IRON ORE PELLETIZING PROCESS
Dr. Hassan Z. Harraz
hharraz2006@yahoo.com
Autum 2023
@Hassan Harraz 2023
Pelletizing Process
Keywords:
Abstract
1. INTRODUCTION
1. INTRODUCTION
1. INTRODUCTION
1. INTRODUCTION
1.1. Straight Grate Induration Process
Figure 3. Schematic diagram of the straight grate induration process /straight grate pelletizing process
(Mourão et al., 2013).
1.2. Grate-Rotary kiln Induration Process
Figure 4. Schematic diagram of the grate-rotary kiln induration process/ grate-kiln pelletizing
process (also known as the rotary-kiln process) (Mourão et al., 2013).
1.2. Iron Ore Pelletizing Rotary Kiln
Figure 2: Ratios of pellets produced by different
pelletizing processes in China in 2000 and 2011.
Table 1: Main producers of iron ore pellets in
the world between 2010 and 2012 (Mt per
year) (Narciso, 2013)
2. PREPARATION IRON ORE PELLETS
Fig. 1: Process flow chart of preparation of pellets
Iron pellets
2.1. Iron Ore Pellets Produced Worldwide
2.2. Potential Future Iron Ore Pellets
Figure 1. World installed pelletizing capacity (millions of tonnes/year).
Source: Prepared by the author with data from Tuck and Virta [2011].
2.3. Potential Future Suppliers of DR Grade Pellet Feed
2.4. Iron Ore Pellets Market Forecast 2023-2033
IronOre Pellets MarketSize, 2022-
2032
3. IRON ORE PELLETIZING PROCESS
Figure 2. Schematic diagram of the pelletizing process.
3.1. Pelletizing Process and Raw Materials
Table 1. Iron ore products classification for ironmaking (after Mourão, 2008).
4. SPECIFICATION REQUIREMENTS OF PELLET FEED
4. SPECIFICATION REQUIREMENTS OF PELLET FEED
5. GREEN BALL FORMATION AND PROPERTIES
5.1. Green Ball Formation
5. GREEN BALL FORMATION AND PROPERTIES
5.1. Green Ball Formation
5. GREEN BALL FORMATION AND PROPERTIES
5.2. Pretreatment of Pellet Feed
6. BINDERS
6.1. Binders and Additives Used in the Pelletizing Process
6.1. New Binders
4.1. New Binders
Table 3. Patents about organic binders in the iron ore pelletizing process.
6.1. New Binders
6.2. Evolution of Binder for Iron Ore Pelletizing
7. INDURATION TECHNOLOGIES
7. INDURATION TECHNOLOGIES…(Cont.)
8. INDURATION OF GREEN PELLETS
8. INDURATION OF GREEN PELLETS
9. QUALITY REQUIREMENTS FOR FIRED PELLETS
Table 2. Quality specification of iron ore pellets.
10. CHALLENGES AND INNOVATIONS IN IRON ORE PELLETIZING
11. DISCUSSIONS
11. DISCUSSIONS
11. DISCUSSIONS
CONCLUSIONS
References
Abouzeid A, Seddik A. Effectof Iron Ore Properties on its Balling Behavior. Elsevier Sequoia S.A.: Lausanne; 1980
Ball D. Agglomeration of Iron Ores. New York: American Elsevier Pub. Co.; 1973
Biswas, A.K. Principles of Blast Furnace Ironmaking; Cootha Publishing House: Brisbane, Australia, 1981; pp. 33–39. ISBN 10:0949917001.
Borim J. Modelagem e controle de um processo de endurecimento de pelotas de minério de ferro [dissertation]. Belo Horizonte: Universidade Federal de
Minas Gerais; 2000
Campos A, FonsecaV. Pelotização. In: Luz A, Sampaio J, França S, editors.Tratamento de minérios. 5th ed. Rio de Janeiro: CETEM/MCT; 2010. pp. 705-750
China Metallurgical Construction Association. Code for Design of Iron Pelletizing Engineering; China Planning Press: Beijing, China, 2009; pp. 20–25. ISBN
1580177244.
