe2O3: 70 wt. pct. (35-38% metal value)
 Al2O3: 10 wt. pct.
 TiO2: 7.0 wt. pct.
 CaO: 7.5 wt. pct
17
RED MUD[10]
18
RED MUD RECOVERY
Product Note
1) Pyro only
Pig iron,
Ti-rich slag
(REE)/
Metallic iron
① smelting : Iron oxide Reduction
in blast furnace or similar reacto
② solid state reduction
Disadvantage
• High Na contents in Red Mud:
sodium oxide deposition -.
• High drying cost of red mud
2) Pyro + Hydro
Pig iron,
REE
(from REE slag)
• Pig iron by reluctant,
Concentration of REE in slag
• Recovery of Concentrated REE by
hydro method
• High sodium contents and Waste
water problem
3) Hydro only REE
• Selective leaching of REE (Fe2O3
is not leached, Using HNO3, Y
• 96%, Sc 80%, light lanthanides
30-50%)
Selective precipitation and Solvent
Extraction
19
RECOVERY OF IRON[10]
20
RECOVERY OF TITANIUM OXIDE[10]
Sintering
Al2O3 + Na2CO3 = 2NaAlO2 + CO2(g)
Temperature of operation : 850-1100oC
Time : 2 hours
Leaching
NaAlO2(s) = NaAlO2(aq)
Temperature of operation : 25-100 oC
Time : 5-30 minutes, Red Mud to water :
2-50 gpl
21
SINTERING AND LEACHING OF ALUMINA[10]
 Copper
1. Sandy ore (granular)
2. Slimy ore (composed of very fine particles that are difficult to
settle)
3. Molybdenite
4. Rhenium
5. Cobalt
22
MINE WASTE LEACHING[9]
23
SANDY ORE[9]
SLIMY ORE[9]
• Using sponge iron • Using hydrogen sulfide
24
25
MOLYBDENITE & RHENIUM[9]
26
COBALT[9]
 Platinum
1. Native platinum ores
2. Gold ores
3. Nonferrous metals sulfide ores
27
MINE WASTE LEACHING[9]
PtC14 + 2NH4Cl →(NH4)2[PtCl6]
PdC12 + 4NH3 →[Pd(NH3)4]C12
[Pd(NH3)4]C12 + 2HCI → [Pd(NH3)2]C12 + 2NH4C1
1. Mattias Bäckström. 2007-2013. Compendium of mining and
processing waste management technologies
2. https://en.wikipedia.org/wiki/Recycling
3. Mark Muller. 2009. Mine wastes. Pages 3-7
4. CJ Mitchell, DJ Harrison, Dr. HL Robinson, Dr N Ghazireh.2004.
minerals from waste. Pages 1-2
5. Pranjit Sharmah. 2013. dumping of mining waste. Pages 5-7
6. S.Najmedin Almasi, Amir Khademian, Reza Yarahmadi. 2015.
Determination of Leaching Cutoff Grade Using. Page 1279
28
REFERENCES
7. Mark Muller. 2009. Environmental and Social Concerns. Pages 3-
4
8. V.GOUTHAM. 2011. Treatment methods of acid mine drainage
and a case study on selective recovery of metals. Page 3
9. Fathi Habashi. 1999. Hydrometallurgy. Pages 242-252 & 229-233
10. Brajendra Mishra. 2015. Bauxite Residue Valorisation and Best
Practices. Pages 3-28
11. https://www.ausimmbulletin.com/feature/towards-zero-waste/
29
REFERENCES

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Use of hydrometallurgy in metal recovery from mine wastes