Fu, J.Y.; Zhu, D.Q. Basic Principles, Techniques and Equipment of the Iron Ore Oxidized Pellets; Central South University Press: Changsha, China, 2005; pp. 323–
336. ISBN 9787811050516.
Gao, Q.; Shen, F.; Jiang, X.; Wei, G.; Zheng, H.Y. Gas-solid reduction kinetic model of MgO-fluxed pellets. Int. J. Miner. Metall. Mater. 2014, 21, 12–17. [CrossRef]
Haas LA, Aldinger JA, Zahl RK. Effectiveness of Organic Binders for Iron Ore Pelletization. Pittsburgh: U.S. Department of the Interior. Bureau of Mines; 1989
(Report of Investigations, RI 9230)
Lima J. Estudo da carboxi-metil-celulose como aglomerante para pelotização [thesis]. São Paulo: Escola Politécnica da Universidade São Paulo; 1991
Metso. Iron ore pelletizing [Internet].2017. Available from: http://www.metso.com/products/iron-ore-pelletizing/ [Accessed: October06, 2017]
Meyer K. Pelletizing of Iron Ores.Heidelberg: Springer-Verlag; 1980. p. 291 não encontrado
Moraes S, Comparação de desempenho de aglomerante orgânico em relação à bentonita na operação de pelotização de concentrados de minério de ferro
brasileiros de diversasprocedências.[dissertation].São Paulo: Escola Politécnica da Universidade São Paulo; 2004
Moraes S, Lima J, Neto J. Influence of dispersants on the rheological and colloidal properties of iron ore ultrafine particles and their effect on the pelletizing
process—Areview. Journal of Materials Research and Technology.2013;2:386-391
Mourão J, Huerta M, de Medeiros U, Cameron I, O’Leary K, Howey C. Guidelines for selecting pellet plant technology. In: 6th International Congress on the
Science and Technology of Ironmaking-ICSTI, Rio de Janeiro, RJ, Brazil, October 14–18, 2012, pp. 2162–2175.
Mourão J. Estudo Prospectivo do Setor Siderúrgico: NT Minério de Ferro e Pelotas Situação Atual e Tendências 2025. Brasília: Centro de Gestão e Estudos
Estratégicos; 2008
Nabeel, M.; Karasev, A.; Jönsson, P.G. Evaluation of dust generation during mechanical wear of iron ore pellets. ISIJ Int. 2016, 56, 960–966. [CrossRef]
Sadrnezhaad, S.K.; Ferdowsi, A.; Payab, H. Mathematical model for a straight grate iron ore pellet induration process of industrial scale. Comp. Mater. Sci. 2009,
44, 296–302. [CrossRef]
Sandra Lúcia de Moraes, José Renato Baptista de Lima and Tiago Ramos Ribeiro. Iron Ore Pelletizing Process: An Overview. Chapter 3.
http://dx.doi.org/10.5772/intechopen.73164
Shen, F.; Gao, Q.; Jiang, X.; Wei, G.; Zheng, H. Effect of magnesia on the compressive strength of pellets. Int. J. Miner. Metall. Mater. 2014, 21, 431–437.
[CrossRef]
Tuck C, Virta R. 2011 minerals yearbook: Iron ore. USGS [Internet]. 2013. Available from: http://minerals.usgs.gov/minerals/pubs/commodity/iron_ore/myb1-
2011-feore.pdf [Accessed: May, 2014]
Vale. Entenda como funciona o processo de pelotização em nossas usinas [Internet]. 2017. Available from:
http://www.vale.com/brasil/PT/aboutvale/news/Paginas/entenda-funcionaprocesso-pelotizacao-usinas.aspx[Accessed: October 06, 2017]
Wynnckyj J, Fahidy T. Solid state sintering in the induration of iron ore pellets. Metallurgical Transactions. 1974; 5: 991-999
References
Bleifuss, R.L., Getzrnan, H.E., 1991. Replacement of limestone and dolomite with lime/dolomite hydrate for the production of fluxed pellets. In: Proceedings,
Annual Meeting—Minnesota Section AIME, 64th Annual Meeting of the Society for Mining, Metallurgy, and Exploration, January 16–17, 1991.