  • 1. USE OF HYDROMETALLURGY IN METAL RECOVERY FROM MINE WASTES BY : ALI MEHRI SUPERVISOR : DR. KARIMI 1
  • 2. CONTENT  Introduction  Types of mine waste  Classification of minerals wastes  Mine waste leaching  References 2
  • 3. Aspects : 1. Economical 2. Environmental 3 THE IMPORTANCE OF RECOVERING WASTE[1]
  • 4.  Creates jobs  Growth of an industry  Utilize smaller solid waste dumpsters  Converting waste materials into new products  Reduce the consumption of fresh raw materials 4 ECONOMICAL ASPECTS
  • 5.  Resource conservation  Reduce energy usage  Air pollution, including reductions in greenhouse gas generation  Reduce water pollution (from land filling) 5 ENVIRONMENTALASPECTS[2]
  • 6. 6 MINERAL EXTRACTION: FROM MINING TO METAL[3] Mining Mineral processing (beneficiation) Metallurgical extraction Mineral concentrate Metal Waste rock Tailings Slags
  • 7. 7 COMPARISON OF WASTE AND PRODUCT[11]
  • 8.  Cut – off grade ores  Tailings from mineral products  Residues 8 TYPES OF MINE WASTE[4][5]
  • 10. 10 WASTE CUT OFF GRADES[6]
  • 11.  “Acid mine drainage” refers to a particular process whereby low pH mine water is formed from the oxidation of sulphide minerals  AMD is particularly prevalent in both metallic mineral and coal mines. 11 WHAT IS AMD[3]
  • 14. General equations for this process are:  2FeS2 + 7O2+ 2H2O → 2Fe2+ + 4SO4 2- + 4H+  4Fe2+ + O2 + 4H+  4Fe3+ + 2H2O  4Fe3+ + 12H2O  4Fe(OH)3 + 12H+  FeS2 + 14Fe3+ + 8H2O → 15Fe2++ 2SO4 2- + 16H+ 14 WHAT IS AMD[8]
  • 15.  Aluminum 1. Gibbsite 2. Bohmite 3. Diaspore 15 MINE WASTE LEACHING[9]
  • 17. 50 % of bauxite is red-mud:- a waste-product from the Bayers Process:  Fe2O3: 70 wt. pct. (35-38% metal value)  Al2O3: 10 wt. pct.  TiO2: 7.0 wt. pct.  CaO: 7.5 wt. pct 17 RED MUD[10]
  • 18. 18 RED MUD RECOVERY Product Note 1) Pyro only Pig iron, Ti-rich slag (REE)/ Metallic iron ① smelting : Iron oxide Reduction in blast furnace or similar reacto ② solid state reduction Disadvantage • High Na contents in Red Mud: sodium oxide deposition -. • High drying cost of red mud 2) Pyro + Hydro Pig iron, REE (from REE slag) • Pig iron by reluctant, Concentration of REE in slag • Recovery of Concentrated REE by hydro method • High sodium contents and Waste water problem 3) Hydro only REE • Selective leaching of REE (Fe2O3 is not leached, Using HNO3, Y • 96%, Sc 80%, light lanthanides 30-50%) Selective precipitation and Solvent Extraction
  • 21. Sintering Al2O3 + Na2CO3 = 2NaAlO2 + CO2(g) Temperature of operation : 850-1100oC Time : 2 hours Leaching NaAlO2(s) = NaAlO2(aq) Temperature of operation : 25-100 oC Time : 5-30 minutes, Red Mud to water : 2-50 gpl 21 SINTERING AND LEACHING OF ALUMINA[10]
  • 22.  Copper 1. Sandy ore (granular) 2. Slimy ore (composed of very fine particles that are difficult to settle) 3. Molybdenite 4. Rhenium 5. Cobalt 22 MINE WASTE LEACHING[9]
  • 24. SLIMY ORE[9] • Using sponge iron • Using hydrogen sulfide 24
  • 27.  Platinum 1. Native platinum ores 2. Gold ores 3. Nonferrous metals sulfide ores 27 MINE WASTE LEACHING[9] PtC14 + 2NH4Cl →(NH4)2[PtCl6] PdC12 + 4NH3 →[Pd(NH3)4]C12 [Pd(NH3)4]C12 + 2HCI → [Pd(NH3)2]C12 + 2NH4C1
  • 28. 1. Mattias Bäckström. 2007-2013. Compendium of mining and processing waste management technologies 2. https://en.wikipedia.org/wiki/Recycling 3. Mark Muller. 2009. Mine wastes. Pages 3-7 4. CJ Mitchell, DJ Harrison, Dr. HL Robinson, Dr N Ghazireh.2004. minerals from waste. Pages 1-2 5. Pranjit Sharmah. 2013. dumping of mining waste. Pages 5-7 6. S.Najmedin Almasi, Amir Khademian, Reza Yarahmadi. 2015. Determination of Leaching Cutoff Grade Using. Page 1279 28 REFERENCES
  • 29. 7. Mark Muller. 2009. Environmental and Social Concerns. Pages 3- 4 8. V.GOUTHAM. 2011. Treatment methods of acid mine drainage and a case study on selective recovery of metals. Page 3 9. Fathi Habashi. 1999. Hydrometallurgy. Pages 242-252 & 229-233 10. Brajendra Mishra. 2015. Bauxite Residue Valorisation and Best Practices. Pages 3-28 11. https://www.ausimmbulletin.com/feature/towards-zero-waste/ 29 REFERENCES

Editor's Notes

  1. Landfilling = دفن : by reducing the need for "conventional" waste disposal Incineration = تبدیل بخاکستر کردن Conventional = مرسوم Emissions = تولید گازهای گلخانه ای Conservation = حفاظت
  2. Whereby = به موجب آن Impacts = اثرات Prevalent = شایع
  3. Precipitated = رسوب
  4. wt. pct=weight percent
  5. Gpl=
  6. در بعضی مواقع کانی های سولفیدی به وسیله ی لایه ای از کانی های اکسیده پوشیده شده اند، بنابراین مانع از جدایش آن به روش فلوتاسیون می شوند.در این حالت اگر کانه دانه ای باشد، به یک شکل و اگر شامل مواد بسیار ریز باشد به شکلی دیگر بازیابی می شوند.