SME-AIME, Littleton, CO, pp. 195–206.
Boldyrev, V.V., Pavlov, S.V., Goldberg, E.L., 1996. Interrelation between fine grinding and mechanicalactivation. Int. J. Miner. Process. 44–45, 181–185.
Chaigneau, R., 2013. A helicopter view on the future of pelletizing. In: 3rd Symposium on Iron Ore Pelletizing. Quebec, Canada. 29 September–2
October, 2013.
CRU Analysis, 2011. Iron Ore Market: Main Report 2011. CRU International Ltd, London.
de Souza, R.P., 1976. Production of pellets in CVRD using hydrated lime as binder, is growing up fast. In: Ironmaking Proceedings, Metallurgical
Society of AIME Iron and Steel Division, 35th Annual Ironmaking Conference, March 29–April 1, St. Louis, MO, pp. 182–196.
Eisele, T.C., Kawatra, S.K., 2010. A review of binders in iron ore pelletization. Miner. Process. Extr. Metall. Rev. 24 (1), 1–90.
Fu, J.-y., Zhu, D.-g., 2007. Principle, Technology and Equipment of Iron Ore Pelletizing. Central South University Press, Changsha, 2007.
Indian Bureau of Mines, 2011. Vision 2020 (Iron & Steel), Chapter4—Agglomeration.
Liu, G.-y., Zhu, D.-q., Pan, J., Zhang, K.-c., Tian, F.-c., Hu, Y.-m., Liu, S.-l., 2005. Industrial tests on using modified bentonite to improve iron ore
pelletizing. Sintering Pelletizing 30 (4), 13–16.
Meyer, K., 1980. Pelletizing of Iron Ores. Springer Verlag, Berlin, ISBN: 3540102159, ISSN: 3514002460.
Mourão, J.M., 2012. Guidelines for selecting pellet plant technology. In: 6th International Congress on the Science and Technology of Ironmaking-ICSTI,
Rio de Janeiro, RJ, Brazil, October 14–18, 2012, pp. 2162–2175.
Murr, D.L., Englund, D.J., 1988. Development and Production of Organic-Limestone Pellets. National Steel Pellet Co. and Hanna Research Center,
Minnesota.
Narciso, J.J., 2013. A compilation of iron ore pellet production, volumes 2010–2012, Primarily from Public Domain Data. In: 3rd Symposium on Iron Ore
Pelletizating, Quebec City, Canada, 30 September, 2013.
Oja, K., 2013. Straight grate vs grate kiln. In: 3rd Symposium on Iron Ore Pelletizing. Quebec, Canada. 29 September–2 October, 2013.
Pan, J., Zhu, D.Q., Xiong, S.A., Mendes, V., 2008. Improving the pelletization of refractory hematite by high pressure grinding rolls. In: Duo, W.D., Yao,
S.C., Hang, W.F., Cheng, Z.L., Long, H. (Eds.), Proceedings of XXIV International Mineral Processing Congress, Beijing, China, pp. 2857–
2865.
Penttinen, M., 2013. Optimizing iron ore pelletization with the use of custom-formulated binder compositions. In: 3rd Symposium on Iron Ore Pelletizing.
Quebec, Canada. 29 September–2 October, 2013.
Poveromo, J.J., 2014. Future trends in Ironmaking, prepared for McMaster blast furnace ironmaking course, May 11–16, 2014.
Qiu, G.-z., Jiang, T., Li, H.-x., Wang, D.-z., 2003a. Functions and molecular structure of organic binders for iron ore pelletization. Colloids Surf. A
Physicochem. Eng. Asp. 224, 11–22.
Qiu, G.-z., Jiang, T., Huang, Z.-c., Zhu, D.-q., 2003b. Characterization of preparing cold bonded pellets for direct reduction using an organic binder. ISIJ
Int. 43 (1), 20–25.
Thomas, S., Collin, B., 2013. Recent technological advancements in high capacity pellet plants. In: 3rd Symposium on Iron Ore Pelletizing, Quebec,
Canada, 29 September–2 October, 2013.
Wang, C.-a., Xiong, S.-a., Zhu, D.-q., 2002. Effect of high pressure roller mill pretreating concentrates on green ball properties. Sintering Pelletizing 27,
12–15.
Wang, C.-a., Wang, X.-j., Hu, C.-f., Huo, L.-c., 2005. Study of the activation mechanisms about pretreating magnetite concentrate by high pressure
grinding. Sintering Pelletizing 30, 16–18.
Zhang, H.-q., Qi, Y.-g., 2005. The application on improving the quality of iron ore pellets by roller press. Min. Eng. 3, 37–39.
Zhu, D.-g., Wang, Z.-y., Pan, J., Li, J., Xu, X.-f., 2007. Improvement of sintering behaviors of Brazilian specularite concentrate by damp milling. Iron
Steel 42, 12–16.
Zhu, D.-Q., Li, H.-M., Yu, W., Wang, B., Pan, J., 2009. An organic activated bentonite mechanism for improving pelletization. J. Chongqing Univ. (Nat.
Sci. Ed.), 32 (5), 582–588.
Zhu, D.-g., Yu, W., Chun, T.-j., Pan, J., 2011b. Improving the pelletization of fluxed hematite pellets by hydrated lime. In: 2011TMS. San Diego, USA, 27
February–3 March 2011.
Zhu, D.-q., Xiong, S.-a., Pan, J., Zhou, X.-l., 2011c. Improving pelletization of magnetite concentrate by organic complex bentonite and its industrial
application. J. Cent. South Univ. 42 (2), 279–286.

Pelletizing Process.pdf

  • 1.
    IRON ORE PELLETIZINGPROCESS Dr. Hassan Z. Harraz hharraz2006@yahoo.com Autum 2023 @Hassan Harraz 2023 Pelletizing Process
  • 2.
  • 3.
  • 4.
  • 5.
  • 6.
  • 7.
  • 8.
    1.1. Straight GrateInduration Process
  • 10.
    Figure 3. Schematicdiagram of the straight grate induration process /straight grate pelletizing process (Mourão et al., 2013).
  • 11.
    1.2. Grate-Rotary kilnInduration Process
  • 12.
    Figure 4. Schematicdiagram of the grate-rotary kiln induration process/ grate-kiln pelletizing process (also known as the rotary-kiln process) (Mourão et al., 2013).
  • 13.
    1.2. Iron OrePelletizing Rotary Kiln
  • 14.
    Figure 2: Ratiosof pellets produced by different pelletizing processes in China in 2000 and 2011. Table 1: Main producers of iron ore pellets in the world between 2010 and 2012 (Mt per year) (Narciso, 2013)
  • 15.
  • 16.
    Fig. 1: Processflow chart of preparation of pellets
  • 17.
  • 18.
    2.1. Iron OrePellets Produced Worldwide
  • 20.
    2.2. Potential FutureIron Ore Pellets
  • 21.
    Figure 1. Worldinstalled pelletizing capacity (millions of tonnes/year). Source: Prepared by the author with data from Tuck and Virta [2011].
  • 22.
    2.3. Potential FutureSuppliers of DR Grade Pellet Feed
  • 23.
    2.4. Iron OrePellets Market Forecast 2023-2033 IronOre Pellets MarketSize, 2022- 2032
  • 24.
    3. IRON OREPELLETIZING PROCESS
  • 26.
    Figure 2. Schematicdiagram of the pelletizing process.
  • 27.
    3.1. Pelletizing Processand Raw Materials
  • 28.
    Table 1. Ironore products classification for ironmaking (after Mourão, 2008).
  • 29.
  • 30.
  • 31.
    5. GREEN BALLFORMATION AND PROPERTIES 5.1. Green Ball Formation
  • 32.
    5. GREEN BALLFORMATION AND PROPERTIES 5.1. Green Ball Formation
  • 33.
    5. GREEN BALLFORMATION AND PROPERTIES 5.2. Pretreatment of Pellet Feed
  • 34.
  • 35.
    6.1. Binders andAdditives Used in the Pelletizing Process
  • 37.
  • 38.
  • 39.
    Table 3. Patentsabout organic binders in the iron ore pelletizing process.
  • 40.
  • 41.
    6.2. Evolution ofBinder for Iron Ore Pelletizing
  • 42.
  • 43.
  • 44.
    8. INDURATION OFGREEN PELLETS
  • 45.
    8. INDURATION OFGREEN PELLETS
  • 46.
    9. QUALITY REQUIREMENTSFOR FIRED PELLETS
  • 47.
    Table 2. Qualityspecification of iron ore pellets.
  • 48.
    10. CHALLENGES ANDINNOVATIONS IN IRON ORE PELLETIZING
  • 49.
  • 50.
  • 51.
  • 52.
  • 53.
    References Abouzeid A, SeddikA. Effectof Iron Ore Properties on its Balling Behavior. Elsevier Sequoia S.A.: Lausanne; 1980 Ball D. Agglomeration of Iron Ores. New York: American Elsevier Pub. Co.; 1973 Biswas, A.K. Principles of Blast Furnace Ironmaking; Cootha Publishing House: Brisbane, Australia, 1981; pp. 33–39. ISBN 10:0949917001. Borim J. Modelagem e controle de um processo de endurecimento de pelotas de minério de ferro [dissertation]. Belo Horizonte: Universidade Federal de Minas Gerais; 2000 Campos A, FonsecaV. Pelotização. In: Luz A, Sampaio J, França S, editors.Tratamento de minérios. 5th ed. Rio de Janeiro: CETEM/MCT; 2010. pp. 705-750 China Metallurgical Construction Association. Code for Design of Iron Pelletizing Engineering; China Planning Press: Beijing, China, 2009; pp. 20–25. ISBN 1580177244. Fu, J.Y.; Zhu, D.Q. Basic Principles, Techniques and Equipment of the Iron Ore Oxidized Pellets; Central South University Press: Changsha, China, 2005; pp. 323– 336. ISBN 9787811050516. Gao, Q.; Shen, F.; Jiang, X.; Wei, G.; Zheng, H.Y. Gas-solid reduction kinetic model of MgO-fluxed pellets. Int. J. Miner. Metall. Mater. 2014, 21, 12–17. [CrossRef] Haas LA, Aldinger JA, Zahl RK. Effectiveness of Organic Binders for Iron Ore Pelletization. Pittsburgh: U.S. Department of the Interior. Bureau of Mines; 1989 (Report of Investigations, RI 9230) Lima J. Estudo da carboxi-metil-celulose como aglomerante para pelotização [thesis]. São Paulo: Escola Politécnica da Universidade São Paulo; 1991 Metso. Iron ore pelletizing [Internet].2017. Available from: http://www.metso.com/products/iron-ore-pelletizing/ [Accessed: October06, 2017] Meyer K. Pelletizing of Iron Ores.Heidelberg: Springer-Verlag; 1980. p. 291 não encontrado Moraes S, Comparação de desempenho de aglomerante orgânico em relação à bentonita na operação de pelotização de concentrados de minério de ferro brasileiros de diversasprocedências.[dissertation].São Paulo: Escola Politécnica da Universidade São Paulo; 2004 Moraes S, Lima J, Neto J. Influence of dispersants on the rheological and colloidal properties of iron ore ultrafine particles and their effect on the pelletizing process—Areview. Journal of Materials Research and Technology.2013;2:386-391 Mourão J, Huerta M, de Medeiros U, Cameron I, O’Leary K, Howey C. Guidelines for selecting pellet plant technology. In: 6th International Congress on the Science and Technology of Ironmaking-ICSTI, Rio de Janeiro, RJ, Brazil, October 14–18, 2012, pp. 2162–2175. Mourão J. Estudo Prospectivo do Setor Siderúrgico: NT Minério de Ferro e Pelotas Situação Atual e Tendências 2025. Brasília: Centro de Gestão e Estudos Estratégicos; 2008 Nabeel, M.; Karasev, A.; Jönsson, P.G. Evaluation of dust generation during mechanical wear of iron ore pellets. ISIJ Int. 2016, 56, 960–966. [CrossRef] Sadrnezhaad, S.K.; Ferdowsi, A.; Payab, H. Mathematical model for a straight grate iron ore pellet induration process of industrial scale. Comp. Mater. Sci. 2009, 44, 296–302. [CrossRef] Sandra Lúcia de Moraes, José Renato Baptista de Lima and Tiago Ramos Ribeiro. Iron Ore Pelletizing Process: An Overview. Chapter 3. http://dx.doi.org/10.5772/intechopen.73164 Shen, F.; Gao, Q.; Jiang, X.; Wei, G.; Zheng, H. Effect of magnesia on the compressive strength of pellets. Int. J. Miner. Metall. Mater. 2014, 21, 431–437. [CrossRef] Tuck C, Virta R. 2011 minerals yearbook: Iron ore. USGS [Internet]. 2013. Available from: http://minerals.usgs.gov/minerals/pubs/commodity/iron_ore/myb1- 2011-feore.pdf [Accessed: May, 2014] Vale. Entenda como funciona o processo de pelotização em nossas usinas [Internet]. 2017. Available from: http://www.vale.com/brasil/PT/aboutvale/news/Paginas/entenda-funcionaprocesso-pelotizacao-usinas.aspx[Accessed: October 06, 2017] Wynnckyj J, Fahidy T. Solid state sintering in the induration of iron ore pellets. Metallurgical Transactions. 1974; 5: 991-999
  • 54.
    References Bleifuss, R.L., Getzrnan,H.E., 1991. Replacement of limestone and dolomite with lime/dolomite hydrate for the production of fluxed pellets. In: Proceedings, Annual Meeting—Minnesota Section AIME, 64th Annual Meeting of the Society for Mining, Metallurgy, and Exploration, January 16–17, 1991. SME-AIME, Littleton, CO, pp. 195–206. Boldyrev, V.V., Pavlov, S.V., Goldberg, E.L., 1996. Interrelation between fine grinding and mechanicalactivation. Int. J. Miner. Process. 44–45, 181–185. Chaigneau, R., 2013. A helicopter view on the future of pelletizing. In: 3rd Symposium on Iron Ore Pelletizing. Quebec, Canada. 29 September–2 October, 2013. CRU Analysis, 2011. Iron Ore Market: Main Report 2011. CRU International Ltd, London. de Souza, R.P., 1976. Production of pellets in CVRD using hydrated lime as binder, is growing up fast. In: Ironmaking Proceedings, Metallurgical Society of AIME Iron and Steel Division, 35th Annual Ironmaking Conference, March 29–April 1, St. Louis, MO, pp. 182–196. Eisele, T.C., Kawatra, S.K., 2010. A review of binders in iron ore pelletization. Miner. Process. Extr. Metall. Rev. 24 (1), 1–90. Fu, J.-y., Zhu, D.-g., 2007. Principle, Technology and Equipment of Iron Ore Pelletizing. Central South University Press, Changsha, 2007. Indian Bureau of Mines, 2011. Vision 2020 (Iron & Steel), Chapter4—Agglomeration. Liu, G.-y., Zhu, D.-q., Pan, J., Zhang, K.-c., Tian, F.-c., Hu, Y.-m., Liu, S.-l., 2005. Industrial tests on using modified bentonite to improve iron ore pelletizing. Sintering Pelletizing 30 (4), 13–16. Meyer, K., 1980. Pelletizing of Iron Ores. Springer Verlag, Berlin, ISBN: 3540102159, ISSN: 3514002460. Mourão, J.M., 2012. Guidelines for selecting pellet plant technology. In: 6th International Congress on the Science and Technology of Ironmaking-ICSTI, Rio de Janeiro, RJ, Brazil, October 14–18, 2012, pp. 2162–2175. Murr, D.L., Englund, D.J., 1988. Development and Production of Organic-Limestone Pellets. National Steel Pellet Co. and Hanna Research Center, Minnesota. Narciso, J.J., 2013. A compilation of iron ore pellet production, volumes 2010–2012, Primarily from Public Domain Data. In: 3rd Symposium on Iron Ore Pelletizating, Quebec City, Canada, 30 September, 2013. Oja, K., 2013. Straight grate vs grate kiln. In: 3rd Symposium on Iron Ore Pelletizing. Quebec, Canada. 29 September–2 October, 2013. Pan, J., Zhu, D.Q., Xiong, S.A., Mendes, V., 2008. Improving the pelletization of refractory hematite by high pressure grinding rolls. In: Duo, W.D., Yao, S.C., Hang, W.F., Cheng, Z.L., Long, H. (Eds.), Proceedings of XXIV International Mineral Processing Congress, Beijing, China, pp. 2857– 2865. Penttinen, M., 2013. Optimizing iron ore pelletization with the use of custom-formulated binder compositions. In: 3rd Symposium on Iron Ore Pelletizing. Quebec, Canada. 29 September–2 October, 2013. Poveromo, J.J., 2014. Future trends in Ironmaking, prepared for McMaster blast furnace ironmaking course, May 11–16, 2014. Qiu, G.-z., Jiang, T., Li, H.-x., Wang, D.-z., 2003a. Functions and molecular structure of organic binders for iron ore pelletization. Colloids Surf. A Physicochem. Eng. Asp. 224, 11–22. Qiu, G.-z., Jiang, T., Huang, Z.-c., Zhu, D.-q., 2003b. Characterization of preparing cold bonded pellets for direct reduction using an organic binder. ISIJ Int. 43 (1), 20–25. Thomas, S., Collin, B., 2013. Recent technological advancements in high capacity pellet plants. In: 3rd Symposium on Iron Ore Pelletizing, Quebec, Canada, 29 September–2 October, 2013. Wang, C.-a., Xiong, S.-a., Zhu, D.-q., 2002. Effect of high pressure roller mill pretreating concentrates on green ball properties. Sintering Pelletizing 27, 12–15. Wang, C.-a., Wang, X.-j., Hu, C.-f., Huo, L.-c., 2005. Study of the activation mechanisms about pretreating magnetite concentrate by high pressure grinding. Sintering Pelletizing 30, 16–18. Zhang, H.-q., Qi, Y.-g., 2005. The application on improving the quality of iron ore pellets by roller press. Min. Eng. 3, 37–39. Zhu, D.-g., Wang, Z.-y., Pan, J., Li, J., Xu, X.-f., 2007. Improvement of sintering behaviors of Brazilian specularite concentrate by damp milling. Iron Steel 42, 12–16. Zhu, D.-Q., Li, H.-M., Yu, W., Wang, B., Pan, J., 2009. An organic activated bentonite mechanism for improving pelletization. J. Chongqing Univ. (Nat. Sci. Ed.), 32 (5), 582–588. Zhu, D.-g., Yu, W., Chun, T.-j., Pan, J., 2011b. Improving the pelletization of fluxed hematite pellets by hydrated lime. In: 2011TMS. San Diego, USA, 27 February–3 March 2011. Zhu, D.-q., Xiong, S.-a., Pan, J., Zhou, X.-l., 2011c. Improving pelletization of magnetite concentrate by organic complex bentonite and its industrial application. J. Cent. South Univ. 42 (2), 279–286.